CN107083150A - A kind of automotive trim UV coating and its preparation method and application - Google Patents
A kind of automotive trim UV coating and its preparation method and application Download PDFInfo
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- CN107083150A CN107083150A CN201710320766.1A CN201710320766A CN107083150A CN 107083150 A CN107083150 A CN 107083150A CN 201710320766 A CN201710320766 A CN 201710320766A CN 107083150 A CN107083150 A CN 107083150A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of automotive trim UV coating and its preparation method and application, include the raw material of following parts by weight：15 20 parts of polyurethane acrylic resin；20 30 parts of epoxy resin；15 20 parts of trimethylolpropane trimethacrylate；35 parts of ultraviolet initiator；0.3 0.8 parts of levelling agent；10 25 parts of ethyl acetate；10 25 parts of butyl acetate.The automotive trim that the present invention is provided is excellent with UV coating properties, and coating can be up to crosslinking be fully cured, and solvent noresidue is not after-tacked, moreover, good dispersion during spraying, levelability is moderate, thixotropy is moderate, coating uniform, without obvious tangerine peel, without pinprick bubble, and free from admixture point is present.Lacquer painting levelling is plentiful, and glossiness is good.The VW TL226 standards of masses can be fully met.
Description
Technical field
The invention belongs to technical field of paint preparation, and in particular to a kind of automotive trim with UV coating and preparation method thereof and
Using.
Background technology
Nowadays with the enhancing and the development of polymer science of people's environmental consciousness, it is desirable to use the cry of environmental protection coating material
The index of coating VOC content, development and application ring are all progressively being tightened up to find competitive advantage by more and more higher, domestic Ge Jia enterprises
Guarantor's type coating.UV paint belongs to environment-friendly type coating, has the advantages that curing rate is fast, operating efficiency is high, so automotive trim UV
The research and development of gloss oil series paint are to comply with market trend, and automotive trim UV gloss oil series paint has in the application of automotive upholstery
Extremely wide prospect.
But, automotive trim is generally plastic cement system, and among existing technology, the adhesive force deficiency of UV gloss oil, painting
Layer hardness is high, wearability, acid and alkali-resistance, salt spray resistance, fuel-proof poor-performing, therefore, how to develop with high attachment
The superior automotive trim of power, high rigidity, properties is technical barrier now urgently to be resolved hurrily with UV coating.
The content of the invention
The invention provides a kind of automotive trim UV coating and its preparation method and application, it is for ABS, PC, ABS+
PC plastic rubber substrate has good adhesive force, and the paint film formed has the performances such as solvent resistant, water resistance.
The technical scheme that the present invention is provided is：
A kind of automotive trim UV coating, includes the raw material of following parts by weight：
The ultraviolet initiator is by the light trigger 2-3 parts by weight of BASF IRGACURE 184 and BASF IRGACURE
TPO photoinitiator 1-2 parts by weight are constituted.Two kinds of light triggers are shared, and can be absorbed the ultraviolet of ultraviolet region different-waveband, be made
The solidification for obtaining UV coating is more thorough, so as to provide more preferable surface property for paint film.
The levelling agent is by BYK-333 types levelling agent 0.2-0.5 parts by weight and BYK-371 type levelling agent 0.1-0.3 weight
Part composition.BYK-333 is organosilicon levelling agent, and BYK-371 is acrylic acid levelling agent, and both, which use cooperatively, can solve long shortwave
Problem, makes the levelability of integral system more preferable.
The polyurethane acrylic resin is polyurethane acroleic acid oligomer；The epoxy resin is that epoxy acrylate is low
Polymers.
In above-mentioned formula, polyurethane acrylic resin is used for providing the adhesive force and surface levelability of matrix, asphalt mixtures modified by epoxy resin
Fat provides dryness and crosslink density, and trimethylolpropane trimethacrylate is used for providing the flexility of paint film, ultraviolet light-initiated
Agent is used for triggering the polymerization of monomer and polyester, and levelling agent provides the levelability of paint film, and ethyl acetate is solvent with butyl acetate, is assigned
In the preferable mobility of paint and solvent release.
The invention also discloses preparation method of the automotive trim with UV coating, the preparation method comprises the following steps：
(1) under the conditions of lucifuge, by 15-20 parts by weight of polyurethane acrylic resin, 20-30 parts by weight epoxy resin and
15-20 parts by weight trimethylolpropane trimethacrylates stir 10min under the conditions of 300-700 revs/min, obtain compound A；
(2) butyl acetate of 10-15 parts by weight is stirred under the conditions of 300-700 revs/min, added under agitation
3-5 parts by weight ultraviolet initiators, stir 15min, obtain mixed material B；
(3) under 300-700 revs/min of stirring condition, material B is slowly added into material A, 0.3- is sequentially added
0.8 parts by weight levelling agent, stirs 15min；
(4) continue under 300-700 revs/min of stirring condition, add ethyl acetate 10-25 parts by weight and butyl acetate 5-
10 parts by weight, adjust thickening degree to 20-30S (25 DEG C, NK-2), the filtering of 300 mesh obtains automotive trim UV coating.
Further, the preparation method comprises the following steps：
(1) under the conditions of lucifuge, by 15-20 parts by weight of polyurethane acrylated oligomer, 20-30 parts by weight epoxy acrylic acid
Ester oligomer and 15-20 parts by weight trimethylolpropane trimethacrylates stir 10min under the conditions of 300-700 revs/min, obtain
To compound A；
(2) butyl acetate of 10-15 parts by weight is stirred under the conditions of 300-700 revs/min, added under agitation
The ultraviolet initiator 2-3 parts by weight of IRGACURE 184 and IRGACURE TPO ultraviolet initiator 1-2 parts by weight, stirring
15min, obtains mixed material B；
(3) under 300-700 revs/min of stirring condition, material B is slowly added into material A, levelling is sequentially added
Agent BYK-333 0.2-0.5 parts by weight and levelling agent BYK-371 0.1-0.3 parts by weight, stir 15min；
(4) continue under 300-700 revs/min of stirring condition, add ethyl acetate 10-25 parts by weight and butyl acetate 5-
10 parts by weight, adjust thickening degree to 20-30S (25 DEG C, NK-2), the filtering of 300 mesh obtains automotive trim UV coating.
Above-mentioned preparation method, to improve the functioning efficiency of UV absorbers, whole preparation process need to be under the conditions of lucifuge
Carry out, cause preparation system to solidify under greenware condition to prevent it from absorbing ultraviolet light in the preparation process of coating
The quality of crosslinking influence UV coating and the filming performance of paint film；Ultraviolet initiator adds again after first must being dissolved through butyl acetate
Enter but among reaction system, to ensure that it is uniformly dispersed in system.
Present invention also offers the paint film formed by automotive trim with UV coating, paint film coating, which can reach, is fully cured friendship
Connection, solvent noresidue is not after-tacked, moreover, good dispersion during spraying, levelability is moderate, thixotropy is moderate, and coating uniform, nothing are substantially
Tangerine peel, without pinprick bubble, free from admixture point is present.Lacquer painting levelling is plentiful, and glossiness is good.
Present invention also offers application of the automotive trim with UV coating, for the beautification to ABS or PC or ABS+PC base materials
And protection.
Present invention also offers application method of the described automotive trim with UV coating, by automotive trim UV coating and UV
Paint thinner is by weight 10:2-3 is allocated, and is sprayed on prime coat, after normal temperature levelling is dried 5 minutes, and 80 DEG C are incubated 10 points
Clock, UV solidifications, UV exposure energies are 600-800MJ/cm2。
The UV paint thinners include the raw material of following parts by weight：50 parts of ethyl acetate；50 parts of butyl acetate；It is prepared
Method is：The ethyl acetate of the butyl acetate of parts by weight 50 and parts by weight 50 was mixed evenly after 10 minutes.
The paint film prepared using the raw material and method of said ratio has good water resistance, ethyl acetate and butyl acetate
With the use of ensure that the deliquescent of each raw material while improving the drying property of construction again.
Compared with prior art, UV paints disclosed by the invention are free of VOC, and crosslinking after hardening is close
Degree is much higher than hot baking type coating, property of the coating in organic solvent each side such as hardness, wear-resisting, acid and alkali-resistance, salt spray resistance, resistance to gasoline
Can index it is very high, particularly its paint film is plentiful, gloss is especially prominent, is compared with solvent based coating, UV paints energy phase used
When in the former 1/5 or so.Compared with traditional heat curing coating, UV paint curing rates are fast, and production efficiency is high, and curing mechanism belongs to one
The chain reaction of free radical is planted, crosslinking curing is completed in moment, and designed production line speed reaches as high as 100m/min, work
Part is offline to be packed, and the use of the efficiency of UV coating is more than 15 times of traditional drying-type coating；The energy is saved, UV coating is by purple
Outer photocuring, General Production Lines energy consumption is within 50kW, and energy expenditure is about the 1/5 of traditional drying-type heat curing coating.
The automotive trim that the present invention is provided is excellent with UV coating properties, and coating can be up to crosslinking be fully cured, and solvent is without residual
Stay and do not after-tack, moreover, good dispersion during spraying, levelability is moderate, and thixotropy is moderate, coating uniform, without obvious tangerine peel, without pinprick
Bubble, free from admixture point is present.Lacquer painting levelling is plentiful, and glossiness is good.
Popular VW TL226 are the most stringent standards of automotive upholstery industry, present most of automotive upholstery manufacturers
Equally detected using VW TL226 standard come the performance to paint, the automotive trim that the present invention is provided is passed through with UV coating
Multinomial performance test is crossed, the requirement of TL226 standards can be fully met.
Embodiment
With specific embodiment 1~5 and comparative example 1~3, the present invention is described in detail below, automobile in each embodiment
Interior trim is shown in Table 1 with the parts by weight and raw material of UV coating, and the preparation method of each embodiment is as follows：
(1) according to the formula of each embodiment in table 1, by polyurethane acroleic acid oligomer, epoxy acrylate oligomer and
Trimethylolpropane trimethacrylate stirs 10min under the conditions of 300-700 revs/min, obtains compound A；
(2) butyl acetate of 10-15 parts by weight is stirred under the conditions of 300-700 revs/min, added under agitation
The ultraviolet initiators of IRGACURE 184 and IRGACURE TPO ultraviolet initiators, stir 15min, obtain mixed material B；
(3) under 300-700 revs/min of stirring condition, material B is slowly added into material A, levelling is sequentially added
Agent BYK-333 and levelling agent BYK-371, stirs 15min；
(4) continue under 300-700 revs/min of stirring condition, add ethyl acetate and butyl acetate 5-10 parts by weight, adjust
Thickening degree to 20-30S (25 DEG C, NK-2), the filtering of 300 mesh obtains automotive trim UV coating.
The whole preparation process of embodiment 1~5 is carried out under the conditions of lucifuge.
Table 1
Automotive trim is shown in Table 2 with the parts by weight and raw material of UV coating in comparative example 1~3, and the preparation method of comparative example 1 is with real
Example 1 is applied, simply without addition epoxy acrylate oligomer；The preparation method be the same as Example 2 of comparative example 2, simply wherein
A kind of ultraviolet initiator and levelling agent are only added, but adds total amount and is not changed；The preparation method be the same as Example of comparative example 3
3, simply the addition of part material is different.
Table 2
UV coating that each embodiment and comparative example are obtained with UV lacquer diluents by weight 10：2-3 is allocated, the UV
Paint thinner includes the raw material of following parts by weight：50 parts of ethyl acetate；50 parts of butyl acetate；Its preparation method is：By weight
50 butyl acetate of part is mixed evenly after 10 minutes with the ethyl acetate of parts by weight 50；By the UV coating spray after allotment
It is applied on the prime coat of dried automotive upholstery, after normal temperature levelling is dried 5 minutes, 80 DEG C are incubated 10 minutes, then
UV solidifications are carried out, UV exposure energies are 600-800MJ/cm2, paint film coating uniform that each embodiment is obtained, without obvious tangerine peel, nothing
Pinprick bubble, free from admixture point is present, and lacquer painting levelling is plentiful, and glossiness is good.
Paint film property is detected, its testing result is as shown in table 3：
Table 3
It is as follows with the testing standard of UV coating for automotive trim：
1. outward appearance：Evaluate film forming whether there is the surface blemishes such as foaming, orange peel, shrinkage cavity, ripple, prickly heat.
2. Storage period：Evaluate whether paint occurs thickening within the shelf-life, be layered, play glue, change colour, return the abnormal feelings such as thick
Condition；
For each performance of above paint film testing standard referring to popular VW TL226 standards.
As can be seen that automotive trim disclosed by the invention can comply fully with the VW of masses with UV coating from above-mentioned table 3
TL226 standards.
The above-mentioned detailed description carried out with reference to embodiment to automotive trim with UV coating and its preparation method and application, is to say
It is bright property rather than limited, several embodiments can be included according to limited scope, therefore it is of the invention total not departing from
Changing and modifications under body design, should belong within protection scope of the present invention.
Claims (10)
1. a kind of automotive trim UV coating, it is characterised in that include the raw material of following parts by weight：
2. automotive trim according to claim 1 UV coating, it is characterised in that the ultraviolet initiator is by BASF
The light trigger 2-3 parts by weight of IRGACURE 184 and BASF IRGACURE TPO photoinitiator 1-2 parts by weight composition.
3. automotive trim according to claim 1 or 2 UV coating, it is characterised in that the levelling agent is by BYK-333 types
Levelling agent 0.2-0.5 parts by weight and BYK-371 type levelling agent 0.1-0.3 parts by weight composition.
4. automotive trim according to claim 1 or 2 UV coating, it is characterised in that the polyurethane acrylic resin
For polyurethane acroleic acid oligomer；The epoxy resin is epoxy acrylate oligomer.
5. the automotive trim according to claim 1 preparation method of UV coating, it is characterised in that the preparation method bag
Include following steps：
(1) under the conditions of lucifuge, by 15-20 parts by weight of polyurethane acrylic resin, 20-30 parts by weight epoxy resin and 15-20
Parts by weight trimethylolpropane trimethacrylate stirs 10min under the conditions of 300-700 revs/min, obtains compound A；
(2) butyl acetate of 10-15 parts by weight is stirred under the conditions of 300-700 revs/min, 3-5 is added under agitation
Parts by weight ultraviolet initiator, stirs 15min, obtains mixed material B；
(3) under 300-700 revs/min of stirring condition, material B is slowly added into material A, 0.3-0.8 is sequentially added
Parts by weight levelling agent, stirs 15min；
(4) continue under 300-700 revs/min of stirring condition, add ethyl acetate 10-25 parts by weight and butyl acetate 5-10 weights
Part is measured, adjusts thickening degree to 20-30S (25 DEG C, NK-2), the filtering of 300 mesh obtains automotive trim UV coating.
6. the automotive trim according to claim 4 preparation method of UV coating, it is characterised in that the preparation method bag
Include following steps：
(1) it is under the conditions of lucifuge, 15-20 parts by weight of polyurethane acrylated oligomer, 20-30 parts by weight epoxy acrylate is low
Polymers and 15-20 parts by weight trimethylolpropane trimethacrylates stir 10min under the conditions of 300-700 revs/min, are mixed
Close material A；
(2) butyl acetate of 10-15 parts by weight is stirred under the conditions of 300-700 revs/min, added under agitation
The ultraviolet initiator 2-3 parts by weight of IRGACURE 184 and IRGACURE TPO ultraviolet initiator 1-2 parts by weight, stirring
15min, obtains mixed material B；
(3) under 300-700 revs/min of stirring condition, material B is slowly added into material A, levelling agent is sequentially added
BYK-333 0.2-0.5 parts by weight and levelling agent BYK-371 0.1-0.3 parts by weight, stir 15min；
(4) continue under 300-700 revs/min of stirring condition, add ethyl acetate 10-25 parts by weight and butyl acetate 5-10 weights
Part is measured, adjusts thickening degree to 20-30S (25 DEG C, NK-2), the filtering of 300 mesh obtains automotive trim UV coating.
7. the paint film that the automotive trim according to claim 1-4 any one is formed with UV coating.
8. the application of the automotive trim UV coating according to claim 1-4 any one, it is characterised in that the automobile
Interior trim is used for the beautification and protection to ABS or PC or ABS+PC base materials with UV coating.
9. the application method of the automotive trim UV coating according to claim 1-4 any one, it is characterised in that by vapour
In-car decorations are with UV coating with UV paint thinners by weight 10:2-3 is allocated, and is sprayed on prime coat, and normal temperature levelling dries 5 points
Zhong Hou, 80 DEG C are incubated 10 minutes, and UV solidifications, UV exposure energies are 600-800MJ/cm2。
10. application method according to claim 9, it is characterised in that the UV paint thinners include following parts by weight
Raw material：50 parts of ethyl acetate；50 parts of butyl acetate；Its preparation method is：By the butyl acetate of parts by weight 50 and parts by weight 50
Ethyl acetate be mixed evenly after 10 minutes.
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| CN201710320766.1A CN107083150B (en) | 2017-05-09 | 2017-05-09 | A kind of UV coating for automobile interiors and its preparation method and application |
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| CN201710320766.1A CN107083150B (en) | 2017-05-09 | 2017-05-09 | A kind of UV coating for automobile interiors and its preparation method and application |
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| CN107083150B CN107083150B (en) | 2019-07-02 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641455A (en) * | 2017-09-27 | 2018-01-30 | 芜湖春风新材料有限公司 | A kind of automotive upholstery anti-fingerprint UV coating, preparation method and applications |
| CN108659698A (en) * | 2018-04-12 | 2018-10-16 | 广东鼎立森新材料有限公司 | A kind of ultraviolet-curing paint and its application method of automobile painting surface protective film |
| CN108918411A (en) * | 2018-07-27 | 2018-11-30 | 江西江铃集团新能源汽车有限公司 | A kind of paint film test method |
| CN111019092A (en) * | 2019-12-25 | 2020-04-17 | 芜湖春风新材料有限公司 | Preparation method of organic silicon modified cathode electrophoresis resin and cathode electrophoresis emulsion prepared by same |
| CN111073427A (en) * | 2019-12-31 | 2020-04-28 | 芜湖春风新材料有限公司 | Dual UV (ultraviolet) curing coating for automotive interior parts, preparation method thereof and paint film formed by dual UV curing coating |
| CN111744747A (en) * | 2020-07-06 | 2020-10-09 | 深圳市中暨复合材料有限公司 | Manufacturing method of novel high-hardness micro-ceramic metal coating plate |
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| CN105368297A (en) * | 2015-11-30 | 2016-03-02 | 江门市凌云涂料有限公司 | High-temperature resistant UV (Ultraviolet) coating material for vacuum plating, preparation method for high-temperature resistant UV coating material and application of high-temperature resistant UV coating material |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105368297A (en) * | 2015-11-30 | 2016-03-02 | 江门市凌云涂料有限公司 | High-temperature resistant UV (Ultraviolet) coating material for vacuum plating, preparation method for high-temperature resistant UV coating material and application of high-temperature resistant UV coating material |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641455A (en) * | 2017-09-27 | 2018-01-30 | 芜湖春风新材料有限公司 | A kind of automotive upholstery anti-fingerprint UV coating, preparation method and applications |
| CN107641455B (en) * | 2017-09-27 | 2019-12-24 | 芜湖春风新材料有限公司 | Anti-fingerprint UV coating for automotive interior parts, and preparation method and application thereof |
| CN108659698A (en) * | 2018-04-12 | 2018-10-16 | 广东鼎立森新材料有限公司 | A kind of ultraviolet-curing paint and its application method of automobile painting surface protective film |
| CN108918411A (en) * | 2018-07-27 | 2018-11-30 | 江西江铃集团新能源汽车有限公司 | A kind of paint film test method |
| CN111019092A (en) * | 2019-12-25 | 2020-04-17 | 芜湖春风新材料有限公司 | Preparation method of organic silicon modified cathode electrophoresis resin and cathode electrophoresis emulsion prepared by same |
| CN111019092B (en) * | 2019-12-25 | 2023-04-18 | 芜湖春风新材料有限公司 | Preparation method of organic silicon modified cathode electrophoresis resin and cathode electrophoresis emulsion prepared by same |
| CN111073427A (en) * | 2019-12-31 | 2020-04-28 | 芜湖春风新材料有限公司 | Dual UV (ultraviolet) curing coating for automotive interior parts, preparation method thereof and paint film formed by dual UV curing coating |
| CN111073427B (en) * | 2019-12-31 | 2022-04-05 | 芜湖春风新材料有限公司 | Dual UV (ultraviolet) curing coating for automotive interior parts, preparation method thereof and paint film formed by dual UV curing coating |
| CN111744747A (en) * | 2020-07-06 | 2020-10-09 | 深圳市中暨复合材料有限公司 | Manufacturing method of novel high-hardness micro-ceramic metal coating plate |
| CN111744747B (en) * | 2020-07-06 | 2022-05-17 | 深圳市中暨复合材料有限公司 | Manufacturing method of novel high-hardness micro-ceramic metal coating plate |
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| CN107083150B (en) | 2019-07-02 |
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