CN107163269A - It is a kind of to the cohesive inorganic agent of PE plastics - Google Patents
It is a kind of to the cohesive inorganic agent of PE plastics Download PDFInfo
- Publication number
- CN107163269A CN107163269A CN201710326578.XA CN201710326578A CN107163269A CN 107163269 A CN107163269 A CN 107163269A CN 201710326578 A CN201710326578 A CN 201710326578A CN 107163269 A CN107163269 A CN 107163269A
- Authority
- CN
- China
- Prior art keywords
- inorganic agent
- plastics
- phosphate
- environmentally friendly
- cohesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
- C09D123/28—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
- C08J2423/28—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
Abstract
The invention discloses a kind of to the cohesive inorganic agent of PE plastics, formula is by weight percentage：Chloridized polyolefin 5% 20%, the polyester phosphate with terminal hydroxy group 5% 20%, acrylated phosphate 5% 20%, environmentally friendly solvent 40% 80%.The present invention has good adherence to various polyolefine materials due to chloridized polyolefin, adhesion promoter is used as using the polyester phosphate with terminal hydroxy group, acrylated phosphate simultaneously, be conducive to further strengthening the adhesion effect, adherence of the PE frostings to coating or ink can be improved, improve its aesthetic property, adhesive force up to 3B grades and more than, in addition the inorganic agent act on PE frostings method it is simple, it is with low cost, be conducive to a wide range of popularization and application of PE plastics.
Description
Technical field
It is more particularly to a kind of to the cohesive inorganic agent of PE plastics the present invention relates to polyethylene surface treatment field.
Background technology
Polyethylene abbreviation PE English names:Polyethylene, polyethylene (PE) is one of five big synthetic resin, is China
The kind that production capacity is maximum in synthetic resin, import volume is most.Polyethylene is broadly divided into LLDPE (LLDPE), low
Density polyethylene (LDPE), high density polyethylene (HDPE) (HDPE) three major types；Corrosion resistance, electrical insulating property (especially high-frequency insulation) is excellent
It is good, glass fiber reinforcement can be used with chlorination, radiation modification.The fusing point of low-pressure polyethylene, rigidity, hardness and intensity are higher, inhale
It is aqueous small, there are good electrical property and radiation resistance；The flexibility of polyethylene from high pressure process, elongation, impact strength and permeability compared with
It is good；Ultra-high molecular weight polyethylene impact strength is high, and endurance is wear-resisting.Low-pressure polyethylene is suitable to make corrosion-resistant part and insulation
Part；Polyethylene from high pressure process is suitable to make film etc., and ultra-high molecular weight polyethylene is suitable to make damping, wear-resisting and driving parts etc..
It is excellent and with low cost with the plastics same performance of polyethylene production, it is resistance to fall, intensity is high, will not be broken, but at present
To large-scale application, trace it to its cause and be that its polarity is very low, paint on the market is to vinyon at present, especially
It is that high-density polyethylene plastics does not have adhesive force, decoration and protection due to coating and ink not attractive in appearance, this just have impact on
The popularization of vinyon and use, and current processing method mainly carries out flame treatment-i.e. with fiery to PE frostings
Flame is roasted to PE frostings, with thermal-flame corrosion PE frostings-so as to increase its surface energy-so that paint,
Coating, ink etc. are attached to above PE plastics, are come out so as to make various beautiful patterns attractive in appearance, but the method danger of flame treatment
Nearly, not environmentally, processing quality is unstable, it is impossible to which ground is not burnt in guarantee, while inefficiency, is not suitable with wide model application.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of to the cohesive inorganic agent of PE plastics, the inorganic agent can be carried
High PE frostings improve its aesthetic property to the adherence of coating or ink, and the inorganic agent acts on PE frostings in addition
Method is simple, with low cost, is conducive to a wide range of popularization and application of PE plastics.
In order to solve the above-mentioned technical problem, the technical scheme is that a kind of to the cohesive inorganic agent of PE plastics,
Its formula is as follows by weight percentage：
Chloridized polyolefin 5%-20%
Polyester phosphate 5%-20% with terminal hydroxy group
Acrylated phosphate 5%-20%
Environmentally friendly solvent 40%-80%
Preferably, the one kind of chloridized polyolefin in haloflex, chlorinated polypropylene.
Preferably, environmentally friendly solvent is selected from least one of ether-ether class, esters solvent, polyalcohol binary esters solvent.
It is further preferred that environmentally friendly solvent is selected from dimethyl carbonate, ethyl acetate, butyl acetate, propylene glycol monomethyl ether acetic acid
At least one of ester, propylene glycol monomethyl ether.
A kind of application method to the cohesive inorganic agent of PE plastics, inorganic agent is entered with water by 5-10% weight ratio
Row dilution, direct spraying is in PE grounds after dilution.
Using above-mentioned technical proposal, because chloridized polyolefin has good adherence to various polyolefine materials, simultaneously
Using the polyester phosphate with terminal hydroxy group, acrylated phosphate as adhesion promoter, be conducive to further strengthening attachment effect
Really, adherence of the PE frostings to coating or ink can be improved, its aesthetic property is improved, adhesive force up to 3B grades and more than, separately
The method that the outer inorganic agent acts on PE frostings is simple, with low cost, is conducive to a wide range of popularization and application of PE plastics.
Embodiment
The embodiment to the present invention is described further below.Herein it should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but does not constitute limitation of the invention.In addition, invention described below
As long as involved technical characteristic does not constitute conflict and can be just mutually combined each other in each embodiment.
Embodiment 1
The present embodiment to the cohesive inorganic agent of PE plastics, its formula is as follows by weight percentage：
Haloflex 5%
Polyester phosphate 5% with terminal hydroxy group
Acrylated phosphate 15%
Dimethyl carbonate 80%
Said components are mixed in a reservoir, is stirred after mixing and obtains the inorganic agent of the present embodiment.It incite somebody to action this
The application method of inorganic agent made from embodiment is：Inorganic agent is diluted with water by 5% weight ratio, directly sprayed after dilution
It is applied to PE grounds.
Embodiment 2
The present embodiment to the cohesive inorganic agent of PE plastics, its formula is as follows by weight percentage：
Chlorinated polypropylene 10%
Polyester phosphate 15% with terminal hydroxy group
Acrylated phosphate 20%
Ethyl acetate 55%
Said components are mixed in a reservoir, is stirred after mixing and obtains the inorganic agent of the present embodiment.It incite somebody to action this
The application method of inorganic agent made from embodiment is：Inorganic agent is diluted with water by 6% weight ratio, directly sprayed after dilution
It is applied to PE grounds.
Embodiment 3
The present embodiment to the cohesive inorganic agent of PE plastics, its formula is as follows by weight percentage：
Haloflex 15%
Polyester phosphate 10% with terminal hydroxy group
Acrylated phosphate 5%
Propylene glycol methyl ether acetate 70%
Said components are mixed in a reservoir, is stirred after mixing and obtains the inorganic agent of the present embodiment.It incite somebody to action this
The application method of inorganic agent made from embodiment is：Inorganic agent is diluted with water by 8% weight ratio, directly sprayed after dilution
It is applied to PE grounds.
Embodiment 4
The present embodiment to the cohesive inorganic agent of PE plastics, its formula is as follows by weight percentage：
Chlorinated polypropylene 20%
Polyester phosphate 20% with terminal hydroxy group
Acrylated phosphate 20%
Propylene glycol monomethyl ether 40%
Said components are mixed in a reservoir, is stirred after mixing and obtains the inorganic agent of the present embodiment.It incite somebody to action this
The application method of inorganic agent made from embodiment is：Inorganic agent is diluted with water by 10% weight ratio, after dilution directly
It is sprayed at PE grounds.
Inorganic agent obtained by above-described embodiment 1-4 is surface-treated by its application method to PE grounds, then used
Identical coating is smeared, and its adhesive force is tested, and is as a result followed successively by and is represented with 1#, 2#, 3#, 4#, while with not
PE grounds daub through processing as a comparison case 1, is represented with 5#, and daub is as a comparison after barbecue with PE surfaces
Example 2, is represented with 6#, and the test of adhesive force is used《The scratch experiment of GBT9286-1998 paint and varnish paint films》, it is as a result as follows：
Result judgement：
It is required that adhesive force is qualified when reaching more than 3B.
5B- scribing edges are smooth, come off at the edge and intersection of line without coating；
4B- comes off in the coating that the intersection of line has small pieces, and the gross area that comes off is less than 5%；
3B- comes off in the coating that there are small pieces at the edge and intersection of line, and come off the gross area 5%~15% it
Between；
2B- has sheet of coating to come off at the edge and intersection of line, and come off the gross area 15%~35% it
Between；
1B- has sheet of coating to come off at the edge and intersection of line, and come off the gross area 35%~65% it
Between；
0B- has sheet of coating to come off at the edge and intersection of line, and the gross area that comes off is more than 65%.
Remarks：When test area is smaller, not requirement must draw 10 lattices, can be according to the small big of test area
It is determined that drawing the number of lattice.
Embodiments of the present invention are explained in detail above, but the invention is not restricted to described embodiment.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out many
Change, modification, replacement and modification are planted, are still fallen within protection scope of the present invention.
Claims (5)
1. it is a kind of to the cohesive inorganic agent of PE plastics, it is characterised in that formula is as follows by weight percentage：
Chloridized polyolefin 5%-20%
Polyester phosphate 5%-20% with terminal hydroxy group
Acrylated phosphate 5%-20%
Environmentally friendly solvent 40%-80%.
2. inorganic agent according to claim 1, it is characterised in that the chloridized polyolefin is selected from haloflex, chlorination
One kind in polypropylene.
3. inorganic agent according to claim 1 or 2, it is characterised in that it is molten that the environmentally friendly solvent is selected from ether-ether class, esters
At least one of agent, polyalcohol binary esters solvent.
4. inorganic agent according to claim 1 or 2, it is characterised in that the environmentally friendly solvent is selected from dimethyl carbonate, acetic acid
At least one of ethyl ester, butyl acetate, propylene glycol methyl ether acetate, propylene glycol monomethyl ether.
5. to the application method of the cohesive inorganic agent of PE plastics described in a kind of claim 1, it is characterised in that by inorganic agent
It is diluted with water by 5-10% weight ratio, direct spraying is in PE grounds after dilution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710326578.XA CN107163269A (en) | 2017-05-10 | 2017-05-10 | It is a kind of to the cohesive inorganic agent of PE plastics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710326578.XA CN107163269A (en) | 2017-05-10 | 2017-05-10 | It is a kind of to the cohesive inorganic agent of PE plastics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107163269A true CN107163269A (en) | 2017-09-15 |
Family
ID=59813869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710326578.XA Pending CN107163269A (en) | 2017-05-10 | 2017-05-10 | It is a kind of to the cohesive inorganic agent of PE plastics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107163269A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109351568A (en) * | 2018-10-12 | 2019-02-19 | 深圳天成真空技术有限公司 | A kind of automobile lamp coating process |
| CN111423754A (en) * | 2020-04-29 | 2020-07-17 | 传美讯电子科技（珠海）有限公司 | Coating liquid for promoting UV ink adhesion and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4428382C2 (en) * | 1994-08-11 | 1996-09-19 | Henkel Kgaa | Use of an aqueous primer for non-polar plastics |
| JPH11323262A (en) * | 1998-05-11 | 1999-11-26 | Hitachi Kasei Polymer Co Ltd | Primer composition |
| CN101613478A (en) * | 2009-07-28 | 2009-12-30 | 西安交通大学 | The preparation method of emulsion type adhesion promoter for polyolefin plastics |
| CN101809072A (en) * | 2007-10-29 | 2010-08-18 | 巴斯夫公司 | Composite articles having excellent adhesion strength and methods of forming the same |
| CN103333544A (en) * | 2013-06-07 | 2013-10-02 | 中国人民银行印制科学技术研究所 | Ultraviolet curing printing ink as well as preparation method and security product thereof |
| CN105524531A (en) * | 2016-01-11 | 2016-04-27 | 上海乘鹰新材料有限公司 | PP substrate base-coating paint composition and preparation method thereof |
-
2017
- 2017-05-10 CN CN201710326578.XA patent/CN107163269A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4428382C2 (en) * | 1994-08-11 | 1996-09-19 | Henkel Kgaa | Use of an aqueous primer for non-polar plastics |
| JPH11323262A (en) * | 1998-05-11 | 1999-11-26 | Hitachi Kasei Polymer Co Ltd | Primer composition |
| CN101809072A (en) * | 2007-10-29 | 2010-08-18 | 巴斯夫公司 | Composite articles having excellent adhesion strength and methods of forming the same |
| CN101613478A (en) * | 2009-07-28 | 2009-12-30 | 西安交通大学 | The preparation method of emulsion type adhesion promoter for polyolefin plastics |
| CN103333544A (en) * | 2013-06-07 | 2013-10-02 | 中国人民银行印制科学技术研究所 | Ultraviolet curing printing ink as well as preparation method and security product thereof |
| CN105524531A (en) * | 2016-01-11 | 2016-04-27 | 上海乘鹰新材料有限公司 | PP substrate base-coating paint composition and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109351568A (en) * | 2018-10-12 | 2019-02-19 | 深圳天成真空技术有限公司 | A kind of automobile lamp coating process |
| CN111423754A (en) * | 2020-04-29 | 2020-07-17 | 传美讯电子科技（珠海）有限公司 | Coating liquid for promoting UV ink adhesion and preparation method thereof |
| CN111423754B (en) * | 2020-04-29 | 2021-10-22 | 传美讯电子科技（珠海）有限公司 | Coating liquid for promoting UV ink adhesion and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101652435B (en) | Peel-coat compositions | |
| CN108003713B (en) | Water-based marking paint and preparation method and construction method thereof | |
| WO2008057878A3 (en) | Articles comprising nonpolar polyolefin and polyurethane, and methods for their preparation and use | |
| CN106497303B (en) | It is a kind of spray painting and preparation method thereof | |
| CN106497391A (en) | Ultraviolet light polymerization Weather-proof self-cleaning coating composition | |
| CN101096339B (en) | Application of alkyl carbonate as industrial solvent | |
| CN107163269A (en) | It is a kind of to the cohesive inorganic agent of PE plastics | |
| CN104231764A (en) | Primerless base painting composition for parts of vehicle, kit comprising the same, painted parts of vehicle | |
| CN102321414A (en) | Aqueous silver powder primer for plastics and preparation method thereof | |
| CN107141912A (en) | Silver powder dipping lacquer of aqueous quick-drying anti-corrosion stable storing and preparation method thereof | |
| CN106366870A (en) | Compound waterborne metallic baking paint and coating method thereof | |
| CN106366799A (en) | Waterborne polyurethane anti-skid terrace coating | |
| CN107779012A (en) | A kind of formula of water resistant coating | |
| CN104231816A (en) | Glazed coating and preparation method thereof | |
| CN103537419B (en) | The coating process of vehicle part | |
| CN102827547A (en) | Aqueous antique paint | |
| CN106893416A (en) | A kind of high polymer plastic-blasting coating | |
| CN105802300A (en) | Water-based glue | |
| CN106590121A (en) | Water-resistant paint | |
| CN207044849U (en) | A kind of automotive trim epidermis | |
| CN105176284A (en) | Water-based glaze-imitation paint and preparing method thereof | |
| CN102978899A (en) | Water-proofing agent for wax cloth | |
| CN102719161A (en) | Double-component aqueous woodenware fitment paint | |
| CN103881556A (en) | UV elastic coating | |
| CN109401378A (en) | A kind of base paint formulation with high adhesion force |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170915 |
|
| RJ01 | Rejection of invention patent application after publication |