CN107142428A - A kind of Cr Mo Ni steel alloys and preparation method thereof - Google Patents

A kind of Cr Mo Ni steel alloys and preparation method thereof Download PDF

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Publication number
CN107142428A
CN107142428A CN201710255728.2A CN201710255728A CN107142428A CN 107142428 A CN107142428 A CN 107142428A CN 201710255728 A CN201710255728 A CN 201710255728A CN 107142428 A CN107142428 A CN 107142428A
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steel
alloy
cooling
dispensing
casting
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CN107142428B (en
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王军
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Ma'anshan Xinlong Special Steel Co Ltd
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Ma'anshan Xinlong Special Steel Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/52Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/19Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • C21D1/20Isothermal quenching, e.g. bainitic hardening
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/28Normalising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention discloses a kind of Cr Mo Ni steel alloys and preparation method thereof, the mass fraction of the steel alloy is:C:0.5 0.6%, Cr:1.0 2.0%, Mo:0.8 1.2%, Ni:2.5 3.0%, Mn:0.1 0.25%, Si:0.2 0.3%, Al:0.2%, Cu:0.3%, Co:0.06%, P:0.08%, S:0.02%, surplus is Fe.By intermediate frequency furnace melting prepared by steel alloy to steel-casting, molten steel cool before cast and poured into a mould after constant temperature holding, and solidification smaller to wall thickness very fast place's isothermal holding during cast, and alloy steel piece is subjected to normalizing and salt bath austempering processing, obtain substantial amounts of pearlized matrix and lower bainite tissue so that alloy rigidity, anti-wear performance and Thermal Resistant Surface performance are greatly improved.

Description

A kind of Cr-Mo-Ni steel alloys and preparation method thereof
Technical field
The present invention relates to metal material field, more specifically a kind of Cr-Mo-Ni steel alloys and preparation method thereof.
Background technology
Steel alloy is the important raw and processed materials of vehicle production parts, and with continuing to develop for automobile industry, automobile is past The direction of lightweight and energy-saving consumption-reducing is developed, and this is accomplished by the structural strength in steel alloy with functionally there is higher requirement, Preferable machining property is needed simultaneously, and such requirement, which is not only, meets automobile using upper primary condition, while It is the safe and reliable guarantee increased the service life.In the prior art, the steel of auto parts machinery are mostly that common middle low content is closed , because these automobile metal accessories are using being usually functionally frequently moving component, often there is fretting wear problem in Jin Gang, Change frequent, add maintenance cost.A kind of raising hardness and anti-wear performance are searched out, while piece surface heat resistance is high It is extremely important that the steel alloy of middle low content just shows.
The content of the invention
There is the good Cr-Mo- of high intensity, wearability in view of the deficiencies of the prior art, the present invention provides a kind of new component Ni steel alloys.
The present invention is realized by following technological means solves above-mentioned technical problem:
A kind of Cr-Mo-Ni steel alloys, the mass fraction of the steel alloy is:C:0.5-0.6%, Cr:1.0-2.0%, Mo:0.8- 1.2%, Ni:2.5-3.0%, Mn:0.1-0.25%, Si:0.2-0.3%, Al:0.2%, Cu:0.3%, Co:0.06%, P: 0.08%, S:0.02%, surplus is Fe and other impurities.
It is preferred that, other impurities include micro B, Ti and Ca, and content of impurities is not higher than 0.05%.
The Cr-Mo-Ni steel alloys, including following preparation process:
Dispensing:It is by mass fraction:C:0.5-0.6%, Cr:1.0-2.0%, Mo:0.8-1.2%, Ni:2.5-3.0%, Mn:0.1-0.25%, Si:0.2-0.3%, Al:0.2%, Cu:0.3%, Co:0.06%, P:0.08%, S:0.02% and Fe Dispensing is completed after well mixed.
The dispensing mixed is put into intermediate frequency furnace melting, and to prepare in steel alloy, fusion process moment detection control molten Temperature is refined, molten steel carries out 60 DEG C -80 DEG C of cooling first when pouring into a mould, constant temperature keeps carrying out moulding by casting again in 20 minutes again after cooling, The very fast place's isothermal holding of and solidification smaller to wall thickness keeps solution mobility in casting process, and quick water cooling work is used during cooling Skill;
The alloy steel piece of moulding by casting is subjected to normalizing and means of isothermal quenching;First by alloy steel piece be heated to 800 DEG C- 1000 DEG C, 3 hours are incubated, 600 DEG C -800 DEG C are then reduced the temperature to, 2 hours is incubated, finally comes out of the stove and be air-cooled to room temperature;It is described Quenching using 160 ± 20 DEG C of salt bath austempering processing, is air-cooled to room temperature first.
The advantage of the invention is that:Carry out cooling processing constant temperature holding 20 minutes before steel alloy cast to molten steel first, really Protect pouring temperature suitable, while the very fast place's isothermal holding of smaller to wall thickness in casting process and solidification keeps solution mobility, carry The high interior tissue uniformity and filling integrality of alloy steel piece, steel alloy passes through normalizing and means of isothermal quenching, on the one hand Higher pearlite matrix is obtained, thinning microstructure improves the hardness and anti-wear performance of material;On the other hand, by keeping for a long time Isothermal hardening in Lower Bainite Transformation area, makes alloy realize the isothermal transformation of austenite, obtains lower bainite tissue.The present invention Beneficial effect be that substantial amounts of pearlized matrix is obtained by normalizing procedure, and by selecting 230 ± 20 DEG C of salt bath austempering, The austenite of steel alloy is set to be transformed into lower bainite tissue so that alloy rigidity, anti-wear performance and Thermal Resistant Surface performance are obtained Very big raising.
Embodiment
With reference to embodiment, the invention will be further described, it is clear that these embodiments are only used for the purpose of illustration, absolutely Do not limit the scope of the invention.
Embodiment 1
A kind of Cr-Mo-Ni steel alloys, the mass fraction of steel alloy is:C:0.5%, Cr:2.0%, Mo:0.8%, Ni:2.5%, Mn:0.2%, Si:0.2%, Al:0.2%, Cu:0.3%, Co:0.06%, P:0.08%, S:0.02% and Fe.Preparation process It is as follows:
Dispensing:It is C by mass fraction:0.5%, Cr:2.0%, Mo:0.8%, Ni:2.5%, Mn:0.2%, Si:0.2%, Al:0.2%, Cu:0.3%, Co:0.06%, P:0.08%, S:Dispensing is completed after 0.02% and Fe raw materials are well mixed.
The dispensing mixed is put into intermediate frequency furnace melting, and to prepare in steel alloy, fusion process moment detection control molten Temperature is refined, molten steel carries out 60 DEG C -80 DEG C of cooling first when pouring into a mould, constant temperature keeps carrying out moulding by casting again in 20 minutes again after cooling, The very fast place's isothermal holding of and solidification smaller to wall thickness keeps solution mobility in casting process, and quick water cooling work is used during cooling Skill;
The alloy steel piece of moulding by casting is subjected to normalizing and means of isothermal quenching;First by alloy steel piece be heated to 800 DEG C- 1000 DEG C, 3 hours are incubated, 600 DEG C -800 DEG C are then reduced the temperature to, 2 hours is incubated, finally comes out of the stove and be air-cooled to room temperature;It is described Quenching using 160 ± 20 DEG C of salt bath austempering processing, is air-cooled to room temperature first.
Alloy steel piece outer surface during to casting complete is observed lacks material defect without obvious shrinkage cavity and porosity and filling.
Metallographic structure observation is done to obtained Cr-Mo-Ni alloy steel curved beams, it is found that it is organized as pearlitic structrure and lower shellfish Family name organizes.
Hardness determination, hardness determination value HRC56 are carried out to obtained alloy.
Embodiment 2
A kind of Cr-Mo-Ni steel alloys, mass fraction is:C:0.5%, Cr:2.0%, Mo:1.2%, Ni:3.0%, Mn: 0.1%, Si:0.2%, Al:0.2%, Cu:0.3%, Co:0.06%, P:0.08%, S:0.02% and surplus Fe.
Steel ingot part preparation, alloy steel piece outer surface during to casting complete are carried out using the identical preparation method of embodiment 1 Observed and lack material defect without obvious shrinkage cavity and porosity and filling.
Metallographic structure observation is done to obtaining Cr-Mo-Ni alloy steel curved beams, it is found that it is organized as pearlitic structrure and lower bayesian Tissue.
Hardness determination, hardness determination value HRC57 are carried out to obtained alloy.
Embodiment 3
A kind of Cr-Mo-Ni steel alloys, mass fraction is:C:0.5%, Cr:1.5%, Mo:1.0%, Ni:2.5%, Mn: 0.2%, Si:0.3%, Al:0.2%, Cu:0.3%, Co:0.06%, P:0.08%, S:0.02% and Fe.
Using the identical preparation method of embodiment 1 carry out steel ingot part preparation, its outer surface is observed without obvious shrinkage cavity, Shrinkage porosite and filling lack material defect.
Metallographic structure observation is done to obtaining Cr-Mo-Ni alloy steel curved beams, it is found that it is organized as pearlitic structrure and lower bayesian Tissue.
Hardness determination, hardness determination value HRC55 are carried out to obtained alloy.
Cr-Mo-Ni of embodiment of the present invention steel alloys find pearlitic structrure and lower bayesian tissue, and have obtained higher Hardness number, meets auto parts and components high intensity, wearability demand.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention is described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic;And these modification or Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (2)

1. a kind of Cr-Mo-Ni steel alloys, it is characterised in that the mass fraction of the steel alloy is:C:0.5-0.6%, Cr:1.0- 2.0%, Mo:0.8-1.2%, Ni:2.5-3.0%, Mn:0.1-0.25%, Si:0.2-0.3%, Al:0.2%, Cu:0.3%, Co:0.06%, P:0.08%, S:0.02%, surplus is Fe.
2. a kind of Cr-Mo-Ni steel alloys preparation method, including following preparation process:
Dispensing:It is by mass fraction:C:0.5-0.6%, Cr:1.0-2.0%, Mo:0.8-1.2%, Ni:2.5-3.0%, Mn: 0.1-0.25%, Si:0.2-0.3%, Al:0.2%, Cu:0.3%, Co:0.06%, P:0.08%, S:0.02% and Fe is mixed Dispensing is completed after uniform;
The dispensing mixed is put into intermediate frequency furnace melting and prepares moment detection control melting temperature in steel alloy, fusion process Degree, molten steel carries out 60 DEG C -80 DEG C of cooling first when pouring into a mould, constant temperature keeps carrying out within 20 minutes moulding by casting again again after cooling, pours into a mould During the very fast place's isothermal holding of and solidification smaller to wall thickness keep solution mobility, quick water-cooling process is used during cooling;
The alloy steel piece of moulding by casting is subjected to normalizing and means of isothermal quenching, first by alloy steel piece be heated to 800 DEG C- 1000 DEG C, 3 hours are incubated, 600 DEG C -800 DEG C are then reduced the temperature to, 2 hours is incubated, finally comes out of the stove and be air-cooled to room temperature;It is described Quenching using 160 ± 20 DEG C of salt bath austempering processing, is air-cooled to room temperature first.
CN201710255728.2A 2017-04-19 2017-04-19 A kind of preparation method of Cr-Mo-Ni steel alloy Active CN107142428B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112662957A (en) * 2020-12-09 2021-04-16 暨南大学 Bainite wear-resistant cast steel with strong wear hardening capacity and preparation method and application thereof

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CN104328363A (en) * 2014-10-20 2015-02-04 俞虹 High-hardness alloy steel
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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