CN107083136A - Polyacrylate coating and its coating process - Google Patents
Polyacrylate coating and its coating process Download PDFInfo
- Publication number
- CN107083136A CN107083136A CN201710334877.8A CN201710334877A CN107083136A CN 107083136 A CN107083136 A CN 107083136A CN 201710334877 A CN201710334877 A CN 201710334877A CN 107083136 A CN107083136 A CN 107083136A
- Authority
- CN
- China
- Prior art keywords
- polyacrylate
- coating
- polyacrylate coating
- agent
- paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/36—Successively applying liquids or other fluent materials, e.g. without intermediate treatment
- B05D1/38—Successively applying liquids or other fluent materials, e.g. without intermediate treatment with intermediate treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2502/00—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
Abstract
One polyacrylate coating, including：Polyacrylate coating priming paint (I)；Polyacrylate coating finish paint (II)；Polyacrylate coating metal dodges paint (III)；And polyacrylate coating varnish (IV), wherein described polyacrylate coating priming paint (I), the polyacrylate coating finish paint (II), the polyacrylate coating metal dodge paint (III), and the polyacrylate coating varnish (IV) is in turn applied one or more.It includes following component：Polyacrylate dispersion 40~80%, coalescents 5~15%, multifunctional assistant 0.15~0.5%, pigment 15~30%, filler 10~30%, auxiliary agent 1~3%, mould inhibitor bactericide 0.15~0.5%, thickener 0.3~0.6%, rheology anti-settling agent 0.5~1.0%, remaining be water.
Description
Technical field
The present invention relates to a kind of polyacrylate coating and its coating process.
Background technology
Solvent based coating is building coating common at present.In woodwork coating, building trade, auto industry, industrial antisepsis
The fields such as erosion, frosting, household electrical appliance, pre-coating, aluminum products, coiled material industry, are still to use solvent based coating as wide
The general coating used.
Traditional solvent based coating is mainly made by varsol and oxo solvent.Exist with being also apparent from scarce
Fall into：It is more complicated in use first, demand is a lot, the condition of such as construction, the material coordinated；Next to that coating sheet as
Rigidity, elasticity is not enough, be applied the surfacing of thing it is unconformable in the case of, also having ftractureed, peel etc. influences, and uses
Life-span is not long；It is pollution environment again, the organic volatile of solvent based coating is extremely unfriendly to environment.
In addition, polyacrylate coating is water paint, using water as decentralized medium.Its chemical property is excellent, and to ring
Border is friendly.Especially water paint, hydrone is combined in three-dimensional battle array, similar to cross-linked polymer.When hydrone is with this
When mode be combined with each other, the intensity of its secondary bond is greater than alcohols.So, water polyacrylic acid coating have it is very wide before
Scape.
The content of the invention
It is an object of the present invention to provide a kind of polyacrylate coating and its coating process, by polyacrylate breast
Liquid, coalescents, multifunctional assistant, pigment, filler, auxiliary agent, mould inhibitor bactericide, thickener, rheology anti-settling agent, and water shape
Into emulsion form coating, with good performance.
It is another object of the present invention to provide a kind of polyacrylate coating and its coating process, by aqueous poly- third
Olefin(e) acid ester paint emulsion is main film forming substance so that the gloss retention and the transparency of the coating are preferable.
It is another object of the present invention to provide a kind of polyacrylate coating and its coating process, the coating is plentiful
Degree is higher, and paint film is fine and closely woven.
It is another object of the present invention to provide a kind of polyacrylate coating and its coating process, the coating is suitable to
Many environment are applied to, with durability, corrosion resistance.
It is another object of the present invention to provide a kind of polyacrylate coating and its coating process, the coating can be with
Acid rain, atmosphere pollution, mould etc. are resisted, protection is preferably provided.
It is another object of the present invention to provide a kind of polyacrylate coating and its coating process, the coating has
High rigidity increases the service life there is provided effectively protecting.
It is another object of the present invention to provide a kind of polyacrylate coating and its coating process, can further by
Membranaceous coating is formed, surface slip is fine and closely woven, possess good permeability.
It is another object of the present invention to provide a kind of polyacrylate coating and its coating process, it includes such as the following group
Point：Polyacrylate dispersion 40~80%, coalescents 5~15%, multifunctional assistant 0.15~0.5%, pigment 15~30%,
Filler 10~30%, auxiliary agent 1~3%, mould inhibitor bactericide 0.15~0.5%, thickener 0.3~0.6%, rheology anti-settling agent
0.5~1.0%, remaining is water.
It is another object of the present invention to provide a kind of polyacrylate coating and its coating process, by spraying or
Roller coat effectively coats the coating, it is ensured that play the performance of the coating.
It is another object of the present invention to provide a kind of polyacrylate coating and its coating process, one is applied by two
Dry, three apply the technique such as a baking and the baking of four painting two so that be applied thing and effectively protected.
It is environmentally friendly it is another object of the present invention to provide a kind of polyacrylate coating and its coating process,
Suitable for widely using.
One side under this invention, the present invention further provides a polyacrylate coating, including：
Polyacrylate coating priming paint (I)；
Polyacrylate coating finish paint (II)；
Polyacrylate coating metal flash paint (III)；And
Polyacrylate coating varnish (IV), wherein the polyacrylate coating priming paint (I), the polyacrylate are applied
Charge level paint (II), the polyacrylate coating metal flash paint (III), and the polyacrylate coating varnish (IV) quilt
In turn it is applied one or more.
According to one embodiment of present invention, the polyacrylate coating priming paint (I) is by multifunctional assistant, disperseed
The painting that agent, wetting agent, defoamer, pigment, filler, polyacrylate dispersion, coalescents and thickener pass through polymerization film formation
Material.
According to one embodiment of present invention, the component of the polyacrylate coating priming paint (I) is divided into two parts, one
Individual slurry fractions, and one with paint part, wherein slurry fractions by weight/mass percentage composition include following component：Deionized water 10~
20wt%, 0.10~0.20wt% of multifunctional assistant, 0.6~1.2wt% of dispersant, 0.3~1.0wt% of wetting agent, defoamer
0.1~0.5wt%, 10~20wt% of pigment, 15~30wt% of filler, wherein the component with paint part presses weight/mass percentage composition bag
Include following component：31~41wt% of polyacrylate dispersion, 3~5wt% of coalescents, 0.11~0.18wt% of defoamer, increasing
Thick dose of 0.5~1.0wt%, 5~10wt% of deionized water.
According to one embodiment of present invention, the polyacrylate coating finish paint (II) be by polyacrylate dispersion,
Multifunctional assistant, defoamer, dispersant, wetting agent, pigment, rheology anti-settling agent, coalescents, mould inhibitor and thickener pass through
The coating of polymerization film formation.
According to one embodiment of present invention, the polyacrylate coating finish paint (II) is included such as by weight/mass percentage composition
Lower component：35~55wt% of polyacrylate dispersion, 0.15~0.3wt% of multifunctional assistant, 0.1~0.3wt% of defoamer,
0.6~1.5wt% of dispersant, 0.2~0.5wt% of wetting agent, 15~30wt% of pigment, 0.5~1.0wt% of rheology anti-settling agent,
8~15wt% of coalescents, 0.1~0.3wt% of mould inhibitor, 0.5~1.0wt% of thickener, remaining is water.
According to one embodiment of present invention, the polyacrylate coating metal flash paint (III) is by polyacrylic acid
Ester emulsion, multifunctional assistant, defoamer, wetting agent, coalescents, silver powder directing agent, anti-rheological agent, aqueous coated silver powder,
The coating that BC solvents and dispersant pass through polymerization film formation.
According to one embodiment of present invention, the component of the polyacrylate coating metal flash paint (III) is further
Including a base-material part, and an aluminium paste part, wherein base-material part includes following component by weight/mass percentage composition：Polyacrylic acid
70~55wt% of ester emulsion, 0.1~0.3wt% of multifunctional assistant, 0.3~0.5wt% of defoamer, wetting agent 0.5~
1.0wt%, 8~15wt% of coalescents, 0.6~1.2wt% of silver powder directing agent, anti-0.5~1.0wt% of rheological agent；It is wherein silver-colored
Slurry part includes following component by weight/mass percentage composition：8~10wt% of aqueous coated silver powder, 3~6wt% of BC solvents, point
0.5~1.0wt% of powder, remaining is water.
According to one embodiment of present invention, the polyacrylate coating varnish (IV) be by polyacrylate dispersion,
The painting that multifunctional assistant, defoamer, wetting agent, levelling agent, coalescents, anti-auxiliary rheological agents and thickener pass through polymerization film formation
Material.
According to one embodiment of present invention, the polyacrylate coating varnish (IV) is included such as by weight/mass percentage composition
Lower component：55~70wt% of polyacrylate dispersion, 0.1~0.4wt% of multifunctional assistant, 0.1~0.5wt% of defoamer, profit
0.5~1.0wt% of humectant, 0.3~0.8wt% of levelling agent, 8~15wt% of coalescents, anti-0.3~0.6wt% of auxiliary rheological agents,
0.4~0.8wt% of thickener, remaining is water.
Other side under this invention, the present invention further provides the polyacrylate coating of a polyacrylate coating
The preparation method of priming paint (I), including：
It is divided into two parts by the component of the polyacrylate coating priming paint (I), a slurry fractions, and one with paint
Part, wherein slurry fractions include following component by weight/mass percentage composition：10~20wt% of deionized water, multifunctional assistant 0.10
~0.20wt%, 0.6~1.2wt% of dispersant, 0.3~1.0wt% of wetting agent, 0.1~0.5wt% of defoamer, pigment 10~
20wt%, 15~30wt% of filler, wherein the component with paint part includes following component by weight/mass percentage composition：Polyacrylate
31~41wt% of emulsion, 3~5wt% of coalescents, 0.11~0.18wt% of defoamer, 0.5~1.0wt% of thickener, go from
Sub- 5~10wt% of water proportioning, deionized water is added in dispersion cylinder, successively by remaining slurry fractions under stirring
Material adds container, stirs；
It is scattered；
It is ground to fineness and reaches 10um and its following；
Rotating speed is adjusted, is added with paint partial material；And
The polyacrylate coating priming paint (I) is filtered out after stirring.
Other side under this invention, the present invention further provides the polyacrylate coating of a polyacrylate coating
The preparation method of finish paint (II), including：
Following component will be included by weight/mass percentage composition：35~55wt% of polyacrylate dispersion, multifunctional assistant 0.15
~0.3wt%, 0.1~0.3wt% of defoamer, 0.6~1.5wt% of dispersant, 0.2~0.5wt% of wetting agent, pigment 15~
30wt%, 0.5~1.0wt% of rheology anti-settling agent, 8~15wt% of coalescents, 0.1~0.3wt% of mould inhibitor, thickener 0.5
~1.0wt%, remaining is put into dispersion cylinder for 8% deionized water in the proportioning of water, and is stirred；
Sequentially add the multifunctional assistant in described proportioning, the defoamer of part, dispersant, wetting agent, stir,
Pigment, rheology anti-settling agent are added, and is disperseed；
Regulate the speed stirring, add polyacrylate dispersion, remaining defoamer, coalescents, mould inhibitor, thickener,
And stir；And
Whether test pH value reaches 8~9, and the polyacrylate coating finish paint (II) is filtered out if reaching.
Other side under this invention, the present invention further provides the polyacrylate coating of a polyacrylate coating
The preparation method of metal flash paint (III), including：
(1) a base-material part, and one are further comprised by the component of the polyacrylate coating metal flash paint (III)
Aluminium paste part, wherein base-material part include following component by weight/mass percentage composition：70~55wt% of polyacrylate dispersion,
0.1~0.3wt% of multifunctional assistant, 0.3~0.5wt% of defoamer, 0.5~1.0wt% of wetting agent, coalescents 8~
15wt%, 0.6~1.2wt% of silver powder directing agent, anti-0.5~1.0wt% of rheological agent；Wherein aluminium paste part is contained by quality percentage
Amount includes following component：8~10wt% of aqueous coated silver powder, 3~6wt% of BC solvents, 0.5~1.0wt% of dispersant, its
The remaining proportioning for water, prepares aluminium paste part, wherein further comprising：BC solvents are added in dispersion cylinder；With under stirring successively
Dispersant, deionized water, aqueous cladded type silver powder are added, and the immersion that is uniformly dispersed is stand-by；
(2) base-material part is prepared, it further comprises：Acrylic acid ester emulsion is placed in another dispersion cylinder；With stirring
Under be added dropwise to multifunctional assistant, defoamer, wetting agent, deionized water, coalescents, silver powder directing agent, anti-rheological agent, and point
Dissipate；
(3) soaked aluminium paste part is added in base-material part, is uniformly dispersed；And
(4) whether test pH value reaches 8~9, and the polyacrylate coating metal flash paint is filtered out if reaching
(III)。
Other side under this invention, the present invention further provides the polyacrylate coating of a polyacrylate coating
The preparation method of metal varnish lacquer (IV), including：
Following component will be included by weight/mass percentage composition：55~70wt% of polyacrylate dispersion, multifunctional assistant 0.1
~0.4wt%, 0.1~0.5wt% of defoamer, 0.5~1.0wt% of wetting agent, 0.3~0.8wt% of levelling agent, coalescents 8
~15wt%, anti-0.3~0.6wt% of auxiliary rheological agents, 0.4~0.8wt% of thickener, remaining is the polyacrylate of the proportioning of water
Emulsion is placed in dispersion cylinder, is added dropwise to multifunctional assistant, wetting agent, defoamer under stirring successively；
Detect whether to whether there is shrinkage cavity and whether fineness is normal；
If normal, dropwise addition coalescents stirring makes full and uniform；And
Anti- rheological agent and thickener are added, and viscosity is adjusted with deionized water, the polyacrylate coating is filtered out clear
Paint (IV).
Other side under this invention, the present invention further provides a polyacrylate coating coating process, using upper
State component and prepare, including：
Pre-treatment one is applied thing；
In turn coat the polyacrylate coating priming paint (I), it is the polyacrylate coating finish paint (II), described poly-
One or more in acrylate paint metal flash paint (III), and the polyacrylate coating varnish (IV)；
Baking；And
Prepare packaging.
According to one embodiment of present invention, the baking condition of the polyacrylate coating priming paint (I)：At least 60~
70℃×10min。
According to one embodiment of present invention, the baking condition of the polyacrylate coating finish paint (II)：At least 150
℃×20min。
According to one embodiment of present invention, the baking condition of the polyacrylate coating metal flash paint (III)：Extremely
It is 150 DEG C × 20min less.
According to one embodiment of present invention, the baking condition of the polyacrylate coating varnish (IV)：At least 150
℃×20min。
Other side under this invention, the present invention further provides polyacrylate coating one by one, is contained by quality percentage
Amount includes following component：40~80wt% of polyacrylate dispersion, 5~15wt% of coalescents, multifunctional assistant 0.15~
0.5wt%, 15~30wt% of pigment, 10~30wt% of filler, 1~3wt% of auxiliary agent, 0.15~0.5wt% of mould inhibitor bactericide,
0.3~0.6wt% of thickener, 0.5~1.0wt% of rheology anti-settling agent, remaining be water.
According to one embodiment of present invention, it is divided into two parts, a slurry fractions, and one with paint part, wherein
Slurry fractions include following component by weight/mass percentage composition：10~20wt% of deionized water, multifunctional assistant 0.10~
0.20wt%, 0.6~1.2wt% of dispersant, 0.3~1.0wt% of wetting agent, 0.1~0.5wt% of defoamer, pigment 10~
20wt%, 15~30wt% of filler, wherein the component with paint part includes following component by weight/mass percentage composition：Polyacrylate
33~37wt% of emulsion, 3~5wt% of coalescents, 0.10~0.20wt% of defoamer, 0.5~1.0wt% of thickener, go from
Sub- 8~10wt% of water.
According to one embodiment of present invention, following component is included by weight/mass percentage composition：Polyacrylate dispersion 35~
55wt%, 0.15~0.3wt% of multifunctional assistant, 0.1~0.3wt% of defoamer, 0.6~1.5wt% of dispersant, wetting agent
0.2~0.5wt%, 15~30wt% of pigment, 0.5~1.0wt% of rheology anti-settling agent, 8~15wt% of coalescents, mould inhibitor
0.1~0.3wt%, 0.5~1.0wt% of thickener, remaining is water.
According to one embodiment of present invention, a base-material part, and an aluminium paste part, wherein base are further comprised
Divide includes following component by weight/mass percentage composition：55~70wt% of polyacrylate dispersion, 0.1~0.3wt% of multifunctional assistant,
0.3~0.5wt% of defoamer, 0.5~1.0wt% of wetting agent, 8~15wt% of coalescents, silver powder directing agent 0.6~
1.2wt%, anti-0.5~1.0wt% of rheological agent；Wherein aluminium paste part includes following component by weight/mass percentage composition：Aqueous bag
8~10wt% of type silver powder, 3~6wt% of BC solvents, 0.5~1.0wt% of dispersant are wrapped up in, remaining is water.
According to one embodiment of present invention, it includes following component by weight/mass percentage composition：Polyacrylate dispersion 55
~70wt%, 0.1~0.4wt% of multifunctional assistant, 0.1~0.5wt% of defoamer, 0.5~1.0wt% of wetting agent, levelling agent
0.3~0.8wt%, 8~15wt% of coalescents, anti-0.3~0.6wt% of auxiliary rheological agents, 0.4~0.8wt% of thickener, its
Yu Weishui.
Embodiment
Describe to be used to disclose the present invention below so that those skilled in the art can realize the present invention.It is excellent in describing below
Embodiment is selected to be only used as citing, it may occur to persons skilled in the art that other obvious modifications.Define in the following description
General principle of the invention can apply to other embodiments, deformation program, improvement project, equivalent and do not carry on the back
From the other technologies scheme of the spirit and scope of the present invention.
The present invention provides a kind of polyacrylate coating and its coating process, and provides corresponding technical testing standard.Institute
Polyacrylate coating is stated to apply including polyacrylate coating priming paint (I), polyacrylate coating finish paint (II), polyacrylate
Expect metal flash paint (III), and polyacrylate coating varnish (IV).It should be noted that the polyacrylate coating
Priming paint (I), the polyacrylate coating finish paint (II), the polyacrylate coating metal flash paint (III), and it is described
Polyacrylate coating varnish (IV) is in turn applied one or more, and then plays its protective value by toasting.
In the preferred embodiment, the polyacrylate coating priming paint (I), the polyacrylate coating finish paint
(II), the polyacrylate coating metal flash paint (III), and the polyacrylate coating varnish (IV) are preferred
Component is further disclosed as follows.It is noted that quality accounting in this preferred embodiment is at least 5 minimums up and down
All it is effectively, for example, the accounting of deionized water 15%, i.e. deionized water can be 10~20% in the selection space of unit；Point
The accounting of powder 0.6%, i.e. dispersant can be 0.1~1.1%.Those skilled in the art understandably there is provided quality accounting
Accurately numeral is not limited to, and there is the scope floated.
The component of the polyacrylate coating priming paint (I) is divided into two parts, a slurry fractions, and one is matched somebody with somebody paint portion
Point, the preferred component (quality accounting) of wherein slurry fractions is：10~20wt% of deionized water, multifunctional assistant 0.10~
0.20wt%, 0.6~1.2wt% of dispersant, 0.3~1.0wt% of wetting agent, 0.1~0.5wt% of defoamer, pigment 10~
20wt%, 15~30wt% of filler, wherein the preferred component (quality accounting) with paint part is：Polyacrylate dispersion 33~
37wt%, 3~5wt% of coalescents, 0.10~0.20wt% of defoamer, 0.5~1.0wt% of thickener, deionized water 8~
10wt%.It should be noted that last need between multifunctional assistant adjustment pH value to 8.0~9.0.
Specifically, the multifunctional assistant is preferably 2-amino-2-methyl-1-propanol, polyacrylic acid, diethylene glycol, carboxylic
Methyl starch sodium, silver-carrying nano basic zirconium phosphate, nano silicon oxide, nano pulp, surfactant, emulsifying agent, esters of acrylic acid
Compound, nitroparaffins mixture, Nano zinc dioxide impact-resistant, pearl mica, ESCALOL 567, monostearate are sweet
One or more kinds of composition among grease.
The defoamer is preferably silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene Ji Wusi
Alcohol ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether, polydimethylsiloxanes
One or more kinds of composition among alkane.
The wetting agent is preferably alkyl sulfate, sulfonate, aliphatic acid or fatty acid ester sulfate, carboxylic acid soaps, phosphorus
Among acid esters, polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene block copolymer it is a kind of or
A variety of compositions.
The dispersant is preferably silicates and alkali metal phosphate class, or triethyl group hexyl phosphoric acid, dodecyl
It is a kind of or many among sodium sulphate, methyl anyl alcohol, cellulose derivative, polyacrylamide, guar gum, fatty acid polyethylene glycol ester
The composition planted.
The coalescents are preferably the strong solvent of ether alcohol class high polymer, such as propandiol butyl ether, propylene glycol methyl ether acetate,
Or No. 200 oil, ethylene glycol, alcohol ester 12 etc..
The thickener be preferably hydrophilic macromolecular compounds, inorganic thickening agent, cellulose ether, natural polymer and its
One or more kinds of composition among derivative, synthesis macromolecule, solvay-type organo-metallic compound, printing thickening agent.
Table 1
The component (quality accounting) of the polyacrylate coating priming paint (I) such as in table 1 for preferred proportioning.According to institute
Polyacrylate coating priming paint (I) component is stated, this preferred embodiment further provides for corresponding preparation method.First, it will go
Ionized water is added in dispersion cylinder, and other slurry fractions materials are added into container successively under stirring, stirred；Its
It is secondary, rotating speed is adjusted, scattered appropriate time at a high speed is carried out, is recommended as 20 ± 5min；Again, be ground to fineness reach 10um and its with
Under；Then, it is put into dispersion cylinder, then adjusts addition under rotating speed to middling speed state and matches somebody with somebody paint partial material；Mistake after finally stirring
Filter out the polyacrylate coating priming paint (I).
The preferred component (quality accounting) of the polyacrylate coating finish paint (II) is：Polyacrylate dispersion 35~
55wt%, 0.15~0.3wt% of multifunctional assistant, 0.1~0.3wt% of defoamer, 0.6~1.5wt% of dispersant, wetting agent
0.2~0.5wt%, 15~30wt% of pigment, 0.5~1.0wt% of rheology anti-settling agent, 8~15wt% of coalescents, mould inhibitor
0.1~0.3wt%, 0.5~1.0wt% of thickener, and deionized water surplus.
Specifically, the multifunctional assistant is preferably 2-amino-2-methyl-1-propanol, polyacrylic acid, diethylene glycol, carboxylic
Methyl starch sodium, silver-carrying nano basic zirconium phosphate, nano silicon oxide, nano pulp, surfactant, emulsifying agent, esters of acrylic acid
Compound, nitroparaffins mixture, Nano zinc dioxide impact-resistant, pearl mica, ESCALOL 567, monostearate are sweet
One or more kinds of composition among grease.
The defoamer is preferably silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene Ji Wusi
Alcohol ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether, polydimethylsiloxanes
One or more kinds of composition among alkane.
The wetting agent is preferably alkyl sulfate, sulfonate, aliphatic acid or fatty acid ester sulfate, carboxylic acid soaps, phosphorus
Among acid esters, polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene block copolymer it is a kind of or
A variety of compositions.
The dispersant is preferably silicates and alkali metal phosphate class, or triethyl group hexyl phosphoric acid, dodecyl
It is a kind of or many among sodium sulphate, methyl anyl alcohol, cellulose derivative, polyacrylamide, guar gum, fatty acid polyethylene glycol ester
The composition planted.
The coalescents are preferably the strong solvent of ether alcohol class high polymer, such as propandiol butyl ether, propylene glycol methyl ether acetate,
Or No. 200 oil, ethylene glycol, alcohol ester 12 etc..
The thickener be preferably hydrophilic macromolecular compounds, inorganic thickening agent, cellulose ether, natural polymer and its
One or more kinds of composition among derivative, synthesis macromolecule, solvay-type organo-metallic compound, printing thickening agent.
The rheology anti-settling agent is preferably organobentonite, castor oil derivative, aerosil, polyolefin-wax, changed
Property rilanit special, the N monomethyls pyrrolidone solution of modified polyurea, one or more kinds of combination among polyamide wax series
Thing.
| Component | Mass fraction/% |
| Polyacrylate dispersion | 35~55 |
| Multifunctional assistant | 0.15~0.3 |
| Defoamer | 0.1~0.3 |
| Dispersant | 0.6~1.5 |
| Wetting agent | 0.2~0.5 |
| Pigment | 15~30 |
| Rheology anti-settling agent | 0.5~1.0 |
| Coalescents | 8~15 |
| Mould inhibitor | 0.1~0.3 |
| Thickener | 0.3~1.0 |
| Deionized water | Surplus |
Table 2
The component (quality accounting) of the polyacrylate coating finish paint (II) in table 2 as summarized.According to described poly- third
The component of olefin(e) acid ester paint finish paint (II), this preferred embodiment further provides for corresponding preparation method.First, in being first formulated
8% deionized water is put into dispersion cylinder, stirring at low speed；Secondly, multifunctional assistant, 50% froth breaking in formula are sequentially added
Agent, dispersant, wetting agent, stir, be slowly added to pigment, rheology anti-settling agent, scattered appropriate time, is recommended as at a high speed
20min；Again, polyacrylate dispersion, remaining 50% defoamer, coalescents, mould inhibitor, increasing are added under moderate-speed mixer
Thick dose, appropriate time is stirred, is recommended as 20 ± 5min；Last test pH value filters out the polyacrylate coating to 8~9
Finish paint (II).
The component of the polyacrylate coating metal flash paint (III) further comprises a base-material part, and one
The preferred component (quality accounting) of aluminium paste part, wherein base-material part is：It is 55~70wt% of polyacrylate dispersion, many
0.1~0.3wt% of function additive, 0.3~0.5wt% of defoamer, 0.5~1.0wt% of wetting agent, 8~15wt% of coalescents,
0.6~1.2wt% of silver powder directing agent, anti-0.5~1.0wt% of rheological agent；Wherein (quality is accounted for the preferred component of aluminium paste part
Than) be：8~10wt% of aqueous coated silver powder, 3~6wt% of BC solvents, 0.5~1.0wt% of dispersant, and deionized water
Surplus.
Specifically, the multifunctional assistant is preferably 2-amino-2-methyl-1-propanol, polyacrylic acid, diethylene glycol, carboxylic
Methyl starch sodium, silver-carrying nano basic zirconium phosphate, nano silicon oxide, nano pulp, surfactant, emulsifying agent, esters of acrylic acid
Compound, nitroparaffins mixture, Nano zinc dioxide impact-resistant, pearl mica, ESCALOL 567, monostearate are sweet
One or more kinds of composition among grease.
The defoamer is preferably silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene Ji Wusi
Alcohol ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether, polydimethylsiloxanes
One or more kinds of composition among alkane.
The wetting agent is preferably alkyl sulfate, sulfonate, aliphatic acid or fatty acid ester sulfate, carboxylic acid soaps, phosphorus
Among acid esters, polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene block copolymer it is a kind of or
A variety of compositions.
The dispersant is preferably silicates and alkali metal phosphate class, or triethyl group hexyl phosphoric acid, dodecyl
It is a kind of or many among sodium sulphate, methyl anyl alcohol, cellulose derivative, polyacrylamide, guar gum, fatty acid polyethylene glycol ester
The composition planted.
The coalescents are preferably the strong solvent of ether alcohol class high polymer, such as propandiol butyl ether, propylene glycol methyl ether acetate,
Or No. 200 oil, ethylene glycol, alcohol ester 12 etc..
The silver powder directing agent be preferably siliceous alcohol functional group high molecular polymer, polyamide and polyester among it is a kind of or
The a variety of composition of person.
Table 3
The component (quality accounting) of the polyacrylate coating metal flash paint (III) in table 3 as summarized.According to institute
Polyacrylate coating metal flash paint (III) component is stated, this preferred embodiment further provides for corresponding preparation method, wrapped
Include：
(1) aluminium paste part is prepared, wherein further comprising：First, BC solvents are added in dispersion cylinder；Secondly, low speed
Dispersant, deionized water, aqueous cladded type silver powder are sequentially added under stirring, and the immersion appropriate time that is uniformly dispersed is stand-by, recommends
For 3h；
(2) base-material part is prepared, it further comprises：First, acrylic acid ester emulsion is placed in another dispersion cylinder；Again
It is secondary, multifunctional assistant, defoamer, wetting agent, deionized water, coalescents, silver powder directing agent, anti-stream are added dropwise under moderate-speed mixer
Become agent, and scattered appropriate time, be recommended as 20min；And
(3) soaked aluminium paste part is added in base-material part, is uniformly dispersed, after measure pH value to 8~9, filtering
Go out the polyacrylate coating metal flash paint (III).
The preferred component (quality accounting) of the polyacrylate coating varnish (IV) is：Polyacrylate dispersion 55~
70wt%, 0.1~0.4wt% of multifunctional assistant, 0.1~0.5wt% of defoamer, 0.5~1.0wt% of wetting agent, levelling agent 0.3
~0.8wt%, 8~15wt% of coalescents, anti-0.3~0.6wt% of auxiliary rheological agents, 0.4~0.8wt% of thickener, and go
Ion water surplus.
Specifically, the multifunctional assistant is preferably 2-amino-2-methyl-1-propanol, polyacrylic acid, diethylene glycol, carboxylic
Methyl starch sodium, silver-carrying nano basic zirconium phosphate, nano silicon oxide, nano pulp, surfactant, emulsifying agent, esters of acrylic acid
Compound, nitroparaffins mixture, Nano zinc dioxide impact-resistant, pearl mica, ESCALOL 567, monostearate are sweet
One or more kinds of composition among grease.
The defoamer is preferably silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene Ji Wusi
Alcohol ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether, polydimethylsiloxanes
One or more kinds of composition among alkane.
The wetting agent is preferably alkyl sulfate, sulfonate, aliphatic acid or fatty acid ester sulfate, carboxylic acid soaps, phosphorus
Among acid esters, polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene block copolymer it is a kind of or
A variety of compositions.
The levelling agent is preferably high boiling solvent or butyl cellulose, or surfactant or polyacrylic acid, carboxylic first
One or more kinds of composition among base cellulose.
The coalescents are preferably the strong solvent of ether alcohol class high polymer, such as propandiol butyl ether, propylene glycol methyl ether acetate,
Or No. 200 oil, ethylene glycol, alcohol ester 12 etc..
The thickener be preferably hydrophilic macromolecular compounds, inorganic thickening agent, cellulose ether, natural polymer and its
One or more kinds of composition among derivative, synthesis macromolecule, solvay-type organo-metallic compound, printing thickening agent.
| Component | Mass fraction/% |
| Water polyacrylic acid emulsion | 55~70 |
| Multifunctional assistant | 0.1~0.4 |
| Defoamer | 0.1~0.5 |
| Wetting agent | 0.5~1.0 |
| Levelling agent | 0.3~0.8 |
| Coalescents | 8~15 |
| Anti- auxiliary rheological agents | 0.3~0.6 |
| Thickener | 0.4~0.8 |
| Deionized water | In right amount |
Table 4
The component (quality accounting) of the polyacrylate coating varnish (IV) in table 4 as summarized.According to described poly- third
The component of olefin(e) acid ester paint varnish (IV), this preferred embodiment further provides for corresponding preparation method.First, by polyacrylic acid
Ester emulsion is placed in dispersion cylinder, is added dropwise to multifunctional assistant, wetting agent, defoamer stirring appropriate time under moderate-speed mixer successively,
It is recommended as 15min；Secondly, detect whether to whether there is shrinkage cavity and whether fineness is normal；Again, if normally, film forming being slowly added dropwise and helps
Agent stirring makes full and uniform, recommendation stirring 20min；Finally, anti-rheological agent and thickener are added, and adjusts viscous with deionized water
Degree, filters out the polyacrylate coating varnish (IV).
The corresponding coating process of the polyacrylate coating that the present invention is provided, it includes：
Pre-treatment one is applied thing；
In turn coat the polyacrylate coating priming paint (I), it is the polyacrylate coating finish paint (II), described poly-
One or more in acrylate paint metal flash paint (III), and the polyacrylate coating varnish (IV)；
Baking；And
Prepare packaging.
It is noted that the baking condition of the polyacrylate coating priming paint (I)：At least 60~70 DEG C ×
10min.Can coat afterwards has good adhesive force, corrosion resistant after the polyacrylate coating finish paint (II), complete film forming
Corrosion, water resistance.
It is noted that the baking condition of the polyacrylate coating finish paint (II)：At least 150 DEG C × 20min.
Its performance refers at least to be designated as：Hardness 2H；Adhesion 1 grade；Shock resistance 50Kgf.cm；Gloss 75 ± 5；Resistance to nitric acid is in nothing in 30min
Foaming；5%NaOH solution in 24h without foaming；Salt spray resistance in 240h without foaming, nondiscolouring.
It is noted that the baking condition of the polyacrylate coating metal flash paint (III)：At least 150 DEG C
×20min.Have excellent adhesive force and chemicals, mechanical property good on aluminum products, coil painting.Specific performance refers to
It is designated as：Apparent metal sense is strong；Hardness 1H；Adhesion 1 grade；Shock resistance 50Kgf.cm；Gloss 75 ± 5；Resistance to nitric acid is in nothing in 30min
Foaming；The solution of resistance to 5%NaOH in 24h without foaming；Salt spray resistance is in non-foaming nondiscolouring in 240h.
It is noted that the baking condition of the polyacrylate coating varnish (IV)：At least 150 DEG C × 20min.
With good adhesive force and permeability, apparent high richness, paint film is fine and closely woven, and endurance is good.Specifically performance indications are：It is resistance to
Nitric acid in 30min without foaming；The solution of resistance to 5%NaOH in 24h without foaming；Shock resistance 50Kgf.cm.
Preferably, the corresponding coating process of the polyacrylate coating of this preferred embodiment is applied to spraying or roller
Apply.A kind of feasible corresponding coating process of the polyacrylate coating is that pre-treatment one is applied thing；Chromaking processing is described
It is applied thing and dries；In turn coat the polyacrylate coating priming paint (I) and the polyacrylate coating finish paint
(II)；Baking；And prepare packaging.
Another feasible corresponding coating process of the polyacrylate coating is that thing is applied described in pre-treatment；Chromaking
Handle the coated thing and dry；In turn coat the polyacrylate coating priming paint (I), the polyacrylate coating
Finish paint (II), and the polyacrylate coating varnish (IV)；Baking；And prepare packaging.
More specifically, another corresponding coating process of the polyacrylate coating suitable for roller coat is described to roll
It is applied thing；Thing is applied described in pre-treatment；Thing is applied described in upper paint line；In turn coat and in turn coat described poly- third
Olefin(e) acid ester paint priming paint (I), the polyacrylate coating finish paint (II), the polyacrylate coating metal flash paint
, and the one or more in the polyacrylate coating varnish (IV) (III)；Baking；And cool down, examine and wind.
Carried out according to described coating process after application, can according to one in specific performance index or several standards come
Verify whether the polyacrylate coating is effectively coated, if protective value can be played.The polyacrylate is applied
Material may be adapted to be applied to outdoor environment, with durability, corrosion resistance.The polyacrylate coating can resist acid
Rain, atmosphere pollution, mould etc., preferably provide protection.And the polyacrylate coating is suitable for being coated on metal
Ground is reasonably resistant to stain there is provided effectively protecting, and increases the service life.
The feasible component of another preferred embodiment of the present invention is disclosed as follows.The polyacrylate coating priming paint (I)
The preferred components (quality accounting) of slurry fractions be：Deionization 15wt%, multifunctional assistant 0.15wt%, dispersant
0.3wt%, wetting agent 0.3wt%, defoamer 0.3wt%, pigment 15wt%, filler 20wt%, wherein with the preferred of paint part
Component (quality accounting) be：Polyacrylate dispersion 36wt%, coalescents 4wt%, defoamer 0.15wt%, thickener
0.3wt%, deionized water 8.5wt%.
The preferred component (quality accounting) of the polyacrylate coating finish paint (II) is：Polyacrylate dispersion
35wt%, multifunctional assistant 0.1wt%, defoamer 0.1wt%, dispersant 0.6wt%, wetting agent 0.2wt%, pigment
15wt%, rheology anti-settling agent 0.5wt%, coalescents 8wt%, mould inhibitor 0.1wt%, thickener 0.5wt%, and deionization
Water surplus.
The preferred component (quality accounting) of the base-material part of the polyacrylate coating metal flash paint (III) is：
Polyacrylate dispersion 70wt%, multifunctional assistant 0.1wt%, defoamer 0.3wt%, wetting agent 0.5wt%, coalescents
8wt%, silver powder directing agent 0.6wt%, anti-rheological agent 0.5wt%；The wherein preferred component (quality accounting) of aluminium paste part
For：Aqueous coated silver powder 8wt%, BC solvent 3wt%, dispersant 0.5wt%, and deionized water surplus.
The preferred component (quality accounting) of the polyacrylate coating varnish (IV) is：Polyacrylate dispersion
55wt%, multifunctional assistant 0.1wt%, defoamer 0.1wt%, wetting agent 0.5wt%, levelling agent 0.3wt%, coalescents
8wt%, anti-auxiliary rheological agents 0.3wt%, thickener 0.4wt%, and deionized water surplus.
The preparation method of this preferred embodiment is illustrated as follows.By the above-mentioned proportioning of the polyacrylate coating priming paint (I),
Deionized water is added in dispersion cylinder, other slurry fractions materials are added into container successively under stirring, stirred；
Secondly, rotating speed is adjusted, scattered 20min at a high speed is carried out；Again, it is ground to fineness and reaches 10um and its following；Then, it is put into scattered
In cylinder, then adjust under rotating speed to middling speed state add with paint partial material；The polyacrylic acid is filtered out after finally stirring
Ester paint priming paint (I).
In the formula of the polyacrylate coating finish paint (II) 8% deionized water is put into dispersion cylinder, low speed is stirred
Mix；Secondly, multifunctional assistant in formula, 0.05wt% defoamer are sequentially added, dispersant, wetting agent, is stirred, slowly
Pigment, rheology anti-settling agent are added, at a high speed scattered 20min；Again, polyacrylate dispersion, remaining is added under moderate-speed mixer
0.05wt% defoamers, coalescents, mould inhibitor, thickener, stir 20min；Last test pH value is filtered out described to 8~9
Polyacrylate coating finish paint (II).
According to the corresponding preparation method of the component of the polyacrylate coating metal flash paint (III), including：
(4) aluminium paste part is prepared, wherein further comprising：First, BC solvents are added in dispersion cylinder；Secondly, low speed
Dispersant, deionized water, aqueous cladded type silver powder are sequentially added under stirring, and the immersion 3h that is uniformly dispersed is stand-by；
(5) base-material part is prepared, it further comprises：First, acrylic acid ester emulsion is placed in another dispersion cylinder；Again
It is secondary, multifunctional assistant, defoamer, wetting agent, deionized water, coalescents, silver powder directing agent, anti-stream are added dropwise under moderate-speed mixer
Become agent, and scattered 20min；And
(6) soaked aluminium paste part is added in base-material part, is uniformly dispersed, after measure pH value to 8~9, filtering
Go out the polyacrylate coating metal flash paint (III).
According to the proportioning of the polyacrylate coating varnish (IV), polyacrylate dispersion is placed in dispersion cylinder, in
Multifunctional assistant, wetting agent, defoamer stirring 15min are added dropwise under speed stirring successively；Secondly, detect whether whether there is shrinkage cavity and thin
Whether degree is normal；Again, if normally, coalescents stirring, which is slowly added dropwise, makes full and uniform, stirring 20min；Finally, add anti-
Rheological agent and thickener, and viscosity is adjusted with deionized water, filter out the polyacrylate coating varnish (IV).
The feasible component of another preferred embodiment of the present invention is disclosed as follows.The polyacrylate coating priming paint (I)
The preferred components (quality accounting) of slurry fractions be：Deionized water 20wt%, multifunctional assistant 0.20wt%, dispersant
1.2wt%, wetting agent 1.0wt%, defoamer 0.5wt%, pigment 10wt%, filler 22.5wt%, wherein with the excellent of paint part
The component (quality accounting) of choosing is：Polyacrylate dispersion 33wt%, coalescents 3wt%, defoamer 0.10wt%, thickener
0.5wt%, deionized water 8wt%.It should be noted that it is last need with multifunctional assistant adjust pH value to 8.0~9.0 it
Between.
The preferred component (quality accounting) of the polyacrylate coating finish paint (II) is：Polyacrylate dispersion
55wt%, multifunctional assistant 0.3wt%, defoamer 0.3wt%, dispersant 1.5wt%, wetting agent 0.5wt%, pigment
17wt%, rheology anti-settling agent 0.8wt%, coalescents 9wt%, mould inhibitor 0.1wt%, thickener 0.7wt%, and deionization
Water surplus.
The preferred component (quality accounting) of the base-material part of the polyacrylate coating metal flash paint (III) is：
Polyacrylate dispersion 55wt%, multifunctional assistant 0.1wt%, defoamer 0.3wt%, wetting agent 0.5wt%, coalescents
8wt%, silver powder directing agent 0.6wt%, anti-rheological agent 0.5wt%；The wherein preferred component (quality accounting) of aluminium paste part
For：Aqueous coated silver powder 8wt%, BC solvent 3wt%, dispersant 0.5wt%, and deionized water surplus.
The preferred component (quality accounting) of the polyacrylate coating varnish (IV) is：Polyacrylate dispersion
70wt%, multifunctional assistant 0.4wt%, defoamer 0.5wt%, wetting agent 1.0wt%, levelling agent 0.8wt%, coalescents
15wt%, anti-auxiliary rheological agents 0.6wt%, thickener 0.8wt%, and deionized water surplus.
The preparation method of this preferred embodiment is illustrated as follows.By the above-mentioned proportioning of the polyacrylate coating priming paint (I),
Deionized water is added in dispersion cylinder, other slurry fractions materials are added into container successively under stirring, stirred；
Secondly, rotating speed is adjusted, scattered 15min at a high speed is carried out；Again, it is ground to fineness and reaches 10um and its following；Then, it is put into scattered
In cylinder, then adjust under rotating speed to middling speed state add with paint partial material；The polyacrylic acid is filtered out after finally stirring
Ester paint priming paint (I).
In the formula of the polyacrylate coating finish paint (II) 8% deionized water is put into dispersion cylinder, low speed is stirred
Mix；Secondly, multifunctional assistant in formula, 0.15wt% defoamer are sequentially added, dispersant, wetting agent, is stirred, slowly
Pigment, rheology anti-settling agent are added, at a high speed scattered 19min；Again, polyacrylate dispersion, remaining is added under moderate-speed mixer
0.15wt% defoamers, coalescents, mould inhibitor, thickener, stir 15min；Last test pH value is filtered out described to 8~9
Polyacrylate coating finish paint (II).
According to the corresponding preparation method of the component of the polyacrylate coating metal flash paint (III), including：
(7) aluminium paste part is prepared, wherein further comprising：First, BC solvents are added in dispersion cylinder；Secondly, low speed
Dispersant, deionized water, aqueous cladded type silver powder are sequentially added under stirring, and the immersion 2h that is uniformly dispersed is stand-by；
(8) base-material part is prepared, it further comprises：First, acrylic acid ester emulsion is placed in another dispersion cylinder；Again
It is secondary, multifunctional assistant, defoamer, wetting agent, deionized water, coalescents, silver powder directing agent, anti-stream are added dropwise under moderate-speed mixer
Become agent, and scattered 19min；And
(9) soaked aluminium paste part is added in base-material part, is uniformly dispersed, after measure pH value to 8~9, filtering
Go out the polyacrylate coating metal flash paint (III).
According to the proportioning of the polyacrylate coating varnish (IV), polyacrylate dispersion is placed in dispersion cylinder, in
Multifunctional assistant, wetting agent, defoamer stirring 17min are added dropwise under speed stirring successively；Secondly, detect whether whether there is shrinkage cavity and thin
Whether degree is normal；Again, if normally, coalescents stirring, which is slowly added dropwise, makes full and uniform, recommendation stirring 23min；Finally, plus
Enter anti-rheological agent and thickener, and viscosity is adjusted with deionized water, filter out the polyacrylate coating varnish (IV).
The feasible component of another preferred embodiment of the present invention is disclosed as follows.The polyacrylate coating priming paint (I)
The preferred components (quality accounting) of slurry fractions be：Deionized water 20wt%, multifunctional assistant 0.10wt%, dispersant
0.6wt%, wetting agent 0.3wt%, defoamer 0.4wt%, pigment 17wt%, filler 15wt%, wherein with the preferred of paint part
Component (quality accounting) be：Polyacrylate dispersion 33wt%, coalescents 3wt%, defoamer 0.10wt%, thickener
0.5wt%, deionized water 10wt%.It should be noted that it is last need with multifunctional assistant adjust pH value to 8.0~9.0 it
Between.
The preferred component (quality accounting) of the polyacrylate coating finish paint (II) is：Polyacrylate dispersion
50wt%, multifunctional assistant 0.3wt%, defoamer 0.3wt%, dispersant 1.5wt%, wetting agent 0.5wt%, pigment
30wt%, rheology anti-settling agent 1.0wt%, coalescents 15wt%, mould inhibitor 0.3wt%, thickener 1.0wt%, and go from
Sub- water surplus.
The preferred component (quality accounting) of the base-material part of the polyacrylate coating metal flash paint (III) is：
Polyacrylate dispersion 65wt%, multifunctional assistant 0.3wt%, defoamer 0.5wt%, wetting agent 1.0wt%, coalescents
9wt%, silver powder directing agent 1.2wt%, anti-rheological agent 1.0wt%；The wherein preferred component (quality accounting) of aluminium paste part
For：Aqueous coated silver powder 8wt%, BC solvent 6wt%, dispersant 1.0wt%, and deionized water surplus.
The preferred component (quality accounting) of the polyacrylate coating varnish (IV) is：Polyacrylate dispersion
60wt%, multifunctional assistant 0.4wt%, defoamer 0.5wt%, wetting agent 1.0wt%, levelling agent 0.8wt%, coalescents
15wt%, anti-auxiliary rheological agents 0.6wt%, thickener 0.8wt%, and deionized water surplus.
The preparation method of this preferred embodiment is illustrated as follows.By the above-mentioned proportioning of the polyacrylate coating priming paint (I),
Deionized water is added in dispersion cylinder, other slurry fractions materials are added into container successively under stirring, stirred；
Secondly, rotating speed is adjusted, scattered 25min at a high speed is carried out；Again, it is ground to fineness and reaches 10um and its following；Then, it is put into scattered
In cylinder, then adjust under rotating speed to middling speed state add with paint partial material；The polyacrylic acid is filtered out after finally stirring
Ester paint priming paint (I).
In the formula of the polyacrylate coating finish paint (II) 8% deionized water is put into dispersion cylinder, low speed is stirred
Mix；Secondly, multifunctional assistant in formula, 0.15wt% defoamer are sequentially added, dispersant, wetting agent, is stirred, slowly
Pigment, rheology anti-settling agent are added, at a high speed scattered 18min；Again, polyacrylate dispersion, remaining is added under moderate-speed mixer
0.15wt% defoamers, coalescents, mould inhibitor, thickener, stir 22min；Last test pH value is filtered out described to 8~9
Polyacrylate coating finish paint (II).
According to the corresponding preparation method of the component of the polyacrylate coating metal flash paint (III), including：
(10) aluminium paste part is prepared, wherein further comprising：First, BC solvents are added in dispersion cylinder；Secondly, low speed
Dispersant, deionized water, aqueous cladded type silver powder are sequentially added under stirring, and the immersion 3.5h that is uniformly dispersed is stand-by；
(11) base-material part is prepared, it further comprises：First, acrylic acid ester emulsion is placed in another dispersion cylinder；Again
It is secondary, multifunctional assistant, defoamer, wetting agent, deionized water, coalescents, silver powder directing agent, anti-stream are added dropwise under moderate-speed mixer
Become agent, and scattered 23min；And
(12) soaked aluminium paste part is added in base-material part, is uniformly dispersed, after measure pH value to 8~9, mistake
Filter out the polyacrylate coating metal flash paint (III).
According to the proportioning of the polyacrylate coating varnish (IV), polyacrylate dispersion is placed in dispersion cylinder, in
Multifunctional assistant, wetting agent, defoamer stirring 19min are added dropwise under speed stirring successively；Secondly, detect whether whether there is shrinkage cavity and thin
Whether degree is normal；Again, if normally, coalescents stirring, which is slowly added dropwise, makes full and uniform, recommendation stirring 23min；Finally, plus
Enter anti-rheological agent and thickener, and viscosity is adjusted with deionized water, filter out the polyacrylate coating varnish (IV).
It should be understood by those skilled in the art that the embodiments of the invention shown in foregoing description be only used as citing and not
The limitation present invention.The purpose of the present invention completely and is effectively realized.The function and structural principle of the present invention is in embodiment
Middle displaying and explanation, under without departing from the principle, embodiments of the present invention can have any deformation or modification.
Claims (23)
1. a polyacrylate coating, including：
Polyacrylate coating priming paint (I)；
Polyacrylate coating finish paint (II)；
Polyacrylate coating metal flash paint (III)；And
Polyacrylate coating varnish (IV), wherein the polyacrylate coating priming paint (I), the polyacrylate coating face
(II), the polyacrylate coating metal flash paint (III) are painted, and the polyacrylate coating varnish (IV) is by successively
Ground is applied one or more.
2. polyacrylate coating according to claim 1, wherein the polyacrylate coating priming paint (I) is by many work(
Energy auxiliary agent, dispersant, wetting agent, defoamer, pigment, filler, polyacrylate dispersion, coalescents and thickener pass through poly-
Synthesize the coating of film.
3. polyacrylate coating according to claim 2, wherein the component of the polyacrylate coating priming paint (I) point
Into two parts, a slurry fractions, and one with paint part, wherein slurry fractions include such as the following group by weight/mass percentage composition
Point：10~20wt% of deionized water, 0.10~0.20wt% of multifunctional assistant, 0.6~1.2wt% of dispersant, wetting agent 0.3~
1.0wt%, 0.1~0.5wt% of defoamer, 10~20wt% of pigment, 15~30wt% of filler, wherein the component with paint part is pressed
Weight/mass percentage composition includes following component：33~37wt% of polyacrylate dispersion, 3~5wt% of coalescents, defoamer 0.10
~0.20wt%, 0.5~1.0wt% of thickener, 8~10wt% of deionized water.
4. polyacrylate coating according to claim 1, wherein the polyacrylate coating finish paint (II) is by gathering
Acrylic acid ester emulsion, multifunctional assistant, defoamer, dispersant, wetting agent, pigment, rheology anti-settling agent, coalescents, mould inhibitor
And the coating that thickener passes through polymerization film formation.
5. polyacrylate coating according to claim 4, wherein the polyacrylate coating finish paint (II) presses quality
Percentage composition includes following component：35~55wt% of polyacrylate dispersion, 0.15~0.3wt% of multifunctional assistant, defoamer
0.1~0.3wt%, 0.6~1.5wt% of dispersant, 0.2~0.5wt% of wetting agent, 15~30wt% of pigment, rheology anti-settling agent
0.5~1.0wt%, 8~15wt% of coalescents, 0.1~0.3wt% of mould inhibitor, 0.5~1.0wt% of thickener, remaining is
Water.
6. polyacrylate coating according to claim 1, wherein the polyacrylate coating metal flash paint (III)
It is by polyacrylate dispersion, multifunctional assistant, defoamer, wetting agent, coalescents, silver powder directing agent, anti-rheological agent, aqueous
The coating that coated silver powder, BC solvents and dispersant pass through polymerization film formation.
7. polyacrylate coating according to claim 6, wherein the polyacrylate coating metal flash paint (III)
Component further comprise a base-material part, and an aluminium paste part, wherein base-material part is included as follows by weight/mass percentage composition
Component：55~70wt% of polyacrylate dispersion, 0.1~0.3wt% of multifunctional assistant, 0.3~0.5wt% of defoamer, wetting
0.5~1.0wt% of agent, 8~15wt% of coalescents, 0.6~1.2wt% of silver powder directing agent, anti-0.5~1.0wt% of rheological agent；
Wherein aluminium paste part includes following component by weight/mass percentage composition：8~10wt% of aqueous coated silver powder, BC solvents 3~
6wt%, 0.5~1.0wt% of dispersant, remaining is water.
8. polyacrylate coating according to claim 1, wherein the polyacrylate coating varnish (IV) is by gathering
Acrylic acid ester emulsion, multifunctional assistant, defoamer, wetting agent, levelling agent, coalescents, anti-auxiliary rheological agents and thickener are logical
Cross the coating of polymerization film formation.
9. polyacrylate coating according to claim 8, wherein the polyacrylate coating varnish (IV) presses quality
Percentage composition includes following component：55~70wt% of polyacrylate dispersion, 0.1~0.4wt% of multifunctional assistant, defoamer
0.1~0.5wt%, 0.5~1.0wt% of wetting agent, 0.3~0.8wt% of levelling agent, 8~15wt% of coalescents, anti-rheology are helped
0.3~0.6wt% of agent, 0.4~0.8wt% of thickener, remaining is water.
10. the preparation method of the polyacrylate coating priming paint (I) of a polyacrylate coating, including：
It is divided into two parts by the component of the polyacrylate coating priming paint (I), a slurry fractions, and one matched somebody with somebody paint portion
Point, wherein slurry fractions include following component by weight/mass percentage composition：10~20wt% of deionized water, multifunctional assistant 0.10~
0.20wt%, 0.6~1.2wt% of dispersant, 0.3~1.0wt% of wetting agent, 0.1~0.5wt% of defoamer, pigment 10~
20wt%, 15~30wt% of filler, wherein the component with paint part includes following component by weight/mass percentage composition：Polyacrylate
31~41wt% of emulsion, 3~5wt% of coalescents, 0.11~0.18wt% of defoamer, 0.5~1.0wt% of thickener, go from
Sub- 5~10wt% of water proportioning, deionized water is added in dispersion cylinder, successively by remaining slurry fractions under stirring
Material adds container, stirs；
It is scattered；
It is ground to fineness and reaches 10um and its following；
Rotating speed is adjusted, is added with paint partial material；And
The polyacrylate coating priming paint (I) is filtered out after stirring.
11. the preparation method of the polyacrylate coating finish paint (II) of a polyacrylate coating, including：
Following component will be included by weight/mass percentage composition：35~55wt% of polyacrylate dispersion, multifunctional assistant 0.15~
0.3wt%, 0.1~0.3wt% of defoamer, 0.6~1.5wt% of dispersant, 0.2~0.5wt% of wetting agent, pigment 15~
30wt%, 0.5~1.0wt% of rheology anti-settling agent, 8~15wt% of coalescents, 0.1~0.3wt% of mould inhibitor, thickener 0.5
~1.0wt%, remaining is put into dispersion cylinder for 8% deionized water in the proportioning of water, and is stirred；
Sequentially add the multifunctional assistant in described proportioning, the defoamer of part, dispersant, wetting agent, stir, add
Pigment, rheology anti-settling agent, and disperse；
Regulate the speed stirring, add polyacrylate dispersion, remaining defoamer, coalescents, mould inhibitor, thickener, and stir
Mix；And
Whether test pH value reaches 8~9, and the polyacrylate coating finish paint (II) is filtered out if reaching.
12. the preparation method of the polyacrylate coating metal flash paint (III) of a polyacrylate coating, including：
(1) a base-material part, and a silver powder are further comprised by the component of the polyacrylate coating metal flash paint (III)
Part is starched, wherein base-material part includes following component by weight/mass percentage composition：It is 55~70wt% of polyacrylate dispersion, multi-functional
0.1~0.3wt% of auxiliary agent, 0.3~0.5wt% of defoamer, 0.5~1.0wt% of wetting agent, 8~15wt% of coalescents, silver powder
0.6~1.2wt% of directing agent, anti-0.5~1.0wt% of rheological agent；Wherein aluminium paste part is included as follows by weight/mass percentage composition
Component：8~10wt% of aqueous coated silver powder, 3~6wt% of BC solvents, 0.5~1.0wt% of dispersant, remaining matches somebody with somebody for water
Than aluminium paste part being prepared, wherein further comprising：BC solvents are added in dispersion cylinder；With sequentially add dispersant under stirring,
Deionized water, aqueous cladded type silver powder, and the immersion that is uniformly dispersed is stand-by；
(2) base-material part is prepared, it further comprises：Acrylic acid ester emulsion is placed in another dispersion cylinder；Drip under agitation
Multifunctional assistant, defoamer, wetting agent, deionized water, coalescents, silver powder directing agent, anti-rheological agent are added, and is disperseed；
(3) soaked aluminium paste part is added in base-material part, is uniformly dispersed；And
(4) whether test pH value reaches 8~9, and the polyacrylate coating metal flash paint (III) is filtered out if reaching.
13. the preparation method of the polyacrylate coating metal varnish lacquer (IV) of a polyacrylate coating, including：
Following component will be included by weight/mass percentage composition：55~70wt% of polyacrylate dispersion, multifunctional assistant 0.1~
0.4wt%, 0.1~0.5wt% of defoamer, 0.5~1.0wt% of wetting agent, 0.3~0.8wt% of levelling agent, coalescents 8~
15wt%, anti-0.3~0.6wt% of auxiliary rheological agents, 0.4~0.8wt% of thickener, remaining is newborn for the polyacrylate of the proportioning of water
Liquid is placed in dispersion cylinder, is added dropwise to multifunctional assistant, wetting agent, defoamer under stirring successively；
Detect whether to whether there is shrinkage cavity and whether fineness is normal；
If normal, dropwise addition coalescents stirring makes full and uniform；And
Anti- rheological agent and thickener are added, and viscosity is adjusted with deionized water, the polyacrylate coating varnish is filtered out
(IV)。
14. a polyacrylate coating coating process, is prepared using the component any in claim 3,5,7 or 9,
Including：
Pre-treatment one is applied thing；
In turn coat the polyacrylate coating priming paint (I), the polyacrylate coating finish paint (II), the polypropylene
One or more in acid esters paint metal metallic finishe (III), and the polyacrylate coating varnish (IV)；
Baking；And
Prepare packaging.
15. polyacrylate coating coating process according to claim 14, wherein the polyacrylate coating priming paint
(I) baking condition：At least 60~70 DEG C × 10min.
16. polyacrylate coating coating process according to claim 14, wherein the polyacrylate coating finish paint
(II) baking condition：At least 150 DEG C × 20min.
17. polyacrylate coating coating process according to claim 14, wherein the polyacrylate coating metal
The baking condition of metallic finishe (III)：At least 150 DEG C × 20min.
18. polyacrylate coating coating process according to claim 14, wherein the polyacrylate coating varnish
(IV) baking condition：At least 150 DEG C × 20min.
19. a polyacrylate coating, includes following component by weight/mass percentage composition：40~80wt% of polyacrylate dispersion,
5~15wt% of coalescents, 0.15~0.5wt% of multifunctional assistant, 15~30wt% of pigment, 10~30wt% of filler, auxiliary agent 1
~3wt%, 0.15~0.5wt% of mould inhibitor bactericide, 0.3~0.6wt% of thickener, 0.5~1.0wt% of rheology anti-settling agent,
Remaining is water.
20. polyacrylate coating according to claim 19, wherein component are divided into two parts, a slurry fractions,
With one with paint part, wherein slurry fractions include following component by weight/mass percentage composition：10~20wt% of deionized water, many work(
0.10~0.20wt% of energy auxiliary agent, 0.6~1.2wt% of dispersant, 0.3~1.0wt% of wetting agent, defoamer 0.1~
0.5wt%, 10~20wt% of pigment, 15~30wt% of filler, wherein the component with paint part is included such as by weight/mass percentage composition
Lower component：33~37wt% of polyacrylate dispersion, 3~5wt% of coalescents, 0.10~0.20wt% of defoamer, thickener
0.5~1.0wt%, 8~10wt% of deionized water.
21. polyacrylate coating according to claim 19, wherein including following component by weight/mass percentage composition：Poly- third
35~55wt% of olefin(e) acid ester emulsion, 0.15~0.3wt% of multifunctional assistant, 0.1~0.3wt% of defoamer, dispersant 0.6~
1.5wt%, 0.2~0.5wt% of wetting agent, 15~30wt% of pigment, 0.5~1.0wt% of rheology anti-settling agent, coalescents 8~
15wt%, 0.1~0.3wt% of mould inhibitor, 0.5~1.0wt% of thickener, remaining is water.
22. polyacrylate coating according to claim 19, wherein component further comprise a base-material part, and a silver medal
Slurry part, wherein base-material part include following component by weight/mass percentage composition：55~70wt% of polyacrylate dispersion, many work(
Can 0.1~0.3wt% of auxiliary agent, 0.3~0.5wt% of defoamer, 0.5~1.0wt% of wetting agent, 8~15wt% of coalescents, silver
0.6~1.2wt% of powder directing agent, anti-0.5~1.0wt% of rheological agent；Wherein aluminium paste part is included such as by weight/mass percentage composition
Lower component：8~10wt% of aqueous coated silver powder, 3~6wt% of BC solvents, 0.5~1.0wt% of dispersant, remaining is water.
23. polyacrylate coating according to claim 19, it includes following component by weight/mass percentage composition：Polypropylene
55~70wt% of acid esters emulsion, 0.1~0.4wt% of multifunctional assistant, 0.1~0.5wt% of defoamer, wetting agent 0.5~
1.0wt%, 0.3~0.8wt% of levelling agent, 8~15wt% of coalescents, anti-0.3~0.6wt% of auxiliary rheological agents, thickener 0.4
~0.8wt%, remaining is water.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2017102942504 | 2017-04-28 | ||
| CN201710294250 | 2017-04-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107083136A true CN107083136A (en) | 2017-08-22 |
| CN107083136B CN107083136B (en) | 2020-04-10 |
Family
ID=59607383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710334877.8A Expired - Fee Related CN107083136B (en) | 2017-04-28 | 2017-05-12 | Polyacrylate paint and coating method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107083136B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109971320A (en) * | 2019-03-19 | 2019-07-05 | 惠州市双信达实业有限公司 | A kind of fire resistant water-based alkyd metallic finishe |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101792570A (en) * | 2010-02-10 | 2010-08-04 | 汤汉良 | Hydroxyl-containing crylic acid polyurethane aqueous dispersion body and application |
| CN101812261A (en) * | 2010-02-10 | 2010-08-25 | 商丘市博大化工有限公司 | Ultra-fast dry repair varnish for automobiles and preparation method thereof |
| CN102351982A (en) * | 2011-07-26 | 2012-02-15 | 青岛德鑫汽车涂料有限公司 | Waterborne acrylic resin and metal flashing paint applying same |
| CN103483900A (en) * | 2013-09-26 | 2014-01-01 | 无锡阳工机械制造有限公司 | Metallic paint filling material |
| CN106189746A (en) * | 2016-08-26 | 2016-12-07 | 太仓市美航涂料有限公司 | A kind of refractory metal metallic finishe and preparation method thereof |
| CN106433344A (en) * | 2016-07-20 | 2017-02-22 | 江苏足迹涂料有限公司 | Water-based metal flashing paint and preparation method thereof |
-
2017
- 2017-05-12 CN CN201710334877.8A patent/CN107083136B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101792570A (en) * | 2010-02-10 | 2010-08-04 | 汤汉良 | Hydroxyl-containing crylic acid polyurethane aqueous dispersion body and application |
| CN101812261A (en) * | 2010-02-10 | 2010-08-25 | 商丘市博大化工有限公司 | Ultra-fast dry repair varnish for automobiles and preparation method thereof |
| CN102351982A (en) * | 2011-07-26 | 2012-02-15 | 青岛德鑫汽车涂料有限公司 | Waterborne acrylic resin and metal flashing paint applying same |
| CN103483900A (en) * | 2013-09-26 | 2014-01-01 | 无锡阳工机械制造有限公司 | Metallic paint filling material |
| CN106433344A (en) * | 2016-07-20 | 2017-02-22 | 江苏足迹涂料有限公司 | Water-based metal flashing paint and preparation method thereof |
| CN106189746A (en) * | 2016-08-26 | 2016-12-07 | 太仓市美航涂料有限公司 | A kind of refractory metal metallic finishe and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109971320A (en) * | 2019-03-19 | 2019-07-05 | 惠州市双信达实业有限公司 | A kind of fire resistant water-based alkyd metallic finishe |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107083136B (en) | 2020-04-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107151493A (en) | Aqueous PVDF fluorocarbon coatings and its coating process | |
| CA1261523A (en) | Washout resistant coatings | |
| CN102146243B (en) | Waterborne single-component thermoplastic plastic paint and production method and construction method thereof | |
| CN102746601B (en) | Water whitening resistance copolymer dispersion for coating material | |
| DE602006000877T2 (en) | emulsion composition | |
| US5219914A (en) | Cospray washout resistant roof mastic | |
| CN106433324A (en) | Non-resin water base colorant and preparation thereof | |
| CN107446093B (en) | Nano-silicon nitride modified epoxy acrylic ester lotion, water-based anticorrosive paint and preparation method | |
| CN107001844A (en) | Water-based paint compositions and its obtained method | |
| US4274884A (en) | Method of removing wallpaper | |
| CN107141912A (en) | Silver powder dipping lacquer of aqueous quick-drying anti-corrosion stable storing and preparation method thereof | |
| CN102181211A (en) | One-component waterborne thermoplastic coating matched with UV-radiation curing coating as well as production method and construction method thereof | |
| JP2006523265A (en) | VOC-free latex coalescent | |
| CN108359354A (en) | A kind of mechanical equipment anti-corrosion sealing wax and preparation method thereof | |
| CN106752498A (en) | A kind of multifunctional aqueous paint and preparation method thereof | |
| CN106634290A (en) | Formaldehyde-free environment-friendly wall paint and preparation technology thereof | |
| CN105801739B (en) | A kind of styrene-acrylic emulsion and the high PVC interiro wall latex paint of resistance to scrub prepared therefrom | |
| CN107083136A (en) | Polyacrylate coating and its coating process | |
| DE2337606C3 (en) | Corrosion inhibiting aqueous paint | |
| CN112812634A (en) | Water-based vacuum cup baking paint and preparation method thereof | |
| CN106433345A (en) | Waterborne acrylic middle coating and preparation method thereof | |
| JPS59105064A (en) | Thermosetting metallic paint | |
| US3264238A (en) | Coating compositions comprising latex paint, hydrocarbon and plastic-surfaced particles | |
| CN110218492A (en) | Aqueous woodware paint | |
| CN108641579A (en) | Environment-friendly aqueous paint of one kind and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20200410 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |