CN107129875A - A kind of glass antidimmer and preparation method thereof - Google Patents

A kind of glass antidimmer and preparation method thereof Download PDF

Info

Publication number
CN107129875A
CN107129875A CN201710408026.3A CN201710408026A CN107129875A CN 107129875 A CN107129875 A CN 107129875A CN 201710408026 A CN201710408026 A CN 201710408026A CN 107129875 A CN107129875 A CN 107129875A
Authority
CN
China
Prior art keywords
parts
solution
weight
water
silester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710408026.3A
Other languages
Chinese (zh)
Inventor
曹宏生
王忠冬
熊畅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Feiya Chemical Industry Co Ltd
Original Assignee
Jiangsu Feiya Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Feiya Chemical Industry Co Ltd filed Critical Jiangsu Feiya Chemical Industry Co Ltd
Priority to CN201710408026.3A priority Critical patent/CN107129875A/en
Publication of CN107129875A publication Critical patent/CN107129875A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/042—Acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/162—Organic compounds containing Si
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2072—Aldehydes-ketones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

This application discloses a kind of glass antidimmer and preparation method thereof, including solution A and solution B, the ratio of solution A and solution B is 5:1；Wherein described solution A includes by weight:0.6 6.5 parts of acetaldehyde that 12 35 parts of hydrochloric acid that 7 18 parts of polyvinyl alcohol, 200 370 parts of water, 20 100 parts of diethanol amine, 10 50 parts of tallow alkyl Propanolamine, 20 60 parts of isopropanol, concentration are 3mol/L, mass content are 40%, 6 17 parts of potassium bichromate；The solution B includes by weight：7 16 parts of polyoxyethylene surfactant, 10 25 parts of calgon, 5 25 parts of penta sodium pentachlorophenate, 27 parts of soap flakes glue, 8 19 parts of silester, 7 22 parts of γ glycidyl ether oxygen propyl trimethoxy silicanes, 11 32 parts of ethanol, 1.3 9.5 parts of glacial acetic acid.Thus, after use, with enough surface strengths, clean harmless, people and animals will not be caused any harm, using simple, good antifogging effect and technology effective time is up to more than half a year, environmentally safe, manufacture craft simply causes cost than relatively low.

Description

A kind of glass antidimmer and preparation method thereof
Technical field
The present invention relates to antifoggant technical field, more particularly to a kind of glass antidimmer and preparation method thereof.
Background technology
When the moisture content that glass both sides occur in the temperature difference, air can condense mist formation on glass, if temperature is too low or even can Energy frosting, so as to reduce the light transmittance of glass, influences sight.In daily life, mist causes many troubles, example to us Such as：When going to warm interior from cold outdoor, fog generation, when automobile just starts, the expiration of people are had on eyeglass Vehicle glass surface can be allowed to cover one layer of fog etc., in order to eliminate the water smoke of glass surface, substantial amounts of glass is occurred in that on the market Glass antifogging product, embodiment mode is also had nothing in common with each other.
But these products have the shortcomings that some are universal：Need to clean glass before use, after contact with water It can not all continue to keep anti-fog effect, product has certain alkalescence in itself, and cause necessarily healthy to user is used for a long time Infringement, the antifog effect duration of product is short to be sprayed repeatedly.
The content of the invention
The purpose of the present invention is to be to provide a kind of glass antidimmer and preparation method thereof, solves above-mentioned prior art problem In one or more.
The glass antidimmer of the present invention, is constituted as follows：
Including solution A and solution B, the ratio of solution A and solution B is 5:1；Wherein described solution A includes by weight:It is poly- 7-18 parts of vinyl alcohol, 200-370 parts of water, 20-100 parts of diethanol amine, 10-50 parts of tallow alkyl Propanolamine, isopropanol 20-60 Part, concentration be 3mol/L 12-35 parts of hydrochloric acid, mass content be 40% 0.6-6.5 parts of acetaldehyde, 6-17 parts of potassium bichromate；Institute State solution B includes by weight：7-16 parts of polyoxyethylene surfactant, 10-25 parts of calgon, penta sodium pentachlorophenate 5-25 Part, 2-7 parts of soap flakes glue, 8-19 parts of silester, γ -7-22 parts of glycidyl ether oxygen propyl trimethoxy silicane, ethanol 11-32 Part, 1.3-9.5 parts of glacial acetic acid.
In one embodiment：Solution A includes by weight：10 parts of polyvinyl alcohol, 210 parts of water, 38 parts of diethanol amine, The acetaldehyde 0.8 that 12 parts of hydrochloric acid that 22 parts of tallow alkyl Propanolamine, 55 parts of isopropanol, concentration are 3mol/L, mass content are 40% Part, 7 parts of potassium bichromate.
In one embodiment：Solution B includes by weight：7.5 parts of polyoxyethylene surfactant, calgon 15 parts, 11 parts of penta sodium pentachlorophenate, 2 parts of soap flakes glue, 11 parts of silester, 8 parts of γ-glycidyl ether oxygen propyl trimethoxy silicane, 13 parts of ethanol, 1.5 parts of glacial acetic acid.
In one embodiment：Polyoxyethylene surfactant is that AEO, tween or alkyl phenol are poly- Oxygen vinethene any of which.
The preparation method of the glass antidimmer of the present invention is as follows, comprises the following steps：
1. solution A is prepared：Polyvinyl alcohol is dissolved in 80 DEG C of hot water, continuous heating is stirred to whole dissolvings, is then cooled down The hydrochloric acid and mass content that addition isopropanol, diethanol amine, tallow alkyl Propanolamine, concentration are 3mol/L after to room temperature are 40% Acetaldehyde, obtained solution A after stirring 3h is standby；
2. solution B is prepared：At 20 DEG C, surfactant is added into stirring in suitable quantity of water until dissolving, then adds soap Piece glue, calgon, penta sodium pentachlorophenate, silester, γ-glycidyl ether oxygen propyl trimethoxy silicane, ethanol, ice vinegar Acid, temperature is brought up at 60 DEG C and is stirred at reflux 5h obtained solutions B, standby；
3. solution A and solution B are stood into 16d, under agitation, solution B is slowly added in solution A, i.e. finished product.
After use, with enough surface strengths, cleaning is harmless, and people and animals will not be caused any harm by the present invention, Using simple, good antifogging effect and technology effective time is up to more than half a year, environmentally safe, manufacture craft simply causes into This is than relatively low.
Embodiment
The present invention is described in further detail below by embodiment.
Embodiment 1
Glass antidimmer, is constituted as follows：
Including solution A and solution B, the ratio of solution A and solution B is 5:1；Wherein, solution A includes by weight:Poly- second 10 parts of enol, 210 parts of water, 38 parts of diethanol amine, 22 parts of tallow alkyl Propanolamine, 55 parts of isopropanol, concentration are 3mol/L salt 0.8 part of acetaldehyde, 7 parts of the potassium bichromate of 12 parts of acid, mass content for 40%；Solution B includes by weight：Live on polyoxyethylene surface 7.5 parts of agent of property, 15 parts of calgon, 11 parts of penta sodium pentachlorophenate, 2 parts of soap flakes glue, 11 parts of silester, γ-glycidyl ether oxygen 8 parts of propyl trimethoxy silicane, 13 parts of ethanol, 1.5 parts of glacial acetic acid.
Wherein, polyoxyethylene surfactant be AEO, tween or APES wherein Any one.
The preparation method of the glass antidimmer of the present invention is as follows, comprises the following steps：
1. solution A is prepared：Polyvinyl alcohol is dissolved in 80 DEG C of hot water, continuous heating is stirred to whole dissolvings, is then cooled down The hydrochloric acid and mass content that addition isopropanol, diethanol amine, tallow alkyl Propanolamine, concentration are 3mol/L after to room temperature are 40% Acetaldehyde, obtained solution A after stirring 3h is standby；
2. solution B is prepared：At 20 DEG C, surfactant is added into stirring in suitable quantity of water until dissolving, then adds soap Piece glue, calgon, penta sodium pentachlorophenate, silester, γ-glycidyl ether oxygen propyl trimethoxy silicane, ethanol, ice vinegar Acid, temperature is brought up at 60 DEG C and is stirred at reflux 5h obtained solutions B, standby；
3. solution A and solution B are stood into 16d, under agitation, solution B is slowly added in solution A, i.e. finished product.
Embodiment 2
Glass antidimmer, is constituted as follows：
Including solution A and solution B, the ratio of solution A and solution B is 5:1；Wherein described solution A includes by weight:It is poly- 7 parts of vinyl alcohol, 200 parts of water, 20 parts of diethanol amine, 10 parts of tallow alkyl Propanolamine, 20 parts of isopropanol, concentration are 3mol/L salt 0.6 part of acetaldehyde, 6 parts of the potassium bichromate of 12 parts of acid, mass content for 40%；The solution B includes by weight：Polyoxyethylene table 7 parts of face activating agent, 10 parts of calgon, 5 parts of penta sodium pentachlorophenate, 2 parts of soap flakes glue, 8 parts of silester, γ-glycidyl ether oxygen 7 parts of propyl trimethoxy silicane, 11 parts of ethanol, 1.3 parts of glacial acetic acid.
Wherein, polyoxyethylene surfactant be AEO, tween or APES wherein Any one.
The preparation method of the glass antidimmer of the present invention is as follows, comprises the following steps：
1. solution A is prepared：Polyvinyl alcohol is dissolved in 75 DEG C of hot water, continuous heating is stirred to whole dissolvings, is then cooled down The hydrochloric acid and mass content that addition isopropanol, diethanol amine, tallow alkyl Propanolamine, concentration are 3mol/L after to room temperature are 40% Acetaldehyde, obtained solution A after stirring 4h is standby；
2. solution B is prepared：At 20 DEG C, surfactant is added into stirring in suitable quantity of water until dissolving, then adds soap Piece glue, calgon, penta sodium pentachlorophenate, silester, γ-glycidyl ether oxygen propyl trimethoxy silicane, ethanol, ice vinegar Acid, temperature is brought up at 60 DEG C and is stirred at reflux 6h obtained solutions B, standby；
3. solution A and solution B are stood into 16d, under agitation, solution B is slowly added in solution A, i.e. finished product.
Embodiment 3
Glass antidimmer, is constituted as follows：
Including solution A and solution B, the ratio of solution A and solution B is 5:1；Wherein described solution A includes by weight:It is poly- 18 parts of vinyl alcohol, 370 parts of water, 100 parts of diethanol amine, 50 parts of tallow alkyl Propanolamine, 60 parts of isopropanol, concentration are 3mol/L's 6.5 parts of acetaldehyde, 17 parts of the potassium bichromate of 35 parts of hydrochloric acid, mass content for 40%；The solution B includes by weight：Polyoxy second 16 parts of alkene surfactant, 25 parts of calgon, 25 parts of penta sodium pentachlorophenate, 7 parts of soap flakes glue, 19 parts of silester, γ-shrink are sweet Oily 22 parts of ether oxygen propyl trimethoxy silicane, 32 parts of ethanol, 9.5 parts of glacial acetic acid.
Wherein, polyoxyethylene surfactant be AEO, tween or APES wherein Any one.
The preparation method of the glass antidimmer of the present invention is as follows, comprises the following steps：
1. solution A is prepared：Polyvinyl alcohol is dissolved in 85 DEG C of hot water, continuous heating is stirred to whole dissolvings, is then cooled down The hydrochloric acid and mass content that addition isopropanol, diethanol amine, tallow alkyl Propanolamine, concentration are 3mol/L after to room temperature are 40% Acetaldehyde, obtained solution A after stirring 3h is standby；
2. solution B is prepared：At 30 DEG C, surfactant is added into stirring in suitable quantity of water until dissolving, then adds soap Piece glue, calgon, penta sodium pentachlorophenate, silester, γ-glycidyl ether oxygen propyl trimethoxy silicane, ethanol, ice vinegar Acid, temperature is brought up at 70 DEG C and is stirred at reflux 4h obtained solutions B, standby；
3. solution A and solution B are stood into 18d, under agitation, solution B is slowly added in solution A, i.e. finished product.
The product of above-described embodiment and conventional antifoggant are as follows for the antifog effect test of glass：
Wherein, inventor is drawn by substantial amounts of experiment, and the present invention after use, with enough surface strengths, is cleaned It is harmless, people and animals will not be caused any harm, using simple, good antifogging effect and technology effective time is up to more than half a year, Environmentally safe, manufacture craft simply causes cost than relatively low.
Described above is only one embodiment of the present invention, it is noted that to those skilled in the art, Without departing from the concept of the premise of the invention, some similar modification and improvement can also be made, these also should be regarded as this Within the protection domain of invention.

Claims (5)

1. a kind of glass antidimmer, it is characterised in that：Including solution A and solution B, the ratio of solution A and solution B is 5:1；Wherein The solution A includes by weight:7-18 parts of polyvinyl alcohol, 200-370 parts of water, 20-100 parts of diethanol amine, tallow alkyl third The acetaldehyde 0.6- that 12-35 parts of hydrochloric acid that 10-50 parts of hydramine, 20-60 parts of isopropanol, concentration are 3mol/L, mass content are 40% 6.5 parts, 6-17 parts of potassium bichromate；The solution B includes by weight：7-16 parts of polyoxyethylene surfactant, hexa metaphosphoric acid 10-25 parts of sodium, 5-25 parts of penta sodium pentachlorophenate, 2-7 parts of soap flakes glue, 8-19 parts of silester, γ-glycidyl ether oxygen propyl trimethoxy 7-22 parts of base silane, 11-32 parts of ethanol, 1.3-9.5 parts of glacial acetic acid.
2. a kind of glass antidimmer according to claim 1, it is characterised in that：The solution A includes by weight：Poly- second 10 parts of enol, 210 parts of water, 38 parts of diethanol amine, 22 parts of tallow alkyl Propanolamine, 55 parts of isopropanol, concentration are 3mol/L salt 0.8 part of acetaldehyde, 7 parts of the potassium bichromate of 12 parts of acid, mass content for 40%.
3. a kind of glass antidimmer according to claim 1, it is characterised in that：The solution B includes by weight：Polyoxy 7.5 parts of pvdf surface activating agent, 15 parts of calgon, 11 parts of penta sodium pentachlorophenate, 2 parts of soap flakes glue, 11 parts of silester, γ-contracting 8 parts of water glycerine ether oxygen propyl trimethoxy silicane, 13 parts of ethanol, 1.5 parts of glacial acetic acid.
4. a kind of glass antidimmer according to claim 1, it is characterised in that：The polyoxyethylene surfactant is fat Fat alcohol APEO, tween or APES any of which.
5. the preparation method of the glass antidimmer according to claim any one of 1-4, it is characterised in that：Including following step Suddenly：
1. solution A is prepared：Polyvinyl alcohol is dissolved in 80 DEG C of hot water, continuous heating is stirred to whole dissolvings, is subsequently cooled to room The hydrochloric acid that isopropanol, diethanol amine, tallow alkyl Propanolamine, concentration are 3mol/L and the second that mass content is 40% are added after temperature Obtained solution A, standby after aldehyde, stirring 3h；
2. solution B is prepared：At 20 DEG C, surfactant is added into stirring in suitable quantity of water until dissolving, then add soap flakes glue, Calgon, penta sodium pentachlorophenate, silester, γ-glycidyl ether oxygen propyl trimethoxy silicane, ethanol, glacial acetic acid, by temperature Degree, which is brought up at 60 DEG C, is stirred at reflux 5h obtained solutions B, standby；
3. solution A and solution B are stood into 16d, under agitation, solution B is slowly added in solution A, i.e. finished product.
CN201710408026.3A 2017-06-02 2017-06-02 A kind of glass antidimmer and preparation method thereof Pending CN107129875A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710408026.3A CN107129875A (en) 2017-06-02 2017-06-02 A kind of glass antidimmer and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710408026.3A CN107129875A (en) 2017-06-02 2017-06-02 A kind of glass antidimmer and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107129875A true CN107129875A (en) 2017-09-05

Family

ID=59733582

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710408026.3A Pending CN107129875A (en) 2017-06-02 2017-06-02 A kind of glass antidimmer and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107129875A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111349420A (en) * 2020-05-22 2020-06-30 中国人民解放军总医院第五医学中心 Antifogging agent and preparation method and application thereof
CN112358809A (en) * 2020-10-29 2021-02-12 华南理工大学 Anti-fog coating based on organic silicon and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1632038A (en) * 2004-11-11 2005-06-29 上海交通大学 Method for making glass antifogging agent
CN1749348A (en) * 2005-10-14 2006-03-22 浙江大学 Glass fog-proof agent and its preparing method
CN102850997A (en) * 2012-08-30 2013-01-02 苏州市德莱尔建材科技有限公司 Long-acting antifogging agent for glass
CN102965221A (en) * 2012-12-04 2013-03-13 南通恒鼎重型机床有限公司 Glass cleaner

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1632038A (en) * 2004-11-11 2005-06-29 上海交通大学 Method for making glass antifogging agent
CN1259386C (en) * 2004-11-11 2006-06-14 上海交通大学 Method for making glass antifogging agent
CN1749348A (en) * 2005-10-14 2006-03-22 浙江大学 Glass fog-proof agent and its preparing method
CN100345929C (en) * 2005-10-14 2007-10-31 浙江大学 Glass fog-proof agent and its preparing method
CN102850997A (en) * 2012-08-30 2013-01-02 苏州市德莱尔建材科技有限公司 Long-acting antifogging agent for glass
CN102850997B (en) * 2012-08-30 2014-05-14 苏州市德莱尔建材科技有限公司 Long-acting antifogging agent for glass
CN102965221A (en) * 2012-12-04 2013-03-13 南通恒鼎重型机床有限公司 Glass cleaner

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
徐宝财主编: "《家用洗涤剂生产及配方》", 31 May 2008 *
李东光主编: "《实用化工产品配方与制备2》", 31 July 2011 *
温辉梁主编: "《化工助剂》", 31 December 2009 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111349420A (en) * 2020-05-22 2020-06-30 中国人民解放军总医院第五医学中心 Antifogging agent and preparation method and application thereof
CN111349420B (en) * 2020-05-22 2020-09-11 中国人民解放军总医院第五医学中心 Antifogging agent and preparation method and application thereof
CN112358809A (en) * 2020-10-29 2021-02-12 华南理工大学 Anti-fog coating based on organic silicon and preparation method and application thereof
CN112358809B (en) * 2020-10-29 2022-01-18 华南理工大学 Anti-fog coating based on organic silicon and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN107129875A (en) A kind of glass antidimmer and preparation method thereof
CN103978799A (en) Alcohol-free fountain solution and preparation method thereof
CN204984195U (en) But self - cleaning's window
CN103694815A (en) Scrapable formaldehyde closed film and preparation method thereof
CN106583322A (en) Optical glass surface cleaning method
CN102850998B (en) Corrosion-resistant glass antifogging agent
CN108277096A (en) A kind of aerosol type glass antidimmer and preparation method thereof
CN106582572A (en) Adsorbent for sewage treatment
CN109806535A (en) A kind of macromolecule hydrogel extinguishing chemical and preparation method thereof
JPH11512764A (en) Materials giving tack and non-wetting
CN105925256A (en) Foaming agent for petroleum exploitation
CN106214523A (en) Amino acid cleansing mousse and preparation method thereof
CN103205241A (en) Long-acting antifogging agent for glass and method for manufacturing long-acting antifogging agent
CN104312768A (en) Glasses cleaning solution
CN107299005A (en) A kind of glass cleaner and preparation method thereof
CN103710118A (en) Water-based cutting cooling antirust liquid and preparation method thereof
CN107841206A (en) A kind of antifog self-cleaning reduction vitaglass coating and preparation method thereof
CN102965221A (en) Glass cleaner
CN205593173U (en) Hot -pump hot -water set with air as source
CN104529182A (en) Ordinary electric heating glass preparation method
CN110130613A (en) A kind of glue of exempting from is drowned oneself the production method on floor
CN103740481B (en) Glass mirror decontamination cleaning solvent and preparation method thereof
CN107746753A (en) A kind of contact lens cleaning solution
CN2840102Y (en) Fogproof glasses
CN109280496A (en) Agricultural cotton adhesive, agricultural cotton and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170905