CN105925178A - Water-based organic and inorganic hybrid anticorrosive paint composition and preparing method thereof - Google Patents
Water-based organic and inorganic hybrid anticorrosive paint composition and preparing method thereof Download PDFInfo
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- CN105925178A CN105925178A CN201610319173.9A CN201610319173A CN105925178A CN 105925178 A CN105925178 A CN 105925178A CN 201610319173 A CN201610319173 A CN 201610319173A CN 105925178 A CN105925178 A CN 105925178A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a water-based organic and inorganic hybrid anticorrosive paint composition. The composite is prepared from, by mass, 20-30% of methylsiloxane, 30-49% of water-based emulsion, 8-11% of film forming auxiliary, 5-8% of filler, 4-9% of anti-corrosion pigment, 2-6% of anti-flash-rust auxiliary, 3-4% of coupling agent, 7-9% of titaniferous organic matter and 2-3% of auxiliary. The organic and inorganic hybrid method is adopted to prepare a novel coating which has high adhesive force of an organic coating and high temperature resistance of an inorganic coating, cross-linking density of the coating is improved by adding the coupling agent and titaniferous organic matter to the water-based emulsion, contact between water molecules and oxygen and a base material is effectively prevented, and an excellent anti-corrosion effect is realized by the adoption of the traditional anti-corrosion pigment; furthermore, preparing process is simple, raw materials are easy to obtain, and production cost is reduced greatly.
Description
Technical field
The invention belongs to chemical anticorrosion technical field of coatings, be specifically related to a kind of aqueous organic inorganic hybridization anticorrosive paint composition and
Preparation method.
Background technology
Currently, environmental pollution is increasingly severe, and China has formulated series of measures to reduce the discharge of pollutant, currently uses
Containing substantial amounts of organic solvent in coating, it is widely used and environment is caused huge pressure, have impact on the body of workmen simultaneously
Body is healthy.Along with the enhancing of people's environmental consciousness, meanwhile, the environmental law Laws & Regulations increasingly stringent in the world, solvent based coating
Use be limited by very large, it is therefore desirable to solve anticorrosive paint solvent contamination problem.In many Environment-friendlyanti-corrosive anti-corrosive paint
In, water paint is the important directions solving environmental issue.But, Environmental Protective Water-paint decay resistance relatively solvent-based coating phase
Difference is very big, and improving water-based anticorrosive paint is important problem.
The feature of water paint maximum replaces organic solvent with water exactly, greatly reduces the discharge of pollutant, thus reduces ring
Border pressure and the harm to workmen, secondly water resource is enriched, and replaces organic solvent with water, takes conveniently, cheap.
But although water-based anticorrosive paint kind present on current market is a lot, can not reach organic solvent antiseptical ability, it is impossible to
Protect base material well, bring unnecessary loss to the industry of China, although some anticorrosion with coat performance is fine, but because it is made
Standby process is complicated, expensive, construction inconvenience, and application is restricted.
Inorganic coating has that heat-resistant stability is good, resistance to oxidation, cryogenic property compression ratio good, bigger, low-surface-energy, Jie put intensity
Advantages of higher, but its bad mechanical property, adhesive force, wearability, poor solvent resistance, cost is high.Organic coating has excellent machine
Tool performance, adhesive property, heat-resist, solvent resistance good, easy machine-shaping, cheap, but its bond energy is little, internal stress
Greatly, easily decompose under high temperature.
In water-based anticorrosive paint technology, there are at present some problems, relatively common such as: coating occurs dodging rust, makes coating mistake
Early lose protective capability；Resistance to elevated temperatures is poor, it is impossible to meets the too high environment of some temperature and uses；Between coating and base material
Adhesive force is inadequate, causes coming off of coating, thus loses antiseptic power.
Provided herein is a kind of aqueous organic inorganic hybridization anticorrosive paint composition and preparation method, be combined with organic coating, inorganic coating
Common advantage.Its preparation process is simple, raw material is easy to get, cheap, convenient construction, simultaneously its anti-sudden strain of a muscle rust ability, anticorrosion
Erosion ability, heatproof, acidproof, alkaline-resisting, solvent resistance is excellent, efficiently solves the deficiency in current technology.
Summary of the invention:
In order to solve the problem and shortage that prior art exists, the invention provides a kind of aqueous organic inorganic hybridization anticorrosive paint group
Compound and preparation method, compositions can salt spray resistance 1000h, resistance to elevated temperatures is excellent, adhesive force is up to 1 grade.The mesh of the present invention
One of be to improve antiseptic property, another purpose is to control the sudden strain of a muscle that formed in metal surface of water to become rusty.
For reaching above-mentioned target, the technical solution used in the present invention is:
A kind of aqueous organic inorganic hybridization anticorrosive paint composition, is 20～30% by methylsiloxane by mass percentage, aqueous
Emulsion is 30～49%, and coalescents is 8～11%, and filler is 5～8%, and corrosion-inhibitive pigments is 4～9%, anti-sudden strain of a muscle rust auxiliary agent
Being 2～6%, coupling agent is 3～4%, and titaniferous Organic substance is 7～9%, auxiliary agent be 2～3% composition；Wherein said methyl silicon
The molecular characterization of oxygen alkane is:
Wherein R is alkyl, and carbon number is 1-18.
Water-based emulsion described above be alkyd emulsion, polyester emulsion, organic silicon emulsion, epoxy emulsion, epoxy novolac emulsion,
One in phenolic aldehyde emulsion, polyvinyl acetate emulsion, acrylic acid ester emulsion, styrene-butadiene emulsion, propyl benzene latex, polyacrylate emulsion
Or multiple any quality compares mixture.
Water-based emulsion described above is preferably the mixture of epoxy emulsion and organic silicon emulsion, and its mixing quality is than for epoxy emulsion:
Organic silicon emulsion=2:1.
Auxiliary agent described above is the one in dispersant, wetting agent, defoamer, lubricant, antiwear assistant, levelling agent or many
Plant any quality and compare mixture.
Auxiliary agent described above is preferably the mixture of dispersant, wetting agent, defoamer, lubricant, antiwear assistant, levelling agent,
Its mixing quality is than being=1:1:2:1:1:1.
Corrosion-inhibitive pigments described above be lead pigment, chromate pigment, zinc powder, non-toxic pigment, Muscovitum, ferrum oxide,
One in titanium white, iron oxide red, Cu-Zn alloy powder, white carbon black, aluminium powder, wherein non-toxic pigment is ion exchangeable pigment, phosphate, molybdenum
Hydrochlorate, borate, ferrite or graphene oxide.
Corrosion-inhibitive pigments described above is preferably the mixture of zinc phosphate, aluminum phosphate, graphene oxide, sodium molybdate, its mixing
Mass ratio is zinc phosphate: aluminum phosphate: graphene oxide: sodium molybdate=1:2:2:1.
Coupling agent described above is amino silicane coupling agent, and its molecular structural formula is:
Wherein R is alkyl, and carbon number is 1-10.
Though coupling agent described above uses amino silicane coupling agent, but is not limited to amino silicane coupling agent.
Titaniferous Organic substance described above, its molecular structural formula is:
Wherein R is alkyl, and carbon number is 1-10.
Coalescents described above is that any quality of one or more in alcohol, alcohol ester, alcohol ether compares mixture.
Coalescents described above is preferably the mixture of lauric acid ester and DAA, and its mixing quality is than for lauric acid
Ester: DAA=1:3.
Anti-sudden strain of a muscle rust auxiliary agent described above is the benzene ring compound containing nitro, and its molecular structural formula is:
Wherein R is H or C1-C10。
Filler described above is one or more matter in triple superphosphate, wollastonite in powder, Muscovitum, Pulvis Talci, Kaolin, dolomite
Amount is arbitrarily than mixture.
Filler described above is preferably Muscovitum.
For achieving the above object, of the present invention another solution is that
The preparation method of a kind of aqueous organic inorganic hybridization anticorrosive paint composition of the present invention, comprises the steps:
(1) component A is prepared: by mass percentage by the methylsiloxane in compositions, water-based emulsion, filler, corrosion-resistant
Pigment, anti-sudden strain of a muscle rust auxiliary agent, titaniferous Organic substance, auxiliary agent and coupling agent, be stirred, mix homogeneously, obtain the emulsion of component A,
Then room temperature preservation, standby；
(2) B component is prepared: weigh coalescents by mass percentage or prepare mixture in mass ratio, obtaining B component,
Room-temperature seal preserves.
A kind of using method of the aqueous organic inorganic hybridization anticorrosive paint of the present invention, step is:
During use, A, B component mix homogeneously are carried out application, put into solidification 1h at 25 DEG C of baking oven, then heat to 120 DEG C
Insulation 1h.
Compared with prior art, have the feature that and beneficial effect are mainly the present invention:
1, coupling agent and titaniferous organic compound are used, the effective crosslink density improving coating, thus exclusion of water molecule and oxygen
With contacting of base material
2, add the benzene ring compound containing nitro and dodge rust auxiliary agent as anti-, and combine with corrosion-inhibitive pigments, drastically increase water
The antiseptic property of property coating.
3, the aqueous solution using epoxy emulsion to mix with organic silicon emulsion, can improve the heat resistance of coating.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is expanded on further.Should be understood that these embodiments are merely to illustrate rather than limit
The scope of the present invention processed.In addition, it is to be understood that after having read the content that the present invention lectures, those skilled in the art can be to this
Invention makes various changes or modifications, and these equivalent form of values fall within the application depended on claims limited range equally.
Embodiment 1
One, the formula of compositions
1, water-based emulsion, coalescents, corrosion-inhibitive pigments, the mixture of auxiliary agent are prepared respectively according to mass ratio；
2, each constituent content of compositions formulated by mass percentage:
Two, preparation and application
1, preparation component A: by mass percentage by the methylsiloxane in compositions, water-based emulsion, filler, corrosion-resistant face
Material, anti-sudden strain of a muscle rust auxiliary agent, titaniferous Organic substance, auxiliary agent and coupling agent, be stirred, mix homogeneously, obtain the emulsion of component A,
Then room temperature preservation, standby；
2, preparation B component: weigh coalescents by mass percentage or prepare mixture in mass ratio, obtaining B component, room
Temperature seals and preserves.
When 3, using, A, B component mix homogeneously are carried out application, put into solidification 1h at 25 DEG C of baking oven, then heat to 120 DEG C
Insulation 1h.
Three, beneficial effect
The present embodiment resulting composition is coated on cold-rolled steel sheet, and the experiment of coating salt spray resistance occurs corroding focus on a small quantity up to 500h,
Adhesive force 2 grades, coating heatproof is up to 300 DEG C.
Embodiment 2
One, the formula of compositions
1, water-based emulsion, coalescents, corrosion-inhibitive pigments, the mixture of auxiliary agent are prepared respectively according to mass ratio；
2, each constituent content of compositions formulated by mass percentage:
Two, preparation method
1, preparation component A: by mass percentage by the methylsiloxane in compositions, water-based emulsion, filler, corrosion-resistant face
Material, anti-sudden strain of a muscle rust auxiliary agent, titaniferous Organic substance, auxiliary agent and coupling agent, be stirred, mix homogeneously, obtain the emulsion of component A,
Then room temperature preservation, standby；
2, preparation B component: select lauric acid ester in mass ratio: DAA=1:3 prepares B component mixture, room
Temperature seals and preserves.
When 3, using, A, B component mix homogeneously are carried out application, put into solidification 1h at 25 DEG C of baking oven, then heat to 120 DEG C
Insulation 1h.
Three, beneficial effect
The present embodiment resulting composition is coated on cold-rolled steel sheet, and the experiment of coating salt spray resistance occurs corroding focus on a small quantity up to 600h,
Adhesion 1 grade, coating heatproof is up to 350 DEG C.
Embodiment 3
One, the formula of compositions
1, water-based emulsion, coalescents, corrosion-inhibitive pigments, the mixture of auxiliary agent are prepared respectively according to mass ratio；
2, each constituent content of compositions formulated by mass percentage:
Two, preparation method is with embodiment 2
Three, beneficial effect
The present embodiment resulting composition is coated on cold-rolled steel sheet, and the experiment of coating salt spray resistance occurs corroding focus on a small quantity up to 650h,
Adhesive force 2 grades, coating heatproof is up to 400 DEG C.
Embodiment 4
One, the formula of compositions
1, water-based emulsion, coalescents, corrosion-inhibitive pigments, the mixture of auxiliary agent are prepared respectively according to mass ratio；
2, each constituent content of compositions formulated by mass percentage:
Two, preparation method is with embodiment 2
Three, beneficial effect
The present embodiment resulting composition is coated on cold-rolled steel sheet, and the experiment of coating salt spray resistance occurs corroding focus on a small quantity up to 650h,
Adhesion 1 grade, coating heatproof is up to 350 DEG C.
Embodiment 5
One, the formula of compositions
1, water-based emulsion, coalescents, corrosion-inhibitive pigments, the mixture of auxiliary agent are prepared respectively according to mass ratio；
2, each constituent content of compositions formulated by mass percentage:
Two, preparation method is with embodiment 2
Three, beneficial effect
The present embodiment resulting composition is coated on cold-rolled steel sheet, and the experiment of coating salt spray resistance occurs corroding focus on a small quantity up to 850h,
Adhesion 1 grade, coating heatproof is up to 450 DEG C.
Embodiment 6
One, the formula of compositions
1, water-based emulsion, coalescents, corrosion-inhibitive pigments, the mixture of auxiliary agent are prepared respectively according to mass ratio；
2, each constituent content of compositions formulated by mass percentage:
Two, preparation method is with embodiment 2
Three, beneficial effect
The present embodiment resulting composition is coated on cold-rolled steel sheet, and the experiment of coating salt spray resistance occurs corroding focus on a small quantity up to 1000h,
Adhesion 1 grade, coating heatproof is up to 550 DEG C.
Embodiment 7
One, the formula of compositions
1, water-based emulsion, coalescents, corrosion-inhibitive pigments, the mixture of auxiliary agent are prepared respectively according to mass ratio；
2, each constituent content of compositions formulated by mass percentage:
Two, preparation method is with embodiment 2
Three, beneficial effect
The present embodiment resulting composition is coated on cold-rolled steel sheet, and the experiment of coating salt spray resistance occurs corroding focus on a small quantity up to 900h,
Adhesion 1 grade, coating heatproof is up to 500 DEG C.
Embodiment 8
One, the formula of compositions
1, water-based emulsion, coalescents, corrosion-inhibitive pigments, the mixture of auxiliary agent are prepared respectively according to mass ratio；
2, each constituent content of compositions formulated by mass percentage:
Two, preparation method is with embodiment 2
Three, beneficial effect
The present embodiment resulting composition is coated on cold-rolled steel sheet, and the experiment of coating salt spray resistance occurs corroding focus on a small quantity up to 800h,
Adhesion 1 grade, coating heatproof is up to 500 DEG C.
The above is only the preferred embodiment of the present invention, it should be pointed out that: to those of ordinary skill in the art,
Without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should be regarded as the present invention
Protection domain.
Claims (10)
1. an aqueous organic inorganic hybridization anticorrosive paint composition, it is characterised in that: by mass percentage by methylsiloxane
Being 20～30%, water-based emulsion is 30～49%, and coalescents is 8～11%, and filler is 5～8%, corrosion-inhibitive pigments be 4～
9%, anti-dodge rust auxiliary agent be 2～6%, coupling agent is 3～4%, and titaniferous Organic substance is 7～9%, auxiliary agent be 2～3% composition；
The molecular characterization of wherein said methylsiloxane is:
Wherein R is alkyl, and carbon number is 1-18.
A kind of aqueous organic inorganic hybridization anticorrosive paint composition the most according to claim 1, it is characterised in that: described
Water-based emulsion is alkyd emulsion, polyester emulsion, organic silicon emulsion, epoxy emulsion, epoxy novolac emulsion, phenolic aldehyde emulsion, poly-second
One or more any quality in alkene acetic acid emulsion, acrylic acid ester emulsion, styrene-butadiene emulsion, propyl benzene latex, polyacrylate emulsion
Compare mixture.
A kind of aqueous organic inorganic hybridization anticorrosive paint composition the most according to claim 1, it is characterised in that: described
Auxiliary agent is that any mass ratio of one or more in dispersant, wetting agent, defoamer, lubricant, antiwear assistant, levelling agent mixes
Compound.
A kind of aqueous organic inorganic hybridization anticorrosive paint composition the most according to claim 1, it is characterised in that: described
Corrosion-inhibitive pigments is lead pigment, chromate pigment, zinc powder, non-toxic pigment, Muscovitum, ferrum oxide, titanium white, iron oxide red, copper
One in bronze, white carbon black, aluminium powder.
A kind of aqueous hybrid inorganic-organic anticorrosive paint composition the most according to claim 1, it is characterised in that: described
Coupling agent be amino silicane coupling agent, its molecular structural formula is:
Wherein R is alkyl, and carbon number is 1-10.
A kind of aqueous organic inorganic hybridization anticorrosive paint composition the most according to claim 1, it is characterised in that: described
Titaniferous Organic substance, its molecular structural formula is:
Wherein R is alkyl, and carbon number is 1-10.
A kind of aqueous organic inorganic hybridization anticorrosive paint composition the most according to claim 1, it is characterised in that: described
Coalescents is that any quality of one or more in alcohol, alcohol ester, alcohol ether compares mixture.
A kind of aqueous organic inorganic hybridization anticorrosive paint composition the most according to claim 1, it is characterised in that: described
The anti-rust auxiliary agent that dodges is the benzene ring compound containing nitro, and its molecular structural formula is:
Wherein R is H or C1-C10。
A kind of aqueous organic inorganic hybridization anticorrosive paint composition the most according to claim 1, it is characterised in that: described
Filler is that any mass ratio of one or more in triple superphosphate, wollastonite in powder, Muscovitum, Pulvis Talci, Kaolin, dolomite mixes
Compound.
10. a preparation method for aqueous organic inorganic hybridization anticorrosive paint composition according to claim 1, its feature
It is to comprise the steps:
(1) component A is prepared: by mass percentage by the methylsiloxane in compositions, water-based emulsion, filler, corrosion-resistant
Pigment, anti-sudden strain of a muscle rust auxiliary agent, titaniferous Organic substance, auxiliary agent and coupling agent, be stirred, mix homogeneously, obtain the emulsion of component A,
Then room temperature preservation, standby；
(2) B component is prepared: weigh coalescents by mass percentage or prepare mixture in mass ratio, obtaining B component,
Room-temperature seal preserves；
(3) when using, A, B component mix homogeneously are carried out application, put into solidification 1h at 25 DEG C of baking oven, then heat to
120 DEG C of insulation 1h.
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