CN107150479A - A kind of preparation method of colored total-light-reflection fabric - Google Patents

A kind of preparation method of colored total-light-reflection fabric Download PDF

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Publication number
CN107150479A
CN107150479A CN201710387558.3A CN201710387558A CN107150479A CN 107150479 A CN107150479 A CN 107150479A CN 201710387558 A CN201710387558 A CN 201710387558A CN 107150479 A CN107150479 A CN 107150479A
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China
Prior art keywords
layer
reflection
light
base material
coating
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CN201710387558.3A
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CN107150479B (en
Inventor
孙飞
朱俊杰
胡玲静
胡庭
叶成斌
陈�光
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ZHEJIANG LONGYOU DAOMING OPTICAL CO Ltd
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ZHEJIANG LONGYOU DAOMING OPTICAL CO Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/30—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being formed of particles, e.g. chips, granules, powder
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/02—Layered materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/14—Printing or colouring
    • B32B38/145—Printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/04—Coating on the layer surface on a particulate layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/28—Multiple coating on one surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/101—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/402—Coloured
    • B32B2307/404—Multi-coloured
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/416—Reflective
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The invention discloses a kind of preparation method of colored total-light-reflection fabric, comprise the following steps：（1）A base material is taken, glass microballoon is implanted on base material, soot layer is formed；（2）At least three layers translucent film plating layer are coated by gas phase coating method successively on the glass microballoon surface of soot layer, so as to form reflecting layer；（3）In step（2）The coating of reflection layer surface containing the adhesive starched in vain and drying, form adhesive layer；（4）A precoat is taken, by precoat and step（3）In adhesive layer laminating, formed white reflection fabric；（5）In the substrate surface transfer of soot layer or printing color pattern, colored design layer is formed, so as to obtain colored total-light-reflection fabric.The colored total-light-reflection fabric obtained by above step, can realize the effect of total-light-reflection, and can highlight the multicolour of colored design layer, can realize required various fancy and color, can preferably protect the personal safety of wearer.

Description

A kind of preparation method of colored total-light-reflection fabric
Technical field
The present invention relates to Reflection fabric field, more particularly to a kind of preparation method of colored total-light-reflection fabric.
Background technology
Reflection fabric is a kind of to be widely applied to traffic safety equipment, pad pasting, protective garment, work clothes, uniform etc. and people The closely bound up high-tech product of the security of the lives and property.It is by the way that glass microballoon is put on fabric, using light in glass The optical principle returned in glass microballon after refraction reflection, makes reflected light mostly return to the one of light source direction by incident light direction Fabric is planted, no matter having good reflex reflection optical property, especially evening at daytime or night, can be played such as daytime one The high-visibility of sample, the safety clothes being made using this high-visibility Reflection fabric, no matter wearer be at remote place, or In the case of light or scattered light interference, can relatively easily it be found, the appearance of Reflection fabric, which is smoothly solved, " to be seen To " and " being seen " this problem in one night.
As Publication No. " CN105286146A ", publication date be on 2 3rd, 2016, it is entitled " a kind of fancy reflection cloth and The application for a patent for invention of its preparation method " discloses a kind of fancy reflection cloth and preparation method thereof, its " by base fabric, composite layer, Coating, focus layer, glass microballoon composition ", the preparation method of the fancy reflection cloth is：Glass microballoon is implanted into, it is then micro- in glass Bead surface coating focuses on coating, is dried into focus layer, is then formed outside beads formed film plated medium by resistance heating manner Coating, is made beads formed film, and composite glue is then formed into composite layer outside coating in geometry by intaglio plate method of roll coating, Then by composite layer and composite for base fabric, after glue curing to be composite, PE composite membranes is peeled off, a kind of ventilative shape fancy reflection is obtained Cloth, remaining PE composite membranes after stripping, is coated with after composite glue, drying composite glue and composite for base fabric, glue to be composite outside coating After water is fully cured, composite membrane is peeled off, non-breathable type fancy reflection cloth is made.
The fancy reflection cloth obtained by technique made above can realize reflective effect, and with required various flowers Formula and color, but also garment material can be directly used as, ready-made clothes can be processed.But the pattern of the fancy reflection cloth is by gravure roll Composite glue is formed flower point type composite layer by coating method in Flower Print outside coating, and will be compound eventually through composite layer Film is bonded on cotton, thus cause this fancy reflection cloth a portion can realize it is reflective, and the color of its fancy, Brightness is all more dim, and its retro-reflecting coefficient is low, and reflex reflection effect is poor.In addition, the fancy reflection cloth needs to take very multiple Miscellaneous processing mode can just produce patterned Reflection fabric, and its cost of manufacture is higher, it is impossible to meet need of the people to production Ask.
The content of the invention
The present invention can not realize that the color of total-light-reflection and its fancy, brightness are all more dark for existing fancy reflection cloth Light, its retro-reflecting coefficient is low, and there is provided a kind of making side of new colored total-light-reflection fabric for the defect such as reflex reflection effect is poor Method.
In order to solve the above-mentioned technical problem, the present invention is achieved through the following technical solutions：
A kind of preparation method of colored total-light-reflection fabric, described preparation method comprises the following steps：
（1）A base material is taken, glass microballoon is implanted on base material, soot layer is formed；
（2）At least three layers translucent plated film are coated by gas phase coating method successively on the glass microballoon surface of soot layer Layer, so as to form reflecting layer；
（3）In step（2）The coating of reflection layer surface containing the adhesive starched in vain and drying, form adhesive layer；
（4）A precoat is taken, by precoat and step（3）In adhesive layer laminating, formed white reflection fabric；
（5）In the substrate surface transfer of soot layer or printing color pattern, colored design layer is formed, so as to obtain colored complete Reflection fabric.
The colored total-light-reflection fabric obtained by above step, is by the reflecting layer on glass microballoon and glass microballoon To realize the effect of retroreflecting, so that whole colour total-light-reflection fabric can realize reflex reflection effect, namely realize The effect of total-light-reflection, the ranges of indices of refraction of wherein glass microballoon is preferably 1.5 ~ 2.5 and preferably 1.93.And in substrate surface Transfer or printing form colored design layer, and in the case where the color of Reflection fabric is white so that the reflective bottom of the present invention Color is transparent, so as to highlight the multicolour of colored design layer, can realize required various fancy and color, and Will not be as only performance is silver gray in the prior art.In addition, reflecting layer is coated successively by least three layers translucent film plating layer Form, the retro-reflecting coefficient in reflecting layer can be greatly promoted so that the present invention can more protrude fancy, the face of colored design layer Color, brightness, not only with more preferable reflex reflection effect, and broken routine reflectorized material may only be assumed office as auxiliary material application The barrier of industry protective clothes or civilian garment industry, color, the pattern that the present invention is formed can not only reach civilian clothes The requirement of fabric is filled, civilian garment industry is applicable to, and is also equipped with good reflex reflection effect, can preferably be protected The personal safety of wearer.
Preferably, a kind of preparation method of colored total-light-reflection fabric described above, described step（2）In, in glass The glass microballoon surface of glass microbead layer coats three layers of translucent film plating layer successively, and three layers of described translucent film plating layer are followed successively by sulphur Change zinc film plating layer, magnesium fluoride film plating layer, zinc sulphide film plating layer, the coating thickness of first layer zinc sulphide film plating layer is 10 nanometers~50 The reflectivity of nanometer and coating back reflection layer reaches 10%~40%, the coating thickness of second layer magnesium fluoride film plating layer for 15 nanometers~ The reflectivity of 45 nanometers and coating back reflection layer reaches 5%~35%, and the coating thickness of third layer zinc sulphide film plating layer is 15 nanometers ~35 nanometers and coating back reflection layer reflectivity reach 20%~70%.
In order to ensure to be optimal under conditions of transparent good reflex reflection effect, the refraction of the invention according to glass microballoon Rate, sets the material and thickness of the three layers of translucent film plating layer coated by gas phase, so as to set corresponding reflectivity so that most The reflecting layer obtained eventually can reach optimal reflex reflection effect, so as at utmost protect the personal safety of wearer.
Preferably, a kind of preparation method of colored total-light-reflection fabric described above, first layer zinc sulphide film plating layer Coating thickness be 18 nanometers~24 nanometers and coating back reflection layer reflectivity reach 25%~40%, second layer magnesium fluoride film plating layer Coating thickness for 20 nanometers~26 nanometers and coating back reflection layer reflectivity reach 15%~35%, third layer zinc sulphide plated film Layer coating thickness for 20 nanometers~24 nanometers and coating back reflection layer reflectivity reach 50%~70%.
In above thickness range, the reflectivity after every layer of translucent film plating layer coating can be better ensured that, it is ensured that The reflectivity of the final products arrived is maximized, so that best reflex reflection effect is obtained, so as at utmost protect wearer's Personal safety.
Preferably, a kind of preparation method of colored total-light-reflection fabric described above, described step（3）In, it is described Containing the adhesive starched in vain by Resin A, curing agent, white slurry, diluent by 100:2:10:20~100:15:50:80 ratio is matched somebody with somebody Than into.
It is high containing the adhesive one side bonding strength starched in vain by above proportions, can be preferably by reflection Layer is bonded with precoat, prevents reflecting layer from being separated with precoat, so as to increase the service life of colored total-light-reflection fabric, the opposing party Face enables to adhesive that purer white is presented, and lifts reflex reflection effect.
It is described containing the adhesive starched in vain preferably, a kind of preparation method of colored total-light-reflection fabric described above 100 are pressed by Resin A, curing agent, white slurry, diluent:4:25:40~100:8:25:40 proportions are formed.
What is be formulated in above proportion has more preferable cohesive containing the adhesive starched in vain, and its color is more It is pure white.
Preferably, a kind of preparation method of colored total-light-reflection fabric described above, described Resin A is solvent-borne type tree Fat or water-base resin.
On the one hand it is because it can more preferably combine solidification using water-base resin or solvent type resin as the stock of Resin A Agent, white slurry, it is ensured that formed containing the sticky of the adhesive starched in vain and pure white degree, be on the other hand not contain to poison because of it Learn material, the healthy of user will not be endangered, also there is certain facilitation to environmental protection, and its have it is nonflammable Characteristic, can effectively reduce the generation of fire.
Preferably, a kind of preparation method of colored total-light-reflection fabric described above, described curing agent is solid for amino Agent or isocyanate curing agent.
There is more preferable heat resistance, water resistance from the cured above dose of adhesive enabled to, so as to lift product Performance.
Preferably, a kind of preparation method of colored total-light-reflection fabric described above, described step（5）In, it is described Transfer modes be：The printing color pattern on one layer of carrier, then the multicolour pattern on carrier is transferred to by transfer modes The substrate surface of soot layer, forms colored design layer.
The colored design layer obtained by above transfer modes becomes apparent from, and transfer process is simpler, and operation is more Easily, production cost can further be reduced.
Preferably, a kind of preparation method of colored total-light-reflection fabric described above, described step（1）In, glass The implantation of microballon is：In substrate surface coated with resins B and drying, glass microballoon half is implanted into resin, glass is formed micro- Pearl layer, described base material is PET or PET composite membranes.
The technique of this plantation pearl mode is most simple, and easy to operate, production cost is minimum.
Preferably, a kind of preparation method of colored total-light-reflection fabric described above, described step（1）In, glass The implantation of microballon is：Described base material is PE composite membranes, and PE composite membranes are heated, make the PE layers of PE composite membrane outer layers Soften later half parcel glass microballoon, so as to form soot layer.
Using at high temperature, bond glass microballoon to reach the effect of fixed glass microballoon by the softening of PE composite membranes, then Depth is settled in PE layers by high temperature settlement Control glass microballoon and reaches 35% ~ 40%, then the product behind gas phase coating reflecting layer Wide-angle retroreflective can more preferably.Wherein PE composite membranes are preferably PE/PET composite membranes, PE/ paper composite membranes.
Brief description of the drawings
Fig. 1 is a kind of structural representation of the colored total-light-reflection fabric obtained according to the present invention；
Fig. 2 is the partial enlarged drawing in A portions in Fig. 1.
Embodiment
The present invention is described in further detail with reference to the accompanying drawings and detailed description, but they are not to the present invention Limitation：
Embodiment 1
A kind of preparation method of colored total-light-reflection fabric, described preparation method comprises the following steps：
（1）A base material 21 is taken, glass microballoon 22 is implanted on base material 21, soot layer 2 is formed；
（2）At least three layers translucent plating are coated by gas phase coating method successively on the surface of glass microballoon 22 of soot layer 2 Film layer 31, so as to form reflecting layer 3；
（3）In step（2）The coating of the surface of reflecting layer 3 containing the adhesive starched in vain and drying, form adhesive layer 4；
（4）A precoat 5 is taken, by precoat 5 and step（3）In adhesive layer 4 fit, formed white reflection fabric；
（5）In the surface transfer of base material 21 or printing color pattern of soot layer 2, colored design layer 1 is formed, so as to obtain coloured silk Color total-light-reflection fabric.
Preferably, described step（2）In, coated successively on the glass microballoon surface of soot layer 2 three layers it is semi-transparent Bright film plating layer 31, three layers of described translucent film plating layer 31 are followed successively by zinc sulphide film plating layer, magnesium fluoride film plating layer, zinc sulphide plated film Layer, the coating thickness of first layer zinc sulphide film plating layer is 10 nanometer and the reflectivity of coating back reflection layer 3 reaches 10%, the second layer The coating thickness of magnesium fluoride film plating layer be 15 nanometers and coating back reflection layer 3 reflectivity reach 5%, third layer zinc sulphide plated film Layer coating thickness for 15 nanometers and coating back reflection layer 3 reflectivity reach 20%.
Preferably, described step（3）In, it is described containing the adhesive starched in vain by Resin A, curing agent, white slurry, dilution Agent presses 100:2:10:20.
Preferably, described Resin A is solvent type resin or water-base resin.
Preferably, described curing agent is amino curing agent or isocyanate curing agent.
Preferably, described step（5）In, described transfer modes are：The printing color pattern on one layer of carrier, then Multicolour pattern on carrier is transferred to the surface of base material 21 of soot layer 2 by transfer modes, colored design layer 1 is formed.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：In the surface coated with resins B of base material 21 And dry, glass microballoon 22 half is implanted into resin, soot layer 2 is formed, described base material 21 for PET or or PET it is compound Film.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：Described base material 21 is compound for PE Film, is heated to PE composite membranes, the PE layers of PE composite membrane outer layers is softened later half parcel glass microballoon 22, so as to form glass Microbead layer 2.
Embodiment 2
A kind of preparation method of colored total-light-reflection fabric, described preparation method comprises the following steps：
（1）A base material 21 is taken, glass microballoon 22 is implanted on base material 21, soot layer 2 is formed；
（2）At least three layers translucent plating are coated by gas phase coating method successively on the surface of glass microballoon 22 of soot layer 2 Film layer 31, so as to form reflecting layer 3；
（3）In step（2）The coating of the surface of reflecting layer 3 containing the adhesive starched in vain and drying, form adhesive layer 4；
（4）A precoat 5 is taken, by precoat 5 and step（3）In adhesive layer 4 fit, formed white reflection fabric；
（5）In the surface transfer of base material 21 or printing color pattern of soot layer 2, colored design layer 1 is formed, so as to obtain coloured silk Color total-light-reflection fabric.
Preferably, described step（2）In, coated successively on the glass microballoon surface of soot layer 2 three layers it is semi-transparent Bright film plating layer 31, three layers of described translucent film plating layer 31 are followed successively by zinc sulphide film plating layer, magnesium fluoride film plating layer, zinc sulphide plated film Layer, the coating thickness of first layer zinc sulphide film plating layer is 50 nanometer and the reflectivity of coating back reflection layer 3 reaches 10%, the second layer The coating thickness of magnesium fluoride film plating layer be 15 nanometers and coating back reflection layer 3 reflectivity reach 5%, third layer zinc sulphide plated film Layer coating thickness for 15 nanometers and coating back reflection layer 3 reflectivity reach 20%.
Preferably, described step（3）In, it is described containing the adhesive starched in vain by Resin A, curing agent, white slurry, dilution Agent presses 100:15:50:80.
Preferably, described Resin A is solvent type resin or water-base resin.
Preferably, described curing agent is amino curing agent or isocyanate curing agent.
Preferably, described step（5）In, described transfer modes are：The printing color pattern on one layer of carrier, then Multicolour pattern on carrier is transferred to the surface of base material 21 of soot layer 2 by transfer modes, colored design layer 1 is formed.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：In the surface coated with resins B of base material 21 And dry, glass microballoon 22 half is implanted into resin, soot layer 2 is formed, described base material 21 for PET or or PET it is compound Film.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：Described base material 21 is compound for PE Film, is heated to PE composite membranes, the PE layers of PE composite membrane outer layers is softened later half parcel glass microballoon 22, so as to form glass Microbead layer 2.
Embodiment 3
A kind of preparation method of colored total-light-reflection fabric, described preparation method comprises the following steps：
（1）A base material 21 is taken, glass microballoon 22 is implanted on base material 21, soot layer 2 is formed；
（2）At least three layers translucent plating are coated by gas phase coating method successively on the surface of glass microballoon 22 of soot layer 2 Film layer 31, so as to form reflecting layer 3；
（3）In step（2）The coating of the surface of reflecting layer 3 containing the adhesive starched in vain and drying, form adhesive layer 4；
（4）A precoat 5 is taken, by precoat 5 and step（3）In adhesive layer 4 fit, formed white reflection fabric；
（5）In the surface transfer of base material 21 or printing color pattern of soot layer 2, colored design layer 1 is formed, so as to obtain coloured silk Color total-light-reflection fabric.
Preferably, described step（2）In, coated successively on the glass microballoon surface of soot layer 2 three layers it is semi-transparent Bright film plating layer 31, three layers of described translucent film plating layer 31 are followed successively by zinc sulphide film plating layer, magnesium fluoride film plating layer, zinc sulphide plated film Layer, the coating thickness of first layer zinc sulphide film plating layer is 10 nanometer and the reflectivity of coating back reflection layer 3 reaches 10%, the second layer The coating thickness of magnesium fluoride film plating layer be 45 nanometers and coating back reflection layer 3 reflectivity reach 5%, third layer zinc sulphide plated film Layer coating thickness for 15 nanometers and coating back reflection layer 3 reflectivity reach 20%.
Preferably, described step（3）In, it is described containing the adhesive starched in vain by Resin A, curing agent, white slurry, dilution Agent presses 100:8:30:50.
Preferably, described Resin A is solvent type resin or water-base resin.
Preferably, described curing agent is amino curing agent or isocyanate curing agent.
Preferably, described step（5）In, described transfer modes are：The printing color pattern on one layer of carrier, then Multicolour pattern on carrier is transferred to the surface of base material 21 of soot layer 2 by transfer modes, colored design layer 1 is formed.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：In the surface coated with resins B of base material 21 And dry, glass microballoon 22 half is implanted into resin, soot layer 2 is formed, described base material 21 for PET or or PET it is compound Film.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：Described base material 21 is compound for PE Film, is heated to PE composite membranes, the PE layers of PE composite membrane outer layers is softened later half parcel glass microballoon 22, so as to form glass Microbead layer 2.
Embodiment 4
A kind of preparation method of colored total-light-reflection fabric, described preparation method comprises the following steps：
（1）A base material 21 is taken, glass microballoon 22 is implanted on base material 21, soot layer 2 is formed；
（2）At least three layers translucent plating are coated by gas phase coating method successively on the surface of glass microballoon 22 of soot layer 2 Film layer 31, so as to form reflecting layer 3；
（3）In step（2）The coating of the surface of reflecting layer 3 containing the adhesive starched in vain and drying, form adhesive layer 4；
（4）A precoat 5 is taken, by precoat 5 and step（3）In adhesive layer 4 fit, formed white reflection fabric；
（5）In the surface transfer of base material 21 or printing color pattern of soot layer 2, colored design layer 1 is formed, so as to obtain coloured silk Color total-light-reflection fabric.
Preferably, described step（2）In, coated successively on the glass microballoon surface of soot layer 2 three layers it is semi-transparent Bright film plating layer 31, three layers of described translucent film plating layer 31 are followed successively by zinc sulphide film plating layer, magnesium fluoride film plating layer, zinc sulphide plated film Layer, the coating thickness of first layer zinc sulphide film plating layer is 10 nanometer and the reflectivity of coating back reflection layer 3 reaches 10%, the second layer The coating thickness of magnesium fluoride film plating layer be 15 nanometers and coating back reflection layer 3 reflectivity reach 5%, third layer zinc sulphide plated film Layer coating thickness for 35 nanometers and coating back reflection layer 3 reflectivity reach 20%.
Preferably, described step（3）In, it is described containing the adhesive starched in vain by Resin A, curing agent, white slurry, dilution Agent presses 100:10:45:60.
Preferably, described Resin A is solvent type resin or water-base resin.
Preferably, described curing agent is amino curing agent or isocyanate curing agent.
Preferably, described step（5）In, described transfer modes are：The printing color pattern on one layer of carrier, then Multicolour pattern on carrier is transferred to the surface of base material 21 of soot layer 2 by transfer modes, colored design layer 1 is formed.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：In the surface coated with resins B of base material 21 And dry, glass microballoon 22 half is implanted into resin, soot layer 2 is formed, described base material 21 for PET or or PET it is compound Film.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：Described base material 21 is compound for PE Film, is heated to PE composite membranes, the PE layers of PE composite membrane outer layers is softened later half parcel glass microballoon 22, so as to form glass Microbead layer 2.
Embodiment 5
A kind of preparation method of colored total-light-reflection fabric, described preparation method comprises the following steps：
（1）A base material 21 is taken, glass microballoon 22 is implanted on base material 21, soot layer 2 is formed；
（2）At least three layers translucent plating are coated by gas phase coating method successively on the surface of glass microballoon 22 of soot layer 2 Film layer 31, so as to form reflecting layer 3；
（3）In step（2）The coating of the surface of reflecting layer 3 containing the adhesive starched in vain and drying, form adhesive layer 4；
（4）A precoat 5 is taken, by precoat 5 and step（3）In adhesive layer 4 fit, formed white reflection fabric；
（5）In the surface transfer of base material 21 or printing color pattern of soot layer 2, colored design layer 1 is formed, so as to obtain coloured silk Color total-light-reflection fabric.
Preferably, described step（2）In, coated successively on the glass microballoon surface of soot layer 2 three layers it is semi-transparent Bright film plating layer 31, three layers of described translucent film plating layer 31 are followed successively by zinc sulphide film plating layer, magnesium fluoride film plating layer, zinc sulphide plated film Layer, the coating thickness of first layer zinc sulphide film plating layer is 18 nanometer and the reflectivity of coating back reflection layer 3 reaches 25%, the second layer The coating thickness of magnesium fluoride film plating layer be 20 nanometers and coating back reflection layer 3 reflectivity reach 15%, third layer zinc sulphide plated film Layer coating thickness for 20 nanometers and coating back reflection layer 3 reflectivity reach 50%.
Preferably, described step（3）In, it is described containing the adhesive starched in vain by Resin A, curing agent, white slurry, dilution Agent presses 100:9:40:55.
Preferably, described Resin A is solvent type resin or water-base resin.
Preferably, described curing agent is amino curing agent or isocyanate curing agent.
Preferably, described step（5）In, described transfer modes are：The printing color pattern on one layer of carrier, then Multicolour pattern on carrier is transferred to the surface of base material 21 of soot layer 2 by transfer modes, colored design layer 1 is formed.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：In the surface coated with resins B of base material 21 And dry, glass microballoon 22 half is implanted into resin, soot layer 2 is formed, described base material 21 for PET or or PET it is compound Film.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：Described base material 21 is compound for PE Film, is heated to PE composite membranes, the PE layers of PE composite membrane outer layers is softened later half parcel glass microballoon 22, so as to form glass Microbead layer 2.
Embodiment 6
A kind of preparation method of colored total-light-reflection fabric, described preparation method comprises the following steps：
（1）A base material 21 is taken, glass microballoon 22 is implanted on base material 21, soot layer 2 is formed；
（2）At least three layers translucent plating are coated by gas phase coating method successively on the surface of glass microballoon 22 of soot layer 2 Film layer 31, so as to form reflecting layer 3；
（3）In step（2）The coating of the surface of reflecting layer 3 containing the adhesive starched in vain and drying, form adhesive layer 4；
（4）A precoat 5 is taken, by precoat 5 and step（3）In adhesive layer 4 fit, formed white reflection fabric；
（5）In the surface transfer of base material 21 or printing color pattern of soot layer 2, colored design layer 1 is formed, so as to obtain coloured silk Color total-light-reflection fabric.
Preferably, described step（2）In, coated successively on the glass microballoon surface of soot layer 2 three layers it is semi-transparent Bright film plating layer 31, three layers of described translucent film plating layer 31 are followed successively by zinc sulphide film plating layer, magnesium fluoride film plating layer, zinc sulphide plated film Layer, the coating thickness of first layer zinc sulphide film plating layer is 24 nanometer and the reflectivity of coating back reflection layer 3 reaches 25%, the second layer The coating thickness of magnesium fluoride film plating layer be 20 nanometers and coating back reflection layer 3 reflectivity reach 15%, third layer zinc sulphide plated film Layer coating thickness for 20 nanometers and coating back reflection layer 3 reflectivity reach 50%.
Preferably, described step（3）In, it is described containing the adhesive starched in vain by Resin A, curing agent, white slurry, dilution Agent presses 100:4:25:40.
Preferably, described Resin A is solvent type resin or water-base resin.
Preferably, described curing agent is amino curing agent or isocyanate curing agent.
Preferably, described step（5）In, described transfer modes are：The printing color pattern on one layer of carrier, then Multicolour pattern on carrier is transferred to the surface of base material 21 of soot layer 2 by transfer modes, colored design layer 1 is formed.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：In the surface coated with resins B of base material 21 And dry, glass microballoon 22 half is implanted into resin, soot layer 2 is formed, described base material 21 for PET or or PET it is compound Film.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：Described base material 21 is compound for PE Film, is heated to PE composite membranes, the PE layers of PE composite membrane outer layers is softened later half parcel glass microballoon 22, so as to form glass Microbead layer 2.
Embodiment 7
A kind of preparation method of colored total-light-reflection fabric, described preparation method comprises the following steps：
（1）A base material 21 is taken, glass microballoon 22 is implanted on base material 21, soot layer 2 is formed；
（2）At least three layers translucent plating are coated by gas phase coating method successively on the surface of glass microballoon 22 of soot layer 2 Film layer 31, so as to form reflecting layer 3；
（3）In step（2）The coating of the surface of reflecting layer 3 containing the adhesive starched in vain and drying, form adhesive layer 4；
（4）A precoat 5 is taken, by precoat 5 and step（3）In adhesive layer 4 fit, formed white reflection fabric；
（5）In the surface transfer of base material 21 or printing color pattern of soot layer 2, colored design layer 1 is formed, so as to obtain coloured silk Color total-light-reflection fabric.
Preferably, described step（2）In, coated successively on the glass microballoon surface of soot layer 2 three layers it is semi-transparent Bright film plating layer 31, three layers of described translucent film plating layer 31 are followed successively by zinc sulphide film plating layer, magnesium fluoride film plating layer, zinc sulphide plated film Layer, the coating thickness of first layer zinc sulphide film plating layer is 18 nanometer and the reflectivity of coating back reflection layer 3 reaches 25%, the second layer The coating thickness of magnesium fluoride film plating layer be 26 nanometers and coating back reflection layer 3 reflectivity reach 15%, third layer zinc sulphide plated film Layer coating thickness for 20 nanometers and coating back reflection layer 3 reflectivity reach 50%.
Preferably, described step（3）In, it is described containing the adhesive starched in vain by Resin A, curing agent, white slurry, dilution Agent presses 100:8:25:40.
Preferably, described Resin A is solvent type resin or water-base resin.
Preferably, described curing agent is amino curing agent or isocyanate curing agent.
Preferably, described step（5）In, described transfer modes are：The printing color pattern on one layer of carrier, then Multicolour pattern on carrier is transferred to the surface of base material 21 of soot layer 2 by transfer modes, colored design layer 1 is formed.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：In the surface coated with resins B of base material 21 And dry, glass microballoon 22 half is implanted into resin, soot layer 2 is formed, described base material 21 for PET or or PET it is compound Film.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：Described base material 21 is compound for PE Film, is heated to PE composite membranes, the PE layers of PE composite membrane outer layers is softened later half parcel glass microballoon 22, so as to form glass Microbead layer 2.
Embodiment 8
A kind of preparation method of colored total-light-reflection fabric, described preparation method comprises the following steps：
（1）A base material 21 is taken, glass microballoon 22 is implanted on base material 21, soot layer 2 is formed；
（2）At least three layers translucent plating are coated by gas phase coating method successively on the surface of glass microballoon 22 of soot layer 2 Film layer 31, so as to form reflecting layer 3；
（3）In step（2）The coating of the surface of reflecting layer 3 containing the adhesive starched in vain and drying, form adhesive layer 4；
（4）A precoat 5 is taken, by precoat 5 and step（3）In adhesive layer 4 fit, formed white reflection fabric；
（5）In the surface transfer of base material 21 or printing color pattern of soot layer 2, colored design layer 1 is formed, so as to obtain coloured silk Color total-light-reflection fabric.
Preferably, described step（2）In, coated successively on the glass microballoon surface of soot layer 2 three layers it is semi-transparent Bright film plating layer 31, three layers of described translucent film plating layer 31 are followed successively by zinc sulphide film plating layer, magnesium fluoride film plating layer, zinc sulphide plated film Layer, the coating thickness of first layer zinc sulphide film plating layer is 18 nanometer and the reflectivity of coating back reflection layer 3 reaches 25%, the second layer The coating thickness of magnesium fluoride film plating layer be 20 nanometers and coating back reflection layer 3 reflectivity reach 15%, third layer zinc sulphide plated film Layer coating thickness for 24 nanometers and coating back reflection layer 3 reflectivity reach 50%.
Preferably, described step（3）In, it is described containing the adhesive starched in vain by Resin A, curing agent, white slurry, dilution Agent presses 100:5:25:40.
Preferably, described Resin A is solvent type resin or water-base resin.
Preferably, described curing agent is amino curing agent or isocyanate curing agent.
Preferably, described step（5）In, described transfer modes are：The printing color pattern on one layer of carrier, then Multicolour pattern on carrier is transferred to the surface of base material 21 of soot layer 2 by transfer modes, colored design layer 1 is formed.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：In the surface coated with resins B of base material 21 And dry, glass microballoon 22 half is implanted into resin, soot layer 2 is formed, described base material 21 for PET or or PET it is compound Film.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：Described base material 21 is compound for PE Film, is heated to PE composite membranes, the PE layers of PE composite membrane outer layers is softened later half parcel glass microballoon 22, so as to form glass Microbead layer 2.
Embodiment 9
A kind of preparation method of colored total-light-reflection fabric, described preparation method comprises the following steps：
（1）A base material 21 is taken, glass microballoon 22 is implanted on base material 21, soot layer 2 is formed；
（2）At least three layers translucent plating are coated by gas phase coating method successively on the surface of glass microballoon 22 of soot layer 2 Film layer 31, so as to form reflecting layer 3；
（3）In step（2）The coating of the surface of reflecting layer 3 containing the adhesive starched in vain and drying, form adhesive layer 4；
（4）A precoat 5 is taken, by precoat 5 and step（3）In adhesive layer 4 fit, formed white reflection fabric；
（5）In the surface transfer of base material 21 or printing color pattern of soot layer 2, colored design layer 1 is formed, so as to obtain coloured silk Color total-light-reflection fabric.
Preferably, described step（2）In, coated successively on the glass microballoon surface of soot layer 2 three layers it is semi-transparent Bright film plating layer 31, three layers of described translucent film plating layer 31 are followed successively by zinc sulphide film plating layer, magnesium fluoride film plating layer, zinc sulphide plated film Layer, the coating thickness of first layer zinc sulphide film plating layer is 20 nanometer and the reflectivity of coating back reflection layer 3 reaches 40%, the second layer The coating thickness of magnesium fluoride film plating layer be 25 nanometers and coating back reflection layer 3 reflectivity reach 35%, third layer zinc sulphide plated film Layer coating thickness for 22 nanometers and coating back reflection layer 3 reflectivity reach 70%.
Preferably, described step（3）In, it is described containing the adhesive starched in vain by Resin A, curing agent, white slurry, dilution Agent presses 100:6:25:40.
Preferably, described Resin A is solvent type resin or water-base resin.
Preferably, described curing agent is amino curing agent or isocyanate curing agent.
Preferably, described step（5）In, described transfer modes are：The printing color pattern on one layer of carrier, then Multicolour pattern on carrier is transferred to the surface of base material 21 of soot layer 2 by transfer modes, colored design layer 1 is formed.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：In the surface coated with resins B of base material 21 And dry, glass microballoon 22 half is implanted into resin, soot layer 2 is formed, described base material 21 for PET or or PET it is compound Film.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：Described base material 21 is compound for PE Film, is heated to PE composite membranes, the PE layers of PE composite membrane outer layers is softened later half parcel glass microballoon 22, so as to form glass Microbead layer 2.
Embodiment 10
A kind of preparation method of colored total-light-reflection fabric, described preparation method comprises the following steps：
（1）A base material 21 is taken, glass microballoon 22 is implanted on base material 21, soot layer 2 is formed；
（2）At least three layers translucent plating are coated by gas phase coating method successively on the surface of glass microballoon 22 of soot layer 2 Film layer 31, so as to form reflecting layer 3；
（3）In step（2）The coating of the surface of reflecting layer 3 containing the adhesive starched in vain and drying, form adhesive layer 4；
（4）A precoat 5 is taken, by precoat 5 and step（3）In adhesive layer 4 fit, formed white reflection fabric；
（5）In the surface transfer of base material 21 or printing color pattern of soot layer 2, colored design layer 1 is formed, so as to obtain coloured silk Color total-light-reflection fabric.
Preferably, described step（2）In, coated successively on the glass microballoon surface of soot layer 2 three layers it is semi-transparent Bright film plating layer 31, three layers of described translucent film plating layer 31 are followed successively by zinc sulphide film plating layer, magnesium fluoride film plating layer, zinc sulphide plated film Layer, the coating thickness of first layer zinc sulphide film plating layer is 23 nanometer and the reflectivity of coating back reflection layer 3 reaches 35%, the second layer The coating thickness of magnesium fluoride film plating layer be 22 nanometers and coating back reflection layer 3 reflectivity reach 32%, third layer zinc sulphide plated film Layer coating thickness for 21 nanometers and coating back reflection layer 3 reflectivity reach 65%.
Preferably, described step（3）In, it is described containing the adhesive starched in vain by Resin A, curing agent, white slurry, dilution Agent presses 100:7:25:40.
Preferably, described Resin A is solvent type resin or water-base resin.
Preferably, described curing agent is amino curing agent or isocyanate curing agent.
Preferably, described step（5）In, described transfer modes are：The printing color pattern on one layer of carrier, then Multicolour pattern on carrier is transferred to the surface of base material 21 of soot layer 2 by transfer modes, colored design layer 1 is formed.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：In the surface coated with resins B of base material 21 And dry, glass microballoon 22 half is implanted into resin, soot layer 2 is formed, described base material 21 for PET or or PET it is compound Film.
Preferably, described step（1）In, the implantation of glass microballoon 22 is：Described base material 21 is compound for PE Film, is heated to PE composite membranes, the PE layers of PE composite membrane outer layers is softened later half parcel glass microballoon 22, so as to form glass Microbead layer 2.
In a word, presently preferred embodiments of the present invention is the foregoing is only, it is equal that all scopes according to the present patent application patent are made Deng change and modification, it should all belong to the covering scope of the present invention.

Claims (10)

1. a kind of preparation method of colored total-light-reflection fabric, it is characterised in that：Described preparation method comprises the following steps：
（1）Take a base material（21）, in base material（21）Upper implantation glass microballoon（22）, form soot layer（2）；
（2）In soot layer（2）Glass microballoon（22）Surface by gas phase coating method coat successively at least three layers it is semi-transparent Bright film plating layer（31）, so as to form reflecting layer（3）；
（3）In step（2）Reflecting layer（3）Surface coating forms adhesive layer containing the adhesive and drying starched in vain（4）；
（4）Take a precoat（5）, by precoat（5）With step（3）In adhesive layer（4）Laminating, forms white reflection fabric；
（5）In soot layer（2）Base material（21）Surface transfer or printing color pattern, form colored design layer（1）, so that Obtain colored total-light-reflection fabric.
2. a kind of preparation method of colored total-light-reflection fabric according to claim 1, it is characterised in that：Described step （2）In, in soot layer（2）Glass microballoon surface coat three layers of translucent film plating layer successively（31）, described three and half Transparent coating layer（31）It is followed successively by zinc sulphide film plating layer, magnesium fluoride film plating layer, zinc sulphide film plating layer, first layer zinc sulphide film plating layer Coating thickness for 10 nanometers~50 nanometers and coating back reflection layer（3）Reflectivity reach 10%~40%, second layer magnesium fluoride The coating thickness of film plating layer is 15 nanometers~45 nanometers and coating back reflection layer（3）Reflectivity reach 5%~35%, third layer sulphur The coating thickness for changing zinc film plating layer is 15 nanometers~35 nanometers and coating back reflection layer（3）Reflectivity reach 20%~70%.
3. a kind of preparation method of colored total-light-reflection fabric according to claim 2, it is characterised in that：First layer zinc sulphide The coating thickness of film plating layer is 18 nanometers~24 nanometers and coating back reflection layer（3）Reflectivity reach 25%~40%, the second layer The coating thickness of magnesium fluoride film plating layer is 20 nanometers~26 nanometers and coating back reflection layer（3）Reflectivity reach 15%~35%, The coating thickness of third layer zinc sulphide film plating layer is 20 nanometers~24 nanometers and coating back reflection layer（3）Reflectivity reach 50% ~70%.
4. a kind of preparation method of colored total-light-reflection fabric according to claim 1, it is characterised in that：Described step （3）In, it is described containing the adhesive starched in vain by Resin A, curing agent, white slurry, diluent by 100:2:10:20~100:15:50: 80 proportions are formed.
5. a kind of preparation method of colored total-light-reflection fabric according to claim 4, it is characterised in that：Described starches containing white Adhesive press 100 by Resin A, curing agent, white slurry, diluent:4:25:40~100:8:25:40 proportions are formed.
6. a kind of preparation method of colored total-light-reflection fabric according to claim 4, it is characterised in that：Described Resin A For solvent type resin or water-base resin.
7. a kind of preparation method of colored total-light-reflection fabric according to claim 4, it is characterised in that：Described curing agent For amino curing agent or isocyanate curing agent.
8. a kind of preparation method of colored total-light-reflection fabric according to claim 1, it is characterised in that：Described step （5）In, described transfer modes are：The printing color pattern on one layer of carrier, then the multicolour pattern on carrier is passed through into transfer Mode is transferred to soot layer（2）Base material（21）Surface, forms colored design layer（1）.
9. a kind of preparation method of colored total-light-reflection fabric according to claim 1, it is characterised in that：Described step （1）In, glass microballoon（22）Implantation be：In base material（21）Surface coated with resins B and drying, by glass microballoon（22）Half It is implanted into resin, forms soot layer（2）, described base material（21）For PET or PET composite membranes.
10. a kind of preparation method of colored total-light-reflection fabric according to claim 1, it is characterised in that：Described step （1）In, glass microballoon（22）Implantation be：Described base material（21）For PE composite membranes, PE composite membranes are heated, made The PE layers of PE composite membrane outer layers soften later half parcel glass microballoon（22）, so as to form soot layer（2）.
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CN108673985A (en) * 2018-06-14 2018-10-19 广东昂斯新材料技术有限公司 A kind of color reflective material and preparation method thereof that band is textured
CN109466141A (en) * 2018-11-24 2019-03-15 东莞市三人行反光材料有限公司 Colored illusion-colour light reflecting transfer film
JP2020008797A (en) * 2018-07-12 2020-01-16 株式会社小松プロセス Retroreflection material, retroreflection object, retroreflective ink or paint, manufacturing method of retroreflective sheet, and manufacturing method of retroreflection object
CN110749947A (en) * 2019-10-29 2020-02-04 浙江龙游道明光学有限公司 Method for manufacturing high-visual-contrast reflective film
CN111610585A (en) * 2020-06-17 2020-09-01 南阳市新长兴光学科技有限公司 Flexible washable colorful reflective fabric
CN114836137A (en) * 2022-04-27 2022-08-02 石狮市晓光服饰反光材料有限公司 Colorful light-reflecting fabric and preparation method thereof
CN114953614A (en) * 2022-03-17 2022-08-30 江苏康大无纺有限公司 Damp-proof quilt for hot-zone island and preparation method thereof

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CN105334559A (en) * 2015-12-09 2016-02-17 施盈吉 High-brightness light-reflecting light-emitting film, making method and article of high-brightness light-reflecting light-emitting film
CN106707386A (en) * 2017-01-21 2017-05-24 浙江夜光明光电科技股份有限公司 Color high light heat pasting film

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CN101680977A (en) * 2007-06-19 2010-03-24 株式会社丸仁 Iridescent reflected light emitting retroreflective material
CN105334559A (en) * 2015-12-09 2016-02-17 施盈吉 High-brightness light-reflecting light-emitting film, making method and article of high-brightness light-reflecting light-emitting film
CN106707386A (en) * 2017-01-21 2017-05-24 浙江夜光明光电科技股份有限公司 Color high light heat pasting film

Cited By (9)

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Publication number Priority date Publication date Assignee Title
CN108673985A (en) * 2018-06-14 2018-10-19 广东昂斯新材料技术有限公司 A kind of color reflective material and preparation method thereof that band is textured
JP2020008797A (en) * 2018-07-12 2020-01-16 株式会社小松プロセス Retroreflection material, retroreflection object, retroreflective ink or paint, manufacturing method of retroreflective sheet, and manufacturing method of retroreflection object
CN109466141A (en) * 2018-11-24 2019-03-15 东莞市三人行反光材料有限公司 Colored illusion-colour light reflecting transfer film
CN110749947A (en) * 2019-10-29 2020-02-04 浙江龙游道明光学有限公司 Method for manufacturing high-visual-contrast reflective film
CN110749947B (en) * 2019-10-29 2021-06-01 浙江龙游道明光学有限公司 Method for manufacturing high-visual-contrast reflective film
CN111610585A (en) * 2020-06-17 2020-09-01 南阳市新长兴光学科技有限公司 Flexible washable colorful reflective fabric
CN114953614A (en) * 2022-03-17 2022-08-30 江苏康大无纺有限公司 Damp-proof quilt for hot-zone island and preparation method thereof
CN114953614B (en) * 2022-03-17 2024-05-03 江苏康大无纺有限公司 Island moistureproof quilt in hot area and preparation method thereof
CN114836137A (en) * 2022-04-27 2022-08-02 石狮市晓光服饰反光材料有限公司 Colorful light-reflecting fabric and preparation method thereof

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