CN107090217A - 一种丙烯基防污涂料 - Google Patents

一种丙烯基防污涂料 Download PDF

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Publication number
CN107090217A
CN107090217A CN201710387406.3A CN201710387406A CN107090217A CN 107090217 A CN107090217 A CN 107090217A CN 201710387406 A CN201710387406 A CN 201710387406A CN 107090217 A CN107090217 A CN 107090217A
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Prior art keywords
antifouling paint
acrylic
staining agent
quinuclidinols
diphenyl
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CN201710387406.3A
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陈春燕
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Wuhu Weiling Digital Technology Co Ltd
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Wuhu Weiling Digital Technology Co Ltd
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Priority to CN201710387406.3A priority Critical patent/CN107090217A/zh
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612—Non-macromolecular compounds
    • C09D5/1625—Non-macromolecular compounds organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1668—Vinyl-type polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

本发明公开了一种丙烯基防污涂料，所述的材料含有以下物质：丙烯酸树脂、松香、滑石粉、硫酸钡、钛白粉、二甲苯、抗污剂、本发明与现有技术相比，不含有机锡，抗污剂的抑菌圈为19mm，所制的涂料的附着力均为2级，硬度3H，耐冲击性能为50Kg.cm。

Description

一种丙烯基防污涂料
技术领域
本发明属于防污涂料，特别属于海洋防污涂料这一技术领域。
背景技术
随着人类的文明的进步，人类对海洋的利用也越来越多，但海洋中同海水接触的船舶、桥梁、海洋石油开采平台的表面容易吸附各种海洋生物，使其受到污损，形成了海洋污损。防污涂料是常用的防止海洋污损的涂料，防污涂料中通常含有有机锡，但国际海事组织(IMO)目前已经禁止在防污涂料中使用有机锡。
发明内容
本发明所要解决的技术问题是提供一种不含有机锡的丙烯基防污涂料。
本发明解决技术问题的技术方案为：一种丙烯基防污涂料，含有以下重量份的物质：
所述的抗污剂为：胡椒乙胺(C9H11NO2)、4,7-二苯基-1,10-菲啰啉、3-奎宁醇的混合物，胡椒乙胺与4,7-二苯基-1,10-菲啰啉、3-奎宁醇的重量比为100：1-3：1-3。
所述的丙烯酸树脂为BS-963丙烯酸树脂。
抗污剂的加入量不能过多，过多使涂料的机械性能下能。
本发明与现有技术相比，不含有机锡，抗污剂的抑菌圈为19mm，所制的涂料的附着力为2级，硬度3H，耐冲击性能为50Kg.cm。
具体实施方式
下面结合实施例对本发明作详细的说明。
本发明的bs-963丙烯酸树脂由江苏三木集团化工厂提供。
实施例1：
一种丙烯基防污涂料，含有以下重量份的物质：
所述的抗污剂为胡椒乙胺(C9H11NO2)、4,7-二苯基-1,10-菲啰啉、3-奎宁醇的混合物，胡椒乙胺、4,7-二苯基-1,10-菲啰啉、3-奎宁醇的重量比为100：1：1。
实施例2：
一种丙烯基防污涂料，含有以下重量份的物质：
所述的抗污剂为胡椒乙胺(C9H11NO2)、4,7-二苯基-1,10-菲啰啉、3-奎宁醇的混合物，胡椒乙胺、4,7-二苯基-1,10-菲啰啉、3-奎宁醇的重量比为100：2：2。
实施例3：
一种丙烯基防污涂料，含有以下重量份的物质：
所述的抗污剂为胡椒乙胺(C9H11NO2)、4,7-二苯基-1,10-菲啰啉、3-奎宁醇的混合物，胡椒乙胺、4,7-二苯基-1,10-菲啰啉、3-奎宁醇的重量比为100：3：1。
实施例4：
除抗污剂的用量为20重量份外，其它与实施例3相同。
本发明的抗污剂用常规的管碟法测量抑菌圈的直径，所述的细菌为金萄菌(ATCC25923)，其抑菌圈为19mm。
将实施例1-4的喷涂于钢板上，实施例1-3的附着力均为2级，硬度3H，耐冲击性能为50Kg.cm,实施例4的耐冲击性能为32Kg.cm。

Claims (3)

1.一种丙烯基防污涂料，其特征在于：含有以下重量份的物质：
2.根据权利要求1所述的一种丙烯基防污涂料，其特征在于：所述的抗污剂为：胡椒乙胺(C9H11NO2)、4,7-二苯基-1,10-菲啰啉、3-奎宁醇的混合物，胡椒乙胺、4,7-二苯基-1,10-菲啰啉、3-奎宁醇的重量比为100：1-3：1-3。
3.根据权利要求1所述的一种丙烯基防污涂料，其特征在于：所述的丙烯酸树脂为BS-963丙烯酸树脂。
CN201710387406.3A 2017-05-26 2017-05-26 一种丙烯基防污涂料 Withdrawn CN107090217A (zh)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101967316A (zh) * 2010-09-08 2011-02-09 中国乐凯胶片集团公司 一种用于海洋船舶与设施的无毒防污涂料及其制备方法
CN103772369A (zh) * 2012-10-25 2014-05-07 中国中化股份有限公司 胡椒乙胺类化合物及其用途
CN104642381A (zh) * 2013-11-20 2015-05-27 富强 一种抗菌剂组合物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101967316A (zh) * 2010-09-08 2011-02-09 中国乐凯胶片集团公司 一种用于海洋船舶与设施的无毒防污涂料及其制备方法
CN103772369A (zh) * 2012-10-25 2014-05-07 中国中化股份有限公司 胡椒乙胺类化合物及其用途
CN104642381A (zh) * 2013-11-20 2015-05-27 富强 一种抗菌剂组合物

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Application publication date: 20170825