CN107082687A - A kind of nano-sized carbon is Se-enriched or mixture fertilizer - Google Patents
A kind of nano-sized carbon is Se-enriched or mixture fertilizer Download PDFInfo
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- CN107082687A CN107082687A CN201710291626.6A CN201710291626A CN107082687A CN 107082687 A CN107082687 A CN 107082687A CN 201710291626 A CN201710291626 A CN 201710291626A CN 107082687 A CN107082687 A CN 107082687A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
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Abstract
A kind of nano-sized carbon is Se-enriched or mixture fertilizer.The multiple materials such as application material nano-sized carbon and low price containing selenium salt and carbonate nitrogenous fertilizer of the present invention are constituted.To improve the salt quantity of low price containing selenium that crop absorbs from soil, it have selected unrighted acid and do associated agent.Ammonia stabilizer with the addition of to the uptake of nitrogenous fertilizer to improve crop.The quality control of nano-sized carbon is benefit below 100 nanometers, and it has small-size effect, high surface area effect and tunnel-effect.Nano-sized carbon has conductive and magnetizing function in water, and its conductance can increase by 30% ~ 50%, the ion of the salt of low price containing selenium can be promoted to ionize, and can promote the activation of the salt ion of low price containing selenium in soil, absorb and convert, be absorbed and produced rich in Organic Selenium food by plant roots.Paddy rice selenium-rich amount is increased by 3.5 times, wheat selenium-rich amount is increased by 52 times, soybean selenium-rich amount is increased by 37 times, corn selenium-rich amount is increased by 134 times.
Description
Technical field
The invention belongs to fertilizer field, and in particular to a kind of nano-sized carbon is Se-enriched or mixture fertilizer.
Background technology
The World Health Organization（WHU）Announce already, according to the report of domestic and international trace elements of selenium cancer-resisting, selenium element anticancer
Beyond the question.Such as Chinese Se-rich lucid ganoderma treasured is in addition to the selenium enriching functions that edible fungi has 10~1000 times in itself, in culture
External source selenium is sprayed during ganoderma extract, sprinkling external source selenium has certain selenium-rich function, from food security, food security and dietotherapy health
For main direction, known achievement has been achieved.
The Research approach of this project is the administration by nano-sized carbon selenium fertilizer, produces the grain of people's daily consumption, vegetables
And fruit, the enzyme of root, stem, leaf and the fruit food synthesis selenoprotein, amino acid selenium and selenium-rich of plant is passed to, into people
In animal body, the content of blood selenium in human body can be improved.By selenoprotein, the targeting of amino acid selenium, to suppress human body
The growth of interior cancer cell and make its apoptosis；The generation of mankind's cardiovascular and cerebrovascular wall blood fat is reduced, so as to play the effect prevented and cured diseases.
Selenium is a kind of trace element, is selenium-rich soil when the Se content in soil is enriched to more than 0.4 mg/kg
Earth, can be widely applied to the production of Se-rich farm products, but content of the selenium in the earth's crust is quite rare and scattered, and average value only has
0.05~0.07 mg/kg, therefore, selenium-rich soil stock number are very rare.Because selenium has powerful Human biology work(
Can, such as removing toxic substances, cancer-resisting, protect angiocarpy and cardiac muscle health, but human body to realize it is more direct, safer, more longlasting, more
Efficiently selenium-supply, it is optimal path to eat the agricultural product such as selenium-rich rice, oil plant, fruits and vegetables and poultry, therefore, selenium-enriched food also just into
If the thirsty gourmet food that people ask, market price is the several times of common agricultural.With the development and progress of mankind's science and technology,
People have new be appreciated and understood by " selenium "：Trace element of the body weight less than several a ten thousandths is accounted for, but with the existence of people
It is closely bound up with health.
By the continuous renewal and improvement of the nano-sized carbon organic selenium fertilizer production technology of 5 years, successfully produce finally organic
Selenium-enriched food, finishing China does not have the history of selenium fertilizer.In order to improve the absorption features of nano-sized carbon selenium-enriched fertilizer, selenium fertilizer has been used
Accompany agent-unrighted acid.Agent can carry root, stem, leaf that selenate radical smoothly enters plant to selenium fertilizer together, and largely
In the fruit for accumulating crop, make the field crops such as corn and soybean, paddy rice, wheat, sunflower；Xi Hong Fei, cucumber, cauliflower, west
16 kinds of vegetable crops such as orchid, ternip, carrot, Chinese cabbage, Kidney bean angle, crystal dish are smoothly enriched with selenium element, improve selenium-rich times
Number reaches 3.5~130 times, realizes the expected purpose of cereal crops and vegetable crop selenium-rich.
The content of the invention
Goal of the invention：It is an object of the invention to provide a kind of Se-enriched or mixture fertilizer containing nano-sized carbon, improve
The absorption features of selenium-enriched fertilizer, realize the purpose of cereal crops and vegetable crop selenium-rich.
Technical scheme：
A kind of nano-sized carbon is Se-enriched or mixture fertilizer, it is characterised in that：In the fertilizer containing nano-sized carbon, the salt of low price containing selenium,
The associated agent of carbonate nitrogenous fertilizer, the salt of low price containing selenium and ammonia stabilizer；
The nanometer carbon content is the 0.02%~2% of gross weight；Nano-sized carbon yardstick is 5 ~ 200 nanometers；
The salt content of low price containing selenium is the 0.05% ~ 5% of gross weight；
Agent content is the 0.1% ~ 1.5% of gross weight to the salt of low price containing selenium together；Agent is unsaturated lipid to the selenium low price salt together
Fat acid；
The ammonia stabiliser content is the 0.1% ~ 5% of gross weight.
Nano-sized carbon described in above-mentioned technical proposal is Se-enriched or mixture fertilizer, it is characterised in that：It is described to contain selenium at a low price
Salt is that sodium selenite or selenic acid are received.
Nano-sized carbon described in above-mentioned technical proposal is Se-enriched or mixture fertilizer, it is characterised in that：The selenium low price salt
Agent is to contain oleic acid C together18H34O2, linoleic acid C18H32O2Or leukotrienes C18H30O2Oils.
Nano-sized carbon described in above-mentioned technical proposal is Se-enriched or mixture fertilizer, it is characterised in that：The selenium low price salt
Agent is soybean oil, sunflower, sesame oil, peanut oil, cottonseed oil or corn oil together.
Nano-sized carbon described in above-mentioned technical proposal is Se-enriched or mixture fertilizer, it is characterised in that：The ammonia stabilizer
For the downstream product DCD of calcium carbide, its chemical formula is N4H4C2。
Nano-sized carbon described in above-mentioned technical proposal is Se-enriched or mixture fertilizer, it is characterised in that：The carbonate nitrogen
Fertilizer includes one or more mixing in ammonium hydrogen carbonate, potassium carbonate or urea.
Nano-sized carbon described in above-mentioned technical proposal is Se-enriched or mixture fertilizer, it is characterised in that：The nano-sized carbon is
The spherical nano-sized carbon produced using electroporation, its diameter is less than 100 nanometers.
Advantage and effect：The present invention in order to improve the absorption features of nano-sized carbon selenium-enriched fertilizer, used selenium fertilizer together agent-
Unrighted acid.Agent can carry root, stem, leaf that selenate radical smoothly enters plant to selenium fertilizer together, and largely work is arrived in accumulation
In the fruit of thing, make the field crops such as corn and soybean, paddy rice, wheat, sunflower；It is Xi Hong Fei, cucumber, cauliflower, broccoli, white
16 kinds of vegetable crops such as radish, carrot, Chinese cabbage, Kidney bean angle, crystal dish are smoothly enriched with selenium element, improve selenium-rich multiple and reach
3.5~130 times, realize the expected purpose of cereal crops and vegetable crop selenium-rich.
Embodiment：
1. the form and biological effectiveness of selenium in plant
Selenium is main in natural plants exists with selenate and Organic Selenium.The existing forms of selenium in poly- selenium plant and non-poly- selenium plant
It is different.In poly- selenium plant, selenium exists in the form of various soluble seleno-amino acids, such as selenium methylselenocysteine.Rather than
In poly- selenium plant, Organic Selenium mainly exists with the form of protein, and water soluble selenium accounts for 20%~25%, rye in such as barley grain
Water soluble selenium can reach 30%~60% in seed.The albumin of selenium-rich corn, globulin and alcohol soluble protein result of study are shown,
Selenium is primarily present in globulin.This is to the regional grain of vast low selenium and the selenium-rich quantity research of feed, and improves the meals of resident
Selenium level is most important to preventing and treating Keshan disease and Kaschin-Beck disease.
Research shows that the bioavailability of selenium is generally higher than animal product in plant product.Wheat in field crop
Biological effectiveness with selenium in corn is higher, and soybean is relatively low.They are respectively equivalent to wait selenium dosage sodium selenite
71%th, 86% and 60%.In selenium-rich product, bean product are the good sources of selenium；And in the mushroom of selenium-rich selenium biological effectiveness compared with
It is low, just correspond to wait the 5~15%. of selenium dosage selenate effect in poly- selenium plant because water-soluble selenium-containing compound content is high,
But it can not directly participate in the protein synthesis in animal body, often be metabolised to excrete for inorganic selenium.So right
Crop sprays a large amount of inorganic seleniums and can not utilized by animal, and strengthens the protein Organic Selenium morphological research of non-poly- selenium plant
There is prior meaning.
2. selenium is to the effect study of plant growth
Research Selenium in Plants is intended merely to the need for meeting humans and animals health in decades, and whether crop must be supplied in itself
Selemium nutrition, the scholar of concern is considerably less.And develop during a small amount of arable farming, using a small amount of selenium to crop growth
Raising with quality of agricultural product has facilitation.For example, can be improved to soil application selenium fertilizer in the Kaschin-Beck Disease Regions in Shaanxi Province
The yield of millet.In northeast, the Kaschin-Beck Disease Regions of Keshan disease carry out the work spray selenium experiment of the crop such as corn and soybean and wheat, obtain
Certain effect of increasing production.In Qinhuangdao Xi Fei study bases, the result of the test of several years shows, the yield that selenium fertilizer can improve soybean exists
20% or so.After spraying selenium to wheat in Area of Keshan Disease, several amino acids changes of contents is larger in measure wheat seed, especially Guang
The content increase of propylhomoserin.Soybean is applied after selenium fertilizer, determined amino acid result shown, the change of amino acid is also larger, wherein group
Propylhomoserin, methionine, phenylalanine content are reduced, and the increase of the content of glycine and isopropyl propylhomoserin, valine etc..
Observed in potted plant experiment when selenium consumption is in 2.5 μ gg-1When following, dry-matter yield of plants with selenium consumption increasing
Plus and increase.It is, in general, that selenium is in the μ gg of low concentration 0.001~0.05-1When, there is stimulating effect to the growth of crop；And selenium concentration
There is inhibitory action to plant growth when too high.For example, when Xi Hong Fei Hydroponic Solutions selenium content is 0.05 μ gg-1When following, it can promote
Xi Hong Fei growth of seedling, and when selenium concentration is more than 0.50 μ gg-1When, inhibitory action can be produced to Xi Hong Fei growths.
3. selenium and health
Selenium is a kind of important biological element in environment, is also a kind of element for acting on complexity, it plays double action to biology,
Se content is too high to produce murder by poisoning to plant, animals and humans, and appropriate selenium then to plant grow play it is important
Facilitation, certain density selenium is then to maintain the health of animals and humans necessary.The scientific research of China and endemic disease
Findings of the survey show, it is known to 22 provinces, the partially or mostly regional selenium deficiency of municipality directly under the Central Government, are distributed population about 2.5 hundred million people.
In decades, the Chinese Academy of Sciences, the Ministry of Public Health, Environmental Protection Agency and Ministry of Geology etc. organize many experts carry out national endemic disease generaI investigation and
Study on prevention, diseases prevention research is carried out for serious selenium deficiency area by augmenting selenium element approach；Or general selenium deficiency area is by applying
The research for increasing humans and animals health with selenium fertilizer has been achieved with certain progress.
Found by the research for many years of countries in the world endemic disease expert, selenium is battalion necessary to a variety of enzymes in mammal
Support element.Being currently known the human diseases relevant with selenium deficiency has：Keshan disease, hypertension, coronary heart disease, dilated cardiomyopathy, stomach cancer,
Tens kinds of colon cancer, liver cancer, cancer of pancreas, hemolytic anemia etc..There are more than 40 kind animals to suffer from more than 20 in the world at present and plant different type
Selenium deficiency disease, it is largely effective to the preventing and treating of its disease after Selenium Supplement.
4. selenium and medical diagnosis on disease
Selenium is the required part of glutathione peroxidase, and the enzyme can make peroxide be reduced into harmless hydroxy compound
Thing, effectively in the 26S Proteasome Structure and Function of protection cell membrane.Selenium can stimulate the generation of immune globulin bletilla antibody, increase the disease-resistant of body
Ability.
Epidemiological study shows that selenium is reduced in cancer patient's serum, especially gi system tumour.Liver cirrhosis patient
Liver blood selenium storage capacity declines, and absorbs by obstacle, causes liver plasma membrane lipid peroxidation injury, cause necrosis of liver cells.
Medical research shows that selenium can increase DNA repair functions, strengthens body immune function.Selenium to cellular gene expression, turn
Record, energetic supersession and membrane structure all have an impact, and can reverse propagation, differentiation and the pernicious performance of tumour cell.So selenium is carried
High body immune function, prevent cell aberration, anti-cancer, press down cancer effect.Research finds that acute leukemic patient is more complete than Healthy People
Blood Se concentration is low by 22%, and glutathione peroxidase activity is low by 20%.Selenium can be with the harmful element knot such as cadmium, lead, aluminium
Synthesis is difficult to the compound dissociated, eliminates their toxin, slows down mankind aging's process.
5. selenium-enriched plant and dietotherapy
Research shows that selenium-enriched plant can synthesize the amino acid containing selenium in vivo, and this amino acid containing selenium is to health and controls
Treat very effective.Selenium is nutrient necessary to selenium deficiency soil plant growth, such as：Corn, paddy rice, soybean, sunflower, dish
Beans, cucumber and tomato etc., have certain effect of increasing production using nano-sized carbon selenium fertilizer.In the area of selenium deficiency, selenium is normally applied to plant
Fertilizer, can both promote the growth of crop, can also cure the illness of human and animal's selenium deficiency.
We have carried out the field experiment of selenium-enriched plant.Its selenium-rich effect, grain are determined by applying selenium fertilizer to 17 kinds of crops
The selenium-rich effect such as food crop, vegetables, oil plant is all apparent.Test result indicates that, crops are to applying selenium fertilizer and not applying selenium fertilizer
Soil absorption selenium amount is widely different, and the selenium of higher amount, the Organic Selenium formed in plant, plant are can absorb using the fertile crops of selenium
Internal organic selenium content can improve 2.35~134 times, effect clearly, so field crop and vegetable can be improved using selenium fertilizer
The Se content of dish.In rudimentary plant, the selenium content of mushroom is higher, is 10~1000 times of higher plant, so mushroom is one
The curing the disease of kind of selenium deficiency area, diseases prevention food.
Selenium is respectfully called " long-lived element ", " king of anticancer " by domestic and international the world of medicine and nutrition educational circles.In eighties of last century 70
Age, the World Health Organization just announces that selenium is the essential trace elements of the human body, and selenium deficiency can have a strong impact on the healthy of people.
Selenium content in tissue is thousand a ten thousandths, but it determines the presence of life, to the huge of human health
Big effect is that other materials are irreplaceable.Selenium deficiency can directly result in human immunological competence's decline, and clinical medicine is proved, threatens people
More than 40 kinds of disease of class health and lives is all relevant with human body selenium deficiency, such as cancer, cardiovascular disease, hepatopathy, cataract, pancreas disease
Disease, diabetes, genital system diseases etc..
The people of whole world countries and regions about more than 40 is in poor selenium, low selenium band.China have more than 70% area, about
700000000 people are in poor Xi Hedixi areas.They lean on the selenium amount that ordinary meal is taken in, and minimal requirement is not reached much so that with
The incidence of disease of the relevant disease of selenium deficiency is greatly improved.As can be seen here, selenium and health are closely bound up, and it is to dominate human life
Important trace element, this point turns into the common recognition of countries in the world scientist.
The Research approach of this project is the administration by selenium fertilizer, produces the grain of people's daily consumption, vegetables and fruit,
The enzyme of root, stem, leaf and the fruit food synthesis selenoprotein, amino acid selenium and selenium-rich of plant is passed to, into humans and animals
In vivo, the content of blood selenium in human body can be improved.It is thin to suppress cancer in human body by selenoprotein, the targeting of amino acid selenium
The growth of born of the same parents and make its apoptosis；The generation of mankind's cardiovascular and cerebrovascular wall blood fat is reduced, so as to play the effect prevented and cured diseases.
6. selenium and sulphur are a pair of Associated Antagonistic Elements
People have found that selenium and sulphur are a pair of Associated Antagonistic Elements in soil-botanical system recently, but in recent years then find both there is also
Conspiracy relation.When research finds that the poly- selenium plant such as the Radix Astragali keeps normal growth, optimal S/Se ratios are 9: 1；Later again found to
The field crop S/Se optimum ratios such as day certain herbaceous plants with big flowers are 1500: 1.In the soil of low-sulfur and low selenium, selenium and sulphur are not present between the two
Mutual antagonism.In low-sulfur nutrient solution, applying selenium can promote the crop seedlings such as wheat and paddy rice to absorb sulfate ion；Low
Selenium or apply selenium it is relatively low in the case of, the absorption of Selenium By The Plants can be promoted by applying sulphur.And high selenium or apply selenium it is higher in the case of, apply sulphur not
Beneficial to the absorption of Selenium By The Plants.
Many is also compared to the interrelationship study between selenium and phosphorus in soil-botanical system, it is considered that, apply phosphorus meeting
Increase the absorption of Selenium By The Plants, and the concentration of phosphorus in plant can also be improved by applying selenium, so there is a synergy between for phosphorus and selenium.
Its reason is probably that, because phosphorus can promote plant root growth, can also promote absorption of the plant to Selenium in Soil.
7. the selection of selenium fertilizer form
According to years of researches and result of the test, selenite, selenate and Organic Selenium etc. may be selected in the form of selenium fertilizer.Organic Selenium
The residuum of animals and plants is mainly derived from, selenium-enriched plant is more difficult to be found, so difficult from Organic Selenium approach resource.And selenate is
High price selenium, difficulty is aoxidized in acid soil and neutral soil, is only capable of existing in the aqueous solution of arid climate and basic soil,
Applicability is seldom, so Se can only be selected4+Selenite.Because selenite is the main body of plant absorption, the full selenium of soil is accounted for
More than the 40% of content.In order to ensure selenium fertilizer is produced successfully, we have selected sodium selenite product.
The selection of agent 8. selenium fertilizer accompanies
In order that plant can smoothly absorb selenium fertilizer, and plant progress selenoprotein synthesis can be entered, be formed in plant
Selenoprotein and amino acid selenium, it is easy to absorbed by human or animal, reach the purpose of preventing and treating diseases.We by grinding for many years
Study carefully, have selected unrighted acid is the agent together of selenium fertilizer, selenium element is smoothly entered in the empty price of unrighted acid, energy
Stable sorption is not fallen off on fertilizer.After being manured into soil, with the enzymolysis of unrighted acid, selenium can be with various organic
Acid group together enters plant, and is transported in the cauline leaf and fruit of plant, is enriched with selenium, and formed selenoprotein and
Amino acid selenium.The unsaturated fatty acids that we mainly select have oleic acid [C18H34O2], linoleic acid [C18H32O2] and leukotrienes
[C18H30O2] etc..And the oils containing above-mentioned unrighted acid mainly has soybean oil, sunflower, sesame oil, peanut oil, cottonseed
Oil and corn oil etc., different unrighted acid species and content can directly influence the absorption quantity of selenium fertilizer.
9. the selection of ammonia stabilizer
Long-actingization of fertilizer, many nutrient ladens and specific function are the directions of Fertilizer development, and the nano-sized carbon that we develop is organic
Selenium fertilizer is exactly special multi-Functional Fertilizers.But for the nitrogen utilization efficiency of raising, extend fertilizer efficiency period, improve crop yield, reduce
The formation of nitrous oxide and nitrite nitrogen, preserves the ecological environment.Ammonia stabilizer can improve the nitrogen utilization efficiency 15% of soil with
On.35 ~ 50 days formation time of nitrified nitrogen in soil and nitrite nitrogen can be slowed down simultaneously, so as to reduce as caused by nitrite nitrogen
Cancer morbidity.Preferably ammonia stabilizer selects the downstream product DCD of calcium carbide（N4H4C2）.It can disposably make base manure for examination fertilizer
Apply, remove process of topdressing from；And 10%-20% effect of increasing production can be obtained.Greenhouse gases (CO can also be reduced2) and nitrogen oxide
(N2O discharge capacity).
Specific composition and effect in the present invention mainly have：
A kind of nano-sized carbon is Se-enriched or mixture fertilizer, it is characterised in that：In the fertilizer containing nano-sized carbon, the salt of low price containing selenium,
The associated agent of carbonate nitrogenous fertilizer, the salt of low price containing selenium and ammonia stabilizer；
The preferred proportion that the nano-carbon material of additive accounts for fertilizer gross weight is 0.02%~2%, and its preferably nano-sized carbon yardstick is 5
~ 200 nanometers.
The preferred proportion that the salt Optimum Contents of low price containing selenium account for gross weight is 0.05% ~ 5%, the preferably salt material of low price containing selenium product
Plant optional sodium selenite or selenic acid is received.
Nano-sized carbon is Se-enriched or mixture fertilizer, is to improve crop from the absorption selenium low price salt content in soil, selection
Unrighted acid does associated agent.Agent of preferably accompanying has the materials such as sunflower oil and corn oil, preferably adding proportion model
Enclose for 0.1% ~ 1.5%.
Ammonia stabilizer with the addition of to the uptake of nitrogenous fertilizer to improve crop.Ammonia stabilizer can improve the Nitrogen utility of soil
Rate more than 15%.35 ~ 50 days formation time of ammoniacal nitrogen conversion nitrate nitrogen and nitrite nitrogen in soil can be slowed down simultaneously, so as to subtract
Few cancer morbidity as caused by nitrite nitrogen.Preferably ammonia stabilizer selects the downstream product DCD of calcium carbide（N4H4C2）.
The applicable preferable nitrogen fertilizers of described ammonia stabilizer are neutral carbonate fertilizer, neutral carbonate fertilizer and selenic acid
Salt has the function that accompanies together, and the crop that can increase selenium salt absorbs.The neutral optional ammonium hydrogen carbonate of carbonate fertilizer, potassium carbonate and urine
Element etc..Preferable consumptions of the ammonia stabilizer DCD in neutral carbonate fertilizer is 0.1% ~ 5%.Ammonia stabilizer DCD can reduce greenhouse
The forming amount 60% ~ 70% of gas nitrous oxide.
Nano-sized carbon is Se-enriched or mixture fertilizer, it is characterised in that the material has small-size effect, high surface area effect
Should and tunnel-effect, have conducting function and magnetizing function in water, the ion in the soil water can be promoted to ionize, soil can be accelerated
The activation of the eutrophication ion such as selenium in water, absorb and be rapidly converted into crop vivo acid selenium and selenoprotein, so that
Inorganic selenate is changed into organic Se-rich food.
Nano-sized carbon is Se-enriched or preparation method of mixture fertilizer, preferably the preparation method of nano-sized carbon, is to use electroporation
The spherical nano-sized carbon of production.Less than 100 nanometers of polarity that preferably nano-sized carbon is produced through electrolytic separation using graphite is spherical to be received
Rice carbon products.The performance of spherical nano-sized carbon is different from general carbon material, and the burning point of nano-sized carbon is 360 degree, common carbon burning point
For 2800 degree.Common carbon is electric conductor, and nano-sized carbon is insulator, and band is magnetic.Common carbon is not dissolved in water, nanometer carbon dissolution
Yu Shui, meets water and becomes superconductor, its conductance increase by 30% ~ 50%.
Nano-sized carbon is Se-enriched or preparation method of mixture fertilizer, it is characterised in that additive air-flow crushing is set up in the technique
Machine, storagetank, computer-metering pump, stir mixing machine, material conveyer, weighing machine, packing machine, freeze-day with constant temperature warehouse etc. are supporting
Production line and corollary equipment.
The present invention is illustrated with specific embodiment：
Embodiment 1
A kind of nano-sized carbon is Se-enriched or mixture fertilizer, wherein containing：
Nano-sized carbon：2%；
Sodium selenite：5%；
Soybean oil：1.5%；
N4H4C2 ：5%；
Remaining is ammonium hydrogen carbonate.
After this formula is applied, broccoli selenium content is compared to 4.7 times of increase of not applying fertilizer.
Embodiment 2
A kind of nano-sized carbon is Se-enriched or mixture fertilizer, wherein containing：
Nano-sized carbon：0.02%；
Selenic acid is received：0.05%；
Sesame oil：0.1%；
N4H4C2 ：0.1%；
Remaining is potassium carbonate.
After this formula is applied, broccoli selenium content is compared to 1.5 times of increase of not applying fertilizer.
Embodiment 3
A kind of nano-sized carbon is Se-enriched or mixture fertilizer, wherein containing：
Nano-sized carbon：1%；
Sodium selenite：3%；
Cottonseed oil：1.12%；
N4H4C2 ：3%；
Remaining is ammonium hydrogen carbonate, potassium carbonate and urea mixing.
After this formula is applied, broccoli selenium content is compared to 4.07 times of increase of not applying fertilizer.
Implementation result：
Crops apply the selenium-rich result after selenium fertilizer.Numerous results of study show that Organic Selenium can constitute many with weight in vivo
Want the structure of biological function.Safe slope boolean report in 1984, machine Binding in vivo glutathione peroxidase（GSH-Px）In
Selenium accounts for 1/3rd of total selenium amount.And organic selenium compounds are better than inorganic selenium to the effect for removing peroxy radical, in view of selenium
Function in human and animal's nutrition, and humans and animals mainly absorb selenium, therefore research plant pair by holophytic nutrition
The sorption enhanced of selenium has prior meaning.
There are corn and soybean, paddy rice, wheat, sunflower etc. for the selenium-rich field crop of examination；There is western orchid for the rich selenium vegetables of examination
Flower, cauliflower, Kidney bean angle, carrot, Red radish, cabbage mustard, cucumber, Xi Hong Fei, Chinese cabbage and ternip etc..Refer to table 1,2.Table 1
Field crop selenium-rich result shows there is obvious selenium-rich knot after applying selenium fertilizer for 5 kinds of staple crops of examination and oil crops
Really, selenium-rich multiple is 2.352~134.0.It is ordered as from selenium-rich content：Soybean ＞ wheat ＞ sunflower ＞ paddy rice ＞ corns, say
The functional foods such as bright exploitation soybean, wheat, because selenium content is high, market prospects are had an optimistic view of.
Selenium-rich effect measuring result of the nano-sized carbon selenium of table 1 fertilizer to field crop（mg/kg）
| Crop | Selenium fertilizer | Chemical Mixed Fertilizer | Selenium-rich amount | Selenium-rich multiple | Detection position |
| Corn | 0.134 | 0.001 | 0.133 | 134.0∶1 | Corn kernel |
| Wheat | 0.237 | 0.005 | 0.233 | 52.67∶1 | Wheat seed |
| Paddy rice | 0.205 | 0.058 | 0.147 | 3.534∶1 | Rice grain |
| Sunflower | 0.207 | 0.088 | 0.119 | 2.352∶1 | Sunflower seed |
| Soybean | 0.374 | 0.010 | 0.364 | 37.40∶1 | Soybean kernel |
Table 1 absorbs selenium amount difference between listing Different Crop, and difference is obvious.It is ordered as by Se content is absorbed：Sunflower ＞ water
Rice ＞ soybean ＞ wheat ＞ corns.It seems that corn and wheat are that nature absorbs two kinds of minimum crops of selenium amount, and someone is big to observing
Joint disease and find during the occurrence regularity of Endemic Area of The Keshan Disease, crowd's state of an illness in drinkable water rice field area is lighter, and it is single edible corn, small
Crowd's incidence of disease in wheat field area is heavier, and this selenium rich ability with crop in itself is relevant, is confirmed herein.
In this experiment, under the conditions of using the fertile equal amount of selenium, Different Crop selenium-rich fold difference is very big, is ordered as：Corn
＞ wheat ＞ soybean ＞ paddy rice ＞ sunflowers.Illustrate corn, wheat selenium-rich effect preferably, this is to Kaschin-Beck disease and Endemic Area of The Keshan Disease
It is very big using the fertile meaning of selenium.Feed can be processed with selenium-rich corn, wheat, soybean and stem straw, the domestic animal such as rear cattle, sheep, pig, chicken
And poultry, the meat product of selenium-rich can be obtained, this is the feasible way for the selenium deficiency food and dietotherapy health for solving people.
Selenium fertilizer is listed in table 2 to the selenium-rich effect of vegetable crop, measurement result shows, broccoli, cauliflower, Kidney bean angle,
The U.S. vegetables such as radish and cabbage mustard of carrot, the heart can serve as rich selenium vegetables supply market, and its Se content is in 0.092-0.220mg/
Kg, belongs to selenium-rich product.Analyzed, be ordered as by applying the vegetables selenium-rich multiple after selenium fertilizer：Cauliflower ＞ cucumber ＞ tomatoes ＞
The U.S. radish ＞ Chinese cabbage ＞ broccoli of the Kidney bean angle ＞ carrot ＞ cabbage mustard ＞ hearts.Broccoli is nature selenium content highest vegetables, not
In the case of fertilising, broccoli selenium content can be made to reach 0.054 mg/kg, optimal food therapy vegetable can be used as.And apply selenium fertilizer
Afterwards, its selenium content is added more than 4 times again, so selenium-rich broccoli commercially has promotion prospect very much.
Selenium-rich effect measuring result of the nano-sized carbon selenium of table 2 fertilizer to vegetable crop（mg/kg）
| Crop | Selenium fertilizer | Chemical Mixed Fertilizer | Selenium-rich amount | Selenium-rich multiple | Detection position |
| Broccoli | 0.220 | 0.054 | 0.166 | 4.074∶1 | Fresh broccoli |
| Cauliflower | 0.149 | 0.002 | 0.147 | 74.50∶1 | Fresh vegetable is spent |
| Kidney bean angle | 0.109 | 0.004 | 0.105 | 27.25∶1 | Fresh fresh kidney beans |
| Carrot | 0.113 | 0.005 | 0.108 | 22.60∶1 | Fresh radish |
| Red radish | 0.107 | 0.011 | 0.096 | 9.727∶1 | Fresh radish |
| Ternip | 0.047 | 0.006 | 0.041 | 7.833∶1 | Fresh radish |
| Chinese cabbage | 0.061 | 0.009 | 0.052 | 6.78∶1 | Fresh Chinese cabbage |
| Cabbage mustard | 0.092 | 0.009 | 0.083 | 10.22∶1 | Fresh cabbage mustard |
| Cucumber | 0.053 | 0.001 | 0.052 | 53.00∶1 | Fresh cucumbers |
| Xi Hong Fei | 0.032 | 0.001 | 0.031 | 32.00∶1 | Fresh Xi Hong Fei |
Result of the test shows, 0.166 is increased to using selenium Feixi orchid selenium-rich amount（mg/kg）, than not applying selenium Feixi orchid containing selenium
4.074 times of amount increase；Increase to 0.147 using the fertile cauliflower selenium-rich amount of selenium（mg/kg）, than not applying the fertile cauliflower selenium content increase of selenium
74.50 times；Increase to 0.108 using the fertile carrot selenium-rich amount of selenium（mg/kg）, than not applying the fertile carrot selenium content increase by 22.60 of selenium
Times etc..Increase to 0.105 using the fertile Kidney bean angle selenium-rich amount of selenium（mg/kg）, 27.25 times are increased than not applying the fertile Kidney bean angle selenium content of selenium
Deng.Increase to 0.052 using the fertile cucumber selenium-rich amount of selenium（mg/kg）, 53.0 times etc. are increased than not applying the fertile cucumber selenium content of selenium.Using
Selenium Feixi Hong Fei selenium-rich amounts increase to 0.031（mg/kg）, 32.0 times etc. are increased than not applying selenium Feixi Hong Fei selenium contents.With selenium fertilizer
The appeal grain of production and vegetables can be recommended as health food at first.To have to human body and substantially cure the disease and healthcare function.
Claims (7)
1. a kind of nano-sized carbon is Se-enriched or mixture fertilizer, it is characterised in that：In the fertilizer containing nano-sized carbon, containing selenium at a low price
The associated agent of salt, carbonate nitrogenous fertilizer, the salt of low price containing selenium and ammonia stabilizer；
The nanometer carbon content is the 0.02%~2% of gross weight；Nano-sized carbon yardstick is 5 ~ 200 nanometers；
The salt content of low price containing selenium is the 0.05% ~ 5% of gross weight；
Agent content is the 0.1% ~ 1.5% of gross weight to the salt of low price containing selenium together；Agent is unsaturated lipid to the selenium low price salt together
Fat acid；
The ammonia stabiliser content is the 0.1% ~ 5% of gross weight.
2. nano-sized carbon according to claim 1 is Se-enriched or mixture fertilizer, it is characterised in that：The salt of low price containing selenium
It is that sodium selenite or selenic acid are received.
3. nano-sized carbon according to claim 1 is Se-enriched or mixture fertilizer, it is characterised in that：The selenium low price salt phase
It is to contain oleic acid C with agent18H34O2, linoleic acid C18H32O2Or leukotrienes C18H30O2Oils.
4. nano-sized carbon according to claim 3 is Se-enriched or mixture fertilizer, it is characterised in that：The selenium low price salt phase
It is soybean oil, sunflower, sesame oil, peanut oil, cottonseed oil or corn oil with agent.
5. nano-sized carbon according to claim 1 is Se-enriched or mixture fertilizer, it is characterised in that：The ammonia stabilizer is
The downstream product DCD of calcium carbide, its chemical formula is N4H4C2。
6. nano-sized carbon according to claim 1 is Se-enriched or mixture fertilizer, it is characterised in that：The carbonate nitrogenous fertilizer
Including the one or more mixing in ammonium hydrogen carbonate, potassium carbonate or urea.
7. nano-sized carbon according to claim 1 is Se-enriched or mixture fertilizer, it is characterised in that：The nano-sized carbon is to adopt
The spherical nano-sized carbon produced with electroporation, its diameter is less than 100 nanometers.
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| CN107540474A (en) * | 2017-09-27 | 2018-01-05 | 潘月玉 | A kind of nano-sized carbon selenium-enriched fertilizer technology of preparing of selenium-rich agaric |
| CN107556113A (en) * | 2017-09-27 | 2018-01-09 | 潘月玉 | A kind of nano-sized carbon selenium-enriched fertilizer technology of preparing of selenium-rich potato |
| CN107673818A (en) * | 2017-09-27 | 2018-02-09 | 潘月玉 | A kind of nano-sized carbon selenium-enriched fertilizer technology of preparing of Selenium-enriched radish |
| CN107673918A (en) * | 2017-09-27 | 2018-02-09 | 潘月玉 | The nano-sized carbon selenium-enriched fertilizer technology of preparing of selenium rich strawberry |
| CN107759309A (en) * | 2017-09-26 | 2018-03-06 | 张志明 | A kind of nano-sized carbon organic selenium-rich fertilizer for cultivating Moringa tea |
| CN107793260A (en) * | 2017-09-18 | 2018-03-13 | 吉林省晟华农村电商创业服务有限公司 | A kind of implantation methods of selenium-enriched organic fertilizer and selenium-rich rice |
| CN107793261A (en) * | 2017-09-27 | 2018-03-13 | 潘月玉 | The nano-sized carbon selenium-enriched fertilizer technology of preparing of selenium-rich citrus |
| CN112552095A (en) * | 2019-09-10 | 2021-03-26 | 株洲本琦生物科技有限责任公司 | Compound fertilizer containing trace selenium element and preparation method thereof |
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| CN107793260A (en) * | 2017-09-18 | 2018-03-13 | 吉林省晟华农村电商创业服务有限公司 | A kind of implantation methods of selenium-enriched organic fertilizer and selenium-rich rice |
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| CN107540474A (en) * | 2017-09-27 | 2018-01-05 | 潘月玉 | A kind of nano-sized carbon selenium-enriched fertilizer technology of preparing of selenium-rich agaric |
| CN107556113A (en) * | 2017-09-27 | 2018-01-09 | 潘月玉 | A kind of nano-sized carbon selenium-enriched fertilizer technology of preparing of selenium-rich potato |
| CN107673818A (en) * | 2017-09-27 | 2018-02-09 | 潘月玉 | A kind of nano-sized carbon selenium-enriched fertilizer technology of preparing of Selenium-enriched radish |
| CN107673918A (en) * | 2017-09-27 | 2018-02-09 | 潘月玉 | The nano-sized carbon selenium-enriched fertilizer technology of preparing of selenium rich strawberry |
| CN107793261A (en) * | 2017-09-27 | 2018-03-13 | 潘月玉 | The nano-sized carbon selenium-enriched fertilizer technology of preparing of selenium-rich citrus |
| CN112552095A (en) * | 2019-09-10 | 2021-03-26 | 株洲本琦生物科技有限责任公司 | Compound fertilizer containing trace selenium element and preparation method thereof |
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