CN107164584A - A kind of water-fastness ox-hide clothing leather processing technology - Google Patents
A kind of water-fastness ox-hide clothing leather processing technology Download PDFInfo
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- CN107164584A CN107164584A CN201710476403.7A CN201710476403A CN107164584A CN 107164584 A CN107164584 A CN 107164584A CN 201710476403 A CN201710476403 A CN 201710476403A CN 107164584 A CN107164584 A CN 107164584A
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/04—Soaking
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/08—Deliming; Bating; Pickling; Degreasing
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C15/00—Apparatus for chemical treatment or washing of hides, skins, or leather
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/04—Mineral tanning
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/28—Multi-step processes
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
The invention belongs to garment material processing technique field there is provided a kind of water-fastness ox-hide clothing leather processing technology, including：Ox-hide pre-treatment；Immersion；Deliming；Pickling；Tanning；Retanning；Rinsing；Dyeing and fat-liquoring；Dry, get damp again, getting rid of soft covering with paint.Ox-hide clothing leather produced by the present invention has a water-wash resistance, odorlessness, without the big advantage of oil stain, mechanical strength, and tannery environmental protection, and pollution-free, production process is old low, and technique is simple.
Description
Technical field
The invention belongs to garment material processing technique field, in particular it relates to a kind of water-fastness ox-hide clothing leather processing work
Skill.
Background technology
Ox-hide leather slightly has not as dress ornament material in people's daily life, the processing technology of ox-hide leather because of the difference of material
Together, the made rapid progress more because of society's great development, the processing of ox-hide leather has obtained long-range development, and the innovation of ox leather processing causes
The quality of ox-hide leather is improved so that ox leather products are increasingly subject to the pro-gaze of consumer.
Tanning is that rawhide is changed into an important step during leather, and the quality of tannery directly influences the thing of finished leather
Physicochemical performance, has important contact with the value of finished leather.Currently employed main tanning agent is chromic salt, chromic salt
Tanning agent has water-fastness, shelf-stable, there is good hydrothermal stability.
But it comes with some shortcomings：One is resource-constrained；Two be to cause environmental pollution, and chromium is used as a heavy metal species
The waste liquid produced during its tanning hide, scurf etc. all inevitably contains trivalent chromium, and these chromed leather wastes will necessarily be to life
State environmental pollution, and a kind of trivalent chromium easy oxidized generation Cr VI, therefore develop environment in use
The good tanning agent of friendly, tanning effect is present goal in research；Three be the shortcomings of price is high, tannery is complicated.
Clothing leather is required to multiple washing, but at present clothing leather repeatedly washing easily causes feel and is hardened, this be by
It is washed off in micromolecular compound therein, reduces leather hand feeling.
The content of the invention
For defect of the prior art, it is an object of the invention to provide a kind of water-fastness ox-hide clothing leather processing technology,
Ox-hide clothing leather produced by the present invention has a water-wash resistance, odorlessness, without the big advantage of oil stain, mechanical strength, and tannery
Environmental protection, pollution-free, production process is old low, and technique is simple.
A kind of water-fastness ox-hide clothing leather processing technology provided according to the present invention, the water-fastness ox-hide clothing leather processing
Technique comprises the following steps：
（1）Ox-hide pre-treatment：Ox-hide is checked, sees dermatotome whether there is breach, the whether rotten hair loss of fold place sutures breach, corruption
Rotten place is cut, and is removed the debris that ox-hide is stained with, is soaked shortening after suture again；
（2）Immersion：Ox-hide plus clear water are soaked, summer soaks 1 day, and winter need to soak 2-3 days；
（3）Deliming；
（4）Pickling：Ox-hide after deliming is entered into mass fraction to soak 2-4h in 10% hydrochloric acid solution, ox-hide is molten with hydrochloric acid
The volume ratio of liquid is 1:2-4；
（5）Tanning：To step（4）Acid solution in plus aluminium tanningagent 3.0-4.2%, soak 30 minutes, add 0.8-1.3% formic acid
Sodium, soaks 30 minutes, adds 0.3-0.6% sodium bicarbonate, soaks 30 minutes, then heats to 30-40 DEG C, stirs 400-
600min；
（6）Retanning：Liquor ratio 160-190%, plus small molecule propenyl retanning agent 1-2%, 50 DEG C of rotation 1.5-2h are reconciled, are added
1.1-3.2% retanning modifying agent and leather machine property improver 0.2-0.6%, rotates 60-70min, adds 0.2-1.0%
Sodium bicarbonate adjust pH value to 4.2-5.8,60-80min is stirred, with 100% vexed washing 2 times, each 10min；
（7）Rinsing：Carried out using oxalic acid after rinsing 60min, then carry out neutralisation treatment；
（8）Dyeing and fat-liquoring：Liquor ratio 100%, adds leather black NG, 1.2-1.5% levelling agent peregal, 50 DEG C of rotation 60-
90min, adds synthetic fat liquor 8% and 1.0-2.4% sulfited fish oil, and 50 DEG C of rotation 50-55min add oil
Fat fixative 0.5%, rotates 30min, adds 1.0-2.0% first acid for adjusting pH value 3.0-4.0, stirs 60-70min；
（9）Dry, get damp again, getting rid of soft covering with paint.
Preferably, the step deliming is specially：
A, the ox-hide after the immersion is subjected in rotary drum deliming handled 1-2 hour, the processing progress, institute in deliming agent
State deliming agent is included by the quality of raw cash skin：Water 50wt%, first ammonia deliming agent 0.5wt%；Sulfuric acid 0.3wt%；
Carry out sofening treatment 1-2 hours after B, deliming processing in softening agent, the softening agent is by accounting for raw cash skin percentage by weight
Meter includes：Water 100wt%；Degreasing agent 0.3wt%；Macerating enzyme 0.3wt%；1398 protein acid 0.03wt%；
Soaked after C, washing in 0.6wt% tannings accelerator and 0.2 degreasing agent 60 minutes, then add 0.6wt% formic acid
Processing 35 minutes, adds 1.3wt% sulfuric acid twice, 30 minutes per treatment；Rotary drum turns 60 minutes, stops 30 minutes, then turn 60 points
Clock, water squeezing after stopping drum overnight.
Preferably, drum is carried out out after the tanning step successively to take horse standing, press water to get rid of soft, split and shaving deburring
It is 1.7-1.8cm that leather bilayer thickness is controlled in step, the split step, then carries out shaving process, controls the leather
Bilayer thickness be 1.2-1.3cm.
Preferably, the retanning modifying agent is any one of sorbierite, D-pantothenyl aleohol, oleamide.
Preferably, the retanning modifying agent is sorbierite.
Preferably, the drying is dried under the conditions of 40-60 DEG C.
Preferably, the leather machine property improver is naringin or amion acetic acid.
Preferably, the grease fixative is any one of D-sorbite, mannitol, aluminate coupling agent.
Compared with prior art, the present invention has following beneficial effect：
（1）The water-fastness ox-hide clothing leather processing technology that the present invention is provided comprises the following steps：Ox-hide pre-treatment；Immersion：By ox
Skin adds clear water to soak, and summer soaks 1 day, and winter need to soak 2-3 days；Deliming；Pickling：It is into mass fraction by the ox-hide after deliming
Soak 2-4h in 10% hydrochloric acid solution, the volume ratio of ox-hide and hydrochloric acid solution is 1:2-4；Tanning：To acid solution in plus aluminium tanningagent
3.0-4.2%, soaks 30 minutes, adds 0.8-1.3% sodium formates, soaks 30 minutes, adds 0.3-0.6% little Su
Beat, soak 30 minutes, then heat to 30-40 DEG C, stir 400-600min；Retanning：Reconcile liquor ratio 160-190%, plus small point
Sub- propenyl retanning agent 1-2%, 50 DEG C of rotation 1.5-2h, adds 1.1-3.2% retanning modifying agent and leather machine performance
Enhancer 0.2-0.6%, rotates 60-70min, and the sodium bicarbonate for adding 0.2-1.0% adjusts pH value to 4.2-5.8, stirs 60-
80min, with 100% it is vexed washing 2 times, each 10min；Rinsing：Carried out using oxalic acid after rinsing 60min, then carry out neutralisation treatment；
Dyeing and fat-liquoring：Liquor ratio 100%, adds leather black NG, 1.2-1.5% levelling agent peregal, 50 DEG C of rotation 60-90min, then adds
Enter synthetic fat liquor 8% and 1.0-2.4% sulfited fish oil, 50 DEG C of rotation 50-55min add grease fixative
0.5%, 30min is rotated, 1.0-2.0% first acid for adjusting pH value 3.0-4.0 is added, 60-70min is stirred；Dry, get damp again, get rid of
Soft covering with paint.Present invention process does not produce waste residue, low toxic and environment-friendly without using containing Chroma-Pak；
（2）Ox-hide clothing leather produced by the present invention has a water-wash resistance, odorlessness, without the big advantage of oil stain, mechanical strength, and tan
Process environmental protection processed, pollution-free, production process is old low, and technique is simple.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention
Rather than limitation the scope of the present invention.
Embodiment 1
A kind of water-fastness ox-hide clothing leather processing technology that the present embodiment is provided, the water-fastness ox-hide clothing leather processing technology bag
Include following steps：
（1）Ox-hide pre-treatment：Ox-hide is checked, sees dermatotome whether there is breach, the whether rotten hair loss of fold place sutures breach, corruption
Rotten place is cut, and is removed the debris that ox-hide is stained with, is soaked shortening after suture again；
（2）Immersion：Ox-hide plus clear water are soaked, summer soaks 1 day, and winter need to soak 2-3 days；
（3）Deliming；
（4）Pickling：Ox-hide after deliming is entered into mass fraction to soak 2-4h in 10% hydrochloric acid solution, ox-hide is molten with hydrochloric acid
The volume ratio of liquid is 1:4；
（5）Tanning：To step（4）Acid solution in plus aluminium tanningagent 4.2%, soak 30 minutes, add 0.8% sodium formate, soak
30 minutes, add 0.6% sodium bicarbonate, soak 30 minutes, then heat to 30-40 DEG C, stir 400-600min；
（6）Retanning：Liquor ratio 190%, plus small molecule propenyl retanning agent 1% are reconciled, 50 DEG C of rotation 1.5-2h add 3.2%
Retanning modifying agent and leather machine property improver 0.2%, rotate 60-70min, add 1.0% sodium bicarbonate regulation pH value
To 4.2-5.8,60-80min is stirred, with 100% vexed washing 2 times, each 10min；
（7）Rinsing：Carried out using oxalic acid after rinsing 60min, then carry out neutralisation treatment；
（8）Dyeing and fat-liquoring：Liquor ratio 100%, adds leather black NG, 1.5% levelling agent peregal, 50 DEG C of rotation 60-90min,
The sulfited fish oil of synthetic fat liquor 8% and 1.0% is added, 50 DEG C of rotation 50-55min add grease fixative
0.5%, 30min is rotated, 2.0% first acid for adjusting pH value 3.0-4.0 is added, 60-70min is stirred；
（9）Dry, get damp again, getting rid of soft covering with paint.
The step deliming is specially：
A, the ox-hide after the immersion is subjected in rotary drum deliming handled 1-2 hour, the processing progress, institute in deliming agent
State deliming agent is included by the quality of raw cash skin：Water 50wt%, first ammonia deliming agent 0.5wt%；Sulfuric acid 0.3wt%；
Carry out sofening treatment 1-2 hours after B, deliming processing in softening agent, the softening agent is by accounting for raw cash skin percentage by weight
Meter includes：Water 100wt%；Degreasing agent 0.3wt%；Macerating enzyme 0.3wt%；1398 protein acid 0.03wt%；
Soaked after C, washing in 0.6wt% tannings accelerator and 0.2 degreasing agent 60 minutes, then add 0.6wt% formic acid
Processing 35 minutes, adds 1.3wt% sulfuric acid twice, 30 minutes per treatment；Rotary drum turns 60 minutes, stops 30 minutes, then turn 60 points
Clock, water squeezing after stopping drum overnight.
Drum is carried out out after the tanning step successively to take horse standing, press water to get rid of soft, split and shaving deburring step, institute
State and control leather bilayer thickness to be 1.7-1.8cm in split step, then carry out shaving process, control the double thickness of the leather
Spend for 1.2-1.3cm.
The retanning modifying agent is sorbierite.
The drying is dried under the conditions of 40-60 DEG C.
The leather machine property improver is naringin or amion acetic acid.
The grease fixative is any one of D-sorbite, mannitol, aluminate coupling agent.
Embodiment 2
A kind of water-fastness ox-hide clothing leather processing technology that the present embodiment is provided, the water-fastness ox-hide clothing leather processing technology bag
Include following steps：
（1）Ox-hide pre-treatment：Ox-hide is checked, sees dermatotome whether there is breach, the whether rotten hair loss of fold place sutures breach, corruption
Rotten place is cut, and is removed the debris that ox-hide is stained with, is soaked shortening after suture again；
（2）Immersion：Ox-hide plus clear water are soaked, summer soaks 1 day, and winter need to soak 2-3 days；
（3）Deliming；
（4）Pickling：Ox-hide after deliming is entered into mass fraction to soak 2-4h in 10% hydrochloric acid solution, ox-hide is molten with hydrochloric acid
The volume ratio of liquid is 1:2；
（5）Tanning：To step（4）Acid solution in plus aluminium tanningagent 3.0%, soak 30 minutes, add 1.3% sodium formate, soak
30 minutes, add 0.3% sodium bicarbonate, soak 30 minutes, then heat to 30-40 DEG C, stir 400-600min；
（6）Retanning：Liquor ratio 160%, plus small molecule propenyl retanning agent 2% are reconciled, 50 DEG C of rotation 1.5-2h add 1.1%
Retanning modifying agent and leather machine property improver 0.6%, rotate 60-70min, add 0.2% sodium bicarbonate regulation pH value
To 4.2-5.8,60-80min is stirred, with 100% vexed washing 2 times, each 10min；
（7）Rinsing：Carried out using oxalic acid after rinsing 60min, then carry out neutralisation treatment；
（8）Dyeing and fat-liquoring：Liquor ratio 100%, adds leather black NG, 1.2% levelling agent peregal, 50 DEG C of rotation 60-90min,
The sulfited fish oil of synthetic fat liquor 8% and 2.4% is added, 50 DEG C of rotation 50-55min add grease fixative
0.5%, 30min is rotated, 1.0% first acid for adjusting pH value 3.0-4.0 is added, 60-70min is stirred；
（9）Dry, get damp again, getting rid of soft covering with paint.
The step deliming is specially：
A, the ox-hide after the immersion is subjected in rotary drum deliming handled 1-2 hour, the processing progress, institute in deliming agent
State deliming agent is included by the quality of raw cash skin：Water 50wt%, first ammonia deliming agent 0.5wt%；Sulfuric acid 0.3wt%；
Carry out sofening treatment 1-2 hours after B, deliming processing in softening agent, the softening agent is by accounting for raw cash skin percentage by weight
Meter includes：Water 100wt%；Degreasing agent 0.3wt%；Macerating enzyme 0.3wt%；1398 protein acid 0.03wt%；
Soaked after C, washing in 0.6wt% tannings accelerator and 0.2 degreasing agent 60 minutes, then add 0.6wt% formic acid
Processing 35 minutes, adds 1.3wt% sulfuric acid twice, 30 minutes per treatment；Rotary drum turns 60 minutes, stops 30 minutes, then turn 60 points
Clock, water squeezing after stopping drum overnight.
Drum is carried out out after the tanning step successively to take horse standing, press water to get rid of soft, split and shaving deburring step, institute
State and control leather bilayer thickness to be 1.7-1.8cm in split step, then carry out shaving process, control the double thickness of the leather
Spend for 1.2-1.3cm.
The retanning modifying agent is D-pantothenyl aleohol.
The drying is dried under the conditions of 40-60 DEG C.
The leather machine property improver is naringin or amion acetic acid.
The grease fixative is any one of D-sorbite, mannitol, aluminate coupling agent.
Embodiment 3
A kind of water-fastness ox-hide clothing leather processing technology that the present embodiment is provided, the water-fastness ox-hide clothing leather processing technology bag
Include following steps：
（1）Ox-hide pre-treatment：Ox-hide is checked, sees dermatotome whether there is breach, the whether rotten hair loss of fold place sutures breach, corruption
Rotten place is cut, and is removed the debris that ox-hide is stained with, is soaked shortening after suture again；
（2）Immersion：Ox-hide plus clear water are soaked, summer soaks 1 day, and winter need to soak 2-3 days；
（3）Deliming；
（4）Pickling：Ox-hide after deliming is entered into mass fraction to soak 2-4h in 10% hydrochloric acid solution, ox-hide is molten with hydrochloric acid
The volume ratio of liquid is 1:2-4；
（5）Tanning：To step（4）Acid solution in plus aluminium tanningagent 3.5%, soak 30 minutes, add 0.9% sodium formate, soak
30 minutes, add 0.5% sodium bicarbonate, soak 30 minutes, then heat to 30-40 DEG C, stir 400-600min；
（6）Retanning：Liquor ratio 170%, plus small molecule propenyl retanning agent 1% are reconciled, 50 DEG C of rotation 1.5-2h add 2.2%
Retanning modifying agent and leather machine property improver 0.4%, rotate 60-70min, add 0.5% sodium bicarbonate regulation pH value
To 4.2-5.8,60-80min is stirred, with 100% vexed washing 2 times, each 10min；
（7）Rinsing：Carried out using oxalic acid after rinsing 60min, then carry out neutralisation treatment；
（8）Dyeing and fat-liquoring：Liquor ratio 100%, adds leather black NG, 1.3% levelling agent peregal, 50 DEG C of rotation 60-90min,
The sulfited fish oil of synthetic fat liquor 8% and 1.7% is added, 50 DEG C of rotation 50-55min add grease fixative
0.5%, 30min is rotated, 1.8% first acid for adjusting pH value 3.0-4.0 is added, 60-70min is stirred；
（9）Dry, get damp again, getting rid of soft covering with paint.
The step deliming is specially：
A, the ox-hide after the immersion is subjected in rotary drum deliming handled 1-2 hour, the processing progress, institute in deliming agent
State deliming agent is included by the quality of raw cash skin：Water 50wt%, first ammonia deliming agent 0.5wt%；Sulfuric acid 0.3wt%；
Carry out sofening treatment 1-2 hours after B, deliming processing in softening agent, the softening agent is by accounting for raw cash skin percentage by weight
Meter includes：Water 100wt%；Degreasing agent 0.3wt%；Macerating enzyme 0.3wt%；1398 protein acid 0.03wt%；
Soaked after C, washing in 0.6wt% tannings accelerator and 0.2 degreasing agent 60 minutes, then add 0.6wt% formic acid
Processing 35 minutes, adds 1.3wt% sulfuric acid twice, 30 minutes per treatment；Rotary drum turns 60 minutes, stops 30 minutes, then turn 60 points
Clock, water squeezing after stopping drum overnight.
Drum is carried out out after the tanning step successively to take horse standing, press water to get rid of soft, split and shaving deburring step, institute
State and control leather bilayer thickness to be 1.7-1.8cm in split step, then carry out shaving process, control the double thickness of the leather
Spend for 1.2-1.3cm.
The retanning modifying agent is any one of sorbierite, D-pantothenyl aleohol, oleamide.
The retanning modifying agent is sorbierite.
The drying is dried under the conditions of 40-60 DEG C.
The leather machine property improver is naringin or amion acetic acid.
The grease fixative is any one of D-sorbite, mannitol, aluminate coupling agent.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of water-fastness ox-hide clothing leather processing technology, it is characterised in that：The water-fastness ox-hide clothing leather processing technology bag
Include following steps：
（1）Ox-hide pre-treatment：Ox-hide is checked, sees dermatotome whether there is breach, the whether rotten hair loss of fold place sutures breach, corruption
Rotten place is cut, and is removed the debris that ox-hide is stained with, is soaked shortening after suture again；
（2）Immersion：Ox-hide plus clear water are soaked, summer soaks 1 day, and winter need to soak 2-3 days；
（3）Deliming；
（4）Pickling：Ox-hide after deliming is entered into mass fraction to soak 2-4h in 10% hydrochloric acid solution, ox-hide is molten with hydrochloric acid
The volume ratio of liquid is 1:2-4；
（5）Tanning：To step（4）Acid solution in plus aluminium tanningagent 3.0-4.2%, soak 30 minutes, add 0.8-1.3% formic acid
Sodium, soaks 30 minutes, adds 0.3-0.6% sodium bicarbonate, soaks 30 minutes, then heats to 30-40 DEG C, stirs 400-
600min；
（6）Retanning：Liquor ratio 160-190%, plus small molecule propenyl retanning agent 1-2%, 50 DEG C of rotation 1.5-2h are reconciled, are added
1.1-3.2% retanning modifying agent and leather machine property improver 0.2-0.6%, rotates 60-70min, adds 0.2-1.0%
Sodium bicarbonate adjust pH value to 4.2-5.8,60-80min is stirred, with 100% vexed washing 2 times, each 10min；
（7）Rinsing：Carried out using oxalic acid after rinsing 60min, then carry out neutralisation treatment；
（8）Dyeing and fat-liquoring：Liquor ratio 100%, adds leather black NG, 1.2-1.5% levelling agent peregal, 50 DEG C of rotation 60-
90min, adds synthetic fat liquor 8% and 1.0-2.4% sulfited fish oil, and 50 DEG C of rotation 50-55min add oil
Fat fixative 0.5%, rotates 30min, adds 1.0-2.0% first acid for adjusting pH value 3.0-4.0, stirs 60-70min；
（9）Dry, get damp again, getting rid of soft covering with paint.
2. water-fastness ox-hide clothing leather processing technology according to claim 1, it is characterised in that：The step deliming is specific
For：
A, the ox-hide after the immersion is subjected in rotary drum deliming handled 1-2 hour, the processing progress, institute in deliming agent
State deliming agent is included by the quality of raw cash skin：Water 50wt%, first ammonia deliming agent 0.5wt%；Sulfuric acid 0.3wt%；
Carry out sofening treatment 1-2 hours after B, deliming processing in softening agent, the softening agent is by accounting for raw cash skin percentage by weight
Meter includes：Water 100wt%；Degreasing agent 0.3wt%；Macerating enzyme 0.3wt%；1398 protein acid 0.03wt%；
Soaked after C, washing in 0.6wt% tannings accelerator and 0.2 degreasing agent 60 minutes, then add 0.6wt% formic acid
Processing 35 minutes, adds 1.3wt% sulfuric acid twice, 30 minutes per treatment；Rotary drum turns 60 minutes, stops 30 minutes, then turn 60 points
Clock, water squeezing after stopping drum overnight.
3. water-fastness ox-hide clothing leather processing technology according to claim 1, it is characterised in that：After the tanning step
Drum is carried out out successively to take horse standing, press water to get rid of control leather bilayer in soft, split and shaving deburring step, the split step
Thickness is 1.7-1.8cm, then carries out shaving process, and the bilayer thickness for controlling the leather is 1.2-1.3cm.
4. water-fastness ox-hide clothing leather processing technology according to claim 1, it is characterised in that：The retanning modifying agent is
Any one of sorbierite, D-pantothenyl aleohol, oleamide.
5. water-fastness ox-hide clothing leather processing technology according to claim 4, it is characterised in that：The retanning modifying agent is
Sorbierite.
6. water-fastness ox-hide clothing leather processing technology according to claim 1, it is characterised in that：The drying is in 40-
It is dried under the conditions of 60 DEG C.
7. water-fastness ox-hide clothing leather processing technology according to claim 1, it is characterised in that：The leather machine performance
Enhancer is naringin or amion acetic acid.
8. water-fastness ox-hide clothing leather processing technology according to claim 1, it is characterised in that：The grease fixative is
Any one of D-sorbite, mannitol, aluminate coupling agent.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710476403.7A CN107164584A (en) | 2017-06-21 | 2017-06-21 | A kind of water-fastness ox-hide clothing leather processing technology |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710476403.7A CN107164584A (en) | 2017-06-21 | 2017-06-21 | A kind of water-fastness ox-hide clothing leather processing technology |
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| CN107164584A true CN107164584A (en) | 2017-09-15 |
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| CN201710476403.7A Withdrawn CN107164584A (en) | 2017-06-21 | 2017-06-21 | A kind of water-fastness ox-hide clothing leather processing technology |
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| CN (1) | CN107164584A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107326120A (en) * | 2017-07-28 | 2017-11-07 | 合肥布竹梦依服装贸易有限公司 | A kind of water-fastness ox-hide clothing leather processing technology |
| CN112237362A (en) * | 2019-07-16 | 2021-01-19 | 上海水星家用纺织品股份有限公司 | Preparation method of cow leather summer sleeping mat with self-purification function and product |
| CN113308582A (en) * | 2021-05-18 | 2021-08-27 | 辽宁富新新材料有限公司 | Light sweet automobile leather with special low odor and production process thereof |
| CN113373269A (en) * | 2021-06-15 | 2021-09-10 | 河南中牛实业有限公司 | Production method of environment-friendly semi-vegetable tanning oil wax leather |
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| CN103215391A (en) * | 2013-04-23 | 2013-07-24 | 何裕华 | Non-chromium leather tanning method |
| CN106222329A (en) * | 2016-09-22 | 2016-12-14 | 湖州东方皮革有限公司 | A kind of environment-friendly type sheepskin garment leather processing technique |
| CN106282439A (en) * | 2016-09-22 | 2017-01-04 | 湖州东方皮革有限公司 | A kind of water-fastness, environment-friendly type clothing leather processing technique |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103215391A (en) * | 2013-04-23 | 2013-07-24 | 何裕华 | Non-chromium leather tanning method |
| CN106222329A (en) * | 2016-09-22 | 2016-12-14 | 湖州东方皮革有限公司 | A kind of environment-friendly type sheepskin garment leather processing technique |
| CN106282439A (en) * | 2016-09-22 | 2017-01-04 | 湖州东方皮革有限公司 | A kind of water-fastness, environment-friendly type clothing leather processing technique |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107326120A (en) * | 2017-07-28 | 2017-11-07 | 合肥布竹梦依服装贸易有限公司 | A kind of water-fastness ox-hide clothing leather processing technology |
| CN112237362A (en) * | 2019-07-16 | 2021-01-19 | 上海水星家用纺织品股份有限公司 | Preparation method of cow leather summer sleeping mat with self-purification function and product |
| CN113308582A (en) * | 2021-05-18 | 2021-08-27 | 辽宁富新新材料有限公司 | Light sweet automobile leather with special low odor and production process thereof |
| CN113373269A (en) * | 2021-06-15 | 2021-09-10 | 河南中牛实业有限公司 | Production method of environment-friendly semi-vegetable tanning oil wax leather |
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Application publication date: 20170915 |