CN107097549A - The technique and UV ink of a kind of utilization UV ink transfer metal wire-drawing effect film - Google Patents
The technique and UV ink of a kind of utilization UV ink transfer metal wire-drawing effect film Download PDFInfo
- Publication number
- CN107097549A CN107097549A CN201710166751.4A CN201710166751A CN107097549A CN 107097549 A CN107097549 A CN 107097549A CN 201710166751 A CN201710166751 A CN 201710166751A CN 107097549 A CN107097549 A CN 107097549A
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- Prior art keywords
- ink
- technique
- metal wire
- drawing effect
- film
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
- B41M5/0358—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the mechanisms or artifacts to obtain the transfer, e.g. the heating means, the pressure means or the transport means
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
Abstract
The invention discloses the technique that a kind of utilization UV ink transfers metal wire-drawing effect film, comprise the following steps：S01：UV ink rollers are applied to material surface；S02：Then covering includes the transfer PET film of wire drawing decorative pattern on UV wet films；S03：Material, UV wet films and PET film whole utilization LED cold light are subjected to semi-solid preparation, then remove PET from film；S04：UV semi-solid preparation films by material and with transfer pattern, which are placed under UV mercury lamps, carries out all solidstate；S05：The printing closing ink on transfer pattern, baking molding obtains the material that surface includes metal wire-drawing effect.Metal wire-drawing effect true to nature can be obtained on material to be processed using the technique in the present invention and UV ink, and with low cost, process consistency is good, production efficiency is high, suitable for industrial mass production.
Description
Technical field
The present invention relates to a kind of transfer printing process, and in particular to a kind of utilization UV ink transfers the work of metal wire-drawing effect film
Skill, and it is related to a kind of UV ink being applied in the technique.
Background technology
The effect of metal wire-drawing is made using common UV ink printing on material to be processed, is used in the prior art
Cross silk-screen printing to reach, fine design is carried out by the pattern of nearly silk screen, so as to obtain a kind of similar wire-drawing effect
Pattern.But it is due to that the silk screen used in the prior art is all flat screen, it is impossible to stereoeffect true to nature is formed, to reach more
For stereoeffect true to nature, then need by the way of multilayer UV ink prints, i.e., after one layer of ink of silk-screen, treat its solidification then
Again in one layer of ink of its surface silk-screen, then solidified, ideal stereoeffect wire drawing pattern can be obtained after being repeated several times.
Although can obtain preferable pattern by the way of multi-sheet printed, cost is in the increase of geometry multiple, because not only will profit
With heat UV curing ink at double, in addition it is also necessary to spend substantial amounts of cost to be used to design integrated artistic flow, and propose multilayer
The new technical barrier such as overprinting process.
To obtain the metal wire-drawing effect on material surface, also there is researcher to use caloric transfer printing technology.Traditional thermal transfer skill
Art refers to utilize the carrier film with pattern decoration layer, by way of heating and pressurizeing, and decorative layer is mounted on into material surface,
Make decorative layer depart from carrier film to be transferred on material body using the cohesive force between material surface and decorative layer.Existing
In transfer printing process in technology, pattern decoration layer is often bonded with carrier film using solvent type PUR.PUR is using print
Thin and uniform coating can be obtained by brushing the method for cloth, at normal temperatures and pressures in solid-state, be formed if heating with certain viscous
The adhesive of property.Although the PUR used in the prior art disclosure satisfy that the demand during using, in transfer process
In can use high temperature, PUR can easily send substantial amounts of organic solvent, environment is polluted, be unfavorable in high temperature environments
Environmental protection.
The content of the invention
The present invention is carried out for multilayer UV ink chromatography in the prior art all in place of Shortcomings and Thermal-printing Technology
Improve there is provided the technique that a kind of utilization UV ink transfers metal wire-drawing effect film, and be applied to above-mentioned technique there is provided one
UV ink.Metal wire-drawing effect true to nature can be obtained on material to be processed using the technique in the present invention and UV ink,
And with low cost, process consistency is good, production efficiency is high, suitable for industrial mass production.
Effect in the present invention is realized by following scheme：
The utilization UV ink provided in the present invention transfers the technique of metal wire-drawing effect film, comprises the following steps：
S01：UV ink rollers are applied to material surface；
S02：Then covering includes the transfer PET film of wire drawing decorative pattern on UV wet films；
S03：Material, UV wet films and PET film whole utilization LED cold light are subjected to semi-solid preparation, then remove PET from film；LED cold light
The condition of solidification is：Using the LED/light source of 360-410nm wavelength, light source luminescent face power is 16-25W/cm2, hardening time is
8-15 seconds；
S04：UV semi-solid preparation films by material and with transfer pattern, which are placed under UV mercury lamps, carries out all solidstate；
The condition of all solidstate is：Ultraviolet ray intensity is 110-125mJ/cm2S, irradiation time is 3-5 minutes；
S05：The printing closing ink on transfer pattern, baking molding obtains the material that surface includes metal wire-drawing effect；
The condition of baking process is：170-190 DEG C, toast 7-10 minutes.
Further, the UV ink formulations and composition used in above-mentioned technique are：
Aliphatic poly amino acrylates UV resins 10-15%
UV epoxy resin 50-60%
Polyester resin 10-15%
Adhesive agent 2-4%
Monomer resin 10-15%
Light curing agent 3-5%
Other auxiliary agents 1-2%
Above-mentioned composition is in percentage by weight；
The preparation method of the UV ink is：First by the raw material in addition to sensitising agent according to UV epoxy resin, aliphatic poly
Amino acrylates UV resins, polyester resin, monomer resin, adhesive agent, the order of other auxiliary agents feed intake successively, then stir equal
Even, grinding distribution；It is ground to 1-6 μm；Then sensitising agent is put into, UV ink needed for being produced after being uniformly mixed.
Further, the light curing agent is TPO, ITS and 184 3 kinds of curing agent with mass ratio 1:1:3 compositions；The list
Body resin is HDDA or TMPTA；The average weight-molecular mass of the aliphatic poly amino acrylates UV resins is 1000-
3000。
It is further preferred that the UV ink formulations and composition that are used in above-mentioned technique are：
Aliphatic poly amino acrylates UV resins 10-12%
UV epoxy resin 52-56%
Polyester resin 10-15%
Adhesive agent 2-4%
Monomer resin 12-14%
Light curing agent 3-4%
Other auxiliary agents 1-2%
Above-mentioned composition is in percentage by weight.
Further, the material that technique is processed in the present invention is preferably used for glass material.
Further, in S02 steps, transfer PET film is heated and gone Electrostatic Treatment before covering；The heating temperature
Spend for 60-150 DEG C, the heat time is 10-30 seconds；It is described to go Electrostatic Treatment using destaticing ion wind rod.
The present invention has the advantages that：
1st, the invention provides the technique that a kind of utilization UV ink transfers metal wire-drawing effect film, and there is provided one suitable for upper
State the UV ink of technique.
2nd, metal wire-drawing effect true to nature can be obtained on material to be processed using the technique in the present invention and UV ink,
And with low cost, process consistency is good, production efficiency is high, suitable for industrial mass production.
Embodiment
UV ink of the application and preparation in transfer printing process first in the present embodiment, it is formulated and constituted as follows, and its composition is pressed
Calculated according to percentage by weight：
It is raising efficiency in the technique application process of the present invention, should not use needs excessive ultraviolet light hardening time could
It is allowed to the UV ink of solidification.Various kinds of resin component, high solid part content of total resin content more than 70% are used in the present invention
UV ink formulations, it is not only environmentally friendly, and mobility is lower slightly, can stablize when ink is in wet film or half-dried membrane stage and be in
Its existing original form, will not arbitrarily flow, fly away in process.The solid part UV ink of height used in the present invention is because of it
With when viscosity rationally, also with stay in grade the characteristics of.
The light curing agent used in above-mentioned UV ink formulations is PO, ITS and 184 3 kinds of curing agent with mass ratio 1:1:3 groups
Into mixed curing agent, match with follow-up LED cold light optical source wavelength, effectively can make ink solidification under LED cold light.Used
Aliphatic poly amino acrylates UV resins middle army's molecular mass be 1000-3000, through practice find, it is above-mentioned heavy relative
The viscosity and curing performance of UV ink made from the aliphatic poly amino acrylates UV resins of molecular mass best suit the present invention
The requirement of middle process.
The preparation method of UV ink is：
First by the raw material in addition to sensitising agent according to UV epoxy resin, aliphatic poly amino acrylates UV resins, polyester
Resin, monomer resin, adhesive agent, the order of other auxiliary agents feed intake successively, then stir, grinding distribution；It is ground to 1-3 μ
m；Then sensitising agent is put into, UV ink needed for being produced after being uniformly mixed.The ductility of UV ink made from summary plus
Work performance and colour generation brightness consider that No. 8 UV ink of selection carry out following transfer printing process.
Transfer printing process is carried out as the material of transfer from glass sheet in the present embodiment, concrete technology step is as follows：
S01：UV ink rollers are applied to material surface；
S02：PET film is removed into surface electrostatic using ion wind rod is destaticed, PET film is then heated, heating-up temperature is 80 DEG C, plus
The hot time is 18 seconds；Then covering includes the transfer PET film of wire drawing decorative pattern on UV wet films；
S03：Material, UV wet films and PET film whole utilization LED cold light are subjected to semi-solid preparation, then remove PET from film；LED cold light
The condition of solidification is：Using the LED/light source of 395nm wavelength, light source luminescent face power is 20W/cm2, hardening time is 10 seconds；
S04：UV semi-solid preparation films by material and with transfer pattern, which are placed under UV mercury lamps, carries out all solidstate；
The condition of all solidstate is：Ultraviolet ray intensity is 120mJ/cm2S, irradiation time is 5 minutes；
S05：The printing closing ink on transfer pattern, baking molding obtains the material that surface includes metal wire-drawing effect；
The condition of baking process is：180 DEG C, toast 8 minutes.
By the glass sheet produced carries out adhesive force test, impact property test, normal temperature bubble is tested, water boils adhesive force
Test, comparative example is with the identical of 200 mesh steel mesh silk-screens using common UV ink of the prior art on identical material surface
Pattern.
Adhesion test method is：The pattern of transfer or printing to material surface carries out hundred lattice experiments, then uses
3M adhesive tapes are even drawn 3 times in same position.Impact property test method be：The pattern of transfer or printing to material surface enters
Row 500g weight 1m height freely falling body is tested.Normal temperature bubble is tested：The pattern of the transfer on material surface or printing is normal
Temperature is soaked into running water 24 hours, then carries out hundred lattice experiments, is then even drawn 3 times in same position using 3M adhesive tapes.Water is boiled
Adhesion test method is：Material is positioned in boiling water to boil hundred lattice experiments are carried out after 1 hour, then using 3M adhesive tapes identical
Even draw 3 times position.
Test result is as follows：
Adhesive force of the UV transfer films prepared of method of the present invention on material surface, shock resistance it can be seen from test result
Performance, anti-poor environment performance all as screen printing process product of the prior art, have fully met commercial Application
Demand, and a kind of good wire drawing for having aluminium sheet very true to nature of the metal wire-drawing surface three-dimensional effect prepared of the inventive method imitates
Really, and after comparative example silk-screen the metal wire-drawing effect for going up mass-tone and grey bottom is too wide in the gap.The preparation method effect provided in the present invention
Rate is high, green pollution-free, can greatly save cost, creates good economic benefit and social benefit.
It is last it should be noted that above example is only entered to the technical scheme that illustrates the embodiment of the present invention rather than to it
Row limitation, although the embodiment of the present invention is described in detail with reference to preferred embodiment, one of ordinary skill in the art
It should be understood that the technical scheme of the embodiment of the present invention can still be modified or equivalent substitution, and these are changed or waited
It can not also make the scope of amended technical scheme disengaging technical scheme of the embodiment of the present invention with replacing.
Claims (10)
1. the technique that a kind of utilization UV ink transfers metal wire-drawing effect film, it is characterised in that comprise the following steps：
S01：UV ink rollers are applied to material surface；
S02：Then covering includes the transfer PET film of wire drawing decorative pattern on UV wet films；
S03：Material, UV wet films and PET film whole utilization LED cold light are subjected to semi-solid preparation, then remove PET from film；
LED cold light solidification condition be：Using the LED/light source of 360-410nm wavelength, light source luminescent face power is 16-25W/cm2,
Hardening time is 8-15 seconds；
S04：UV semi-solid preparation films by material and with transfer pattern, which are placed under UV mercury lamps, carries out all solidstate；
The condition of all solidstate is：Ultraviolet ray intensity is 110-125mJ/cm2S, irradiation time is 3-5 minutes；
S05：The printing closing ink on transfer pattern, baking molding obtains the material that surface includes metal wire-drawing effect；
The condition of baking process is：170-190 DEG C, toast 7-10 minutes.
2. the technique for transferring metal wire-drawing effect film using UV ink as claimed in claim 1, it is characterised in that：In the technique
The UV ink formulations and composition used are：
Aliphatic poly amino acrylates UV resins 10-15%
UV epoxy resin 50-60%
Polyester resin 10-15%
Adhesive agent 2-4%
Monomer resin 10-15%
Light curing agent 3-5%
Other auxiliary agents 1-2%
Above-mentioned composition is in percentage by weight；
The preparation method of the UV ink is：First by the raw material in addition to sensitising agent according to UV epoxy resin, aliphatic poly
Amino acrylates UV resins, polyester resin, monomer resin, adhesive agent, the order of other auxiliary agents feed intake successively, then stir equal
Even, grinding distribution；It is ground to 1-6 μm；Then sensitising agent is put into, UV ink needed for being produced after being uniformly mixed.
3. the technique for transferring metal wire-drawing effect film using UV ink as claimed in claim 2, it is characterised in that：The photocuring
Agent is TPO, ITS and 184 3 kinds of curing agent with mass ratio 1:1:3 compositions.
4. the technique for transferring metal wire-drawing effect film using UV ink as claimed in claim 2, it is characterised in that：The monomer tree
Fat is HDDA or TMPTA.
5. the technique for transferring metal wire-drawing effect film using UV ink as claimed in claim 2, it is characterised in that：The aliphatic
The average weight-molecular mass of poly- amino acrylates UV resins is 1000-3000.
6. the technique for transferring metal wire-drawing effect film using UV ink as claimed in claim 2, it is characterised in that：In the technique
The UV ink formulations and composition used are：
Aliphatic poly amino acrylates UV resins 10-12%
UV epoxy resin 52-56%
Polyester resin 10-15%
Adhesive agent 2-4%
Monomer resin 12-14%
Light curing agent 3-4%
Other auxiliary agents 1-2%
Above-mentioned composition is in percentage by weight.
7. the technique for transferring metal wire-drawing effect film using UV ink as claimed in claim 1, it is characterised in that：The material is
Glass material.
8. the technique for transferring metal wire-drawing effect film using UV ink as claimed in claim 1, it is characterised in that：In S02 steps,
Transfer PET film is heated and gone Electrostatic Treatment before covering.
9. the technique for transferring metal wire-drawing effect film using UV ink as claimed in claim 8, it is characterised in that：The heating temperature
Spend for 60-150 DEG C, the heat time is 10-30 seconds.
10. the technique for transferring metal wire-drawing effect film using UV ink as claimed in claim 8, it is characterised in that：It is described go it is quiet
Electric treatment is using destaticing ion wind rod.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710166751.4A CN107097549A (en) | 2017-03-20 | 2017-03-20 | The technique and UV ink of a kind of utilization UV ink transfer metal wire-drawing effect film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710166751.4A CN107097549A (en) | 2017-03-20 | 2017-03-20 | The technique and UV ink of a kind of utilization UV ink transfer metal wire-drawing effect film |
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| Publication Number | Publication Date |
|---|---|
| CN107097549A true CN107097549A (en) | 2017-08-29 |
Family
ID=59675196
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|---|---|---|---|
| CN201710166751.4A Pending CN107097549A (en) | 2017-03-20 | 2017-03-20 | The technique and UV ink of a kind of utilization UV ink transfer metal wire-drawing effect film |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112969325A (en) * | 2021-02-24 | 2021-06-15 | Oppo广东移动通信有限公司 | Shell assembly, preparation method thereof and electronic equipment |
| CN112976754A (en) * | 2020-12-30 | 2021-06-18 | 常州市天润木业有限公司 | Manufacturing method of anti-doublet plate with 3D effect |
| CN115179674A (en) * | 2022-08-15 | 2022-10-14 | 福建鸣友新材料科技有限公司 | UV (ultraviolet) photocuring thermal transfer ribbon and preparation method thereof |
| CN117206150A (en) * | 2023-08-04 | 2023-12-12 | 索菲亚家居股份有限公司 | Edge sealing belt with metal wiredrawing texture effect and processing method |
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| CN112976754A (en) * | 2020-12-30 | 2021-06-18 | 常州市天润木业有限公司 | Manufacturing method of anti-doublet plate with 3D effect |
| CN112969325A (en) * | 2021-02-24 | 2021-06-15 | Oppo广东移动通信有限公司 | Shell assembly, preparation method thereof and electronic equipment |
| CN115179674A (en) * | 2022-08-15 | 2022-10-14 | 福建鸣友新材料科技有限公司 | UV (ultraviolet) photocuring thermal transfer ribbon and preparation method thereof |
| CN117206150A (en) * | 2023-08-04 | 2023-12-12 | 索菲亚家居股份有限公司 | Edge sealing belt with metal wiredrawing texture effect and processing method |
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