CN107141893A - A kind of weather-proof manifolding paint for papers of ecological, environmental protective and preparation method thereof - Google Patents
A kind of weather-proof manifolding paint for papers of ecological, environmental protective and preparation method thereof Download PDFInfo
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- CN107141893A CN107141893A CN201710420477.9A CN201710420477A CN107141893A CN 107141893 A CN107141893 A CN 107141893A CN 201710420477 A CN201710420477 A CN 201710420477A CN 107141893 A CN107141893 A CN 107141893A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/06—Copolymers with styrene
- C09D109/08—Latex
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D113/00—Coating compositions based on rubbers containing carboxyl groups
- C09D113/02—Latex
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of weather-proof manifolding paint for papers of ecological, environmental protective, include the raw material of following parts by weight:14 20 parts of plant amylum, 40 50 parts of latex, 13 parts of calcium carbonate, 14 parts of talcum powder, 13 parts of sodium carboxymethylcellulose, 24 parts of processing aid, 0.7 1.3 parts of bactericide, 0.4 0.8 parts of nano titanium oxide, 23 parts of additive of coloring.The manifolding paint for papers of the present invention has that preferable dispersion effect and rheological characteristic are good, and foam is less, and its antioxidant capacity and water resistance are stronger, additionally there is certain bactericidal property, it is high using the carbon paper intensity of this coating preparation, warpage is difficult, printing adaptability is good, chromonic layer is coated with evenly, reduce and show money or valuables one carries unintentionally a little, while the raw material components of the present invention employ substantial amounts of plant amylum, safe and reliable, cost is relatively low, technique is concise, with higher practical value and good application prospect.
Description
Technical field
The present invention relates to paper products manufacturing technology field, and in particular to a kind of weather-proof manifolding paint for papers of ecological, environmental protective and its
Preparation method.
Background technology
NCR is a kind of novel carbon paper, and its surface is coated with special coating, and containing in the coating has
Pressure-sensitive effect and electronics supply the leuco dye and the Receptive acid developer material of electronics for the property given.Utilize leuco dye and colour developing
Chemical color reaction, the colour generation directly on paper, so as to show the information such as word, pattern on paper occur for material.At present, factory
While family is desirable in guarantee NCR quality, its production cost is reduced as far as possible.By lifting curtain coater car
To improve the yield of NCR the phenomenons such as point, holiday that show money or valuables one carries unintentionally occur, so as to influence carbonless copying in speed in coating process
The quality of paper.In addition, there is exposed fiber, hole, the apparent defect, very big shadow such as coarse in the body paper surface majority of NCR
The quality of NCR is rung.
Compared with traditional carbon paper, NCR is easy to use and pollution-free, thus is widely used in invoice, computickets
According to grade numerous areas.At present, existing a kind of preparation method of double side blue record carbon-paper, employs the blue face of stability
The grease of material and high-melting-point wax material and non-drying, is made neutral coating, then dip coated is in carbon paper by high speed beater
On be made.Carbon paper writing made from this method is bright-coloured, good endurance, but wax material used and grease are due to without Over emulsfication
Effect becomes water paint, when paper dip-coating contains non-drying oil lipid material, easily pollutes paper, the crocking resistance of paper compared with
Difference, and surface can not print.Also a kind of dry carbon paper and its production method, using body paper coated on one side have isolation and
The isolation coating of binder effect, is then coated with one layer of coloured transfer coating on separation layer.In order to improve carbon paper
Quality, calender press polish is first used using coating machine after intermediate isolating coating, then with coating machine on intermediate isolating coating
Coloured transfer layer is coated with, is then polished.Carbon paper less pollution, writing made from the method are more visible, light resistance is good, with preferable
Antifalsification and archives.But carbon paper is prepared using the method, it is longer to there is complex manufacturing, flow, and coating
Employed in preparation process emulsification and grinding steps, waste time and energy, production efficiency it is not high, and colored coating transfer effect owe
It is good, and increase press polish or polishing process in coating paper production process, add the difficulty and parameter of operation.
The content of the invention
, should it is an object of the invention to provide a kind of weather-proof manifolding paint for papers of ecological, environmental protective for the defect of prior art
Manifolding paint for papers has that preferable dispersion effect and rheological characteristic are good, and foam is less, and its antioxidant capacity and water resistance are stronger, in addition
Also there is certain bactericidal property, it is high using the carbon paper intensity of this coating preparation, warpage is difficult, printing adaptability is good, color development
Layer is coated with evenly, reduces and shows money or valuables one carries unintentionally a little, while the raw material components of the present invention employ substantial amounts of plant amylum, safely may be used
Lean on, cost it is relatively low, technique is concise, with higher practical value and good application prospect.
The present invention solves technical problem and adopted the following technical scheme that:
The invention provides a kind of weather-proof manifolding paint for papers of ecological, environmental protective, include the raw material of following parts by weight:
14-20 parts of plant amylum, 40-50 parts of latex, 1-3 parts of calcium carbonate, 1-4 parts of talcum powder, 1-3 parts of sodium carboxymethylcellulose,
2-4 parts of processing aid, 0.7-1.3 parts of bactericide, 0.4-0.8 parts of nano titanium oxide, 2-3 parts of additive of coloring.
Preferably, the weather-proof manifolding paint for papers of the ecological, environmental protective includes the raw material of following parts by weight:
17 parts of plant amylum, 45 parts of latex, 2 parts of calcium carbonate, 2.5 parts of talcum powder, 2 parts of sodium carboxymethylcellulose, processing aid 3
Part, 1 part of bactericide, 0.6 part of nano titanium oxide, 2.5 parts of additive of coloring.
Preferably, the plant amylum is that potato starch, cornstarch, tapioca, wheaten starch compare 2 according to weight:
1:1:The mixture of 2 compositions.
Preferably, the latex is one kind in styrene-butadiene latex, carboxylic styrene butadiene latex, carboxyl fourth cyanogen latex.
Preferably, the processing aid is that levelling agent, dispersant, defoamer, resistance to hydrated agent, antioxidant compare 1 according to weight:
1:0.5:2:The mixture of 1.5 compositions;The levelling agent is polyester modification siloxanes, and the dispersant is hexenyl stearic bicine diester
Amine, the defoamer is polyoxyethylene polyoxypropylene glycerin ether, and the resistance to hydrated agent is the poly- urea of polyamide, potassium zirconium carbonate, carbon
One kind in sour zirconium ammonium, the antioxidant is dilauryl thiodipropionate.
Preferably, the bactericide is that bactericide of iso-thiazolinone, chloramines compare 2 according to weight:The mixture of 1 composition.
Preferably, the blue or green blue mill base liquid that the coloring additive is 40%.
The present invention also provides a kind of preparation method of the weather-proof manifolding paint for papers of ecological, environmental protective, comprises the following steps:
Step one, weigh on request and prepare each component raw material;
Step 2, calcium carbonate, talcum powder, sodium carboxymethylcellulose, processing aid, bactericide, nano titanium oxide is added high
In fast mixer, stirred 20-30 minutes in the case where speed of agitator is 300-400r/min, obtain mixture A;
Step 3, plant amylum is added appropriate water, is added in homogenizer, in the case where speed of agitator is 150-250r/min
Stirring 10-20 minutes, is warming up to 55-65 DEG C, adds mixture A prepared by latex and step 2, is 300- in speed of agitator
Stirred 20-30 minutes under 400r/min, add coloring additive and continue to stir 15-25 minutes, the ecological, environmental protective invented
Weather-proof manifolding paint for papers.
Preferably, the preparation process of the weather-proof manifolding paint for papers of the ecological, environmental protective is:
Step one, weigh on request and prepare each component raw material;
Step 2, calcium carbonate, talcum powder, sodium carboxymethylcellulose, processing aid, bactericide, nano titanium oxide is added high
In fast mixer, stirred 25 minutes in the case where speed of agitator is 350r/min, obtain mixture A;
Step 3, plant amylum is added appropriate water, is added in homogenizer, is stirred in the case where speed of agitator is 200r/min
15 minutes, 60 DEG C are warming up to, mixture A prepared by latex and step 2 is added, 25 are stirred in the case where speed of agitator is 350r/min
Minute, add coloring additive and continue to stir 20 minutes, the weather-proof manifolding paint for papers of ecological, environmental protective invented.
Compared with prior art, the present invention has following beneficial effect:
(1)A kind of plant amylum of the weather-proof manifolding paint for papers addition of ecological, environmental protective of the present invention is mainly potato starch, corn
Starch, tapioca, the mixture of wheaten starch composition, on the one hand its that body paper surface can be effectively reduced in coated paper is fine
That ties up is exposed, fills up paper hole, on the other hand can reduce the consumption of latex, improves the environmental-protecting performance of coating.
(2)A kind of processing aid of the weather-proof manifolding paint for papers addition of ecological, environmental protective of the present invention is mainly levelling agent, divided
Powder, defoamer, resistance to hydrated agent, the mixture of antioxidant composition, levelling agent can make the rheological characteristic of coating preferably, and coating is more
It is uniform, dispersant can be such that material easily disperses, and reduce the viscosity of coating, improve its stability and rheological characteristic, and defoamer can be with
The foam in coating is reduced, the flake paper defects of paper is reduced, resistance to hydrated agent can strengthen the water resistance of paper, antioxidant can be with
Strengthen the weather resistance of coating, extend the service life of carbon paper.
(3)A kind of bactericide of the weather-proof manifolding paint for papers addition of ecological, environmental protective of the present invention is OIT, chloramines
The mixture of composition, can effectively kill the health of the details on carbon paper surface, on the one hand protection, on the other hand reduce
Erosion of the bacterium to paper, extends service life.
(4)A kind of weather-proof manifolding paint for papers of ecological, environmental protective of the present invention is used as material of main part, predominantly benzene using latex
One kind in ethylene-butylene latex, carboxylic styrene butadiene latex, carboxyl fourth cyanogen latex so that using the carbon paper of the coating preparation
Surface strength is high, not dry linting;Finished product warpage is small, and printing adaptability is good.
(5)A kind of weather-proof manifolding paint for papers of ecological, environmental protective of the present invention has preferable dispersion effect and rheological characteristic good,
Foam is less, and its antioxidant capacity and water resistance are stronger, additionally with certain bactericidal property, utilizes the manifolding of this coating preparation
Paper intensity is high, is difficult warpage, printing adaptability is good, and chromonic layer is coated with evenly, reduces and shows money or valuables one carries unintentionally a little, while the original of the present invention
Material component employs substantial amounts of plant amylum, and safe and reliable, cost is relatively low, and technique is concise, with higher practical value and good
Good application prospect.
Embodiment
With reference to specific embodiment, the technical scheme in the embodiment of the present invention is clearly and completely described, shown
So, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the reality in the present invention
Example is applied, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made all belongs to
In the scope of protection of the invention.
Embodiment 1.
A kind of weather-proof manifolding paint for papers of ecological, environmental protective of the present embodiment, includes the raw material of following parts by weight:
14 parts of plant amylum, 40 parts of latex, 1 part of calcium carbonate, 1 part of talcum powder, 1 part of sodium carboxymethylcellulose, 2 parts of processing aid,
0.7 part of bactericide, 0.4 part of nano titanium oxide, 2 parts of additive of coloring.
Plant amylum in the present embodiment is potato starch, cornstarch, tapioca, wheaten starch compare 2 according to weight:
1:1:The mixture of 2 compositions.
Latex in the present embodiment is styrene-butadiene latex.
Processing aid in the present embodiment is levelling agent, dispersant, defoamer, resistance to hydrated agent, antioxidant according to weight ratio
1:1:0.5:2:The mixture of 1.5 compositions;The levelling agent is polyester modification siloxanes, and the dispersant is that hexenyl is double stearic
Acid amides, the defoamer is polyoxyethylene polyoxypropylene glycerin ether, and the resistance to hydrated agent is the poly- urea of polyamide, the antioxidant
For dilauryl thiodipropionate.
Bactericide in the present embodiment is bactericide of iso-thiazolinone, chloramines compares 2 according to weight:The mixture of 1 composition.
The blue or green blue mill base liquid that coloring additive in the present embodiment is 40%.
A kind of preparation method of the weather-proof manifolding paint for papers of ecological, environmental protective of the present embodiment, comprises the following steps:
Step one, weigh on request and prepare each component raw material;
Step 2, calcium carbonate, talcum powder, sodium carboxymethylcellulose, processing aid, bactericide, nano titanium oxide is added high
In fast mixer, stirred 20 minutes in the case where speed of agitator is 300r/min, obtain mixture A;
Step 3, plant amylum is added appropriate water, is added in homogenizer, is stirred in the case where speed of agitator is 150r/min
10 minutes, 55 DEG C are warming up to, mixture A prepared by latex and step 2 is added, 20 are stirred in the case where speed of agitator is 300r/min
Minute, add coloring additive and continue to stir 15 minutes, the weather-proof manifolding paint for papers of ecological, environmental protective invented.
Embodiment 2.
A kind of weather-proof manifolding paint for papers of ecological, environmental protective of the present embodiment, includes the raw material of following parts by weight:
20 parts of plant amylum, 50 parts of latex, 3 parts of calcium carbonate, 4 parts of talcum powder, 3 parts of sodium carboxymethylcellulose, 4 parts of processing aid,
1.3 parts of bactericide, 0.8 part of nano titanium oxide, 3 parts of additive of coloring.
Plant amylum in the present embodiment is potato starch, cornstarch, tapioca, wheaten starch compare 2 according to weight:
1:1:The mixture of 2 compositions.
Latex in the present embodiment is carboxylic styrene butadiene latex.
Processing aid in the present embodiment is levelling agent, dispersant, defoamer, resistance to hydrated agent, antioxidant according to weight ratio
1:1:0.5:2:The mixture of 1.5 compositions;The levelling agent is polyester modification siloxanes, and the dispersant is that hexenyl is double stearic
Acid amides, the defoamer is polyoxyethylene polyoxypropylene glycerin ether, and the resistance to hydrated agent is potassium zirconium carbonate, and the antioxidant is sulphur
For dipropionic acid dilauryl.
Bactericide in the present embodiment is bactericide of iso-thiazolinone, chloramines compares 2 according to weight:The mixture of 1 composition.
The blue or green blue mill base liquid that coloring additive in the present embodiment is 40%.
A kind of preparation method of the weather-proof manifolding paint for papers of ecological, environmental protective of the present embodiment, comprises the following steps:
Step one, weigh on request and prepare each component raw material;
Step 2, calcium carbonate, talcum powder, sodium carboxymethylcellulose, processing aid, bactericide, nano titanium oxide is added high
In fast mixer, stirred 30 minutes in the case where speed of agitator is 400r/min, obtain mixture A;
Step 3, plant amylum is added appropriate water, is added in homogenizer, is stirred in the case where speed of agitator is 250r/min
20 minutes, 65 DEG C are warming up to, mixture A prepared by latex and step 2 is added, 30 are stirred in the case where speed of agitator is 400r/min
Minute, add coloring additive and continue to stir 25 minutes, the weather-proof manifolding paint for papers of ecological, environmental protective invented.
Embodiment 3.
A kind of weather-proof manifolding paint for papers of ecological, environmental protective of the present embodiment, includes the raw material of following parts by weight:
17 parts of plant amylum, 45 parts of latex, 2 parts of calcium carbonate, 2.5 parts of talcum powder, 2 parts of sodium carboxymethylcellulose, processing aid 3
Part, 1 part of bactericide, 0.6 part of nano titanium oxide, 2.5 parts of additive of coloring.
Plant amylum in the present embodiment is potato starch, cornstarch, tapioca, wheaten starch compare 2 according to weight:
1:1:The mixture of 2 compositions.
Latex in the present embodiment is carboxyl fourth cyanogen latex.
Processing aid in the present embodiment is levelling agent, dispersant, defoamer, resistance to hydrated agent, antioxidant according to weight ratio
1:1:0.5:2:The mixture of 1.5 compositions;The levelling agent is polyester modification siloxanes, and the dispersant is that hexenyl is double stearic
Acid amides, the defoamer is polyoxyethylene polyoxypropylene glycerin ether, and the resistance to hydrated agent is zirconium carbonate ammonium, and the antioxidant is sulphur
For dipropionic acid dilauryl.
Bactericide in the present embodiment is bactericide of iso-thiazolinone, chloramines compares 2 according to weight:The mixture of 1 composition.
The blue or green blue mill base liquid that coloring additive in the present embodiment is 40%.
A kind of preparation method of the weather-proof manifolding paint for papers of ecological, environmental protective of the present embodiment, comprises the following steps:
Step one, weigh on request and prepare each component raw material;
Step 2, calcium carbonate, talcum powder, sodium carboxymethylcellulose, processing aid, bactericide, nano titanium oxide is added high
In fast mixer, stirred 25 minutes in the case where speed of agitator is 350r/min, obtain mixture A;
Step 3, plant amylum is added appropriate water, is added in homogenizer, is stirred in the case where speed of agitator is 200r/min
15 minutes, 60 DEG C are warming up to, mixture A prepared by latex and step 2 is added, 25 are stirred in the case where speed of agitator is 350r/min
Minute, add coloring additive and continue to stir 20 minutes, the weather-proof manifolding paint for papers of ecological, environmental protective invented.
A kind of manifolding paint for papers of the present invention has that preferable dispersion effect and rheological characteristic are good, and foam is less, its antioxygen
Ability and water resistance are stronger, additionally with certain bactericidal property, high using the carbon paper intensity of this coating preparation, are difficult to stick up
Song, printing adaptability is good, and chromonic layer is coated with evenly, reduces and shows money or valuables one carries unintentionally a little, while the raw material components of the present invention are employed greatly
The plant amylum of amount, safe and reliable, cost is relatively low, and technique is concise, with higher practical value and good application prospect.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It may be appreciated other embodiment.
Claims (9)
1. a kind of weather-proof manifolding paint for papers of ecological, environmental protective, it is characterised in that include the raw material of following parts by weight:
14-20 parts of plant amylum, 40-50 parts of latex, 1-3 parts of calcium carbonate, 1-4 parts of talcum powder, 1-3 parts of sodium carboxymethylcellulose,
2-4 parts of processing aid, 0.7-1.3 parts of bactericide, 0.4-0.8 parts of nano titanium oxide, 2-3 parts of additive of coloring.
2. a kind of weather-proof manifolding paint for papers of ecological, environmental protective according to claim 1, it is characterised in that the ecological, environmental protective
Weather-proof manifolding paint for papers includes the raw material of following parts by weight:
17 parts of plant amylum, 45 parts of latex, 2 parts of calcium carbonate, 2.5 parts of talcum powder, 2 parts of sodium carboxymethylcellulose, processing aid 3
Part, 1 part of bactericide, 0.6 part of nano titanium oxide, 2.5 parts of additive of coloring.
3. a kind of weather-proof manifolding paint for papers of ecological, environmental protective according to claim 1 or 2, it is characterised in that the plant
Starch is potato starch, cornstarch, tapioca, wheaten starch compare 2 according to weight:1:1:The mixture of 2 compositions.
4. a kind of weather-proof manifolding paint for papers of ecological, environmental protective according to claim 1 or 2, it is characterised in that the latex
For one kind in styrene-butadiene latex, carboxylic styrene butadiene latex, carboxyl fourth cyanogen latex.
5. a kind of weather-proof manifolding paint for papers of ecological, environmental protective according to claim 1 or 2, it is characterised in that the processing
Auxiliary agent is levelling agent, dispersant, defoamer, resistance to hydrated agent, antioxidant compare 1 according to weight:1:0.5:2:The mixing of 1.5 compositions
Thing;The levelling agent is polyester modification siloxanes, and the dispersant is hexenyl bis-stearamides, and the defoamer is polyoxy third
Alkene polyoxyethylene glycerol ether, the resistance to hydrated agent is one kind in the poly- urea of polyamide, potassium zirconium carbonate, zirconium carbonate ammonium, described anti-
Oxygen agent is dilauryl thiodipropionate.
6. a kind of weather-proof manifolding paint for papers of ecological, environmental protective according to claim 1 or 2, it is characterised in that the sterilization
Agent is bactericide of iso-thiazolinone, chloramines compares 2 according to weight:The mixture of 1 composition.
7. a kind of weather-proof manifolding paint for papers of ecological, environmental protective according to claim 1 or 2, it is characterised in that the coloring
Additive is 40% blue or green blue mill base liquid.
8. a kind of method for preparing the weather-proof manifolding paint for papers of ecological, environmental protective as claimed in claim 1 or 2, it is characterised in that
Comprise the following steps:
Step one, weigh on request and prepare each component raw material;
Step 2, calcium carbonate, talcum powder, sodium carboxymethylcellulose, processing aid, bactericide, nano titanium oxide is added high
In fast mixer, stirred 20-30 minutes in the case where speed of agitator is 300-400r/min, obtain mixture A;
Step 3, plant amylum is added appropriate water, is added in homogenizer, in the case where speed of agitator is 150-250r/min
Stirring 10-20 minutes, is warming up to 55-65 DEG C, adds mixture A prepared by latex and step 2, is 300- in speed of agitator
Stirred 20-30 minutes under 400r/min, add coloring additive and continue to stir 15-25 minutes, the ecological, environmental protective invented
Weather-proof manifolding paint for papers.
9. a kind of preparation method of the weather-proof manifolding paint for papers of ecological, environmental protective according to claim 8, it is characterised in that institute
Stating step is:
Step one, weigh on request and prepare each component raw material;
Step 2, calcium carbonate, talcum powder, sodium carboxymethylcellulose, processing aid, bactericide, nano titanium oxide is added high
In fast mixer, stirred 25 minutes in the case where speed of agitator is 350r/min, obtain mixture A;
Step 3, plant amylum is added appropriate water, is added in homogenizer, is stirred in the case where speed of agitator is 200r/min
15 minutes, 60 DEG C are warming up to, mixture A prepared by latex and step 2 is added, 25 are stirred in the case where speed of agitator is 350r/min
Minute, add coloring additive and continue to stir 20 minutes, the weather-proof manifolding paint for papers of ecological, environmental protective invented.
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Citations (2)
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CN101381973A (en) * | 2008-09-27 | 2009-03-11 | 上海东升新材料有限公司 | Coating for carbon-free paper with developer layer and use thereof |
CN102230299A (en) * | 2011-04-22 | 2011-11-02 | 金华盛纸业(苏州工业园区)有限公司 | Chemical painting for curtain coating |
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2017
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CN101381973A (en) * | 2008-09-27 | 2009-03-11 | 上海东升新材料有限公司 | Coating for carbon-free paper with developer layer and use thereof |
CN102230299A (en) * | 2011-04-22 | 2011-11-02 | 金华盛纸业(苏州工业园区)有限公司 | Chemical painting for curtain coating |
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Application publication date: 20170908 |