CN109971320A - A kind of fire resistant water-based alkyd metallic finishe - Google Patents
A kind of fire resistant water-based alkyd metallic finishe Download PDFInfo
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- CN109971320A CN109971320A CN201910207894.4A CN201910207894A CN109971320A CN 109971320 A CN109971320 A CN 109971320A CN 201910207894 A CN201910207894 A CN 201910207894A CN 109971320 A CN109971320 A CN 109971320A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention discloses a kind of fire resistant water-based alkyd metallic finishe, including base coat and finishing coat.Ingredient in base coat, finishing coat only has minute quantity volatile organic matter, environmentally friendly;The solidification cross-linking system that base coat, finishing coat are all made of water-based hydroxyl acrylic acid modified saturated polyester resin and coalescing agent is formed, rapid curing forms a film under high temperature environment, forms fine and close paint film layer;Iron oxide red, iron oxide yellow are dispersed in the paint layer of base coat formation in base coat, are increased fast light, the high temperature resistance of base coat, are formed heat-resisting paint layer heat-resisting, that glossiness is low on the surface of the workpiece;Pearl powder, silver powder directing agent are dispersed in finishing coat, the surface cure that finishing coat is sprayed on heat-resisting paint layer forms effect paint film layer, has special metallic travel;After base coat, finishing coat are fully cured, two layers of paint film layer that is fine and close and engaging is formed, there is good high temperature resistant, wear-resisting property.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of fire resistant water-based alkyd applied to metal spraying protection
Metallic finishe.
Background technique
Metallic paint also known as metallic finishe refer to and the air-curing coatings of fine metal particle are added in Qi Jizhong, are formed
Paint film by light after being irradiated, and the fine metal particle in paint film reflects light through paint film hole, thus in appearance
The visual effect of flash metal luster is presented.Existing metallic paint majority is the coating of organic solvent type, the row of VOC in paint application
It is high-volume high, it is larger to the injury of environment and human body, with the increase of ecological requirements, is also gradually appeared in coating industry and be with water
The aqueous metallic paint of solvent, it may have good application effect, but the paint film that is formed of aqueous metallic paint easy quilt under high temperature environment
It destroys, when at the workpiece applied after spraying under high temperature environment, paint film layer is easily peeled off, and shows the paint film that aqueous metallic paint is formed
Layer performance is not sufficiently stable, and structure needs a kind of metallic paint with high temperature resistance vulnerable to heat damage.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of fire resistant water-based alkyd metallic finishe.
The technical scheme adopted by the invention to achieve the purpose is as follows:
A kind of fire resistant water-based alkyd metallic finishe, comprising:
Base coat, it includes the components of following parts by weight: 42~45 parts of water-based acrylic resin, hexamethoxy methyl trimerization
6 parts of melamine resin, 2.5 parts of iron oxide red, 3.5 parts of iron oxide yellow, 2~4 parts of dimethylethanolamine, aqueous wetting agent 0.3~0.5
Part, 0.5 part of aqueous dispersion, 0.1~0.3 part of aqueous defoamer, 0.3~0.5 part of aqueous levelling agent, 3~4 parts of coalescing agent,
10~20 parts of deionized water;
Finishing coat, it includes the components of following parts by weight: 45~50 parts of water-based acrylic resin, hexamethoxy methyl melamine
5.5 parts of polyimide resin, 3~5 parts of pearl powder, 2~4 parts of dimethylethanolamine, 0.3~0.5 part of aqueous wetting agent, aqueous dispersion
It 0.5 part, 0.1~0.3 part of aqueous defoamer, 0.5~1 part of aqueous levelling agent, 3~4 parts of coalescing agent, 1 part of silver powder directing agent, goes
10~20 parts of ionized water;
Wherein, water-based acrylic resin is water-based hydroxyl acrylic acid modified saturated polyester resin, using Guangzhou south resin
One of WA-320, WA-350 or WA-370 water-and acrylate of Co., Ltd;The aqueous wetting agent, which is selected from, wins wound moral
One or more of Gu Sai Co., Ltd TEGO-245, TEGO-260, TEGO-270;The aqueous dispersion is using wide
The K-355 of Zhou Keming Chemical Industry Science Co., Ltd;The aqueous defoamer be selected from Yingchuang Degussa Co., Ltd TEGO-825,
The one or two of TEGO-845;The aqueous levelling agent uses the TEGO-410 of Yingchuang Degussa Co., Ltd;The film forming
Auxiliary agent is selected from one or more of Lauryl Alcohol ester, propylene glycol monomethyl ether, propandiol butyl ether;The silver powder directing agent uses
SP-7006 silver powder directing agent.
Further illustrate, the preparation method of the base coat the following steps are included: first by water-based acrylic resin, go
Ionized water, suitable dimethylethanolamine are uniformly mixed, and under 600~700 revs/min of speed, are successively slowly added to aqueous disappear
Infusion, aqueous wetting agent and aqueous dispersion are dispersed with stirring 5~10 minutes, are added and are matched toner, at 1500~2000 revs/min
Speed under high speed dispersion 40~50 minutes, revolving speed is transferred to 600~700 revs/min, puts into hexamethoxymethyl melamine
Resin disperses that aqueous levelling agent is added after ten minutes, redisperse 8~10 minutes.
It further illustrates, the preparation method of the finishing coat is the following steps are included: first by water-based acrylic resin, part
Deionized water, suitable dimethylethanolamine are uniformly mixed, under 600~700 revs/min of speed, are successively slowly added to defoam
Agent, wetting agent and dispersing agent are dispersed with stirring 5~10 minutes, add pearl powder, keep 600~700 revs/min of speed point
40~50 points are dissipated, continuously adds HMMM resin, aqueous levelling agent is added in dispersion after ten minutes, then divides
It dissipates 8~10 minutes.
Further illustrate, the application method of the fire resistant water-based alkyd metallic finishe the following steps are included:
A, by after workpiece clean surface to be sprayed, first jet background paint is placed in flash dryer, in 85~90 DEG C of rings
It is flashed 10 minutes under border;
B, the workpiece after a step process is taken out, finishing coat is sprayed on its surface after cooling, is placed in flash dryer
In, it is flashed under 85~90 DEG C of environment after ten minutes, is warming up to 150~155 DEG C and toasts 25 minutes, taking-up is cooled to room temperature i.e.
It can.
Compared with prior art, the beneficial effects of the present invention are:
Ingredient in base coat, finishing coat only has minute quantity volatile organic matter, environmentally friendly;Base coat, finishing coat are adopted
The solidification cross-linking system formed with water-based hydroxyl acrylic acid modified saturated polyester resin and coalescing agent, under high temperature environment quickly
Film-forming forms fine and close paint film layer;Iron oxide red, iron oxide yellow are dispersed in the paint layer of base coat formation in base coat,
Fast light, the high temperature resistance for increasing base coat form heat-resisting paint layer heat-resisting, that glossiness is low on the surface of the workpiece;In finishing coat
It is dispersed with pearl powder, silver powder directing agent, the surface cure that finishing coat is sprayed on heat-resisting paint layer forms effect paint film layer, and it is special to have
Metallic travel;First the flash process through 85~90 DEG C is not fully cured in workpiece surface for base coat, and finishing coat is sprayed on workpiece
Not fully cured through 85~90 DEG C of flash process after upper, workpiece finally toasts under 150~155 DEG C of flash process, makes bottom
Colored paint, finishing coat are fully cured, and form two layers of paint film layer that is fine and close and engaging, have good high temperature resistant, wear-resisting property.
Specific embodiment
In order to further understand the content, features and effects of the present invention, hereby enumerating following embodiment explanation.
Gained sample carries out heat resistance and wear-resisting property test in embodiment, is tested by following experimental method:
A, ROHS is tested: being tested with XRF test, European Union's ROHS standard method of test, test result is lower than nuisance
Matter content standard is qualification.
B, it adhesive force test (3M glue): is tested with the detection method of GB1720 standard.
C, boiling is tested: it is tested using thermostat water bath, thermostat water bath is warming up to 100 DEG C of holding constant temperature, it will
Sample is put into impregnate 30min in a water bath after take out, clean water stain, after room temperature 2 hours, the appearance of sample survey paint film has
Without significant change, the bad phenomenons such as paint film is non-discolouring, falls off, cracks, blistering are qualification.
D, high-temp resisting high-humidity resisting test: tested using high and low temperature alternating humidity test chamber, by sample be placed on 70 ± 2 DEG C,
Taken out after 72 hours in 90%RH chamber, observation paint film appearance whether there is or not obvious discoloration, no blistering, crack, fall off etc. it is bad existing
As without then qualified.
E, low temperature environment is tested: being tested using high and low temperature alternating humidity test chamber, sample is placed on -30 ± 2 DEG C of examinations
It is taken out after 72 hours in tryoff, observation paint film appearance is whether there is or not obvious discoloration, and no blistering, the bad phenomenons such as crack, fall off, without then
It is qualified.
F, hot environment is tested: being tested using high and low temperature alternating humidity test chamber, sample is placed on 70 DEG C of ± 2 DEG C of examinations
It is taken out after 24 hours in tryoff, observation paint film appearance is whether there is or not obvious discoloration, and no blistering, the bad phenomenons such as crack, fall off, without then closing
Lattice.
Embodiment 1
The base coat contains the following parts by weight: WA-350 water-based acrylic resin 43g, hexamethoxy methyl three
Cymel 6g, iron oxide red 2.5g, iron oxide yellow 3.5g, dimethylethanolamine 3g, TEGO-245 wetting agent 0.2g,
TEGO-260 wetting agent 0.2g, K-355 dispersing agent 0.5g, TEGO-825 defoaming agent 0.2g, TEGO-410 levelling agent 0.4g, ten
Two carbon alcohol ester 4g, deionized water 15.6g;
The finishing coat contains the following parts by weight: WA-350 water-based acrylic resin 44g, hexamethoxy methyl trimerization
Melamine resin 5.5g, pearl powder 5g, 2~4 parts of dimethylethanolamine, TEGO-245 wetting agent 0.2g, TEGO-260 wetting agent
0.2g, K-355 dispersing agent 0.5g, TEGO-825 defoaming agent 0.2g, TEGO-410 levelling agent 0.7g, Lauryl Alcohol ester 4g, silver powder
Directing agent 1g, deionized water 16.4g.
After several test board clean surfaces, base coat is first sprayed, is placed in flash dryer, under 90 DEG C of environment
Flash distillation 10 minutes;Several test boards are taken out, finishing coat is sprayed on its surface after cooling, is placed in flash dryer,
It is flashed under 90 DEG C of environment after ten minutes, is warming up to 150 DEG C and toasts 25 minutes, taking-up is cooled to room temperature.
Performance test is made to the paint film layer formed on several test boards, test result is as follows table:
Detection project | Test result | Determine |
ROHS test | Meet | It is qualified |
Adhesive force tests (3M glue) | 5B | It is qualified |
Boiling test | It is without exception | It is qualified |
High-temp resisting high-humidity resisting test | It is without exception | It is qualified |
Low temperature environment test | It is without exception | It is qualified |
Hot environment test | It is without exception | It is qualified |
Embodiment 2
The base coat contains the following parts by weight: WA-370 water-based acrylic resin 45g, hexamethoxy methyl three
Cymel 6g, iron oxide red 2.5g, iron oxide yellow 3.5g, dimethylethanolamine 3g, TEGO-260 wetting agent 0.4g, K-
355 dispersing agent 0.5g, TEGO-845 defoaming agent 0.2g, TEGO-410 levelling agent 0.4g, Lauryl Alcohol ester 4g, deionized water
13.5g;
The finishing coat contains the following parts by weight: WA-370 water-based acrylic resin 44g, hexamethoxy methyl trimerization
Melamine resin 5.5g, pearl powder 5g, 2~4 parts of dimethylethanolamine, TEGO-260 wetting agent 0.4g, K-355 dispersing agent 0.5g,
TEGO-845 defoaming agent 0.2g, TEGO-410 levelling agent 0.7g, Lauryl Alcohol ester 4g, silver powder directing agent 1g, deionized water
16.5g。
After several test board clean surfaces, base coat is first sprayed, is placed in flash dryer, under 90 DEG C of environment
Flash distillation 10 minutes;Several test boards are taken out, finishing coat is sprayed on its surface after cooling, is placed in flash dryer,
It is flashed under 90 DEG C of environment after ten minutes, is warming up to 150 DEG C and toasts 25 minutes.
Performance test is made to the paint film layer formed on several test boards, test result is as follows table:
Detection project | Test result | Determine |
ROHS test | Meet | It is qualified |
Adhesive force tests (3M glue) | 5B | It is qualified |
Boiling test | It is without exception | It is qualified |
High-temp resisting high-humidity resisting test | It is without exception | It is qualified |
Low temperature environment test | It is without exception | It is qualified |
Hot environment test | It is without exception | It is qualified |
Embodiment 3
The base coat contains the following parts by weight: WA-370 water-based acrylic resin 47g, hexamethoxy methyl three
Cymel 6g, iron oxide red 2.5g, iron oxide yellow 3.5g, dimethylethanolamine 3g, TEGO-260 wetting agent 0.2g,
TEGO-270 wetting agent 0.2g, K-355 dispersing agent 0.5g, TEGO-845 defoaming agent 0.2g, TEGO-410 levelling agent 0.4g, third
Glycol butyl ether 4g, deionized water 16.6g;
The finishing coat contains the following parts by weight: WA-370 water-based acrylic resin 44g, hexamethoxy methyl trimerization
Melamine resin 5.5g, pearl powder 5g, 2~4 parts of dimethylethanolamine, TEGO-260 wetting agent 0.2g, TEGO-270 wetting agent
0.2g, K-355 dispersing agent 0.5g, TEGO-845 defoaming agent 0.2g, TEGO-410 levelling agent 0.7g, propandiol butyl ether 4g, silver powder
Directing agent 1g, deionized water 17.4g.
After several test board clean surfaces, base coat is first sprayed, is placed in flash dryer, under 90 DEG C of environment
Flash distillation 10 minutes;Several test boards are taken out, finishing coat is sprayed on its surface after cooling, is placed in flash dryer,
It is flashed under 90 DEG C of environment after ten minutes, is warming up to 150 DEG C and toasts 25 minutes.
Performance test is made to the paint film layer formed on several test boards, test result is as follows table:
The above is only the preferred embodiments of the present invention, and is not intended to limit the present invention in any form,
Any simple modification made to the above embodiment according to the technical essence of the invention, equivalent variations and modification, belong to
The range of technical solution of the present invention.
Claims (4)
1. a kind of fire resistant water-based alkyd metallic finishe characterized by comprising
Base coat, it includes the components of following parts by weight: 42~45 parts of water-based acrylic resin, hexamethoxymethyl melamine
6 parts of resin, 2.5 parts of iron oxide red, 3.5 parts of iron oxide yellow, 2~4 parts of dimethylethanolamine, 0.3~0.5 part of aqueous wetting agent,
0.5 part of aqueous dispersion, 0.1~0.3 part of aqueous defoamer, 0.3~0.5 part of aqueous levelling agent, 3~4 parts of coalescing agent, go from
10~20 parts of sub- water;
Finishing coat, it includes the components of following parts by weight: 45~50 parts of water-based acrylic resin, hexamethoxymethyl melamine tree
5.5 parts of rouge, 3~5 parts of pearl powder, 2~4 parts of dimethylethanolamine, 0.3~0.5 part of aqueous wetting agent, 0.5 part of aqueous dispersion,
0.1~0.3 part of aqueous defoamer, 0.5~1 part of aqueous levelling agent, 3~4 parts of coalescing agent, 1 part of silver powder directing agent, deionized water
10~20 parts;
Wherein, water-based acrylic resin is water-based hydroxyl acrylic acid modified saturated polyester resin.
2. a kind of fire resistant water-based alkyd metallic finishe according to claim 1, which is characterized in that the preparation of the base coat
The following steps are included: first by water-based acrylic resin, deionized water, suitable dimethylethanolamine is uniformly mixed method, 600~
Under 700 revs/min of speed, it is successively slowly added to aqueous defoamer, aqueous wetting agent and aqueous dispersion, it is dispersed with stirring 5~
It 10 minutes, is added and matches toner, revolving speed is transferred to 600 by high speed dispersion 40~50 minutes under 1500~2000 revs/min of speed
~700 revs/min, HMMM resin is put into, aqueous levelling agent, redisperse 8 is added in dispersion after ten minutes
~10 minutes.
3. a kind of fire resistant water-based alkyd metallic finishe according to claim 1, which is characterized in that the preparation side of the finishing coat
Method is the following steps are included: first by water-based acrylic resin, and portions of de-ionized water, suitable dimethylethanolamine is uniformly mixed, and 600
Under~700 revs/min of speed, it is successively slowly added to defoaming agent, wetting agent and dispersing agent, is dispersed with stirring 5~10 minutes, then plus
Enter pearl powder, keeps 40~50 points of Rate Dispersion of 600~700 revs/min, continuously add hexamethoxymethyl melamine tree
Rouge disperses that aqueous levelling agent is added after ten minutes, redisperse 8~10 minutes.
4. a kind of fire resistant water-based alkyd metallic finishe according to claim 1, which is characterized in that the fire resistant water-based alcohol
The application method of sour metallic finishe the following steps are included:
A, by after workpiece clean surface to be sprayed, first jet background paint is placed in flash dryer, under 85~90 DEG C of environment
Flash distillation 10 minutes;
B, the workpiece after a step process is taken out, finishing coat is sprayed on its surface after cooling, is placed in flash dryer,
It is flashed under 85~90 DEG C of environment after ten minutes, is warming up to 150~155 DEG C and toasts 25 minutes, taking-up is cooled to room temperature.
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CN109456651A (en) * | 2018-10-17 | 2019-03-12 | 广东伊思曼新材料科技股份有限公司 | A kind of multifunctional aqueous enamel paint and preparation method thereof |
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US20080003368A1 (en) * | 2003-05-19 | 2008-01-03 | Basf Corporation | Particulate coatings having improved chip resistance, uv durability, and color stability |
CN102010648A (en) * | 2010-11-29 | 2011-04-13 | 常州市武进晨光金属涂料有限公司 | Floating coat-free shining base coat used for metal pieces and preparation method thereof |
US20160152862A1 (en) * | 2013-07-17 | 2016-06-02 | Basf Coatings Gmbh | Aqueous dispersion of a copolymer |
CN106189746A (en) * | 2016-08-26 | 2016-12-07 | 太仓市美航涂料有限公司 | A kind of refractory metal metallic finishe and preparation method thereof |
CN107083136A (en) * | 2017-04-28 | 2017-08-22 | 叶镜枝 | Polyacrylate coating and its coating process |
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