CN107176274B - Chemical gas storage type underwater life-saving equipment - Google Patents
Chemical gas storage type underwater life-saving equipment Download PDFInfo
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- CN107176274B CN107176274B CN201710565210.9A CN201710565210A CN107176274B CN 107176274 B CN107176274 B CN 107176274B CN 201710565210 A CN201710565210 A CN 201710565210A CN 107176274 B CN107176274 B CN 107176274B
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- Prior art keywords
- support body
- outlet
- wristwatch
- fluid channel
- life
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- 239000000126 substance Substances 0.000 title claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 73
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 72
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 49
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 31
- 229940024548 aluminum oxide Drugs 0.000 claims abstract description 6
- 239000012530 fluid Substances 0.000 claims description 46
- 229910052751 metal Inorganic materials 0.000 claims description 37
- 239000002184 metal Substances 0.000 claims description 37
- 230000007246 mechanism Effects 0.000 claims description 20
- 239000012943 hotmelt Substances 0.000 claims description 18
- 239000000376 reactant Substances 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000012780 transparent material Substances 0.000 claims description 8
- 238000007789 sealing Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 abstract description 80
- 239000001257 hydrogen Substances 0.000 abstract description 8
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 7
- 229910000831 Steel Inorganic materials 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 6
- 239000010959 steel Substances 0.000 abstract description 6
- 230000009182 swimming Effects 0.000 abstract description 2
- 239000002585 base Substances 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 7
- 239000003814 drug Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000001960 triggered effect Effects 0.000 description 4
- 210000000707 wrist Anatomy 0.000 description 4
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 210000004247 hand Anatomy 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63C—LAUNCHING, HAULING-OUT, OR DRY-DOCKING OF VESSELS; LIFE-SAVING IN WATER; EQUIPMENT FOR DWELLING OR WORKING UNDER WATER; MEANS FOR SALVAGING OR SEARCHING FOR UNDERWATER OBJECTS
- B63C9/00—Life-saving in water
- B63C9/08—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like
- B63C9/13—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like attachable to body member, e.g. arm, neck, head or waist
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63C—LAUNCHING, HAULING-OUT, OR DRY-DOCKING OF VESSELS; LIFE-SAVING IN WATER; EQUIPMENT FOR DWELLING OR WORKING UNDER WATER; MEANS FOR SALVAGING OR SEARCHING FOR UNDERWATER OBJECTS
- B63C9/00—Life-saving in water
- B63C9/08—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like
- B63C9/087—Body suits, i.e. substantially covering the user's body ; Immersion suits, i.e. substantially completely covering the user
- B63C9/105—Body suits, i.e. substantially covering the user's body ; Immersion suits, i.e. substantially completely covering the user having gas-filled compartments
- B63C9/1055—Body suits, i.e. substantially covering the user's body ; Immersion suits, i.e. substantially completely covering the user having gas-filled compartments inflatable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63C—LAUNCHING, HAULING-OUT, OR DRY-DOCKING OF VESSELS; LIFE-SAVING IN WATER; EQUIPMENT FOR DWELLING OR WORKING UNDER WATER; MEANS FOR SALVAGING OR SEARCHING FOR UNDERWATER OBJECTS
- B63C9/00—Life-saving in water
- B63C9/08—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like
- B63C9/13—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like attachable to body member, e.g. arm, neck, head or waist
- B63C9/15—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like attachable to body member, e.g. arm, neck, head or waist having gas-filled compartments
- B63C9/155—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like attachable to body member, e.g. arm, neck, head or waist having gas-filled compartments inflatable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63C—LAUNCHING, HAULING-OUT, OR DRY-DOCKING OF VESSELS; LIFE-SAVING IN WATER; EQUIPMENT FOR DWELLING OR WORKING UNDER WATER; MEANS FOR SALVAGING OR SEARCHING FOR UNDERWATER OBJECTS
- B63C9/00—Life-saving in water
- B63C9/08—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like
- B63C9/18—Inflatable equipment characterised by the gas-generating or inflation device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63C—LAUNCHING, HAULING-OUT, OR DRY-DOCKING OF VESSELS; LIFE-SAVING IN WATER; EQUIPMENT FOR DWELLING OR WORKING UNDER WATER; MEANS FOR SALVAGING OR SEARCHING FOR UNDERWATER OBJECTS
- B63C9/00—Life-saving in water
- B63C9/08—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like
- B63C9/13—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like attachable to body member, e.g. arm, neck, head or waist
- B63C2009/131—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like attachable to body member, e.g. arm, neck, head or waist specially adapted for being attachable to a single arm or wrist
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
The invention discloses chemical gas storage type underwater lifesaving equipment, which comprises an active lifesaving wristwatch and a life jacket substitute gas generating device; the two are designed into chemical gas storage, and finally released hydrogen is generated by H in water, so that the chemical energy is stored in aluminum and sodium hydroxide by ingenious utilization, water in danger is used as a trigger, and the water which is the cause of the danger is used as a reaction raw material for gas supply, so that the cost of the underwater life-saving equipment is greatly reduced, meanwhile, a large high-pressure steel bottle is not used, the life-saving wristwatch is small and easy to wear, and the life-saving wristwatch can be used as a life-saving tool for swimming beginners and underwater life saving.
Description
Technical Field
The invention relates to the technical field of underwater lifesaving, in particular to chemical gas storage type underwater lifesaving equipment.
Background
At present, main life saving equipment mainly comprises a life saving wristwatch and a life saving jacket, wherein a gas storage device can be divided into physical gas storage and chemical gas storage according to principles, and main components of the physical gas storage are an air bag, a high-pressure steel cylinder filled with compressed gas and a pressure reducing valve. When the switch mechanism is triggered, the gas in the high-pressure gas cylinder is released into the air bag through the pressure reducing valve, and the air bag is filled with the gas to generate buoyancy so as to float the person. However, the high-pressure steel bottle has potential safety hazards and the pressure reducing valve has potential safety hazards, more importantly, the device is expensive, the life-saving wristwatch is small, but the high-pressure steel bottle is added to make the life-saving wristwatch large in size, inconvenient to use and difficult to popularize in daily life.
The physical gas storage is mainly compressed air or nitrogen, the chemical gas storage in the invention is to store gas in chemical bonds, after a certain mechanism is triggered, chemical agents in the life saving device are mixed and reacted to generate gas, the generated gas is different in carbon dioxide, organic gas, nitrogen, hydrogen and the like, and the chemical gas storage can be divided into two types according to the reaction without introducing water: the device does not introduce water as a trigger and water as a trigger, does not introduce water as a trigger, does not involve water introduction and water backflow prevention when water is dangerous, but needs to separate at least two medicaments respectively, ensures that the medicaments can be fully mixed to rapidly produce gas when the danger comes and gas production is needed, and has a complex structure and a difficult mixing effect. The invention adopts the introduced water as trigger, namely the water also participates in the reaction, and the technical problems which we need to face equally mainly comprise: the water is introduced, the check device is required to be started at the moment of starting gas production, the gas produced is ensured not to leak, and other chemical substances produced by chemical gas production are generally harmful and are not allowed to leak. Therefore, the invention creatively obtains the following technical scheme based on the gas production principle and solving the technical problems.
Disclosure of Invention
The invention aims at overcoming the defects of the prior art and providing chemical gas storage type underwater lifesaving equipment which has the advantages of small structure, convenience in carrying, safety, stability and low cost.
The invention is based on the principle that:
the sodium hydroxide reacts with the aluminum part and water to generate hydrogen, and a great deal of heat is instantaneously discharged.
The technical scheme of the invention is as follows:
the chemical gas storage type underwater lifesaving equipment is an active lifesaving wristwatch or a device for replacing gas production by a life jacket, and the following description is given respectively:
a. active life-saving wristwatch
The active life saving wristwatch comprises an external wristwatch device and an internal gas generating device arranged in the external wristwatch device;
the external wristwatch device includes:
the lower base is connected with a watchband;
the upper watchcase comprises a connecting part at the periphery and an extending part formed by gathering the bottoms of the connecting parts towards the center, wherein the connecting part is connected with the upper part of the lower base in a sealing way through a trigger spring mechanism, an inlet and a fluid channel connected with the inlet are arranged on the extending part, at least one check valve is arranged in the fluid channel, and a check valve is arranged at the outlet of the fluid channel;
the upper dial plate is connected to the upper part of the upper watchcase connecting part in a sealing way through a trigger spring mechanism, the upper dial plate and the upper watchcase are enclosed to form a central cavity, and the outlet of the fluid channel is communicated with the central cavity;
the internal gas generating apparatus is mounted within the central cavity, comprising:
the thermosensitive metal sheet is fixed at the outlet of the fluid channel and deforms after being heated to close the check valve at the outlet of the flow channel, so that the outlet of the fluid channel is closed;
the elastic support body is a hollow cavity capable of elastically deforming in the vertical direction, the elastic support body is in a compressed state, the upper part of the elastic support body is limited by an upper dial plate, the lower part of the elastic support body is arranged on the thermosensitive metal sheet, and the side parts and the lower part of the elastic support body are respectively provided with a channel to be communicated with the central cavity;
a hot melt film wrapped in a compressed state around the side of the elastic support body and closing the side channels, so that the inner cavity of the elastic support body forms a 'container' with only an upper opening;
the gas generating reactant is placed in the container and can react rapidly to generate gas when meeting water;
the air bag is folded or compressed and arranged in the central cavity, the heat-sensitive metal sheet, the elastic support body and the hot melt film are all wrapped in the air bag, and the inlet of the air bag is connected and communicated with the outlet of the fluid channel in a sealing way.
b. Device for replacing gas production of life jacket
The life jacket substitute gas generating device comprises:
the device comprises a device shell, a water inlet and a gas outlet, wherein the lower part of the device shell is provided with the water inlet, the upper part of the device shell is provided with the gas outlet, and the water inlet is closed by triggering an opening mechanism and can be opened by triggering the opening mechanism; a fluid channel is connected above the water inlet, and an outlet of the fluid channel is communicated with an inner cavity of the device shell; at least one check valve is arranged in the fluid channel, and a check valve is arranged at the outlet of the fluid channel;
the thermosensitive metal sheet is fixed at the outlet of the fluid channel and deforms after being heated to close the check valve at the outlet of the flow channel, so that the outlet of the fluid channel is closed;
the support body is a hollow cavity, the lower part of the support body is arranged on the thermosensitive metal sheet, and the side part and the lower part of the support body are respectively provided with a channel to be communicated with the inner cavity of the device shell;
a hot melt film wrapping around the side of the support body and closing the side channels, so that the inner cavity of the support body forms an open-top "container";
the gas generating reactant is placed in the container, and the gas generating reactant can react rapidly to generate gas when meeting water.
Further preferably, the external wristwatch device further includes a connection string having one end connected to the lower base and the other end connected to the upper case, and the connection string is in a relaxed state. Further, the connecting rope disc is arranged in a cavity formed between the lower base and the upper watchcase, the upper end of the connecting rope is connected with the extension part of the upper watchcase, and the other end of the connecting rope is connected with the upper surface of the lower base.
Further preferably, the elastic support body is a spring.
Further preferably, the active life-saving wristwatch and the life jacket substitute gas generating device further comprise splash-proof filter screens which are arranged on the upper opening of the elastic support body or the support body. Further, the splash-proof filter screen is made of aluminum.
Further preferably, the fluid channels of the active life-saving wristwatch and the life jacket substitute gas generating device are spiral channels; the heat-sensitive metal sheet is arranged above the check valve at the outlet of the fluid channel, and the heat-sensitive metal sheet is deformed downwards by heating to press the check valve at the outlet to be closed.
Further preferably, the gas generating reactants of the active life saving wristwatch and the life jacket substitute gas generating device are metal aluminum and sodium hydroxide. Further, the sodium hydroxide is granular; the metal aluminum is a mixture of aluminum powder and aluminum wires. Further, the mass of the sodium hydroxide is 9.1g; the mass of the aluminum powder is 4.65g; the aluminum wire is an aluminum wire with the diameter of 0.8mm, and the mass of the aluminum wire is 1.55g.
Further preferably, the upper dial plate is made of transparent material, or an observation port made of transparent material is arranged on the upper dial plate; the air bag is made of transparent materials, and the inner surface of the air bag is coated with phenolphthalein.
Further preferably, a heat insulation device is arranged outside the device shell.
Compared with the traditional physical gas storage mode, the active life-saving wristwatch and the life jacket replace the gas generating device, the design is chemical gas storage, and hydrogen finally released is generated by H in water, so that chemical energy is stored in aluminum and sodium hydroxide by ingenious utilization, water which is used as a trigger when danger occurs is used as a dangerous reason, namely water is used as a reaction raw material for gas supply, the cost of underwater life-saving equipment is greatly reduced, meanwhile, a large high-pressure steel bottle is not needed, the life-saving wristwatch is small and easy to wear, and the life-saving wristwatch can be used as a life-saving tool for swimming beginners and underwater life saving.
Drawings
FIG. 1 is a schematic view of an active life-saving wristwatch of the present invention in an unused state;
FIG. 2 is a schematic view of the active life-saving wristwatch of the present invention in a use state after water intake is completed;
FIG. 3 is a schematic view (top view) of the fluid passage intake of the active life-saving wristwatch of the present invention;
FIG. 4 is a schematic diagram of a life jacket alternative gas generating apparatus according to the present invention;
FIG. 5 is a schematic view (top view) of the fluid passage inlet of the lifejacket alternative gas generating apparatus of the present invention;
in fig. 1-3: the watch comprises a watch band (1), a lower check valve (2), an upper check valve (3), a heat-sensitive metal sheet (4), an upper watch case (5), a connecting part (51), an extending part (52), an inlet (521), a fluid channel (522), an outlet (523), an upper dial plate (6), a splash-proof filter screen (7), an observation port (8), a spring (9), a hot-melt film (10), an air bag (11), a trigger spring mechanism (12), a lower watch seat (13), a connecting rope (14) and a central cavity.
In fig. 4-5: (21) A lower check valve, (22) a heat insulation device, (23) an upper check valve, (24) a heat sensitive metal sheet, (25) a hot melt film and a support body, (26) a device housing, (27) an air outlet, (28) a splash screen, and (29) a trigger opening mechanism.
Detailed Description
Example 1
Referring to fig. 1-3, an active life saving wristwatch includes an external wristwatch device and an internal gas generating device mounted therein;
the external wristwatch device includes:
a lower base 13, the lower base 13 is connected with a watchband 1;
the upper case 5, the upper case 5 includes a connecting portion 51 on the outer circumference and an extension portion 52 formed by gathering the bottom of the connecting portion 51 toward the center, the connecting portion 51 is hermetically connected to the upper portion of the lower base 13 by triggering the pop-up mechanism 12, an inlet 521 and a fluid passage 522 connected thereto are provided on the extension portion 52, the fluid passage 522 is a spiral passage, a plurality of check valves (i.e., the lower check valves 2) are provided in the fluid passage 522, and an outlet 523 of the fluid passage is provided with the upper check valve 3.
An upper dial 6, the upper dial 6 is hermetically connected to the upper part of the upper case connecting part 51 by triggering the pop-up mechanism 12, and both the upper dial 6 and the upper case 5 enclose to form a central cavity 15, and an outlet 523 of the fluid passage 522 communicates with the central cavity 15; the upper dial plate is provided with an observation port 8 made of transparent materials.
And a connection string 14, the connection string 14 being wound in a cavity formed between the lower base 13 and the upper case 5 in a relaxed state, the upper end of the connection string 14 being connected to the upper case extension 52, and the other end being connected to the upper surface of the lower base 13.
The internal gas generating means is mounted within the central cavity 15, comprising:
a thermosensitive metal sheet 4; the heat sensitive metal sheet 4 is installed above the upper check valve 3, and the heat sensitive metal sheet 4 is deformed downward by heat to press the upper check valve 3 to close, thereby closing the fluid passage 522, while the metal sheet is deformed to be separated from the bottom of the spring, and the bottom passage starts to circulate.
And the spring 9 is in a compressed state, and the upper part of the spring 9 is limited by the upper dial 6 and the lower part of the spring is arranged on the thermosensitive metal sheet 4.
The hot melt film 10, the hot melt film 10 is wrapped around the side of the spring in a compressed state, so that the inner hole of the spring 9 forms a container with an upper opening.
A splash prevention screen 7, the splash prevention screen 7 is installed on the upper opening of the spring 9.
The gas generating reactant is placed in a container formed by the spring 9, and the gas generating reactant can react rapidly to generate gas when meeting water; the gas generating reactants are metallic aluminum and sodium hydroxide; the sodium hydroxide is granular; the metal aluminum is a mixture of aluminum powder and aluminum wires.
An air bag 11, wherein the air bag 11 is arranged in the central cavity 15 in a folding or compressing way, the air bag 11 wraps the thermosensitive metal sheet 4, the spring 7 (including gas generating reactant therein), the hot melt film 10 and the splash-proof filter screen 7, and the inlet of the air bag 11 is connected and communicated with the outlet 523 of the fluid channel in a sealing way; the air bag 11 is made of transparent material, and the inner surface of the air bag 11 is coated with phenolphthalein.
The whole system is completely closed and is waterproof under the normal state, the internal components are all in a sealing state, and the internal parts contacted with sodium hydroxide are all strong alkali resistant.
The working process of the invention is as follows:
and in the first step, the spring-up mechanism is triggered to feed water when opened. When the user encounters a danger in water, the upper dial 6 is opened after the trigger spring mechanism 12 is pressed (the opening mode is selected according to the requirement, for example, the upper dial is turned to one side through a hinge or the whole is fallen off), the compressed air bag 11 begins to expand, the spring 9 springs upwards, the compressed hot melt film 10 is carried up, a reaction container slightly higher than the height of the wristwatch body is formed inside the wristwatch by the spring 9 and the hot melt film 10, and the design is used for providing enough reaction raw materials and solvents for the reaction of aluminum and sodium hydroxide. The lower watch seat 13 is separated from the upper watch case 5 while the trigger spring mechanism 12 is pressed down, and the connecting rope 14 coiled in the wristwatch is torn off, so that the design is used for preventing the reaction heat release moment from being slightly higher in temperature and possibly causing scalding; at this time, water enters the bladder 11 through the fluid passage 522, and as the water inflow increases, the water level at the bottom of the bladder increases gradually and does not form the upper end of the reaction vessel of the hot melt film 10.
When water in the wrist surface starts to flow into the reaction container formed by the hot melt film 10, sodium hydroxide is dissolved in the water and the sodium hydroxide reacts with metal aluminum to release heat, so that the heat-sensitive metal sheet 4 is heated to deform to close the upper check valve 3, the closed fluid channel 522 is not filled with water, meanwhile, the metal sheet is separated from the bottom of the spring due to the deformation of the heat-sensitive metal sheet 4, the bottom channel flows in water, the reaction rate is increased, and the heat generated in the moment in the reaction stage can dissolve the hot melt film 10 to increase the reaction rate, so that the gas production rate is accelerated. Splash can be generated at the beginning of the reaction, and the splash-proof filter screen 7 is specially designed for preventing the splash, so that the reaction raw materials are prevented from being sprayed away, and the final reduction of gas yield is avoided. The splash-proof filter screen 7 is made of aluminum, and can still react with excessive sodium hydroxide slowly to generate hydrogen when the reaction approaches to tail sound, so that the stability of the pressure in the air bag is ensured, and the closing state of the upper check valve and the lower check valve is further ensured. The principle of this reaction is that aluminum reacts with aqueous sodium hydroxide to produce hydrogen and sodium metaaluminate, which react spontaneously with concomitant exotherm.
Before use, the color of the air bag is observed from the observation port 8, if the air bag changes color, the chemical components in the wristwatch are proved to be invalid and cannot be used, in addition, the wristwatch can be shaken by hands under normal use state by controlling the filling amount of aluminum and sodium hydroxide, if the sound is abnormal, the internal chemical substances are proved to be invalid, and the wristwatch is checked before use by the checking control of the two points, so that the reliability of the wristwatch is ensured.
The above-mentioned heat-sensitive metal sheet 4 is designed to be heat-sensitive material as the upper material, and the lower material may be designed to be heat-sensitive material to be crimped over the upper check valve, and the crimped outward expansion after being heated closes the upper check valve 3.
In the invention, 4 groups of comparison tests are mainly set on the reaction water inflow, 5 groups of comparison tests are set on the reaction medicament formula, and main observation parameters comprise the highest water temperature T1 of the reaction environment, the highest temperature T2 of the reaction and the complete filling time S of the air bag.
The principle of the invention: 2al+2naoh+2h2o=2naalo2+3h2 ∈
The medicament proportion is as follows: the generation of 7L of hydrogen under standard conditions requires 8.3g of sodium hydroxide and 5.6g of aluminum, the analytically pure grade reagent adopted in the experiment is granular, the aluminum is divided into aluminum powder and 0.8mm aluminum wire, and the excess of the reaction raw materials is 10 percent, namely 9.1g of sodium hydroxide and 6.2g of aluminum, in order to ensure the sufficient gas yield.
1. The reaction water inflow and experimental results are as follows
Reaction water inflow (ml) | Ambient maximum water temperature T1 (. Degree.C) | Maximum temperature T2 (. Degree. C.) of reaction | Time S (seconds) for complete filling of air bag |
50 | 40 | 130 | >60 |
100 | 39 | 127 | 5 |
200 | 35 | 119 | 5.5 |
300 | 28 | 101 | 11 |
(the experimental proportion is tested by adopting the proportion with the medicament number of 2), and the experimental result analysis is that: the experimental result shows that the gas production is insufficient due to the too small water inflow, the water which is needed to be reacted is gasified into the air bag by the preliminary analysis of the reaction heat release, so that the water needed by the reaction is insufficient, in addition, when the water inflow is too large, the liquid water is gasified to be small due to the low reaction temperature, so that the gas charging speed is slowed down, and the water inflow is about 100 ml. That is, the inflow should be reduced while ensuring that the reaction gas production is sufficient, and the inflow in the wrist watch is controlled by the built-in spring, and the air bag swelled after the wrist watch is started forms negative pressure to guide the water to flow into the wrist watch.
2. The proportion of the reaction agent and the experimental result are as follows
Medicament proportion number | Sodium hydroxide weight (g) | Aluminum powder weight (g) | Weight of aluminum wire (g) | Ambient maximum water temperature T1 (. Degree.C) | Maximum temperature T2 (. Degree. C.) of reaction | Time S (seconds) for complete filling of air bag |
1 | 9.1 | 6.2 | 0 | 40 | 129 | 4.5 |
2 | 9.1 | 4.65 | 1.55 | 38 | 115 | 5 |
3 | 9.1 | 3.1 | 3.1 | 31 | 107 | 15 |
4 | 9.1 | 1.55 | 4.65 | 28 | 95 | >60 |
5 | 9.1 | 0 | 6.2 | 26 | 79 | >60 |
(the water yield of the experiment is 100 ml) analysis of experimental results: the experimental result shows that the reaction is more intense along with the increase of the aluminum powder proportion, the reaction instant heat release amount is increased, the reaction temperature is increased, the gas production speed is increased, and the first group and the second group of comparison experiments show that although the aluminum powder proportion is reduced, the gas production speed is not greatly influenced. Further, it was observed in the experiments that the more the aluminum powder mixture ratio was, the more the reaction solution boiled, the more the reaction substance was sprayed, wherein the first group of experiments were sprayed more strongly, the pressure in the air bag was initially maintained at a pressure of 10KP or more, but the air bag pressure in the first group of experiments had a tendency to decrease over time, in addition, there was liquid water condensation in the air bag over time, and the less water eventually condensed down with the decrease in aluminum powder mixture ratio, which suggests that part of the water was gasified and charged into the air bag due to the high temperature of the reaction, and the water vapor in the air bag was cooled into liquid water by the ambient water, resulting in a decrease in the air bag pressure. It is worth mentioning that after 5 hours, the air bag pressure is observed again, the air bag pressure of the experimental group with less aluminum powder proportion is higher instead, and the preliminary analysis is that the instant high temperature of the aluminum powder and sodium hydroxide reaction not only gasifies part of liquid water, but also takes away part of liquid water and part of aluminum powder, so that the reaction raw material is reduced, and the gas production is reduced.
Summary of the experiment: in the early stage of the inflatable air bag, a large amount of water vapor is actually introduced, so that adverse factors are not generated for life saving, the key is that after the pressure is reduced under the condensation of the water vapor, the pressure of hydrogen is required to be supplemented, so that the reaction is not too severe, a certain aluminum wire is required to be added after the condensation of the later water vapor, the air bag cannot react at the first time, and the pressure can be supplemented when the subsequent pressure is reduced, so that the gas production rate is ensured, the proportion of aluminum powder is ensured, and in the above groups of comparison tests, the proportion of the second group of agents is optimal in five groups.
Example 2
Referring to fig. 4-5, a life jacket alternative gas generating apparatus includes:
the device housing 26, the lower part of the device housing 26 is provided with a water inlet, the upper part is provided with an air outlet 27, the water inlet is closed by a trigger opening mechanism 29 and can be opened by triggering the trigger opening mechanism; a fluid channel is connected above the water inlet, and is a spiral channel; a plurality of check valves (namely, lower check valves 21) are arranged in the fluid channel, the outlet of the fluid channel is communicated with the inner cavity of the device shell 26, and an upper check valve 23 is arranged at the outlet of the fluid channel; the device housing is also provided with a thermal insulation means 22 (to prevent scalding).
A heat-sensitive metal sheet 24, the heat-sensitive metal sheet 24 is arranged above the upper check valve 23, and the heat-sensitive metal sheet 24 is deformed downwards by heat to press the outlet upper check valve 23 to close, so as to seal the fluid channel;
the support body is a hollow cavity, the lower part of the support body is arranged on the thermosensitive metal sheet 24, and the side part and the lower part of the support body are respectively provided with a channel which is communicated with the inner cavity of the device shell 26;
a hot melt film wrapping the side portion of the support body and closing the side portion passage, thereby forming a container with an upper opening in the inner cavity of the support body;
the gas generating reactant is placed in a container formed by the support body and the hot melt film, and the gas generating reactant can react rapidly to generate gas when meeting water. The gas generating reactants are metallic aluminum and sodium hydroxide. The sodium hydroxide is granular; the metal aluminum is a mixture of aluminum powder and aluminum wires.
The splash-proof filter screen 28, the splash-proof filter screen 28 is installed on the upper opening of the supporting body, and the splash-proof filter screen 28 is made of aluminum.
The traditional life jacket comprises a high-pressure gas storage steel cylinder, a pressure reducing valve and an air bag, the cost is mainly concentrated in the two parts, the life jacket replaces a gas producing device to adopt a chemical gas storage mode, the cost is low, the action principle is similar to that of the active life jacket, when the life jacket is used, the gas outlet 27 of the device is connected with the air bag, after the triggering opening mechanism 29 is triggered, water enters the device shell 26 and then passes through the upper part of the supporting body, the water enters the reaction container to react with a gas producing reactant, and the produced gas fills the inner cavity of the device shell and enters the air bag through the gas outlet 27, so that the life jacket is fully filled with the gas to enter a working state.
The present invention is not limited to the above-described embodiments, and various changes may be made without departing from the spirit of the present invention within the knowledge of those skilled in the art, and the contents after the changes still fall within the scope of the present invention.
Claims (10)
1. A chemical gas storage type underwater lifesaving device, which is characterized in that: the lifesaving equipment is an active lifesaving wristwatch or a lifejacket instead of a gas generating device;
a. active life-saving wristwatch
The active life saving wristwatch comprises an external wristwatch device and an internal gas generating device arranged in the external wristwatch device;
the external wristwatch device includes:
the lower base is connected with a watchband;
the upper watchcase comprises a connecting part at the periphery and an extending part formed by gathering the bottoms of the connecting parts towards the center, wherein the connecting part is sealed and connected to the upper part of the lower base by triggering a bouncing mechanism, a water inlet and a fluid channel connected with the water inlet are arranged on the extending part, at least one check valve is arranged in the fluid channel, and a check valve is arranged at the outlet of the fluid channel;
the upper dial plate is connected to the upper part of the upper watchcase connecting part in a sealing way through a trigger spring mechanism, the upper dial plate and the upper watchcase are enclosed to form a central cavity, and the outlet of the fluid channel is communicated with the central cavity;
the internal gas generating apparatus is mounted within the central cavity, comprising:
the thermosensitive metal sheet is fixed at the outlet of the fluid channel and deforms after being heated to close the upper check valve, so that the outlet of the fluid channel is closed;
the elastic support body is a hollow cavity capable of elastically deforming in the vertical direction, the elastic support body is in a compressed state, the upper part of the elastic support body is limited by an upper dial plate, the lower part of the elastic support body is arranged on the thermosensitive metal sheet, and the side parts and the lower part of the elastic support body are respectively provided with a channel to be communicated with the central cavity;
a hot melt film wrapped in a compressed state around the side of the elastic support body and closing the side channels, so that the inner cavity of the elastic support body forms a 'container' with only an upper opening;
the gas generating reactant is placed in the container and can react rapidly to generate gas when meeting water;
the air bag is folded or compressed in the central cavity, the heat-sensitive metal sheet, the elastic support body and the hot melt film are all wrapped in the air bag, and the inlet of the air bag is connected and communicated with the outlet of the fluid channel in a sealing way;
b. device for replacing gas production of life jacket
The life jacket substitute gas generating device comprises:
the device comprises a device shell, a water inlet and a gas outlet, wherein the lower part of the device shell is provided with the water inlet, the upper part of the device shell is provided with the gas outlet, and the water inlet is closed by triggering an opening mechanism and can be opened by triggering the opening mechanism; a fluid channel is connected above the water inlet, and an outlet of the fluid channel is communicated with an inner cavity of the device shell; at least one check valve is arranged in the fluid channel, and a check valve is arranged at the outlet of the fluid channel;
the thermosensitive metal sheet is fixed at the outlet of the fluid channel and deforms after being heated to close the check valve at the outlet of the flow channel, so that the outlet of the fluid channel is closed;
the support body is a hollow cavity, the lower part of the support body is arranged on the thermosensitive metal sheet, and the side part and the lower part of the support body are respectively provided with a channel to be communicated with the inner cavity of the device shell;
a hot melt film wrapping around the side of the support body and closing the side channels, so that the inner cavity of the support body forms an open-top "container";
the gas generating reactant is placed in the container, and the gas generating reactant can react rapidly to generate gas when meeting water.
2. A chemical gas storage type underwater rescue apparatus as defined in claim 1, wherein: the external wristwatch device further includes:
the connecting rope, one end of connecting rope is connected with lower base, the other end is connected with last watchcase, just connecting rope is in the lax state.
3. A chemical gas storage type underwater rescue apparatus as defined in claim 2, wherein: the connecting rope disc is arranged in a cavity formed between the lower base and the upper watchcase, the upper end of the connecting rope is connected with the extension part of the upper watchcase, and the other end of the connecting rope is connected with the upper surface of the lower base.
4. A chemical gas storage type underwater rescue apparatus as defined in claim 1, wherein: the elastic support body is a spring.
5. A chemical gas storage type underwater rescue apparatus as defined in claim 1 or 4, wherein:
the active life saving wristwatch further comprises a splash-proof filter screen, wherein the splash-proof filter screen is arranged on an upper opening of the elastic support body;
the life jacket substitute gas generating device further comprises a splash-proof filter screen, wherein the splash-proof filter screen is arranged on an upper opening of the support body.
6. A chemical gas storage type underwater rescue apparatus as defined in claim 1, wherein: the fluid channels of the active life-saving wristwatch and the life jacket substitute for the gas generating device are spiral channels; the heat-sensitive metal sheet is arranged above the check valve at the outlet of the runner, and the heat-sensitive metal sheet is deformed downwards by heating to press the check valve at the outlet to be closed.
7. A chemical gas storage type underwater rescue apparatus as defined in claim 1, wherein: the gas generating reactants of the active life saving wristwatch and the life jacket replacing gas generating device are metal aluminum and sodium hydroxide.
8. A chemical gas storage type underwater rescue apparatus as defined in claim 7, wherein: the sodium hydroxide is granular; the metal aluminum is a mixture of aluminum powder and aluminum wires; the mass of the sodium hydroxide is 9.1g; the mass of the aluminum powder is 4.65g; the aluminum wire is an aluminum wire with the diameter of 0.8mm, and the mass of the aluminum wire is 1.55g.
9. A chemical gas storage type underwater rescue apparatus as defined in claim 1, wherein: the upper dial plate is made of transparent materials, or an observation port made of transparent materials is arranged on the upper dial plate; the air bag is made of transparent materials, and the inner surface of the air bag is coated with phenolphthalein.
10. A chemical gas storage type underwater rescue apparatus as defined in claim 1, wherein: and a heat insulation device is arranged outside the device shell.
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CN109653704A (en) * | 2018-11-28 | 2019-04-19 | 山东省地质矿产勘查开发局第三水文地质工程地质大队(山东省鲁南地质工程勘察院) | Water stopper, layered water stopping device and system applied to geothermal well water pumping test |
CN110689775A (en) * | 2019-10-17 | 2020-01-14 | 山西科林矿山检测技术有限责任公司 | Compressed oxygen self-rescuer simulation drilling teaching instrument |
CN115337868A (en) * | 2021-05-14 | 2022-11-15 | 广东小天才科技有限公司 | Gas generating device |
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