CN107187153B - The PP synthetic papers and its special-purpose ink that a kind of open air uses - Google Patents

The PP synthetic papers and its special-purpose ink that a kind of open air uses Download PDF

Info

Publication number
CN107187153B
CN107187153B CN201710388267.6A CN201710388267A CN107187153B CN 107187153 B CN107187153 B CN 107187153B CN 201710388267 A CN201710388267 A CN 201710388267A CN 107187153 B CN107187153 B CN 107187153B
Authority
CN
China
Prior art keywords
parts
weight
green
raw material
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710388267.6A
Other languages
Chinese (zh)
Other versions
CN107187153A (en
Inventor
叶骏强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201710388267.6A priority Critical patent/CN107187153B/en
Publication of CN107187153A publication Critical patent/CN107187153A/en
Application granted granted Critical
Publication of CN107187153B publication Critical patent/CN107187153B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/104—Oxysalt, e.g. carbonate, sulfate, phosphate or nitrate particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The PP synthetic papers and its special-purpose ink that a kind of open air uses, the PP synthetic papers are five-layer co-squeezing synthetic paper, from top to bottom respectively ink-absorbed coated layer, substrate layer, sandwich layer, sub- substrate layer and layer；The preparing raw material of the ink-absorbed coated layer in parts by weight, comprising：90~95 parts of acrylic resin, 1~3 part of hyperbranched poly propylene, 5~7 parts of quaternary ammonium salt-modified meso-porous nano material, 0.3~0.5 part of 1 hydroxycyclohexylphenylketone；The preparing raw material of the substrate layer in parts by weight, comprising：The isotactic polypropylene of 90~95 parts by weight, the syndiotactic polypropylene of 3~5 parts by weight, the random polypropylene of 0.5~1 parts by weight, the hyperbranched poly propylene of 1 parts by weight；The preparing raw material of the sandwich layer in parts by weight, comprising：90 parts of hyperbranched poly propylene.

Description

The PP synthetic papers and its special-purpose ink that a kind of open air uses
Technical field
The present invention relates to PP synthetic papers field, and in particular to the PP synthetic papers and its special-purpose ink that a kind of open air uses.
Technical background
In recent years, proportion of the digital publishing in information-intensive society is increasing, from most basic digital book, digital sound Picture, to numerical map, digital library.Digital publishing one develops towards diversified forms, while again to individualized development, it is existing extensive Property, there is independence again.Digital publishing have it is quick, it is convenient, the advantages of not available for the traditional publication mode such as personalized service, It is currently under the Fast Growth stage.At the same time, reader is more and more stronger to personalization reading, personalized service demand, and Traditional culture service of publishing far can not but meet this demand.Thus, using the network facilities such as broadband, wireless, make individual character The digital culture publication content of change is implanted in each digital home, by as the new model of future society cultural spreading.
With the fast development of electronic information technology, the technology of digital product has obtained continuous breakthrough, traditional printing Electronic digital air brushing technology is more and more used with printing and making.Because air brushing technology has, writing speed is fast, it is colored to be easy to Change, using it is convenient and pollution-free the features such as, while PP synthetic papers are a kind of degradable environment-friendly paper so that inkjet printing is prevented The application of water uvioresistant PP synthetic papers is more and more common.But the normal inkjet printing waterproof PP synthetic papers produced in the market The drawbacks of more be present, some inkjet printing waterproof PP synthetic papers in use because its coating surface porosity is relatively low, So that ink falls when on coating from printer nozzle, it is impossible to which rapid draing, ink absorb and horizontal proliferation because having little time, usually Mixed color phenomenon, strong influence printing effect occurs；Some inkjet printing waterproof PP synthetic paper fixing properties are poor, preserving Easily there is mutually oozing for different colours in period, causes image to be blurred；Some inkjet printing waterproof PP synthetic papers do not possess absorption Ultraviolet function, after exposing out of doors for a long time, there is more serious color error ratio in image.
For the above situation, the present invention provides a kind of PP synthetic papers and its special-purpose ink that outdoor can be used.
The content of the invention
The present invention provides the PP synthetic papers and its special-purpose ink that a kind of open air uses, and the PP synthetic papers close for five-layer co-squeezing Into paper, from top to bottom respectively ink-absorbed coated layer, substrate layer, sandwich layer, sub- substrate layer and layer；
The preparing raw material of the ink-absorbed coated layer in parts by weight, comprising：90~95 parts of acrylic resin, 1~3 part Hyperbranched poly propylene, 5~7 parts of quaternary ammonium salt-modified meso-porous nano material, 0.3~0.5 part of 1- hydroxy-cyclohexyl phenyl ketones；
The preparing raw material of the substrate layer in parts by weight, comprising：The isotactic polypropylene of 90~95 parts by weight, 3~5 weights Measure the syndiotactic polypropylene of part, the random polypropylene of 0.5~1 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the sandwich layer in parts by weight, comprising：90 parts of hyperbranched poly propylene；
The preparing raw material of the sub- substrate layer in parts by weight, comprising：The isotactic polypropylene of 90~95 parts by weight, 3~5 The syndiotactic polypropylene of parts by weight, the random polypropylene of 0.5~1 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the layer in parts by weight, comprising：The acrylic resin of 85~95 parts by weight, 1~3 weight Measure the hyperbranched poly propylene, the talcum powder of 1~4 parts by weight of part.
As one embodiment of the present invention, the preparing raw material of the special-purpose ink in parts by weight, comprising：3 weights Measure the melon ring modification acrylate of part, the aqueous polyurethane of 30 parts by weight, the pigment of 4 parts by weight, the 2- (methyl-props of 3 parts by weight Olefin(e) acid) ethyl ester 3,5- diaminobenzoic acids, the auxiliary agent of 8 parts by weight, the water of 80 parts by weight.
As one embodiment of the present invention, the preparing raw material of the ink-absorbed coated layer in parts by weight, comprising：90 parts Polyacrylic resin, 1 part of hyperbranched poly propylene, 5 parts of quaternary ammonium salt-modified meso-porous nano material, 0.3 part of 1- hydroxyl rings Base phenyl ketone；
The preparing raw material of the substrate layer in parts by weight, comprising：The isotactic polypropylene of 93 parts by weight, 4 parts by weight Syndiotactic polypropylene, the random polypropylene of 0.7 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the sandwich layer in parts by weight, comprising：90 parts of hyperbranched poly propylene；
The preparing raw material of the sub- substrate layer in parts by weight, comprising：The isotactic polypropylene of 93 parts by weight, 4 parts by weight Syndiotactic polypropylene, random polypropylene, the hyperbranched poly propylene of 1 parts by weight of 0.7 parts by weight；
The preparing raw material of the layer in parts by weight, comprising：The polyacrylic resin of 90 parts by weight, 1 parts by weight Hyperbranched poly propylene, the talcum powder of 2 parts by weight.
As one embodiment of the present invention, the hyperbranched polyacrylic preparation method：Third is inputted in a kettle Alkene, the alkyl aluminum and catalyst for being dissolved in toluene are added, the pressure for lifting propylene is 0.1~2.0MPa, and it is 65 DEG C to control temperature, instead It is 30 minutes between seasonable；Reaction terminate after toward oxygen is passed through in reaction mixture, the reaction time is 2 hours；Finally use acidic ethanol Reduce and precipitate, filtration washing, obtain hyperbranched poly propylene.
As one embodiment of the present invention, the preparation method of the quaternary ammonium salt-modified meso-porous nano material：
1) by N, N, N', N'- tetra- (2- hydroxypropyls) ethylenediamine, 2- (2- chloroethyls) malononitrile and ethyl acetate mixture Add in the four-hole boiling flask equipped with stirring and condensing unit, in temperature 50 C, under the conditions of pressure is 0.9Mpa, uniform stirring 12 is small When, cooling is stood, and product 1 is made；
2) it is 6 according to mol ratio by product 1 and 1,5- diisocyanate pentanes：1 and account for reactant gross mass 1% to first Benzene sulfonic acid is added in the four-hole boiling flask, at 1100 DEG C of temperature and 20Mpa pressure, uniform stirring 5 hours, in 100 DEG C of temperature Under degree, removing solvent is vacuumized, quaternary ammonium salt is made；
3) by meso-porous nano silica and Silane coupling agent KH550 according to mol ratio 3：1 mixes in ethanol solution Stirring, reacts 4 hours at 60 DEG C, then adds quaternary ammonium salt, continues reaction 2 hours, obtains quaternary ammonium salt-modified meso-porous nano material Material.
As one embodiment of the present invention, the preparation method of the melon ring modification acrylate：Add into reactor Enter melon ring, ammonium persulfate, deionized water, stir, be passed through nitrogen, be warming up to 80 DEG C, react 2-3h, acrylate is slowly added dropwise, After being added dropwise, 80 DEG C of insulation reaction 8-10h, stop reaction, be cooled to room temperature, add acetone, stir, filtering, 40 DEG C of decompressions 48h is dried, obtains melon ring modification acrylate, grinds, is sealed.
As one embodiment of the present invention, the preparation method of the aqueous polyurethane is：(1) it is 2,4- toluene two is different Cyanate and PPG are dissolved separately in dimethyl sulfoxide solvent, obtain isocyanate solution and polyhydric alcohol solutions；Its In, the mol ratio of isocyanate group and hydroxyl is 3：2；
(2) at 90 DEG C, under nitrogen protection atmosphere, side stirring, isocyanate solution is added in alcoholic solution, isocyanates is molten After the completion of liquid adds, reaction system insulation reaction 12h；Then protective agent caprolactam is added into reaction system, at 100 DEG C Continue to react 10h；
(3) after reaction terminates, after being evaporated under reduced pressure out solvent, gained material is dissolved through tetrahydrofuran, settled in methyl alcohol After filtering, by it in 120 DEG C of vacuum drying 12h, aqueous polyurethane is obtained.
As one embodiment of the present invention, the color of the pigment is selected from pale purple, purple, deep barba hispanica, deep phthalein is blue, middle iron Blue, sea blue, the light barba hispanica of blue, middle phthalein, light phthalein are blue, bluish grey, day phthalein indigo plant, day barba hispanica, peacock blue, dark-grey, middle grey, light grey, silver grey, extra large Ash, lightskyblue, it is pale blue, young it is blue, sapphire blue, vivid blue, light it is sea blue, in it is sea blue, deep-sea is blue, Jing Lan, gorgeous blue, middle ashy green, lake are green, precious It is green, bud green, fresh water lake is green, apple green, pale green, bright green, in green, dark green, olive green, eggshell be green, light apple green, deep pea green, aircraft It is grey, pea green, olive is grey, grass green, breen, military vehicle is green, cardamom is green, light green, ice is grey, lathe is grey, beautiful ash, ostrich ash, pearl, cream, Yellow, yellowish, middle yellow, the deep yellow, iron oxide yellow of ivory, lemon, army are yellow, milky white, cream-coloured, yellowish grey, light brown, reddish brown yellow, purple brown, orange, brown, brown One kind in Huang, iron oxide red, bright red, bright red, purplish red, Exocarpium Citri Rubrum, pink, rose pink, rose-red, light rose-red.
As one embodiment of the present invention, the auxiliary agent in defoamer, wetting dispersing agent and thickener one Kind is a variety of.
As one embodiment of the present invention, the melon ring is cucurbit [6] urea.
Embodiment
Participate in the election of the detailed description of the invention below for being preferable to carry out method and including embodiment this hair can be more easily understood Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with art of the present invention The identical implication that technical staff is generally understood that.When contradiction be present, the definition in this specification is defined.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ", " having ", " containing " or its any other deformation, it is intended that cover including for non-exclusionism.For example, the combination comprising listed elements Thing, step, method, product or device are not necessarily limited to those key elements, but can include not expressly listed other key elements or Such a composition, step, method, product or the intrinsic key element of device.
Conjunction " Consists of " excludes any key element do not pointed out, step or component.If be used in claim, this Phrase will make claim be closed, it is not included the material in addition to the material of those descriptions, but relative normal Except rule impurity.When being rather than immediately following in the clause that phrase " Consists of " appears in claim main body after theme, It is only limited to the key element described in the clause；Other key elements are not excluded outside the claim as entirety.
Equivalent, concentration or other values or parameter are excellent with scope, preferred scope or a series of upper limit preferred values and lower limit During the Range Representation that choosing value limits, this, which is appreciated that, specifically discloses by any range limit or preferred value and any scope All scopes that any pairing of lower limit or preferred value is formed, regardless of whether the scope separately discloses.For example, when open During scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc..When number range is described herein, unless otherwise indicated, otherwise the scope is intended to include its end Value and all integers and fraction within the range.
Singulative includes plural number and object is discussed, unless the context clearly dictates otherwise." optional " or it is " any It is a kind of " refer to that the item that describes thereafter or event may or may not occur, and the description include situation that event occurs and The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, and it is specific to represent that the present invention is not limited to this Quantity, include the part of the amendment of the acceptable change without cause related basic function close to the quantity.Phase Answer, modify a numerical value with " about ", " about " etc., mean that the invention is not restricted to the exact numerical.It is approximate in some examples Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, scope limits can be with Combine and/or exchange, these scopes include all subranges contained therebetween if not stated otherwise.
In addition, indefinite article " one kind " before key element of the present invention or component and "one" to key element or the quantitative requirement of component (i.e. occurrence number) unrestriction.Therefore "one" or " one kind " should be read as including one or at least one, and odd number The key element or component of form also include plural form, unless the obvious purport of the quantity refers to singulative.
" polymer " means by the polymerizable compound prepared by the monomer that polymerize identical or different type.Generic term " polymer " includes term " homopolymer ", " copolymer ", " terpolymer " and " EVA ".
The present invention provides the PP synthetic papers and its special-purpose ink that a kind of open air uses, and the PP synthetic papers close for five-layer co-squeezing Into paper, from top to bottom respectively ink-absorbed coated layer, substrate layer, sandwich layer, sub- substrate layer and layer；
The preparing raw material of the ink-absorbed coated layer in parts by weight, comprising：90~95 parts of acrylic resin, 1~3 part Hyperbranched poly propylene, 5~7 parts of quaternary ammonium salt-modified meso-porous nano material, 0.3~0.5 part of 1- hydroxy-cyclohexyl phenyl ketones；
The preparing raw material of the substrate layer in parts by weight, comprising：The isotactic polypropylene of 90~95 parts by weight, 3~5 weights Measure the syndiotactic polypropylene of part, the random polypropylene of 0.5~1 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the sandwich layer in parts by weight, comprising：90 parts of hyperbranched poly propylene；
The preparing raw material of the sub- substrate layer in parts by weight, comprising：The isotactic polypropylene of 90~95 parts by weight, 3~5 The syndiotactic polypropylene of parts by weight, the random polypropylene of 0.5~1 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the layer in parts by weight, comprising：The acrylic resin of 85~95 parts by weight, 1~3 weight Measure the hyperbranched poly propylene, the talcum powder of 1~4 parts by weight of part.
Acrylic resin：Heretofore described acrylic resin purchase is produced from brilliant same moral Chemical Co., Ltd. of Foshan City Product model AC-1023.
Hyperbranched poly propylene：Heretofore described hyperbranched polyacrylic preparation method is as follows：Third is inputted in a kettle Alkene, the alkyl aluminum and catalyst for being dissolved in toluene are added, the pressure for lifting propylene is 0.1~2.0MPa, and diethyl zinc is chain tra nsfer Agent, it is 65 DEG C to control temperature, and the reaction time is 30 minutes；Reaction terminate after toward being passed through oxygen, reaction time 2 in reaction mixture Hour；Finally reduced and precipitated with acidic ethanol, filtration washing, obtain hyperbranched poly propylene.
Wherein, the alkyl aluminum is aluminium diethyl monochloride, and the catalyst is ethylidene acenaphthene (alpha-diimine) Raney nickel, In polymerization system, the concentration of ethylidene acenaphthene (alpha-diimine) Raney nickel is 5~100 μm of ol/L, the aluminium in alkyl aluminum with it is sub- The mol ratio of nickel in ethyl acenaphthene (alpha-diimine) nickel complex is 20~800, and (α-two is sub- with ethylidene acenaphthene for zinc in diethyl zinc Amine) mol ratio of nickel in nickel complex is 50~300.
Quaternary ammonium salt-modified meso-porous nano material：The preparation method of heretofore described quaternary ammonium salt-modified meso-porous nano material is such as Under：
1) by N, N, N', N'- tetra- (2- hydroxypropyls) ethylenediamine, 2- (2- chloroethyls) malononitrile and ethyl acetate mixture Add in the four-hole boiling flask equipped with stirring and condensing unit, in temperature 50 C, under the conditions of pressure is 0.9Mpa, uniform stirring 12 is small When, cooling is stood, and product 1 is made；
2) it is 6 according to mol ratio by product 1 and 1,5- diisocyanate pentanes：1 and account for reactant gross mass 1% to first Benzene sulfonic acid is added in the four-hole boiling flask, at 100 DEG C of temperature and 20Mpa pressure, uniform stirring 5 hours, in 100 DEG C of temperature Under, removing solvent is vacuumized, quaternary ammonium salt is made；
3) by meso-porous nano silica and Silane coupling agent KH550 according to mol ratio 3：1 mixes in ethanol solution Stirring, reacts 4 hours at 60 DEG C, then adds quaternary ammonium salt, continues reaction 2 hours, obtains quaternary ammonium salt-modified meso-porous nano material Material.
Wherein, N in step 1), N, N', N'- tetra- (2- hydroxypropyls) ethylenediamine, 2- (2- chloroethyls) malononitrile and acetic acid The mol ratio of ethyl ester is 1：2：20.
The weight part ratio of step 3) intermediary hole nano silicon and quaternary ammonium salt is 1：1.
Heretofore described meso-porous nano silica is bought from Shanghai traditional Chinese medicines Co., Ltd.
1- hydroxycyclohexylphenylketones：Heretofore described 1- hydroxycyclohexylphenylketones purchase tries from sigma chemistry Agent.
Isotactic polypropylene：Heretofore described isotactic polypropylene is bought from Sigma's chemical reagent.
Syndiotactic polypropylene：Heretofore described syndiotactic polypropylene is bought from Suzhou Yu Chenlong engineering plastics Co., Ltd, board Number：2300NC.
Random polypropylene：Heretofore described random polypropylene purchase plastifies Co., Ltd, the trade mark from Suzhou Fu Lixuan： RJ700。
Talcum powder：Heretofore described talcum powder is bought from Ou Senna Chemical Co., Ltd.s of Jiangyin City.
The PP synthetic papers and its special-purpose ink that a kind of open air uses, the preparing raw material of the special-purpose ink is according to parts by weight Meter, comprising：The melon ring modification acrylate of 3 parts by weight, the aqueous polyurethane of 30 parts by weight, the pigment of 4 parts by weight, 3 parts by weight 2- (methacrylic acid) ethyl ester 3,5- diaminobenzoic acids, the auxiliary agent of 8 parts by weight, the water of 80 parts by weight.
Melon ring modification acrylate：The preparation method of the melon ring modification acrylate：Melon ring, mistake are added into reactor Ammonium sulfate, deionized water, stirring, are passed through nitrogen, are warming up to 80 DEG C, react 2-3h, acrylate is slowly added dropwise, is added dropwise Afterwards, 80 DEG C of insulation reaction 8-10h, stopping reaction, be cooled to room temperature, add acetone, stir, filtering, 40 DEG C are dried under reduced pressure 48h, Melon ring modification acrylate is obtained, grinds, is sealed.
As one embodiment of the present invention, the melon ring and the ammonium persulfate, the mol ratio of the acrylate For 1：5：25；The melon ring and the weight ratio of the deionized water, the acetone are 1：15：12.
As one embodiment of the present invention, the melon ring is cucurbit [6] urea.
Aqueous polyurethane：The preparation method of the aqueous polyurethane is：
(1) 2,4- toluene di-isocyanate(TDI)s and PPG are dissolved separately in dimethyl sulfoxide solvent, obtained different Cyanic acid ester solution and polyhydric alcohol solutions；Wherein, the mol ratio of isocyanate group and hydroxyl is 3：2；
(2) at 90 DEG C, under nitrogen protection atmosphere, side stirring, isocyanate solution is added in polyhydric alcohol solutions, isocyanic acid After the completion of ester solution adds, reaction system insulation reaction 12h；Then protective agent caprolactam is added into reaction system, 100 Continue to react 10h at DEG C；
(3) after reaction terminates, after being evaporated under reduced pressure out solvent, gained material is dissolved through tetrahydrofuran, settled in methyl alcohol After filtering, by it in 120 DEG C of vacuum drying 12h, aqueous polyurethane is obtained.
Pigment：The color of the pigment is selected from pale purple, purple, deep barba hispanica, deep phthalein is blue, middle barba hispanica, blue, sea blue, the light iron of middle phthalein Blue, light phthalein is blue, bluish grey, day phthalein indigo plant, day barba hispanica, peacock blue, dark-grey, middle grey, light grey, silver grey, extra large ash, lightskyblue, pale blue, young It is blue, sapphire blue, vivid blue, light it is sea blue, in it is sea blue, deep-sea is blue, Jing Lan, gorgeous blue, middle ashy green, lake is green, treasured is green, bud green, fresh water lake is green, apple Light green, pale green, bright green, in green, dark green, olive green, eggshell it is green, it is light it is apple green, depth is pea green, aircraft is grey, pea green, olive is grey, careless Green, breen, military vehicle are green, cardamom is green, light green, ice is grey, lathe is grey, beautiful ash, ostrich ash, pearl, cream, ivory, lemon are yellow, it is yellowish, in Yellow, deep yellow, iron oxide yellow, army be yellow, milky white, cream-coloured, yellowish grey, light brown, reddish brown yellow, purple brown, orange, brown, pale brown, iron oxide red, bright red, big One kind in red, purplish red, Exocarpium Citri Rubrum, pink, rose pink, rose-red, light rose-red, black.
Pigment is the medium such as material, its not soluble in water, oily and solvent of some whites or colored fine-powder state, But it can be evenly dispersed therein.Pigment can assign film various properties, such as：Covering power, mechanical property, endurance quality, The performance such as anti-corrosion and antirust.Pigment variety is various, there is a variety of sorting techniques, can be divided into natural pigment and synthesis face by its source Material；Inorganic pigment and organic pigment can be according to chemical composition divided into；It can divide again by its effect in coating and covering with paint work progress For coloring pigment, extender pigment, rust resisting pigment etc..
Red pigment includes but is not limited to vermilion, cadmium red, chrome vermillion, toluidine red, lithol red, contraposition in coloring pigment It is red；Yellow uitramarine includes but is not limited to lead chromate yellow, cadmium yellow, merimee's yellow, everbright fast yellow, benzidine yellow；Blue pigment includes but is not limited to It is barba hispanica, ultramarine, phthalocyanine blue, peacock blue；Chinese white includes but is not limited to zinc oxide, lithopone (lithopone), titanium white；Black face Material includes but is not limited to carbon black, pine soot, graphite, nigrosine；Viridine green includes but is not limited to that chrome green, zinc green, iron is green, phthalocyanine It is green；Violet pigment includes but is not limited to ultramarine violet, cobalt violet, manganese violet, crystal violet, benzyl violet；Iron oxide pigment includes but is not limited to Reddle, umber, loess, iron oxide red, iron oxide yellow, iron oxide black, iron oxide brown；Metallic pigments include but is not limited to aluminium powder (silver powder), copper powder (bronze).
Extender pigment includes alkali salt, silicate, magnalium light metal compound.Alkali salt includes but is not limited to Blanc fixe (blanc fixe), calcium carbonate (chalk powder, old powder, chalk), calcium sulfate (gypsum)；Silicate includes but is not limited to Talcum powder (magnesium silicate), magnetic native (kaolin, main component are alumina silicate), silica flour, mica powder, flake asbestos, diatomite；Magnalium Light metal compound includes but is not limited to magnesium carbonate, magnesia, aluminium hydroxide.
Rust resisting pigment includes physical rust resisting pigment and chemical rust pigment.Physical rust resisting pigment includes but is not limited to Iron oxide red, aluminium powder, graphite, zinc oxide, basic lead carbonate, basic lead sulfates；Chemical rust pigment is including but not limited to red Pellet, zinc yellow, calcium plumbate, zinc powder, lead powder, barium potassium chrome yellow, alkaline lead chromate yellow.
2- (methacrylic acid) ethyl ester 3,5- diaminobenzoic acids：No. cas is 76067-81-7, buys from Shanghai source leaf and gives birth to Thing Science and Technology Ltd..
Auxiliary agent：One or more of the auxiliary agent in defoamer, wetting dispersing agent and thickener.
Wetting dispersing agent：The wetting dispersing agent includes but is not limited to：Sulfosuccinate, alkylnaphthalene sulfonate, castor-oil plant Oily sulfonate, lauryl sulfate, dodecyl sodium sulfate, aikylpyridinium chloride, APES, fatty alcohol APEO, polyoxyethylene fatty acid ester, acetylenic glycols, tripolyphosphate, calgon, sodium metasilicate, 2- amino -2- first Base propyl alcohol.
Thickener：Thickener selection methylcellulose, carboxymethyl cellulose, hydroxyethyl cellulose and its various fibers Plain derivative, the one or more in polyvinyl alcohol, polyacrylate, polyacrylamide.
Defoamer：The defoamer includes but is not limited to：Methanol, ethanol, isopropanol, sec-butyl alcohol, n-butanol.Polar organic The example of series of compounds includes but is not limited to：Amylalcohol, dibutyl carbitol (DBC), tributyl phosphate, oleic acid, tall oil, metallic soap, The low surfactant of HLB value.
As the trade name of defoamer, include but is not limited to：SPA-102, SPA-202,201 methyl-silicone oils, Foamaster AP、Foamaster VL、NOPCO 8034、NOPCO 8034-L、SN-Defoamer 113、SN-Defoamer 154、SN-Defoamer 414、SN-Defoamer 456、NOPCO DF-122-NS、NOPCO NX2、Bevaloid 667、 Bevaloid 6371、Bevaloid 618F、Bevaloid 581B、Bevaloid 680、Bevaloid 6223、Bevaloid 6420、Bevaloid 311M、Bevaloid 6537、Bevaloid 6236、BYK-W、BYK-031、BYK-035、BYK-040、 BYK-069、BYK-073、BYK-020、BYK-080。
As one embodiment of the present invention, the preparing raw material of the ink-absorbed coated layer in parts by weight, comprising：90 parts Polyacrylic resin, 1 part of hyperbranched poly propylene, 5 parts of quaternary ammonium salt-modified meso-porous nano material, 0.3 part of 1- hydroxyl rings Base phenyl ketone；
The preparing raw material of the substrate layer in parts by weight, comprising：The isotactic polypropylene of 93 parts by weight, 4 parts by weight Syndiotactic polypropylene, the random polypropylene of 0.7 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the sandwich layer in parts by weight, comprising：90 parts of hyperbranched poly propylene；
The preparing raw material of the sub- substrate layer in parts by weight, comprising：The isotactic polypropylene of 93 parts by weight, 4 parts by weight Syndiotactic polypropylene, random polypropylene, the hyperbranched poly propylene of 1 parts by weight of 0.7 parts by weight；
The preparing raw material of the layer in parts by weight, comprising：The polyacrylic resin of 90 parts by weight, 1 parts by weight Hyperbranched poly propylene, the talcum powder of 2 parts by weight.
The second aspect of the present invention provides the preparation technology of the PP synthetic papers：Five layers of the PP synthetic papers are prepared former Material is blended respectively, and five layers of sheet is then made by five layers of T-shaped head extrusion, then enters under certain temperature and stretching ratio Row longitudinal stretching, high temperature stenter is entered back into after longitudinal stretching cross directional stretch is carried out according to certain angle, then cooled down, cut Side, batch, finally cut finished product.
Specific extrusion step：Five-layer co-squeezing enters same die head
The superiors are ink-absorbed coated layer, by a single screw extrusion machine, by preparing raw material in the mixed-hopper of extruder front end After uniform stirring, in the runner for the superiors for squeezing into same die head；
The second layer is substrate layer, by a single screw extrusion machine, by preparing raw material in the mixed-hopper of extruder front end After even stirring, in the runner for the second layer for squeezing into same die head；
Third layer is sandwich layer, by a series connection single screw extrusion machine, by preparing raw material in the mixed-hopper of extruder front end After uniform stirring, in the runner for the third layer for squeezing into same die head；
4th layer is sub- substrate layer, by a single screw extrusion machine, by preparing raw material in the mixed-hopper of extruder front end After uniform stirring, squeeze into the 4th layer of runner of same die head；
Orlop is layer, by a single screw extrusion machine, by preparing raw material in the mixed-hopper of extruder front end After even stirring, squeeze into the undermost runner of same die head.
The preheating section temperature of wherein longitudinal stretching is：134/134//136/136/136/136/136/134/130/130 ℃；Stretch section temperature is 135/134/134/142 DEG C；Sizing section temperature be：145/145/145/145/145℃.Longitudinal stretching Than：4.5-5.5 again.
The preheating section temperature of wherein cross directional stretch is：167/167/167/167/167/165/169℃；Stretch section temperature is 155/155/155/155/155℃；Sizing section temperature be：171/171/171/171/168℃.Cross directional stretch ratio：9 times.
The third aspect of the present invention provides the preparation method of the special-purpose ink：The preparing raw material of special-purpose ink is blended, It is uniformly mixed.
Mechanism is explained：Conventional PP synthetic papers are unable to rapid draing, and ink absorbs and horizontal proliferation because having little time, usually can There is mixed color phenomenon, strong influence printing effect；It can not expose out of doors for a long time simultaneously, otherwise image occurs more serious Color error ratio, therefore PP synthetic papers are used primarily in the exhibition of interior.The present invention provides a kind of PP synthetic papers that outdoor can be used And its special-purpose ink, it not only can quickly absorb, dry ink, and can be long-term use of out of doors, be not in color error ratio Situations such as.The reason for its is possible improves product because of hyperbranched poly propylene gives inside PP synthetic papers " foaminess " Absorbability, in combination with meso-porous nano material, ink, while the quaternary ammonium salt pair of the middle offer of the present invention can be absorbed faster Ink have it is very strong bound, can quick ink solidification.Simultaneously in the present invention, there is provided five layers of PP synthetic papers preparation it is former Material passes through most appropriate ratio, and the addition of the raw material such as 1- hydroxycyclohexylphenylketones, improves what product exposed out of doors Performance.
Embodiment 1：Present embodiment provides the PP synthetic papers and its special-purpose ink that a kind of open air uses, the PP synthesis Paper is five-layer co-squeezing synthetic paper, from top to bottom respectively ink-absorbed coated layer, substrate layer, sandwich layer, sub- substrate layer and layer；
The preparing raw material of the ink-absorbed coated layer in parts by weight, comprising：90~95 parts of acrylic resin, 1~3 part Hyperbranched poly propylene, 5~7 parts of quaternary ammonium salt-modified meso-porous nano material, 0.3~0.5 part of 1- hydroxycyclohexylphenylketones；
The preparing raw material of the substrate layer in parts by weight, comprising：The isotactic polypropylene of 90~95 parts by weight, 3~5 weights Measure the syndiotactic polypropylene of part, the random polypropylene of 0.5~1 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the sandwich layer in parts by weight, comprising：90 parts of hyperbranched poly propylene；
The preparing raw material of the sub- substrate layer in parts by weight, comprising：The isotactic polypropylene of 90~95 parts by weight, 3~5 The syndiotactic polypropylene of parts by weight, the random polypropylene of 0.5~1 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the layer in parts by weight, comprising：The acrylic resin of 85~95 parts by weight, 1~3 weight Measure the hyperbranched poly propylene, the talcum powder of 1~4 parts by weight of part.
Embodiment 2：The PP synthetic papers and its special-purpose ink that a kind of open air described in embodiment 1 uses, it is described special The preparing raw material of ink in parts by weight, comprising：The melon ring modification acrylate of 3 parts by weight, the water-based poly- ammonia of 30 parts by weight Ester, the pigment of 4 parts by weight, 2- (methacrylic acid) the ethyl ester 3,5- diaminobenzoic acids of 3 parts by weight, the auxiliary agent of 8 parts by weight, 80 The water of parts by weight.
Embodiment 3:The PP synthetic papers and its special-purpose ink that a kind of open air described in embodiment 1 uses, the blotting The preparing raw material of coating in parts by weight, comprising：90 parts of polyacrylic resin, 1 part of hyperbranched poly propylene, 5 parts of season Ammonium salt is modified meso-porous nano material, 0.3 part of 1- hydroxy-cyclohexyl phenyl ketones；
The preparing raw material of the substrate layer in parts by weight, comprising：The isotactic polypropylene of 93 parts by weight, 4 parts by weight Syndiotactic polypropylene, the random polypropylene of 0.7 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the sandwich layer in parts by weight, comprising：90 parts of hyperbranched poly propylene；
The preparing raw material of the sub- substrate layer in parts by weight, comprising：The isotactic polypropylene of 93 parts by weight, 4 parts by weight Syndiotactic polypropylene, random polypropylene, the hyperbranched poly propylene of 1 parts by weight of 0.7 parts by weight；
The preparing raw material of the layer in parts by weight, comprising：The polyacrylic resin of 90 parts by weight, 1 parts by weight Hyperbranched poly propylene, the talcum powder of 2 parts by weight.
Embodiment 4：The PP synthetic papers and its special-purpose ink that a kind of open air described in embodiment 1 uses, the over-expense Change polyacrylic preparation method：Propylene is inputted in a kettle, is added the alkyl aluminum and catalyst for being dissolved in toluene, is lifted propylene Pressure is 0.1~2.0MPa, and it is 65 DEG C to control temperature, and the reaction time is 30 minutes；Reaction terminate after toward being passed through in reaction mixture Oxygen, reaction time are 2 hours；Finally reduced and precipitated with acidic ethanol, filtration washing, obtain hyperbranched poly propylene.
Embodiment 5：The PP synthetic papers and its special-purpose ink that a kind of open air described in embodiment 1 uses, the quaternary ammonium Salt is modified the preparation method of meso-porous nano material：
1) by N, N, N', N'- tetra- (2- hydroxypropyls) ethylenediamine, 2- (2- chloroethyls) malononitrile and ethyl acetate mixture Add in the four-hole boiling flask equipped with stirring and condensing unit, in temperature 50 C, under the conditions of pressure is 0.9Mpa, uniform stirring 12 is small When, cooling is stood, and product 1 is made；
2) it is 6 according to mol ratio by product 1 and 1,5- diisocyanate pentanes：1 and account for reactant gross mass 1% to first Benzene sulfonic acid is added in the four-hole boiling flask, at 1100 DEG C of temperature and 20Mpa pressure, uniform stirring 5 hours, in 100 DEG C of temperature Under degree, removing solvent is vacuumized, quaternary ammonium salt is made；
3) by meso-porous nano silica and Silane coupling agent KH550 according to mol ratio 3：1 mixes in ethanol solution Stirring, reacts 4 hours at 60 DEG C, then adds quaternary ammonium salt, continues reaction 2 hours, obtains quaternary ammonium salt-modified meso-porous nano material Material.
Embodiment 6：The PP synthetic papers and its special-purpose ink that a kind of open air described in embodiment 2 uses, the melon ring The preparation method of modification acrylate：Melon ring, ammonium persulfate, deionized water are added into reactor, stirring, is passed through nitrogen, is risen Temperature reacts 2-3h, acrylate is slowly added dropwise to 80 DEG C, after being added dropwise, 80 DEG C of insulation reaction 8-10h, stops reaction, cooling To room temperature, acetone is added, is stirred, filtering, 40 DEG C are dried under reduced pressure 48h, obtain melon ring modification acrylate, grinding, are sealed.
Embodiment 7：The PP synthetic papers and its special-purpose ink that a kind of open air described in embodiment 2 uses, it is described water-based The preparation method of polyurethane is：
(1) 2,4- toluene di-isocyanate(TDI)s and PPG are dissolved separately in dimethyl sulfoxide solvent, obtained different Cyanic acid ester solution and polyhydric alcohol solutions；Wherein, the mol ratio of isocyanate group and hydroxyl is 3：2；
(2) at 90 DEG C, under nitrogen protection atmosphere, side stirring, isocyanate solution is added in alcoholic solution, isocyanates is molten After the completion of liquid adds, reaction system insulation reaction 12h；Then protective agent caprolactam is added into reaction system, at 100 DEG C Continue to react 10h；
(3) after reaction terminates, after being evaporated under reduced pressure out solvent, gained material is dissolved through tetrahydrofuran, settled in methyl alcohol After filtering, by it in 120 DEG C of vacuum drying 12h, aqueous polyurethane is obtained.
Embodiment 8：The PP synthetic papers and its special-purpose ink that a kind of open air described in embodiment 2 uses, the pigment Color selected from pale purple, purple, deep barba hispanica, deep phthalein is blue, middle barba hispanica, blue, sea blue, the light barba hispanica of middle phthalein, light phthalein is blue, bluish grey, day phthalein is blue, Its barba hispanica, peacock blue, dark-grey, middle grey, light grey, silver grey, extra large ash, lightskyblue, it is pale blue, young it is blue, sapphire blue, vivid blue, light it is sea blue, in It is sea blue, deep-sea is blue, Jing Lan, gorgeous blue, middle ashy green, lake is green, treasured is green, bud green, fresh water lake is green, apple green, pale green, bright green, in it is green, deep Green, olive green, eggshell be green, it is light it is apple green, depth is pea green, aircraft is grey, pea green, olive is grey, grass green, breen, military vehicle is green, cardamom is green, It is light green, ice is grey, lathe is grey, beautiful ash, ostrich ash, pearl, cream, ivory, yellow, yellowish, middle yellow, the deep yellow, iron oxide yellow of lemon, army are yellow, it is milky white, Cream-coloured, yellowish grey, light brown, reddish brown yellow, purple brown, orange, brown, pale brown, iron oxide red, bright red, bright red, purplish red, Exocarpium Citri Rubrum, pink, rose pink, One kind in rose-red, light rose-red.
Embodiment 9：The PP synthetic papers and its special-purpose ink that a kind of open air described in embodiment 2 uses, the auxiliary agent One or more in defoamer, wetting dispersing agent and thickener.
Embodiment 10：The PP synthetic papers and its special-purpose ink that a kind of open air described in embodiment 2 uses, the melon ring For cucurbit [6] urea.
The present invention is specifically described below by embodiment.It is necessarily pointed out that following examples are only used In the invention will be further described, it is impossible to be interpreted as limiting the scope of the invention, professional and technical personnel in the field Some the nonessential modifications and adaptations made according to the content of the invention described above, still fall within protection scope of the present invention.
In addition, if without other explanations, raw materials used is all commercially available.
Embodiment 1：The present embodiment provides the PP synthetic papers and its special-purpose ink that a kind of open air uses, and the PP synthetic papers are Five-layer co-squeezing synthetic paper, from top to bottom respectively ink-absorbed coated layer, substrate layer, sandwich layer, sub- substrate layer and layer；
The preparing raw material of the ink-absorbed coated layer in parts by weight, comprising：90 parts of polyacrylic resin, 1 part of over-expense Change polypropylene, 5 parts of quaternary ammonium salt-modified meso-porous nano material, 0.3 part of 1- hydroxy-cyclohexyl phenyl ketones；
The preparing raw material of the substrate layer in parts by weight, comprising：The isotactic polypropylene of 93 parts by weight, 4 parts by weight Syndiotactic polypropylene, the random polypropylene of 0.7 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the sandwich layer in parts by weight, comprising：90 parts of hyperbranched poly propylene；
The preparing raw material of the sub- substrate layer in parts by weight, comprising：The isotactic polypropylene of 93 parts by weight, 4 parts by weight Syndiotactic polypropylene, random polypropylene, the hyperbranched poly propylene of 1 parts by weight of 0.7 parts by weight；
The preparing raw material of the layer in parts by weight, comprising：The polyacrylic resin of 90 parts by weight, 1 parts by weight Hyperbranched poly propylene, the talcum powder of 2 parts by weight；
The preparing raw material of the special-purpose ink in parts by weight, comprising：The melon ring modification acrylate of 3 parts by weight, 30 The aqueous polyurethane of parts by weight, the pigment of 4 parts by weight, 3 parts by weight 2- (methacrylic acid) ethyl ester 3,5- diaminobenzoic acids, The water of the auxiliary agent of 8 parts by weight, 80 parts by weight.
The acrylic resin is bought from brilliant same moral Chemical Co., Ltd. of Foshan City, product type AC-1023.
The hyperbranched polyacrylic preparation method is as follows：Propylene is inputted in a kettle, adds the alkyl for being dissolved in toluene Aluminium and catalyst, the pressure for lifting propylene is 1.0MPa, and diethyl zinc is chain-transferring agent, and it is 65 DEG C to control temperature, the reaction time For 30 minutes；Reaction terminate after toward oxygen is passed through in reaction mixture, the reaction time is 2 hours；Finally reduction with acidic ethanol simultaneously Precipitation, filtration washing, obtains hyperbranched poly propylene.
Wherein, the alkyl aluminum is aluminium diethyl monochloride, and the catalyst is ethylidene acenaphthene (alpha-diimine) Raney nickel, In polymerization system, the concentration of ethylidene acenaphthene (alpha-diimine) Raney nickel is 10 μm of ol/L, aluminium and ethylidene in alkyl aluminum The mol ratio of nickel in acenaphthene (alpha-diimine) nickel complex is 100, and zinc is matched somebody with somebody with ethylidene acenaphthene (alpha-diimine) nickel in diethyl zinc The mol ratio of nickel in compound is 150.
The preparation method of the quaternary ammonium salt-modified meso-porous nano material is as follows：
1) by N, N, N', N'- tetra- (2- hydroxypropyls) ethylenediamine, 2- (2- chloroethyls) malononitrile and ethyl acetate mixture Add in the four-hole boiling flask equipped with stirring and condensing unit, in temperature 50 C, under the conditions of pressure is 0.9Mpa, uniform stirring 12 is small When, cooling is stood, and product 1 is made；
2) it is 6 according to mol ratio by product 1 and 1,5- diisocyanate pentanes：1 and account for reactant gross mass 1% to first Benzene sulfonic acid is added in the four-hole boiling flask, at 100 DEG C of temperature and 20Mpa pressure, uniform stirring 5 hours, in 100 DEG C of temperature Under, removing solvent is vacuumized, quaternary ammonium salt is made；
3) by meso-porous nano silica and Silane coupling agent KH550 according to mol ratio 3：1 mixes in ethanol solution Stirring, reacts 4 hours at 60 DEG C, then adds quaternary ammonium salt, continues reaction 2 hours, obtains quaternary ammonium salt-modified meso-porous nano material Material.
Wherein, N in step 1), N, N', N'- tetra- (2- hydroxypropyls) ethylenediamine, 2- (2- chloroethyls) malononitrile and acetic acid The mol ratio of ethyl ester is 1：2：20.
The weight part ratio of step 3) intermediary hole nano silicon and quaternary ammonium salt is 1：1.
1- hydroxycyclohexylphenylketones：Heretofore described 1- hydroxycyclohexylphenylketones purchase tries from sigma chemistry Agent.
Isotactic polypropylene：Heretofore described isotactic polypropylene is bought from Sigma's chemical reagent.
Syndiotactic polypropylene：Heretofore described syndiotactic polypropylene is bought from Suzhou Yu Chenlong engineering plastics Co., Ltd, board Number：2300NC.
Random polypropylene：Heretofore described random polypropylene purchase plastifies Co., Ltd, the trade mark from Suzhou Fu Lixuan： RJ700。
Talcum powder：Heretofore described talcum powder is bought from Ou Senna Chemical Co., Ltd.s of Jiangyin City.
The preparation method of the melon ring modification acrylate：Melon ring, ammonium persulfate, deionized water are added into reactor, Stirring, is passed through nitrogen, is warming up to 80 DEG C, reacts 2h, acrylate is slowly added dropwise, after being added dropwise, 80 DEG C of insulation reaction 9h, stops Only react, be cooled to room temperature, add acetone, stir, filtering, 40 DEG C are dried under reduced pressure 48h, obtain melon ring modification acrylate, grind Mill, is sealed.
The mol ratio of the melon ring and the ammonium persulfate, the acrylate is 1：5：25；The melon ring is gone with described Ionized water, the weight ratio of the acetone are 1：15：12.
The melon ring is cucurbit [6] urea.
The preparation method of the aqueous polyurethane is：
(1) 2,4- toluene di-isocyanate(TDI)s and PPG are dissolved separately in dimethyl sulfoxide solvent, obtained different Cyanic acid ester solution and polyhydric alcohol solutions；Wherein, the mol ratio of isocyanate group and hydroxyl is 3：2；
(2) at 90 DEG C, under nitrogen protection atmosphere, side stirring, isocyanate solution is added in polyhydric alcohol solutions, isocyanic acid After the completion of ester solution adds, reaction system insulation reaction 12h；Then protective agent caprolactam is added into reaction system, 100 Continue to react 10h at DEG C；
(3) after reaction terminates, after being evaporated under reduced pressure out solvent, gained material is dissolved through tetrahydrofuran, settled in methyl alcohol After filtering, by it in 120 DEG C of vacuum drying 12h, aqueous polyurethane is obtained.
The color of the pigment is selected from black.
2- (methacrylic acid) ethyl ester 3,5- diaminobenzoic acids：No. cas is 76067-81-7, buys from Shanghai source leaf and gives birth to Thing Science and Technology Ltd..
The auxiliary agent is selected from dodecyl sodium sulfate, carboxymethyl cellulose and ethanol.
The second aspect of the present embodiment provides the preparation technology of the PP synthetic papers：By five layers of preparation of the PP synthetic papers Raw material is blended respectively, five layers of sheet is then made by five layers of T-shaped head extrusion, then under certain temperature and stretching ratio Longitudinal stretching is carried out, high temperature stenter is entered back into after longitudinal stretching cross directional stretch is carried out according to certain angle, then cool down, Trimming, batch, finally cut finished product.
Specific extrusion step：Five-layer co-squeezing enters same die head
The superiors are ink-absorbed coated layer, by a single screw extrusion machine, by preparing raw material in the mixed-hopper of extruder front end After uniform stirring, in the runner for the superiors for squeezing into same die head；
The second layer is substrate layer, by a single screw extrusion machine, by preparing raw material in the mixed-hopper of extruder front end After even stirring, in the runner for the second layer for squeezing into same die head；
Third layer is sandwich layer, by a series connection single screw extrusion machine, by preparing raw material in the mixed-hopper of extruder front end After uniform stirring, in the runner for the third layer for squeezing into same die head；
4th layer is sub- substrate layer, by a single screw extrusion machine, by preparing raw material in the mixed-hopper of extruder front end After uniform stirring, squeeze into the 4th layer of runner of same die head；
Orlop is layer, by a single screw extrusion machine, by preparing raw material in the mixed-hopper of extruder front end After even stirring, squeeze into the undermost runner of same die head.
The preheating section temperature of wherein longitudinal stretching is：134/134//136/136/136/136/136/134/130/130 ℃；Stretch section temperature is 135/134/134/142 DEG C；Sizing section temperature be：145/145/145/145/145℃.Longitudinal stretching Than：5 times.
The preheating section temperature of wherein cross directional stretch is：167/167/167/167/167/165/169℃；Stretch section temperature is 155/155/155/155/155℃；Sizing section temperature be：171/171/171/171/168℃.Cross directional stretch ratio：9 times.
The third aspect of the present embodiment provides the preparation method of the special-purpose ink：The preparing raw material of special-purpose ink is total to It is mixed, it is uniformly mixed.
Embodiment 2：Difference with embodiment 1 is, the preparing raw material of the ink-absorbed coated layer mesoporous is received without quaternary ammonium salt-modified Rice material.
Embodiment 3：Difference with embodiment 1 is that the preparing raw material of the ink-absorbed coated layer is without hyperbranched poly propylene.
Embodiment 4：Difference with embodiment 1 is that the preparing raw material of the ink-absorbed coated layer is without 1- hydroxycyclohexylphenyls Ketone.
Embodiment 5：Difference with embodiment 1 is that the quaternary ammonium salt-modified meso-porous nano material is chlorination dodecyl Dimethyl benzyl ammonium improved silica.
Embodiment 6：Difference with embodiment 1 is, all isotactic polypropylene of preparing raw material of the base material.
Embodiment 7：Difference with embodiment 1 is that the preparing raw material of the base material is without hyperbranched poly propylene.
Embodiment 8：Difference with embodiment 1 is, the preparing raw material of the substrate layer in parts by weight, comprising：85 The isotactic polypropylene of parts by weight, the syndiotactic polypropylene of 7 parts by weight, the random polypropylene of 1.7 parts by weight, 1 parts by weight it is hyperbranched Polypropylene.
Embodiment 9：Difference with embodiment 1 is that the PP synthetic papers are without sandwich layer.
Embodiment 10：Difference with embodiment 1 is that the preparing raw material of the subunit material does not include hyperbranched poly propylene.
Embodiment 11：Difference with embodiment 1 is that the preparing raw material of the layer is without hyperbranched poly propylene.
Embodiment 12：Difference with embodiment 1 is that the preparing raw material of the special-purpose ink is without melon ring modified acroleic acid Ester.
Embodiment 13：Difference with embodiment 1 is that the preparing raw material of the special-purpose ink is without aqueous polyurethane.
Embodiment 14：Difference with embodiment 1 is that the preparing raw material of the special-purpose ink is without 2- (methacrylic acid) second Ester 3,5- diaminobenzoic acids.
Test：
The special-purpose ink is printed on the PP synthetic papers with the wide format printer of Hewlett-Packard 5800.
1st, colour fasteness to sunlight is tested：Detected using standard blue colour atla；
2nd, hardening time determines：Measure the time being completely dried；
3rd, adhesion strength is tested：According to standard ASTM C 633-2001 test；
4th, the measure of PP synthetic papers definition：The definition of PP synthetic papers is to be ejected on PP synthetic papers to spread by ink droplet The ratio of the diameter of ink droplet is come what is characterized before rear diameter and diffusion, and the ratio is smaller, and definition is better.This experiment uses The diameter of forward and backward ink droplet is sprayed in the measurement of GB1216-85 types outside micrometer.
Foregoing example is merely illustrative, some features of the feature for explaining the disclosure.Appended claim It is intended to require the scope as wide as possible being contemplated that, and embodiments as presented herein is only according to all possible embodiment Combination selection embodiment explanation.Therefore, the purpose of applicant is appended claim not by the explanation present invention Feature example selectional restriction.And the progress in science and technology will not formed due to the inaccuracy of language performance and not The possible equivalent or son being presently considered are replaced, and these changes should also be interpreted by appended in the conceived case Claim covers.

Claims (5)

1. the PP synthetic papers that a kind of open air uses, it is characterised in that the PP synthetic papers are five-layer co-squeezing synthetic paper, from top to bottom Respectively ink-absorbed coated layer, substrate layer, sandwich layer, sub- substrate layer and layer；
The preparing raw material of the ink-absorbed coated layer in parts by weight, comprising：90~95 parts of acrylic resin, 1~3 part of over-expense Change polypropylene, 5~7 parts of quaternary ammonium salt-modified meso-porous nano material, 0.3~0.5 part of 1- hydroxycyclohexylphenylketones；
The preparing raw material of the substrate layer in parts by weight, comprising：The isotactic polypropylene of 90~95 parts by weight, 3~5 parts by weight Syndiotactic polypropylene, random polypropylene, the hyperbranched poly propylene of 1 parts by weight of 0.5~1 parts by weight；
The preparing raw material of the sandwich layer in parts by weight, comprising：90 parts of hyperbranched poly propylene；
The preparing raw material of the sub- substrate layer in parts by weight, comprising：The isotactic polypropylene of 90~95 parts by weight, 3~5 weight Syndiotactic polypropylene, the random polypropylene, the hyperbranched poly propylene of 1 parts by weight of 0.5~1 parts by weight of part；
The preparing raw material of the layer in parts by weight, comprising：The acrylic resin of 85~95 parts by weight, 1~3 parts by weight Hyperbranched poly propylene, the talcum powder of 1~4 parts by weight；
Wherein, the hyperbranched polyacrylic preparation method：Input propylene in a kettle, add the alkyl aluminum that is dissolved in toluene and Catalyst, the pressure for lifting propylene is 0.1~2.0MPa, and it is 65 DEG C to control temperature, and the reaction time is 30 minutes；After reaction terminates Oxygen is passed through into reaction mixture, the reaction time is 2 hours；Finally reduced and precipitated with acidic ethanol, filtration washing, surpassed Branched p 0 lypropylene；
The preparation method of the quaternary ammonium salt-modified meso-porous nano material：
1) N, N, N', N'- tetra- (2- hydroxypropyls) ethylenediamine, 2- (2- chloroethyls) malononitrile and ethyl acetate mixture are added In four-hole boiling flask equipped with stirring and condensing unit, in temperature 50 C, under the conditions of pressure is 0.9Mpa, uniform stirring 12 hours, Cooling is stood, and product 1 is made；
2) it is 6 according to mol ratio by product 1 and 1,5- diisocyanate pentanes：1 and account for reactant gross mass 1% to toluene sulphur Acid is added in the four-hole boiling flask, at 1100 DEG C of temperature and 20Mpa pressure, uniform stirring 5 hours, and at a temperature of 100 DEG C, Removing solvent is vacuumized, quaternary ammonium salt is made；
3) by meso-porous nano silica and Silane coupling agent KH550 according to mol ratio 3：1 mixes in ethanol solution, Reacted 4 hours at 60 DEG C, then add quaternary ammonium salt, continued reaction 2 hours, obtain quaternary ammonium salt-modified meso-porous nano material.
2. the PP synthetic papers that a kind of open air described in claim 1 uses, it is characterised in that the preparing raw material of the ink-absorbed coated layer In parts by weight, comprising：90 parts of polyacrylic resin, 1 part of hyperbranched poly propylene, 5 parts quaternary ammonium salt-modified mesoporous receive Rice material, 0.3 part of 1- hydroxy-cyclohexyl phenyl ketones；
The preparing raw material of the substrate layer in parts by weight, comprising：Advised between the isotactic polypropylene of 93 parts by weight, 4 parts by weight Polypropylene, the random polypropylene of 0.7 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the sandwich layer in parts by weight, comprising：90 parts of hyperbranched poly propylene；
The preparing raw material of the sub- substrate layer in parts by weight, comprising：Between the isotactic polypropylene of 93 parts by weight, 4 parts by weight Isotactic polypropylene, the random polypropylene of 0.7 parts by weight, the hyperbranched poly propylene of 1 parts by weight；
The preparing raw material of the layer in parts by weight, comprising：The polyacrylic resin of 90 parts by weight, 1 parts by weight it is super The talcum powder of branched p 0 lypropylene, 2 parts by weight.
3. the special-purpose ink for the PP synthetic papers that a kind of open air for described in claim 1 uses, it is characterised in that described special The preparing raw material of ink in parts by weight, comprising：The melon ring modification acrylate of 3 parts by weight, the water-based poly- ammonia of 30 parts by weight Ester, the pigment of 4 parts by weight, 2- (methacrylic acid) the ethyl ester 3,5- diaminobenzoic acids of 3 parts by weight, the auxiliary agent of 8 parts by weight, 80 The water of parts by weight；
Wherein, the preparation method of the melon ring modification acrylate：Melon ring, ammonium persulfate, deionized water are added into reactor, Stirring, is passed through nitrogen, is warming up to 80 DEG C, reacts 2-3h, acrylate is slowly added dropwise, after being added dropwise, 80 DEG C of insulation reaction 8- 10h, stop reaction, be cooled to room temperature, add acetone, stir, filtering, 40 DEG C are dried under reduced pressure 48h, obtain melon ring modified acroleic acid Ester, grinding, is sealed；
Wherein, the melon ring is cucurbit [6] urea；
The preparation method of the aqueous polyurethane is：
(1) 2,4- toluene di-isocyanate(TDI)s and PPG are dissolved separately in dimethyl sulfoxide solvent, obtain isocyanic acid Ester solution and polyhydric alcohol solutions；Wherein, the mol ratio of isocyanate group and hydroxyl is 3：2；
(2) at 90 DEG C, under nitrogen protection atmosphere, side stirring, isocyanate solution is added in alcoholic solution, isocyanate solution adds After the completion of entering, reaction system insulation reaction 12h；Then protective agent caprolactam is added into reaction system, is continued at 100 DEG C React 10h；
(3) after reaction terminates, after being evaporated under reduced pressure out solvent, gained material is dissolved through tetrahydrofuran, in methyl alcohol sedimentation and mistake After filter, by it in 120 DEG C of vacuum drying 12h, aqueous polyurethane is obtained.
4. the special-purpose ink for the PP synthetic papers that the open air described in claim 3 uses, it is characterised in that the color choosing of the pigment From pale purple, purple, deep barba hispanica, deep phthalein is blue, middle barba hispanica, blue, sea blue, the light barba hispanica of middle phthalein, light phthalein are blue, bluish grey, day phthalein indigo plant, day barba hispanica, Peacock blue, dark-grey, middle grey, light grey, silver grey, extra large ash, lightskyblue, it is pale blue, young it is blue, sapphire blue, vivid blue, light it is sea blue, in it is sea blue, deep Sea blue, Jing Lan, gorgeous blue, middle ashy green, lake is green, treasured is green, bud green, fresh water lake is green, apple green, pale green, bright green, in green, dark green, olive It is green, eggshell is green, it is light it is apple green, depth is pea green, aircraft is grey, pea green, olive is grey, grass green, breen, military vehicle is green, cardamom is green, light green, ice Ash, lathe ash, beautiful ash, ostrich ash, pearl, cream, ivory, yellow, yellowish, middle yellow, the deep yellow, iron oxide yellow of lemon, army are yellow, milky white, cream-coloured, light Yellow grey, light brown, reddish brown yellow, purple brown, orange, brown, pale brown, iron oxide red, bright red, bright red, purplish red, Exocarpium Citri Rubrum, pink, rose pink, rose-red, One kind in light rose-red.
5. the special-purpose ink for the PP synthetic papers that the open air described in claim 3 uses, it is characterised in that the auxiliary agent is selected from defoaming One or more in agent, wetting dispersing agent and thickener.
CN201710388267.6A 2017-05-27 2017-05-27 The PP synthetic papers and its special-purpose ink that a kind of open air uses Active CN107187153B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710388267.6A CN107187153B (en) 2017-05-27 2017-05-27 The PP synthetic papers and its special-purpose ink that a kind of open air uses

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710388267.6A CN107187153B (en) 2017-05-27 2017-05-27 The PP synthetic papers and its special-purpose ink that a kind of open air uses

Publications (2)

Publication Number Publication Date
CN107187153A CN107187153A (en) 2017-09-22
CN107187153B true CN107187153B (en) 2018-03-27

Family

ID=59874629

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710388267.6A Active CN107187153B (en) 2017-05-27 2017-05-27 The PP synthetic papers and its special-purpose ink that a kind of open air uses

Country Status (1)

Country Link
CN (1) CN107187153B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110452627A (en) * 2018-05-07 2019-11-15 上海纳尔实业股份有限公司 PP gum pad pasting and its manufacturing method
CN110126409B (en) * 2019-05-10 2021-05-18 保定乐凯新材料股份有限公司 Multilayer film with metal wiredrawing effect layer
CN117621585A (en) * 2024-01-25 2024-03-01 烟台富利新材料科技有限公司 Ultraviolet-resistant and aging-resistant polypropylene synthetic paper and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1846984A (en) * 2005-11-28 2006-10-18 申达集团有限公司 Five layer co-extruding biaxial stretched synthetic PP paper and its prepn process
CN101698756A (en) * 2007-11-14 2010-04-28 谢群林 Black ink used for printing on PP synthetic paper and production method thereof
CN102015923A (en) * 2008-05-01 2011-04-13 精工爱普生株式会社 Ink composition for inkjet recording
CN102501675A (en) * 2011-10-14 2012-06-20 江苏格美高科技发展有限公司 Matte polypropylene inkjet photo paper suitable for ECO-solvent ink
CN102909982A (en) * 2012-09-12 2013-02-06 浙江欧丽数码喷绘材料有限公司 Waterproof PP(propene polymer) synthesized paper for ink-jet printing and preparation method thereof
CN104275956A (en) * 2014-09-28 2015-01-14 江苏奥力广告材料股份有限公司 Ink jet advertisement consumable material and production method thereof
CN104861857A (en) * 2015-06-16 2015-08-26 华东理工大学 Method for preparing environment-friendly synthetic paper ink-jet printing coating
CN105968576A (en) * 2016-06-29 2016-09-28 阜阳市远大印刷有限公司 PP (polypropylene) synthetic paper with composite modified palygorskite and method for preparing PP synthetic paper

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8133556B2 (en) * 2009-08-12 2012-03-13 Brady Worldwide, Inc. Durable multilayer inkjet recording media topcoat

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1846984A (en) * 2005-11-28 2006-10-18 申达集团有限公司 Five layer co-extruding biaxial stretched synthetic PP paper and its prepn process
CN101698756A (en) * 2007-11-14 2010-04-28 谢群林 Black ink used for printing on PP synthetic paper and production method thereof
CN102015923A (en) * 2008-05-01 2011-04-13 精工爱普生株式会社 Ink composition for inkjet recording
CN102501675A (en) * 2011-10-14 2012-06-20 江苏格美高科技发展有限公司 Matte polypropylene inkjet photo paper suitable for ECO-solvent ink
CN102909982A (en) * 2012-09-12 2013-02-06 浙江欧丽数码喷绘材料有限公司 Waterproof PP(propene polymer) synthesized paper for ink-jet printing and preparation method thereof
CN104275956A (en) * 2014-09-28 2015-01-14 江苏奥力广告材料股份有限公司 Ink jet advertisement consumable material and production method thereof
CN104861857A (en) * 2015-06-16 2015-08-26 华东理工大学 Method for preparing environment-friendly synthetic paper ink-jet printing coating
CN105968576A (en) * 2016-06-29 2016-09-28 阜阳市远大印刷有限公司 PP (polypropylene) synthetic paper with composite modified palygorskite and method for preparing PP synthetic paper

Also Published As

Publication number Publication date
CN107187153A (en) 2017-09-22

Similar Documents

Publication Publication Date Title
CN107187153B (en) The PP synthetic papers and its special-purpose ink that a kind of open air uses
CN103436095B (en) Ultraviolet-curing water-based inkjet ink
CN101914324B (en) Modified polyurethane resin emulsion dye ink and application thereof
CN101688072B (en) Dark pigments reflecting ir radiation, method for the production thereof, and use thereof
CN105017863B (en) Water-based ink, its preparation method and printed matter
NO315166B1 (en) Dyestuff composition for paint products and their use
CN100395295C (en) Water printing ink using synthetic water solid acrylate resin as base material and its preparation method
MXPA98001402A (en) Coloring composition for pint products
CN103709833A (en) Polymer coated inorganic pigment paste for color modulation of production line and preparation method thereof
CN102186931A (en) Azo pigments, coloring compositions, coloring method and colored articles
CN107189594A (en) A kind of novel aqueous waterproof heat insulating decorative coating and its preparation technology
CN105368140A (en) Photo-cured high-temperature colored glass printing ink and preparation method therefor and painting method thereof
CN106916487A (en) A kind of package typography with pearly-lustre texture and its printing-ink for calling
CN102341461A (en) Infrared absorbing material, method for synthesizing same, coloring composition, ink, toner, printed material, image recording method and image information detecting method
CN101864210A (en) Alcohol-soluble printing ink and preparation method thereof
CN102190907A (en) Pigment dispersion, ink composition using the same, and printed material
CN109880049A (en) A kind of colored preparation method and application for covering polyaminoester emulsion of copolymerization
CN111791614A (en) Pearlescent color-transfer thermal transfer ribbon and preparation method thereof
CN101760089B (en) Sub-nanometer blue water-based preparation used for hydrophilic coating and preparation method
CN105462404B (en) A kind of aqueous fluorescent anti-counterfeit paint composition of only ultraviolet identification
CN107325654B (en) A kind of air brushing coating and preparation method thereof adapting to Latex ink
CN1690135A (en) Anti-false printing ink of light-coloured infrared absorption powder with high absorptivity
TW201807078A (en) Black azo pigment and colorant
CN101565555B (en) Rare earth complex red pigment with excellent pigment performance and application thereof
CN104387862B (en) A kind of printing-ink aluminium foil and cross aluminium foil clear dope and preparation method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant