CN107162422A - A kind of fire-resistant oxidation resistant ceramic glaze and preparation method thereof - Google Patents

A kind of fire-resistant oxidation resistant ceramic glaze and preparation method thereof Download PDF

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Publication number
CN107162422A
CN107162422A CN201710560201.0A CN201710560201A CN107162422A CN 107162422 A CN107162422 A CN 107162422A CN 201710560201 A CN201710560201 A CN 201710560201A CN 107162422 A CN107162422 A CN 107162422A
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parts
glaze
nano
oxide
fire
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周冬菊
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Dehua Dehua Ceramics Co Ltd
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Dehua Dehua Ceramics Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/04Frit compositions, i.e. in a powdered or comminuted form containing zinc
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels

Abstract

The present invention discloses a kind of fire-resistant oxidation resistant domestic ceramics glaze and preparation method thereof, is related to ceramic glaze manufacture technology field, and the glaze includes following raw material:Nano aluminium oxide;Nano silicon;Nano boron nitride powder, nano silicon carbide boron powder;Zinc oxide;Kaolin;Burn talcum;Sodium oxide molybdena;Calcium oxide;Surfactant;Glass fiber;Nano titanium oxide;Zinc nitrate;Yttrium nitrate.The preparation method includes following preparation process:(1)Prepare antiseptic;(2)Prepare fire-resistant oxidation resistant base-material;(3)Prepare mixing glaze slip;(4)Prepare final glaze.The present invention makes domestic porcelain be not easy to be oxidized by fire-resistant oxidation resistant base-material, keep porcelain surface-brightening, and by the proportioning for changing original glaze, talcum and zinc oxide are burnt in addition, advantageously reduce the coefficient of expansion of glaze slip, glaze surface elastic is improved, the mobility of glaze slip is improved, so as to reduce the possibility that glaze produces the defect of pin hole and tangerine glaze.

Description

A kind of fire-resistant oxidation resistant ceramic glaze and preparation method thereof
Technical field
The present invention relates to ceramic glaze manufacture technology field, more particularly to a kind of fire-resistant oxidation resistant ceramic glaze and its system Preparation Method.
Background technology
Domestic porcelain is liked and used by broad masses of the people for a long time, because it has the advantage that:First, it is easy to Washing and holding are clean.Household china glaze light, it is fine and smooth, easily washed away using after contamination.Second, better heat stability, heat transfer Slowly.Tableware for daily use is difficult the performance burst when having the anxious heat quenching change for being subjected to certain temperature difference.It is more excellent than glassware for this point More, it is the non-conductor of heat, and heat transfer is slow.For containing boiling water or boiling hot food, less scalded one's hand when end is taken.3rd, change Learn property stable, it is durable in use.This point is more superior than metallic article such as bronze, brass or copper ware, ironware, aluminium device etc., and domestic porcelain is for a long time Use under, oxidation reaction can occur for porcelain surface, make porcelain surface color shade, influence porcelain view and admire, and due to make Technology it is limited, porcelain surface can be caused pin hole occur, can so cause the substantial amounts of foul of porcelain adsorption.
The content of the invention
The problem to be solved in the present invention, which is to provide one kind, makes domestic porcelain be not easy to be oxidized, and keeps porcelain surface-brightening, And strengthen fire-resistant oxidation resistant ceramic glaze of porcelain stain resistance and preparation method thereof.Therefore, now proposing following technical side Case:
The present invention provides a kind of fire-resistant oxidation resistant domestic ceramics glaze, includes the raw material of following mass parts:It is nano oxidized 4-7 parts of aluminium;35-50 parts of nano silicon;5-10 parts of nano boron nitride powder, 5-10 parts of nano silicon carbide boron powder;Zinc oxide 3-6 parts;5-10 parts of kaolin;Burn 3-5 parts of talcum;3-6 parts of sodium oxide molybdena;3-6 parts of calcium oxide;1-3 parts of surfactant;Glass fiber 15-18 parts;15-25 parts of nano titanium oxide;0.5-0.8 parts of zinc nitrate;0.5-0.8 parts of yttrium nitrate.
Further improvement of these options, includes the raw material of following mass parts:5 parts of nano aluminium oxide;Nanometer titanium dioxide 43 parts of silicon;7 parts of nano boron nitride powder, 7 parts of nano silicon carbide boron powder;4 parts of zinc oxide;8 parts of kaolin;Burn 4 parts of talcum;Oxidation 4 parts of sodium;4 parts of calcium oxide;2 parts of surfactant;16 parts of glass fiber;20 parts of nano titanium oxide;0.6 part of zinc nitrate;Yttrium nitrate 0.6 part.
Further improvement of these options, the glass fiber is glass fiber industrial waste.
The present invention also provides a kind of preparation method of the fire-resistant oxidation resistant domestic ceramics glaze as described in above-mentioned scheme, wraps Include following steps:
(1) antiseptic is prepared:Take the component of following parts by weight:4-7 parts of nano aluminium oxide;35-50 parts of nano silicon; 5-10 parts of nano boron nitride powder, 5-10 parts of nano silicon carbide boron powder;3-6 parts of zinc oxide;5-10 parts of kaolin;Burn talcum 3-5 Part;3-6 parts of sodium oxide molybdena;3-6 parts of calcium oxide;1-3 parts of surfactant;15-18 parts of glass fiber;15-25 parts of nano titanium oxide; 0.5-0.8 parts of zinc nitrate;0.5-0.8 parts of yttrium nitrate;By glacial acetic acid, distilled water and absolute ethyl alcohol with 1-1.5: 2-3: 8-10 Mass ratio is uniformly mixed to prepare solvent, then adds zinc nitrate, yttrium nitrate and the surfactant of said ratio amount into solvent, its The mass ratio of middle solvent and zinc nitrate is 11-14: 0.33-0.45;Then electric agitator stirring 10-15min is reused, is mixed Solution is closed, the nano titanium oxide of proportional quantity is then added while stirring into gained mixed solution, obtains antiseptic;
(2) fire-resistant oxidation resistant base-material is prepared:Nano boron nitride powder and nano silicon carbide boron powder are put into according to proportioning In tumbling ball mill, using wet ball grinding 22-26h, then dry mixed-powder, and by gained mixed-powder in 500- 10-20h is reacted under 600 DEG C of temperature conditionss, is reacted after nitrogen atmosphere and under 800-900 DEG C of temperature conditionss, at nitridation 5-7h is managed, that is, anti-oxidant base-material is made;
(3) mixing glaze slip is prepared:By nano aluminium oxide, nano silicon, zinc oxide, kaolin, burning talcum, oxidation Sodium, calcium oxide, glass fiber are sufficiently mixed by proportional quantity, obtain mixed resin, anti-oxidant base prepared by mixed resin and step (2) Antiseptic prepared by material and step (1) is mixed according to mass ratio for 1: 1: 1 ratio uniform, then carries out wet ball grinding 10- The glaze slip sieving removal of impurity after 15h, ball milling;
(4) final glaze is prepared:Mixing glaze slip obtained by step (3) is fired into frit;Then room temperature is cooled to, that is, is made Glaze.
In further improvement of these options, step (1), the glacial acetic acid, distilled water, absolute ethyl alcohol and zinc nitrate Mass ratio be 1: 2: 10:0.33.
Further improvement of these options, in step (2), the mixed-powder obtained after ball milling is placed on 550 DEG C of temperature 15h is reacted under the conditions of degree, then anti-oxidant base-material is made in 850 DEG C of nitrogen treatment 6h under nitrogen atmosphere.
Further improvement of these options, in step (4), the firing temperature that frit is made in the glaze slip is 800- 1200 DEG C, firing time is 3-5h.
Compared with prior art, the beneficial effects of the present invention are:
(1) anti-oxidant composite base has been made using nano silicon carbide boron powder and nano boron nitride powder in glaze in the present invention Material, because boron carbide powder is from microstructure, molecular structure is close, makes it have higher intensity, fusing point height and corrosion resistant Corrosion, so makes this composite have higher mechanical property, good processability and good thermal shock resistance, Then anti-oxidant composite base-material is used in glaze, the inoxidizability of glaze can be strengthened, can make glaze in different temperature Expect surface-brightening, so that the porcelain being made keeps attractive in appearance, will not shade or turn to be yellow.
(2) traditional porcelain, can be because the deficiency of glaze formula, causes ceramic products in sintering process in manufacturing process There is gas, thus glaze pin hole, tangerine glaze and glaze pit can be formed on porcelain surface, so as to so in use can There are a large amount of dirty situations of pin hole absorption.So the present invention adds appropriate burning talcum wherein, glaze slip is advantageously reduced The coefficient of expansion, improves glaze surface elastic, improves the mobility of glaze slip, so as to reduce the possibility that glaze produces the defect of pin hole and tangerine glaze Property;The zinc oxide of addition can also expand the melting temperature of glaze frit, improve the covering power of glaze.
Embodiment
To be easy to understand the technical means, the inventive features, the objects and the advantages of the present invention, with reference to Embodiment, is expanded on further the present invention.
Embodiment 1
The present embodiment provides a kind of fire-resistant oxidation resistant domestic ceramics glaze, includes the raw material of following mass parts:Nano oxygen Change 4 parts of aluminium;35 parts of nano silicon;5 parts of nano boron nitride powder, 5 parts of nano silicon carbide boron powder;3 parts of zinc oxide;Kaolin 5 parts;Burn 3 parts of talcum;3 parts of sodium oxide molybdena;3 parts of calcium oxide;1 part of surfactant;15 parts of glass fiber industrial waste;Nanometer titanium dioxide 15 parts of titanium;0.5 part of zinc nitrate;0.5 part of yttrium nitrate.
The present embodiment also provides a kind of preparation method of fire-resistant oxidation resistant domestic ceramics glaze described above, including following Step:
(1) antiseptic is prepared:Glacial acetic acid, distilled water and absolute ethyl alcohol are uniformly mixed to prepare solvent, then by nitric acid Zinc, yttrium nitrate and surfactant are added in the solvent according to proportional quantity, wherein glacial acetic acid, distilled water, absolute ethyl alcohol And the mass ratio of zinc nitrate is 1: 2.2: 8: 0.35, electricity consumption agitator is stirred vigorously 10min afterwards, obtains mixed solution, so The nano titanium oxide for adding proportional quantity in backward mixed solution while stirring can obtain antiseptic;
(2) fire-resistant oxidation resistant base-material is prepared:Nano boron nitride powder and nano silicon carbide boron powder are put into according to proportioning In tumbling ball mill, using wet ball grinding 22h, then dry mixed-powder, and by gained mixed-powder in 500 DEG C of temperature 10h is reacted under the conditions of degree, is reacted after nitrogen atmosphere and under 800 DEG C of temperature conditionss, nitrogen treatment 5h, that is, is made anti-oxidant Base-material;
(3) mixing glaze slip is prepared:By nano aluminium oxide, nano silicon, zinc oxide, kaolin, burning talcum, oxidation Sodium, calcium oxide, glass fiber are sufficiently mixed by proportional quantity, obtain mixed resin, anti-oxidant base prepared by mixed resin and step (2) Antiseptic prepared by material and step (1) is mixed according to mass ratio for 1: 1: 1 ratio uniform, then carries out wet ball grinding 10h, The glaze slip sieving removal of impurity after ball milling;
(4) final glaze is prepared:Glaze slip is placed in 800 DEG C, firing time is to be fired into frit under conditions of 3h;Then it is cold But room temperature is arrived, that is, glaze is made.
Embodiment 2
The present embodiment provides a kind of fire-resistant oxidation resistant domestic ceramics glaze, includes the raw material of following mass parts:Nano oxygen Change 5 parts of aluminium;43 parts of nano silicon;7 parts of nano boron nitride powder, 7 parts of nano silicon carbide boron powder;4 parts of zinc oxide;Kaolin 8 parts;Burn 4 parts of talcum;4 parts of sodium oxide molybdena;4 parts of calcium oxide;2 parts of surfactant;16 parts of glass fiber industrial waste;Nanometer titanium dioxide 20 parts of titanium;0.6 part of zinc nitrate;0.6 part of yttrium nitrate.
The present embodiment also provides a kind of preparation method of fire-resistant oxidation resistant domestic ceramics glaze described above, including following Step:
(1) antiseptic is prepared:Glacial acetic acid, distilled water and absolute ethyl alcohol are uniformly mixed to prepare solvent, then by nitric acid Zinc, yttrium nitrate and surfactant are added in the solvent according to proportional quantity, wherein glacial acetic acid, distilled water, absolute ethyl alcohol And the mass ratio of zinc nitrate is 1: 2: 10: 0.33, electricity consumption agitator is stirred vigorously 13min afterwards, obtains mixed solution, then The nano titanium oxide for adding proportional quantity while stirring into mixed solution can obtain antiseptic;
(2) fire-resistant oxidation resistant base-material is prepared:Nano boron nitride powder and nano silicon carbide boron powder are put into according to proportioning In tumbling ball mill, using wet ball grinding 24h, then dry mixed-powder, and by gained mixed-powder in 550 DEG C of temperature 15h is reacted under the conditions of degree, is reacted after nitrogen atmosphere and under 850 DEG C of temperature conditionss, nitrogen treatment 6h, that is, is made anti-oxidant Base-material;
(3) mixing glaze slip is prepared:By nano aluminium oxide, nano silicon, zinc oxide, kaolin, burning talcum, oxidation Sodium, calcium oxide, glass fiber are sufficiently mixed by proportional quantity, obtain mixed resin, anti-oxidant base prepared by mixed resin and step (2) Antiseptic prepared by material and step (1) is mixed according to mass ratio for 1: 1: 1 ratio uniform, then carries out wet ball grinding 13h, The glaze slip sieving removal of impurity after ball milling;
(4) final glaze is prepared:Glaze slip is placed in 1000 DEG C, firing time is to be fired into frit under conditions of 4h;Then Room temperature is cooled to, that is, glaze is made.
Embodiment 3
The present embodiment provides a kind of fire-resistant oxidation resistant domestic ceramics glaze, includes the raw material of following mass parts:Nano oxygen Change 6 parts of aluminium;46 parts of nano silicon;8 parts of nano boron nitride powder, 8 parts of nano silicon carbide boron powder;5 parts of zinc oxide;Kaolin 9 parts;Burn 4.5 parts of talcum;5 parts of sodium oxide molybdena;5 parts of calcium oxide;2.5 parts of surfactant;17 parts of glass fiber industrial waste;Nanometer two 23 parts of titanium oxide;0.7 part of zinc nitrate;0.7 part of yttrium nitrate.
The present embodiment also provides a kind of preparation method of fire-resistant oxidation resistant domestic ceramics glaze described above, including following Step:
(1) antiseptic is prepared:Glacial acetic acid, distilled water and absolute ethyl alcohol are uniformly mixed to prepare solvent, then by nitric acid Zinc, yttrium nitrate and surfactant are added in the solvent according to proportional quantity, wherein glacial acetic acid, distilled water, absolute ethyl alcohol And the mass ratio of zinc nitrate is 1.2: 2.5: 9: 0.4, electricity consumption agitator is stirred vigorously 14min afterwards, obtains mixed solution, so The nano titanium oxide for adding proportional quantity in backward mixed solution while stirring can obtain antiseptic;
(2) fire-resistant oxidation resistant base-material is prepared:Nano boron nitride powder and nano silicon carbide boron powder are put into according to proportioning In tumbling ball mill, using wet ball grinding 25h, then dry mixed-powder, and by gained mixed-powder in 580 DEG C of temperature 18h is reacted under the conditions of degree, is reacted after nitrogen atmosphere and under 880 DEG C of temperature conditionss, nitrogen treatment 5.5h, that is, antioxygen is made Change base-material;
(3) mixing glaze slip is prepared:By nano aluminium oxide, nano silicon, zinc oxide, kaolin, burning talcum, oxidation Sodium, calcium oxide, glass fiber are sufficiently mixed by proportional quantity, obtain mixed resin, anti-oxidant base prepared by mixed resin and step (2) Antiseptic prepared by material and step (1) is mixed according to mass ratio for 1: 1: 1 ratio uniform, then carries out wet ball grinding 14h, The glaze slip sieving removal of impurity after ball milling;
(4) final glaze is prepared:Glaze slip is placed in 1100 DEG C, firing time is to be fired into frit under conditions of 4.5h;So After be cooled to room temperature, that is, be made glaze.
Embodiment 4
The present embodiment provides a kind of fire-resistant oxidation resistant domestic ceramics glaze, includes the raw material of following mass parts:Nano oxygen Change 7 parts of aluminium;50 parts of nano silicon;10 parts of nano boron nitride powder, 10 parts of nano silicon carbide boron powder;6 parts of zinc oxide;Kaolinite 10 parts of soil;Burn 5 parts of talcum;6 parts of sodium oxide molybdena;6 parts of calcium oxide;3 parts of surfactant;18 parts of glass fiber industrial waste;Nanometer two 25 parts of titanium oxide;0.8 part of zinc nitrate;0.8 part of yttrium nitrate.
The present embodiment also provides a kind of preparation method of fire-resistant oxidation resistant domestic ceramics glaze described above, including following Step:
(1) antiseptic is prepared:Glacial acetic acid, distilled water and absolute ethyl alcohol are uniformly mixed to prepare solvent, then by nitric acid Zinc, yttrium nitrate and surfactant are added in the solvent according to according to proportional quantity, wherein glacial acetic acid, distilled water, anhydrous The mass ratio of ethanol and zinc nitrate is 1.5: 3: 10: 0.45, and electricity consumption agitator is stirred vigorously 15min afterwards, obtains mixing molten Liquid, the nano titanium oxide for then adding proportional quantity while stirring into mixed solution can obtain antiseptic;
(2) fire-resistant oxidation resistant base-material is prepared:Nano boron nitride powder and nano silicon carbide boron powder are put into according to proportioning In tumbling ball mill, using wet ball grinding 26h, then dry mixed-powder, and by gained mixed-powder in 600 DEG C of temperature 20h is reacted under the conditions of degree, is reacted after nitrogen atmosphere and under 900 DEG C of temperature conditionss, nitrogen treatment 7h, that is, is made anti-oxidant Base-material;
(3) mixing glaze slip is prepared:By nano aluminium oxide, nano silicon, zinc oxide, kaolin, burning talcum, oxidation Sodium, calcium oxide, glass fiber are sufficiently mixed by proportional quantity, obtain mixed resin, anti-oxidant base prepared by mixed resin and step (2) Antiseptic prepared by material and step (1) is mixed according to mass ratio for 1: 1: 1 ratio uniform, then carries out wet ball grinding 15h, The glaze slip sieving removal of impurity after ball milling;
(4) final glaze is prepared:Glaze slip is placed in 1200 DEG C, firing time is to be fired into frit under conditions of 5h;Then Room temperature is cooled to, that is, glaze is made.
Particular product performance parameters obtained by above-described embodiment are as shown in table 1:
Particular product performance parameters contrast table obtained by the above-described embodiment of table 1.
Obtained from upper table, embodiment 1 to embodiment 4 utilizes nano silicon carbide boron powder and nm-class boron nitride in glaze Anti-oxidant composite base-material has been made in powder, because boron carbide powder is from microstructure, and molecular structure is close, make it have compared with High intensity, fusing point height and corrosion resistance, so makes this composite have higher mechanical property, good machinability Energy and good thermal shock resistance, then anti-oxidant composite base-material is used in glaze, can strengthen the inoxidizability of glaze, It can make frit surface light in different temperature, so that the porcelain being made keeps attractive in appearance, will not shade or turn to be yellow.In addition Tradition, can be because the deficiency of glaze formula, causes ceramic products to occur gas in sintering process in the manufacturing process of porcelain, this Sample will form the present of glaze pin hole, tangerine glaze and glaze pit on porcelain surface, so as to so occur in use The a large amount of dirty situations of pin hole absorption.So the present invention adds appropriate burning talcum wherein, the expansion of glaze slip is advantageously reduced Coefficient, improves glaze surface elastic, improves the mobility of glaze slip, so as to reduce the possibility that glaze produces the defect of pin hole and tangerine glaze; The zinc oxide of addition can also expand the melting temperature of glaze frit, improve the covering power of glaze.
Those of ordinary skill in the art it should be appreciated that the embodiment of the above be intended merely to explanation the present invention, And be not used as limitation of the invention, as long as in the spirit of the present invention, the change to embodiment described above Change, modification will all fall in scope of the presently claimed invention.

Claims (7)

1. a kind of fire-resistant oxidation resistant domestic ceramics glaze, it is characterised in that include the raw material of following mass parts:Nano aluminium oxide 4-7 parts;35-50 parts of nano silicon;5-10 parts of nano boron nitride powder, 5-10 parts of nano silicon carbide boron powder;Zinc oxide 3-6 Part;5-10 parts of kaolin;Burn 3-5 parts of talcum;3-6 parts of sodium oxide molybdena;3-6 parts of calcium oxide;1-3 parts of surfactant;Glass fiber 15- 18 parts;15-25 parts of nano titanium oxide;0.5-0.8 parts of zinc nitrate;0.5-0.8 parts of yttrium nitrate.
2. a kind of fire-resistant oxidation resistant domestic ceramics glaze according to claim 1, it is characterised in that including following quality The raw material of part:5 parts of nano aluminium oxide;43 parts of nano silicon;7 parts of nano boron nitride powder, 7 parts of nano silicon carbide boron powder; 4 parts of zinc oxide;8 parts of kaolin;Burn 4 parts of talcum;4 parts of sodium oxide molybdena;4 parts of calcium oxide;2 parts of surfactant;16 parts of glass fiber;Receive 20 parts of titanium dioxide of rice;0.6 part of zinc nitrate;0.6 part of yttrium nitrate.
3. fire-resistant oxidation resistant domestic ceramics glaze according to claim 1 or 2, it is characterised in that:The glass fiber is Glass fiber industrial waste.
4. a kind of preparation method of fire-resistant oxidation resistant domestic ceramics glaze as claimed in claim 3, it is characterised in that including Following steps:
Prepare antiseptic:Take the component of following parts by weight:4-7 parts of nano aluminium oxide;35-50 parts of nano silicon;Nanometer nitrogen Change 5-10 parts of boron powder, 5-10 parts of nano silicon carbide boron powder;3-6 parts of zinc oxide;5-10 parts of kaolin;Burn 3-5 parts of talcum;Oxidation 3-6 parts of sodium;3-6 parts of calcium oxide;1-3 parts of surfactant;15-18 parts of glass fiber;15-25 parts of nano titanium oxide;Zinc nitrate 0.5-0.8 parts;0.5-0.8 parts of yttrium nitrate;By glacial acetic acid, distilled water and absolute ethyl alcohol with 1-1.5: 2-3: 8-10 mass ratio It is uniform to be mixed to prepare solvent, then add into solvent zinc nitrate, yttrium nitrate and the surfactant of said ratio amount, wherein solvent Mass ratio with zinc nitrate is 11-14: 0.33-0.45;Then electric agitator stirring 10-15min is reused, mixing is obtained molten Liquid, then adds the nano titanium oxide of proportional quantity, obtains antiseptic while stirring into gained mixed solution;
Prepare fire-resistant oxidation resistant base-material:Nano boron nitride powder and nano silicon carbide boron powder are put into roller according to said ratio In formula ball mill, using wet ball grinding 22-26h, then dry mixed-powder, and by gained mixed-powder in 500-600 DEG C Temperature conditionss under react 10-20h, react after nitrogen atmosphere and under 800-900 DEG C of temperature conditionss, nitrogen treatment 5- 7h, that is, be made anti-oxidant base-material;
Prepare mixing glaze slip:By nano aluminium oxide, nano silicon, zinc oxide, kaolin, burning talcum, sodium oxide molybdena, oxidation Calcium, glass fiber are sufficiently mixed by proportional quantity, obtain mixed resin, by mixed resin and step(2)Prepare anti-oxidant base-material and Step(1)The antiseptic of preparation is mixed according to mass ratio for 1: 1: 1 ratio uniform, then carries out wet ball grinding 10-15h, ball The glaze slip sieving removal of impurity after mill;
Prepare final glaze:By step(3)Gained mixing glaze slip is fired into frit;Then room temperature is cooled to, that is, glaze is made.
5. a kind of preparation method of fire-resistant oxidation resistant domestic ceramics glaze according to claim 4, it is characterised in that:Step Suddenly(1)In, the glacial acetic acid, distilled water, the mass ratio of absolute ethyl alcohol and zinc nitrate are 1: 2: 10: 0.33.
6. a kind of preparation method of fire-resistant oxidation resistant domestic ceramics glaze according to claim 4, it is characterised in that: Step(2)In, the mixed-powder obtained after ball milling, which is placed under 550 DEG C of temperature conditionss, reacts 15h, then under nitrogen atmosphere Anti-oxidant base-material is made after 850 DEG C of nitrogen treatment 6h.
7. a kind of preparation method of fire-resistant oxidation resistant domestic ceramics glaze according to claim 4, it is characterised in that: Step(4)In, the firing temperature that frit is made in the glaze slip is 800-1200 DEG C, and firing time is 3-5h.
CN201710560201.0A 2017-07-11 2017-07-11 A kind of fire-resistant oxidation resistant ceramic glaze and preparation method thereof Pending CN107162422A (en)

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CN107804973A (en) * 2017-11-21 2018-03-16 常州市奥普泰科光电有限公司 A kind of ceramic glaze
CN107777886A (en) * 2017-11-22 2018-03-09 恩平市新锦成陶瓷有限公司 A kind of ceramic glaze of ink-jet infiltration and preparation method thereof and application process
CN109970341A (en) * 2019-04-23 2019-07-05 廖祥胜 Antifouling and antibiosis ceramic glaze and preparation method thereof
CN109970341B (en) * 2019-04-23 2022-03-08 潮州市华利达陶瓷制作有限公司 Antifouling antibacterial ceramic glaze and preparation method thereof
CN111515124A (en) * 2020-06-05 2020-08-11 江苏拜富科技股份有限公司 Matt ceramic glaze with strong anti-pollution capability and strong color development
CN112194369A (en) * 2020-10-26 2021-01-08 佛山市东鹏陶瓷发展有限公司 Wear-resistant frit, preparation method of frit and glaze using frit
CN112194369B (en) * 2020-10-26 2022-03-25 佛山市东鹏陶瓷发展有限公司 Wear-resistant frit, preparation method of frit and glaze using frit
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Application publication date: 20170915