CN107141979A - A kind of super-hydrophobic polyester protective paint - Google Patents
A kind of super-hydrophobic polyester protective paint Download PDFInfo
- Publication number
- CN107141979A CN107141979A CN201710354679.8A CN201710354679A CN107141979A CN 107141979 A CN107141979 A CN 107141979A CN 201710354679 A CN201710354679 A CN 201710354679A CN 107141979 A CN107141979 A CN 107141979A
- Authority
- CN
- China
- Prior art keywords
- super
- protective paint
- polyester protective
- hydrophobic
- fine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of super-hydrophobic polyester protective paint, the invention belongs to chemical technology field, its formula is characterized in：It is made up of the styrene of polyester resin molten night, plain boiled water, Lan Shui, paraffin styrene solution, zinc oxide ultra_fine powderses, ultra-fine Fischer-Tropsch wax micro mist, dimethyl ketone, dispersant 904S, calcium carbonate kaolin.The finished product of the present invention can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing and ship, bridge, the surface of all kinds of outdoor indoor hardware equipment, be the coating that its work is protected.The present invention has micron order and the dual coarse structure of nanoscale simultaneously, so just having the super-hydrophobic self-cleaning function of lotus leaf effect, after product using the present invention, the surface long term of object need not manually be cleaned and returned newly from overcoating brush, save substantial amounts of manpower and materials, also do not corroded simultaneously by wind and rain, the service life of 3 times of conventional polyester protective paints, strictly a kind of service life is permanent and super-hydrophobic polyester protective paint of excellent performance.
Description
Technical field
The invention belongs to chemical field, the present invention relates to a kind of Polyester Paint, and in particular to be a kind of super-hydrophobic polyester
Protective paint.
Background technology
Polyester protective paint is that one kind can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing, hull bottom is anti-swims
The protective coating for the structure such as biological, deck is anti-wear.But polyester protective lacquer coat does not have hydrophobic self-cleaning function, short-term very important person
Work is cleaned and returned newly from overcoating brush, and service life is not long, wastes manpower and materials.
The content of invention
The purpose of the present invention is：There is provided it is a kind of there is self-cleaning function, need not manually clean for a long time and from overcoating brush return newly,
A large amount of manpower and materials can be saved, not by erosion by wind and rain, service life is permanent and super-hydrophobic polyester protective paint of excellent performance.
To achieve the above object, the technical solution adopted in the present invention is a kind of super-hydrophobic polyester protective paint, and it is formulated
It is characterized in：By the styrene solution of polyester resin, plain boiled water, Lan Shui, paraffin styrene solution, zinc oxide ultra_fine powderses (0.1um~
0.5um particle diameters), ultra-fine Fischer-Tropsch wax micro mist (15nm~65nm particle diameters), dimethyl ketone, dispersant 904S, calcium carbonate kaolinite local soil type
Into.
The percentage by weight of its component is：
Beneficial effects of the present invention：The present invention is that zinc oxide ultra_fine powderses (0.1um~0.5um particle diameters), ultra-fine Fischer-Tropsch wax is micro-
The peptizaiton that powder (15nm~65nm particle diameters) is risen by dispersant 904S, is highly dispersed in polyester protective paint, distributive law
More than 97%, after the finished product using the present invention, the super-hydrophobic self-cleaning surface of paint film formation tool lotus leaf effect is determined with half ball
The contact angle of multiple polyester protective paint film samples and water, more than 150 °；Moreover, sample is carried out by using electron microscope
Observation, find its surface while having micron order and the dual coarse structure of nanoscale.The finished product of the present invention can apply to steel
Anti-corrosion, wood preservation erosion, concrete carbonization preventing and ship, bridge, the surface of all kinds of outdoor indoor hardware equipment, make object
Surface there is the super-hydrophobic self-cleaning function of lotus leaf effect, need not can manually clean and be returned newly from overcoating brush for a long time, save
Substantial amounts of manpower and materials, and do not corroded by wind and rain, the service life of 3 times of conventional polyester protective paints, it is that one kind uses the longevity
Order the super-hydrophobic polyester protective paint of permanent and excellent performance.
Embodiment
The following examples are that the present invention is made further to prove, the invention is not restricted to this.
Embodiment one
A kind of super-hydrophobic polyester protective paint, its component and weight proportion are as follows：
Embodiment two
A kind of super-hydrophobic polyester protective paint, its component and weight proportion are as follows：
Embodiment three
A kind of super-hydrophobic polyester protective paint, its component and weight proportion are as follows：
Finished product obtained by the three above embodiment of the present invention is respectively coated on three pieces of slides, surveyed with half ball
The contact angle of fixed these three samples and water：
1st, the contact angle of the slide sample of embodiment one and water is 152.6 °
2nd, the contact angle of the slide sample of embodiment two and water is 150.8 °
3rd, the contact angle of the slide sample of embodiment three and water is 151.8 °
The sample of three above embodiment is determined with half ball, finished product its surface wettability of the present invention is all showed
For superhydrophobic characteristic.
A kind of super-hydrophobic polyester protective paint of the present invention, applies in western district of Guangdong, Duo Jia advertising companies has been supplied, at it
Used on the surface of outdoor large advertisement metal structure skeleton；Made comparisons with common polyester protective paint, product institute of the invention
Super-hydrophobic self-cleaning function with lotus leaf effect, makes the surface of metal structure not corroded by wind and rain, permanent light such as new, saving
Substantial amounts of manpower and materials, product of the invention has the service life of 3 times of conventional polyester protective paints, and strictly one kind uses the longevity
Order the super-hydrophobic polyester protective paint of permanent and excellent performance.
Claims (2)
1. a kind of super-hydrophobic polyester protective paint, it is characterised in that：The percentage by weight of the formula each component is：Polyester resin
Styrene solution 50%--83%, plain boiled water 2%--22%, Lan Shui 2%--24%, paraffin styrene solution 3%--23%, oxidation
Zinc powder 3%--25%, ultra-fine Fischer-Tropsch wax micro mist 2%--26%, dimethyl ketone 2%--22%, dispersant 904S 2%--
24%th, calcium carbonate kaolin 1%--23%.
2. a kind of super-hydrophobic polyester protective paint according to claim 1, it is characterized in that：Zinc oxide ultra_fine powderses 0.1um~
0.5um particle diameters, ultra-fine Fischer-Tropsch wax micro mist 15nm~65nm particle diameters, the peptizaiton risen by dispersant 904S, high degree of dispersion
In polyester protective paint, distributive law is more than 97%, and using after this finished product, paint film formation has the super-hydrophobic self-cleaning table of lotus leaf effect
Face, the contact angle of multiple polyester protective paint film samples and water is determined with half ball, more than 150 °.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710354679.8A CN107141979A (en) | 2017-05-11 | 2017-05-11 | A kind of super-hydrophobic polyester protective paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710354679.8A CN107141979A (en) | 2017-05-11 | 2017-05-11 | A kind of super-hydrophobic polyester protective paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107141979A true CN107141979A (en) | 2017-09-08 |
Family
ID=59777544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710354679.8A Pending CN107141979A (en) | 2017-05-11 | 2017-05-11 | A kind of super-hydrophobic polyester protective paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107141979A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104212316A (en) * | 2014-09-11 | 2014-12-17 | 叶长青 | Stain-resistant latex paint |
| CN105694682A (en) * | 2016-03-24 | 2016-06-22 | 安徽圣德建材科技有限公司 | Superhydrophobic polyester resin powder paint |
| CN106381033A (en) * | 2016-08-31 | 2017-02-08 | 黄山天马铝业有限公司 | Ultra-hydrophobic aluminum foil and production method thereof |
-
2017
- 2017-05-11 CN CN201710354679.8A patent/CN107141979A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104212316A (en) * | 2014-09-11 | 2014-12-17 | 叶长青 | Stain-resistant latex paint |
| CN105694682A (en) * | 2016-03-24 | 2016-06-22 | 安徽圣德建材科技有限公司 | Superhydrophobic polyester resin powder paint |
| CN106381033A (en) * | 2016-08-31 | 2017-02-08 | 黄山天马铝业有限公司 | Ultra-hydrophobic aluminum foil and production method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 周长庚: "《实用油漆施工手册》", 31 March 1992, 河北科学技术出版社 * |
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Application publication date: 20170908 |
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