CN107072911A - Reduce the composition of stench - Google Patents
Reduce the composition of stench Download PDFInfo
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- CN107072911A CN107072911A CN201580052656.0A CN201580052656A CN107072911A CN 107072911 A CN107072911 A CN 107072911A CN 201580052656 A CN201580052656 A CN 201580052656A CN 107072911 A CN107072911 A CN 107072911A
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- composition
- stench
- reduction
- smell
- heterocycles
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0026—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring
- C11B9/003—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring the ring containing less than six carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0061—Essential oils; Perfumes compounds containing a six-membered aromatic ring not condensed with another ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0069—Heterocyclic compounds
- C11B9/0073—Heterocyclic compounds containing only O or S as heteroatoms
- C11B9/0084—Heterocyclic compounds containing only O or S as heteroatoms the hetero rings containing more than six atoms
Abstract
There is provided the composition for reducing stench.Said composition includes spice mixt, and it includes：(a) at least one material for reducing smell；At least one N heterocycle selected from aromatics N heterocyclic moiety and N, S heterocyclic moiety (b).At least one material for reducing smell shows odour value (OV), the general denary logarithm (log that the odour value (OV) has10OV 5.5) are greater than about.
Description
Invention field
This disclosure relates to reduce the composition of stench.More specifically, this disclosure relates to the reduction with some fragrance components
The composition of stench, the fragrance component reduces the sensory perception of the stench of wide scope.
Background of invention
Product for resisting stench is well-known in the art.The many commercializations of design, industrialization, family and individual
Care product is applied or wherein using the stench in their environment to shelter them.Product is also possible to applying or using
During and/or application or stench is generated when using, or their own because of its composition and functional raw material composition inherently
There is stench.
Cosmetics, industrialization and the intrinsic stench of household products are for from household cleaners to personal care product's scope
Be for many different articles for use one extensively and common problem, the personal care product include antiperspirant, deodorant,
Sunless tanning agent (sunless tanner), hair dye, shampoo and conditioner, hand lotion and skin cream, agent for permanent hair waving and relaxation
Agent etc..
It is the product that includes ammonia, such as hair dye to the most challenging product of spices some.Due to the physics of ammonia
Characteristic, such as high vapour pressure and its extremely excitant and undesirable sensation olfactive characteristics, so ammonia is considered as being most difficult to
To cover one of stench that spices is covered using target stench.
Although largely attempting to carry out in an inventive manner with method, the ammonia in covering product such as hair dyeing product
Feel to be still a difficult task.Covering ammonia difficulty be for physically and non-chemical modes covering ammonia because
Generating any type of chemical bond between ammonia and another aromatic or chemicals in product will cause performance to reduce, and sometimes
Even make product unstable.
Therefore, there is still a need for providing the composition for reducing stench, it reduces the stench sensory perception of wide scope, including consumption
The stench of based on nitrogen, based on sulphur in product, acid and aldehyde.
Summary of the invention
In one embodiment, reducing the composition of stench includes spice mixt, and it includes：(a) at least one subtracts
The material of few smell；At least one N- heterocycle selected from aromatics N- heterocyclic moiety and N, S- heterocyclic moiety (b).Described at least one
The material for planting reduction smell shows odour value (OV), the general denary logarithm that the odour value (OV) has
(log10OV 5.5) are greater than about.
In another embodiment, the consumer goods include spice mixt and the component based on nitrogen.The spice mixt
Including：(i) at least one material for reducing smell；(ii) at least one is selected from aromatics N- heterocyclic moieties and N, S- heterocyclic moiety
N- heterocycles.The component based on nitrogen includes the component based on nitrogen selected from ammonia, the amine of substitution and its mixture.It is described at least
A kind of material for reducing smell shows odour value (OV), the general denary logarithm that the odour value (OV) has
(log10OV 5.5) are greater than about.
In another embodiment, hair coloring preparation composition includes spice mixt and the component based on nitrogen.The spices
Mixture includes：(i) at least one material for reducing smell；(ii) at least one is miscellaneous selected from aromatics N- heterocyclic moieties and N, S-
The N- heterocycles of loop section.The component based on nitrogen includes the component based on nitrogen selected from ammonia, the amine of substitution and its mixture.Institute
The material for stating at least one reduction smell is shown：Odour value (OV), it is general decimal base that the odour value (OV) has
Logarithm (log10OV 5.5) are greater than about；About 0.001- about 160 (ng/L) odor detection threshold (ODTi)；About 0.1- about 100,
000 (μ g/L) standard equilibration headspace concentration
These and other feature, aspect and the advantage of specific embodiment are to those skilled in the art from reading sheet
It is apparent in open.
Detailed description of the invention
The wide in range description of a large amount of different embodiments of this disclosure is hereafter enumerated.This specification should be considered only as showing
Example property and the simultaneously all possible embodiment of non-depicted because the every kind of possible embodiment of description if not impossible to
, it is also possible to it is unpractical.It should be appreciated that arbitrary characteristics as described herein, characteristic, composition, composition, component, product,
Step or method can be deleted, in whole or in part with any other feature as described herein, characteristic, composition, composition, group
Point, product, step or Combination of Methods or substituted by them.State-of-the-art technology sheet or patent can be used to file the skill researched and developed after day
The embodiment that art implements a large amount of alternative selections, they still fall within the scope of claim.The whole quoted from herein is gone out
Version thing and patent are incorporated herein by reference.
This disclosure relates to reduce the composition and its method of stench.The composition of the reduction stench of the disclosure includes reducing width
The spice mixt of the sensory perception of scope stench, the stench of the wide scope includes, such as based on nitrogen, based on sulphur, acid and aldehyde
Stench.
" stench " refers to be usually compound undesirable or beastly for most people, such as with base
In nitrogen, based on sulphur, the acid smell related to the stench of aldehyde.
The standard equilibration headspace concentration that " odour value " of fragrance component is defined as representing with microgram/l/ also with micro-
Gram/odor detection threshold (ODT that represent of liThe ratio between).
Term " log10OV " refers to the logarithm of general (or with ten be bottom) of odour value defined above.
" odor detection threshold " (ODTi) refer to mean concentration, it can be felt higher than its aromatic (i) by group member
And osphresiometer can be used to measure.
" standard equilibration headspace concentration " refers to composition with conc forms, i.e., the solid of this composition or liquid form at 20 DEG C
The concentration balanced at temperature and 1 atmospheric pressure.Can use known quantitative headspace analysis technology any number of measurement it, ginseng
See, such as Mueller and Lamparsky Perfumes：Art, Science and Technology, the 6th chapter, " The
Measurement of Odors ", 176-179 pages (Elsevier 1991).
A. spice mixt
According to the disclosure, reducing the composition of stench includes spice mixt, and it includes：At least one material for reducing smell
Material；With at least one N- heterocycles.The composition for reducing stench can also be included for the other optional of application-specific
Composition.The material and N- heterocycles for reducing smell shelter the ability selection of stench based on it, and the stench is because having the thing based on nitrogen
Matter (such as ammonia, methylamine, ethamine, dimethylamine, indoles, scatol and cadaverine), based on sulphur material (for example hydrogen sulfide, methyl mercaptan,
Ethyl mercaptan, dimethyl sulfide, diethyl sulfide and dimethyl disulphide), sour stench (such as acetic acid, butyric acid and valeric acid) and aldehyde stench (example
Such as formaldehyde, acetaldehyde, butyraldehyde and isopentyl aldehyde) cause.
This ability determines according to many factors, including, the general denary logarithm (log of such as odour value10OV),
And reduce the composition of stench to shelter stench for preparation.In another embodiment, factor can also include gas
Taste threshold value (ng/L) and vapour pressure (μ g/L) are to determine ability that fragrance component covers stench.
The composition of the reduction stench of the disclosure can be used for being widely applied and be not limited to any specific multiplicative model
Or product form.According to the disclosure, an example of the consumer goods includes hair dyeing/hair care massage products.Although being described in detail herein
Embodiment be related to hair dyeing/hair care massage products, but the disclosure is applied to various cosmetics and personal care product, example
Such as, fabric and spray for refreshing air and body odor agent, laundry detergent and additive, room freshener or indoor deodorization are gone
Agent, household cleaning agent, lavatory cylinder cleaning agent, dishwashing detergent, shower cream, shampoo, conditioner etc..
The composition for reducing stench can be also used for numerous environment or product comprising foul odour.For example and not to this
It is disclosed to limit：Environment, such as soot, cat rubbish, chicken chicken coop, water treatment plant and pond, rubbish, kennel, refining animal oil oil
Factory (rendering plants), food processing factory, timber mill, canned fish factory, sewer, septic tank, paper mill and wash one's hands
Between；With bathroom nursing, indoor pure and fresh, with fresh air, pet nursing, adult-incontinence, household cleaning, massage product etc. of taking care of hair.
However, for convenience, discussion below will focus on the amine environment of ammonia and substitution, such as massage products of having hair dyed/take care of hair.
It is not bound to theory, it is believed that the environment for including stench amine, the spice mixt of the disclosure, which is provided, substantially to be subtracted
Effect of the amine of few ammonia/substituted to trident (the 5th brain) nerve stimulation.Term used herein " substantially reduces trigeminal neuralgia thorn
Swash " refer to that on bottom line intranasal stimulation or burn feeling are equal to or less than composition caused by the stench based on ammonia amine
Fragrance component odor level on be felt.Think when trigeminal neuralgia is stimulated by height-ammonia amine composition, burn feeling or
Excitement has exceeded stimulation smell, any fragrance of such as sense of smell.
1. reduce the material of smell
According to an embodiment, the composition of the reduction stench of the disclosure can include the material of at least one reduction smell
Material, to relax the effect of stench.The material of suitable reduction smell can have odour value (OV), odour value (OV) tool
General denary logarithm (the log having10OV 5.5) are greater than about；In another embodiment, log10OV is greater than about 6.0；
In another embodiment, log10OV is greater than about 6.4；And in another embodiment, log10OV is greater than about 7.0.
The material of the reduction smell of the disclosure can also be according to its standard equilibration headspace concentrationWith smell detection threshold
It is worth (ODTi) define.In one embodiment, the material of suitable reduction smell can have about 0.10- about 100,000 μ
G/L'sOr each any numerical value in the range of being somebody's turn to do.In another embodiment,Headspace concentration can be about
The μ g/L of 1.0- about 10,000；And in another embodiment,Headspace concentration can be about the μ g/L of 10- about 5,000.
In terms of odor detection threshold, the material of suitable reduction smell can have about 0.001- about 160ng/L's
ODTiOr each any numerical value in the range of being somebody's turn to do.In another embodiment, ODTiIt can be about 0.01- about 100ng/L；And
In another embodiment, ODTiIt can be about 0.05- about 10ng/L.
The material of the suitable reduction smell of the disclosure includes saturated alkyl aldehydes, and it includes but is not limited to aldehyde C12MNA
(the 2- methyl hendecanal)；Aldehyde C8 octyl groups (octanal)；Aldehyde C9 (aldehyde C-9)；Aldehyde C6 hexyls (hexanal)；CALYPSONE (6- methoxyl group -2,
6- dimethyl octanal)；With aldehyde C7HEPTYLIC (enanthaldehyde).In one embodiment, the saturated alkyl aldehydes is selected from aldehyde
C12MNA and CALYPSONE.
In another embodiment, the material of suitable reduction smell includes unsaturated alkyl aldehydes, and it is included but not
It is limited to decylene-1-aldehyde, cis-4 ((Z)-decyl- 4- olefine aldehydrs)；Decenal -4- trans ((E)-decyl- 4- olefine aldehydrs)；(the 9- of decenal -9
Decenal), melonal (2,6- dimethyl-g -5- olefine aldehydrs)；Ligustral C (2,4- dimethyleyelohexane -3- cyclohexene carboxaldehydes)；Nonadienal
(olefine aldehydrs of (2E, 6Z)-nonyl- 2,6- bis-)；PINOACETALDEHYDE (3- (ring [3.1.1] hept-2-ene" of 6,6- dimethyl two -2-
Base) propionic aldehyde)；SHISOLIA (4- vinyl cyclohexyl -1- cyclohexene carboxaldehydes)；With Marseille aldehyde (two rings [2.2.2] octyl- 5- alkene -2- formaldehyde).
In one embodiment, the unsaturated alkyl aldehydes is selected from melonal, ligustral C, SHISOLIA and Marseille aldehyde.
In another embodiment, the material of suitable reduction smell includes aromatic aldehydes, and it includes but is not limited to fennel
Fragrant aldehyde paracresol (4-methoxybenzaldehyde), cyanine aldehyde (3- (3- isopropyl phenyls) butyraldehyde)；Hydrocinnamicaldehyde (3- hydrocinnamicaldehydes)；
With p-methylphenyl aldehyde (4- tolyl aldehydes).
In another embodiment, the material of suitable reduction smell includes Glycolic acid esters, and it includes but is not limited to
Allyl amyl glycolate (2- (isoamoxy) allyl acetate).
In another embodiment, the material of suitable reduction smell includes alcohols, and it includes but is not limited to amyl group second
Yl methanol (octyl- 1- alkene -3- alcohol)；Linalool (3,7- dimethyl-octa -1,6- dien-3-ols)；Nonadienol -2,6 ((2E,
6Z)-nonyl- 2,6- diene -1- alcohol)；Nonenol -6- cis ((Z)-nonyl- 6- alkene -1- alcohol)；Polysantalol ((E) -3,3- diformazans
Base -5- (2,2,3- trimethyl -3- cyclopentene -1- bases) -4- amylene -2- alcohol)；With 2,6- dimethyl enanthol (2,6- dimethyl-gs-
2- alcohol)；Hexenol -3 is cis (cis-hex- 3- alkene -1- alcohol).In one embodiment, the alcohols is selected from linalool, nonyl
Dienol -2,6, nonenol -6- cis, polysantalol, 2,6- dimethyl enanthol and hexenol -3 are cis.
In another embodiment, the material of suitable reduction smell includes the fragrance component of sulfur-bearing, and it is included but not
It is limited to ANJERUK (1- phenylethanethiols)；CORPS PAMPLEMOUSSE (the rings of (4S) -4,7,7- trimethyl -6- thias two
[3.2.1] octane)；To sulfydryl menthene (2- (4- methyl cyclohexane -3- alkene -1- bases) propyl- 2- mercaptan)；And thiogeraniol
((E) -3,7- dimethyl-octa -2,6- diene -1- mercaptan).
In another embodiment, the material of suitable reduction smell includes benzo dioxaClass
(benzodioxepines), it includes but is not limited to watermelon ketone (CALONE) (7- methyl -2H- benzos [b] [Isosorbide-5-Nitrae] dioxa- 3 (4H) -one)；With aurones (AZURONE) (7- isopentyl -2H- benzos [b] [1,4] dioxa- 3 (4H) -one).
In another embodiment, the material of suitable reduction smell includes ketone, and it includes but is not limited to left-handed perfume (or spice)
Celery ketone (2- methyl -5- (propyl- 1- alkene -2- bases) hexamethylene -2- ketenes)；Damascenone ((E) -1- (2,6,6- 3-methyl cyclohexanol -1,
3- diene -1- bases) but-2-ene -1- ketone)；Damascone α ((E) -1- (2,6,6- 3-methyl cyclohexanol -2- alkene -1- bases) but-2-ene -
1- ketone)；Damascone β ((E) -1- (2,6,6- 3-methyl cyclohexanol -1- alkene -1- bases) but-2-ene -1- ketone)；Damascone δ ((E) -1-
(2,6,6- 3-methyl cyclohexanol -3- alkene -1- bases) but-2-ene -1- ketone)；Filbertone ((E) -5- methyl hept-2-ene" -4- ketone)；Lattice are fluffy
Ketone (1- (3,3- dimethyleyelohexane -1- alkene -1- bases) amyl- 4- alkene -1- ketone)；IRISANTHEME ((E) -3- methyl -4- (2,6,6-
3-methyl cyclohexanol -2- alkene -1- bases) butyl- 3- alkene -2- ketone)；NEROLIONE (1- (3- methyl benzofuran -2- bases) ethyl ketone)；Method
Old ketone (2- cyclohexyl hept- 1,6- diene -3- ketone)；POMAROSE ((2E, 5E) -5,6,7- trimethyl octyl- 2,5- diene -4-
Ketone)；Irisone α (E) -4- (2,6,6- 3-methyl cyclohexanol -2- alkene -1- bases) butyl- 3- alkene -2- ketone；Irisone β (E) -4-
(2,6,6- 3-methyl cyclohexanol -1- alkene -1- bases) butyl- 3- alkene -2- ketone；With dihydro jasmone (the amyl- 2- alkene of 3- methyl -2- amyl group rings
Ketone).
In another embodiment, the material of suitable reduction smell include epoxides, furans, pyran and its
The partly or completely derivative of perhydrogenating, including but not limited to CASSYRANE (the 5- tert-butyl group -2- methyl -5- propyl group -2H- furans
Mutter)；Fragrant rose oxide (4- methylene -2- phenyl tetrahydrochysene -2H- pyrans)；Spiceleaf pyrans (2- methyl -4- methylene -6- phenyl four
Hydrogen -2H- pyrans)；Cyclic ethers (2,4- dimethyl -4- phenyl tetrahydrofuran)；Rose oxide (4- methyl -2- (2- methyl propyl- 1- alkene -1-
Base) tetrahydrochysene -2H- pyrans)；With Cineole ((1s, 4s) -1,3,3- trimethyl -2- oxabicyclos [2.2.2] octane).
In another embodiment, the material of suitable reduction smell includes phenols, and it includes but is not limited to methoxy first
Phenol (2- methoxyl group -4- methylphenols)；Dihydroeugenol (2- methoxyl group -4- propylphenols)；Guaiacol (2- methoxybenzenes
Phenol)；Vanillyl alcohol (2- ethyoxyl -4- methylphenols)；With eugenol (Coryophyllic acid).
In another embodiment, the material of suitable reduction smell includes phenolic ester class, and it includes but is not limited to acetic acid
Paracresol ester (the p- toluene ester of acetic acid)；To p-cresyl isobutyrate (the p- toluene ester of isobutyric acid)；With second position phenethyl methyl ether (2-
Methoxy ethyl) benzene)；
In another embodiment, the material of suitable reduction smell includes nitrile, and it includes but is not limited to cumonitrile
(4- isopropyls benzonitrile)；With violet nitrile (VIOLET NITRILE) ((2E, 6Z)-nonyl- 2,6- diene nitriles).
In another embodiment, the material of suitable reduction smell includes fragrant ethers, and it includes but is not limited to two
Hydrogen anethole (DIHYDRO ANETHOLE) (1- methoxyl group -4- propylbenzenes)；With cyclopropyl anisole (1- (Cvclopropvlmethvl)-
4- methoxybenzenes).
In another embodiment, the material of suitable reduction smell includes esters, and it includes but is not limited to safflower
Acetoacetic ester (2,6,6- 3-methyl cyclohexanol -1,3- diene -1- Ethyl formates)；FOLIONE (octyl- 2- ynoic acid methyl esters)；Acetic acid hexene
Ester, cis -3 (cis-hex- 3- alkene ester)；Aminomethyl phenyl acetic acid esters (2- phenylacetates)；Ethyl 2-methylbutyrate
(ethyl 2-methylbutyrate)；Ethyl isobutyrate (2 Methylpropionic acid ethyl ester)；Ethyl isovalerate (3 Methylbutanoic acid ethyl ester)；Propionic acid second
Ester (ethyl propionate)；With pears alcohol ester (acetic acid 3- methyl but-2-ene -1- base esters).
In another embodiment, the material of suitable reduction smell includes lactone, and it includes but is not limited to tonka-bean
Lactone (3,6- dimethyl -3a, 4,5,6,7,7a- hexahydro -3H- benzofuran-2-ones)；With third nonalactone (PRUNOLIDE)
(5- amyl groups dihydrofuran -2 (3H) -one).
In another embodiment, the material of suitable reduction smell includes Anthranilate class, it include but
It is not limited to methyl anthranilate (2- Methyl anthranilates).
In another embodiment, the material of suitable reduction smell includes carboxylic acid, and it includes but is not limited to pure benzene
Guanidine-acetic acid (2- phenylacetic acids).
In another embodiment, the material of suitable reduction smell includes terpene and hydro carbons, including but not limited to ten
One carbon triolefin ((3E, 5Z)-ten one carbon -1,3,5- triolefins)；With laurene (7- methyl -3- methylene octyl- 1,6- diene).
LogP values can be used to determine the hydrophobicity of the material of above-mentioned reduction smell, i.e. physicochemical characteristic.Reduce the material of smell
The Octanol/water Partition Coefficients (P) of material are the ratio between its equilibrium concentrations in pungent alcohol and water.It can also use Hansch's and Leo
Fragment method is extremely advantageously calculated logP values and provided with clogP.Referring to A.Leo, Comprehensive Medicinal
Chemistry, volume 4, C.Hansch et al., p295, Pergamon publishing houses, 1990, and provided with clogP.According to this public affairs
Open, at least one material for reducing smell there can be about 4 or less clogP；In another embodiment, it is described
At least one material for reducing smell can have about 3 or less clogP；And in another embodiment, it is described at least
A kind of material for reducing smell can have about 2.5 or less clogP.
The spice mixt can comprising account for the spice mixt weight about 0.0001%- about 99% or its in the range of
The material of the reduction smell of each any numerical value.In another embodiment, the spice mixt can include and account for the perfume
Expect the material of the reduction smell of mixture weight at least about 0.001%；In another embodiment, the spice mixt can
With the material for reducing smell of the Bao Zhanhan spice mixt weight at least about 1.0%；And in another embodiment, it is described
Spice mixt can include the material for the reduction smell for accounting for the spice mixt weight at least about 5.0%.
2.N- heterocycles
According to an embodiment, the composition of the reduction stench of the disclosure can also include at least one N- heterocycles with slow
With stench effect.It has been found that covering of some N- heterocycles to ammonia and amine stench in some applications has actively impact.
In one embodiment, N- heterocycles include at least one fragrance component, and it has a kind of aromatics N- heterocyclic moieties
Or a kind of N, S- heterocyclic moiety.In another embodiment, suitable N- heterocycles include but is not limited to BIGARYL (8- are (secondary
Butyl) -5,6,7,8- tetrahydroquinolines), ethyl dimethyl pyrazine (5- ethyl -2,3- dimethyl pyrazines), isobutyl ylmethoxy pyrrole
Piperazine (2- isobutyl group -3- IBMPs), methoxy methyl pyrazine (2- methoxyl group -3- methylpyrazines), isopropyl methyl thiazole
(2- ethyl -4- methyl-1,3-thiazoles), VETHYMINE (2,4- diethoxy -5- methylpyrimidines, ZINARINE (2- (2,4- bis-
Methylcyclohexyl) pyridine), 8- (amyl- 2- yls) -5,6,7,8- tetrahydroquinolines, 8- (amyl- 3- yls) -5,6,7,8- tetrahydroquinolines, 7-
Sec-butyl -6,7- dihydro -5H- cyclopentas [b] pyridine, 7- (amyl- 2- yls) -6,7- dihydro -5H- cyclopentas [b] pyrrole
Pyridine, 7- (amyl- 3- yls) -6,7- dihydro -5H- cyclopentas [b] pyridine, 7- (3- methyl but-2-enes base) -6,7- dihydros -5H-
Cyclopenta [b] pyridine, sec-butyl quinoline (6- (sec-butyl) quinoline), isobutyl quinoline (2- isobutyl quinolines), isopropyl
Quinoline (6- isopropyl quinolines), lepidine (6- methylquinolines), pyrrole draw imperial (6- (sec-butyl) quinoline), CORPS RACINE
(2- (3- phenyl propyls) pyridine), CORYLONE PYRAZINE (5- methyl -6,7- dihydro -5H- cyclopentas [b] pyrazine),
Hydroxy ethyl methyl thiazole (4- ethyl -5- methylthiazol -2- alcohol), Isohexyl methoxy pyrazine (2- methoxyl groups -3- (4- methyl
Amyl group) pyrazine), isoquinolin, 5- methyl-quinoxalins.
In one embodiment, suitable N- heterocycles have odour value (OV), and it is general that the odour value (OV) has
Denary logarithm (log10OV 5.5) are greater than about.
In another embodiment, the spice mixt can include and account for the spice mixt weight about
0.0001%- about 99% or each any numerical value in the range of it N- heterocycles；In another embodiment, the spices is mixed
Compound can be comprising accounting for the spice mixt weight about 0.0001%- about 35% or the N- of each any numerical value in the range of it is miscellaneous
Ring；In another embodiment, the spice mixt can include and account for the spice mixt weight about 0.001%- about
10% or the N- heterocycles of each any numerical value in the range of it；In another embodiment, the spice mixt can be wrapped
Containing the N- heterocycles for accounting for spice mixt weight 0.01%- about 5% or each any numerical value in the range of it.In another implementation
In scheme, the spice mixt can include the N- heterocycles for accounting for the spice mixt weight at least about 0.0001%；Another
In individual embodiment, the spice mixt can include the N- heterocycles for accounting for the spice mixt weight at least about 0.001%；And
In another embodiment, the spice mixt can be miscellaneous comprising the N- for accounting for the spice mixt weight at least about 0.01%
Ring.
It is not intended to be bound by theory, it is believed that when N- heterocycles and with greater than about 5.5 log10The material of OV reduction smell
In the presence of expecting together, the material for reducing smell is compared to the stench efficiency of its own, and N- heterocycles can increase spice mixt pair
The efficiency of stench caused by it there is the amine of ammonia and substitution.
3. optional compositions
Reduce stench composition can optionally include extra composition, its include but is not limited to thickener, solvent,
Enzyme, stabilizer, surfactant, chelating agent and oxidant, this depends on the difference of application method.In one embodiment,
For example, composition for hair dying can include viscosity/gel strength conditioning agent, oil ＆ fat, wax, hydro carbons, polyalcohols, amide-type,
Silicone derivative, cationic surface active agent, anionic surfactant, amphoteric surfactant, non-ionic surface
Activating agent, non-ionic polymer substance, cationic high-molecular material, anionic polymer substance, Amphiphatic high polymer thing
Matter, protein derivatives and amino acid, preservative, chelating agent, stabilizer, oxidation retarder, plant extracts, crude drug are extracted
Thing, vitamin, color additives, essence, pigment, ultra-violet absorber etc. are used as additive.
Embodiment
Provide the following example only for the purposes of illustration, but they are not construed as limiting the present invention, because not taking off
From the situation of disclosure spirit and scope, many versions of the invention are possible.Embodiment 3 and 4 is suitable for this
The spice mixt of the disclosed composition for reducing stench.Examples 1 and 2 are comparative examples.
The first composition for reducing stench includes the spice mixt (embodiment 1) for banksia rose spices.Embodiment 1 includes
Low odour value material ((log10OV) it is less than 5.5).Embodiment 1 is free of N- heterocycles.
Embodiment 1
Banksia rose spices
The composition of second of reduction stench is included for the spice mixt (embodiment 2) of blue or green fragrant spices.Embodiment 2 includes
High odour value material ((log10OV) it is greater than about 5.5).Embodiment 2 is also free of N- heterocycles.
Embodiment 2
Blue or green perfume spices
The third composition for reducing stench is included for the spice mixt (embodiment 3) of blue or green fragrant spices.Embodiment 3 includes
High odour value material ((log10OV) it is greater than about 5.5).Embodiment 3 also comprising at least one N- heterocycles (BIGARYL with
ZINARINE)。
Embodiment 3
Blue or green perfume spices
Embodiment 1-3 flavor compositions are evaluated by the suitable member of a group, for example, 6 professional group members,
They live through training and reduce scoring to ammonia odor to reduce the grade being classified and based on table 1 to ammonia odor.
Table 1
Method of testing
Following method of testings and equipment can be used for the embodiment for testing the disclosure.
Product comprising embodiment 1-3 is put into inside permanent hair color as described below with 0.7% and evaluated.
Permanent hair color is as follows：
A phases
B phases
C phases
The LCW silica dimethyl silylation compounds 1.00 of COVASILIC 15
D phases
TRIETHANOLAMINE BASF triethanolamine qsp pH=8 (4.5%)
E phases
F phases
Spices Qi Huadun spices 0.50
Method：
- A and B phases are heated at 80 DEG C and under stirring respectively.
- C phases are added in B phases under agitation.
- A phases are added in B phases under agitation.
- cooling at 40 DEG C is maintained at, adjust pH with D phases.
- and then sequentially add the raw materials of E phases.
It is primarily based on 40ml glass jars bottle and evaluates the product.Cylinder bottle is kept open 30 seconds, to balance, then carried out
Evaluate first.The second assessment enters when mixing permanent hair color product with isometric 20 volumes of hydrogenperoxide steam generator
OK.The cylinder of mixture of group member's records appraisal comprising single hair dye product and subsequent hydrogen peroxide and hair dye product
The ammonia sense of discomfort being directly perceptible when bottle or alms bowl.
It hereafter have recorded the result (table 2) comprising 6% with two kinds of different products of 14% ammonium hydroxide respectively.Result is remembered
Record the average value scored for group member.
Table 2
The composition of 4th kind of reduction stench is included for the spice mixt (embodiment 4) of orange blade profile spices.Embodiment 4 is wrapped
Include high odour value material ((log10OV) it is greater than about 5.5).Embodiment 4 also includes at least one N- heterocycles (BIGARYL).
Embodiment 4
Product comprising embodiment 4 is put into 0.7% and prepares the hair dye provided above by with 14% ammonium hydroxide
In and by a group based on the grade evaluation in table 1.It is primarily based on 40ml glass jars bottle and evaluates the product.Cylinder bottle is kept
It is open 30 seconds, to balance, then evaluated first.The second assessment mixing permanent hair color product with it is isometric
Carried out during hydrogenperoxide steam generator.Ammonia sense of discomfort is recorded as 2.0 by the group after having identical ideas.
Size disclosed herein and numerical value are understood not to be limited strictly to described exact numerical values recited.And unless otherwise
Specify, otherwise expected each such size is all referring to described value and the functionally equivalent scope around the numerical value.For example,
It is expected that the size for being disclosed as " 40mm " refers to " about 40mm ".
Although example and describe specific embodiments of the present invention, those skilled in the art it is clear that
Various other changes and modification can be being carried out without departing from the spirit and scope of the present invention.Therefore, it is contemplated that pending power
Profit covers all such changes and modification in requiring, they belong to the scope of the present invention.
Claims (19)
1. the composition of stench is reduced, comprising：
Spice mixt, it includes the material of (a) at least one reduction smell；It is at least one to be selected from aromatics N- heterocycle portion (b)
Point and N, S- heterocyclic moiety N- heterocycles；
Wherein described at least one material for reducing smell shows odour value (OV), the odour value (OV) have it is general with
Ten be the logarithm (log at bottom10OV 5.5) are greater than about.
2. the composition of the reduction stench of claim 1, wherein the material for reducing smell is to account for the spice mixt weight
The level of amount at least about 0.0001% is present.
3. the composition of the reduction stench of claim 1, wherein the material for reducing smell is to account for the spice mixt weight
The level of amount at least about 1.0% is present.
4. the composition of the reduction stench of claim 1, wherein the spice mixt is to account for the malodor control compositions weight
The about 0.0001%- about 99% of amount amount is present.
5. the composition of the reduction stench of claim 1, wherein the material for reducing smell shows the μ of about 0.001- about 160
G/L threshold odour number.
6. the composition of the reduction stench of claim 1, wherein the material for reducing smell shows about 0.1- about 100,000
μ g/L standard equilibration headspace concentration
7. the composition of the reduction stench of claim 1, wherein the N- heterocycles show odour value (OV), the odour value
(OV) the general denary logarithm (log having10OV 5.5) are greater than about.
8. the composition of the reduction stench of claim 1, wherein the N- heterocycles are selected from 8- (sec-butyl) -5,6,7,8- tetrahydrochysenes
Quinoline) and 2- (2,4- Dimethylcyclohexyls) pyridine).
9. the composition of the reduction stench of claim 1, wherein the material for reducing smell is selected from saturated alkyl aldehydes, insatiable hunger
With alkyl aldehyde, aromatics aldehydes, Glycolic acid esters, alcohols, the fragrance component of sulfur-bearing, benzo dioxaClass, ketone, epoxidation
Thing, furans, pyran, phenols, phenolic ester class, aromatics ethers, esters, lactone, Anthranilate class, carboxylic acids, terpene
Class, hydro carbons and its mixture.
10. claim 9 reduction stench composition, wherein the saturated alkyl aldehydes be selected from aldehyde C-12mna and
Calypsone。
11. claim 9 reduction stench composition, wherein the unsaturated alkyl aldehydes be selected from melonal, ligustral C,
Shisolia and Marseille aldehyde.
12. the composition of the reduction stench of claim 9, wherein the alcohols is selected from linalool, nonadienol -2,6, nonene
Alcohol -6- is cis, polysantalol, 2,6- dimethyl enanthol and hexenol -3- are cis.
13. the composition of the reduction stench of claim 9, wherein the fragrance component of the sulfur-bearing is Anjeruk.
14. the composition of the reduction stench of claim 9, wherein the benzo dioxaClass is selected from watermelon ketone and aurones.
15. claim 9 reduction stench composition, wherein the ketone be selected from L-CARVONE, the fluffy ketone of lattice,
Irisantheme, Nerolione, pharaone, irisone α, irisone β and dihydro jasmone.
16. the composition of the reduction stench of claim 9, wherein the esters are selected from acetic acid hexene ester, cis -3, enyl propionic acid
Ester, cis -3 and aminomethyl phenyl acetic acid esters.
17. the composition of the reduction stench of claim 1, wherein the material for reducing smell shows the (μ of about 0.01- about 100
G/L odor detection threshold (ODT)i)。
18. the consumer goods, comprising：
(a) spice mixt, it includes the material of (i) at least one reduction smell；(ii) at least one is miscellaneous selected from aromatics N-
The N- heterocycles of loop section and N, S- heterocyclic moiety；With
(b) component based on nitrogen selected from ammonia, the amine of substitution and its mixture；
Wherein described at least one material for reducing smell shows odour value (OV), the odour value (OV) have it is general with
Ten be the logarithm (log at bottom10OV 5.5) are greater than about.
19. hair coloring preparation composition, comprising：
(a) spice mixt, it includes the material of (i) at least one reduction smell；(ii) at least one is miscellaneous selected from aromatics N-
The N- heterocycles of loop section and N, S- heterocyclic moiety；With
(b) component based on nitrogen selected from ammonia, the amine of substitution and its mixture；
Wherein described at least one material for reducing smell is shown：Odour value (OV), it is general that the odour value (OV) has
Denary logarithm (log10OV 5.5) are greater than about；About 0.001- about 160 (μ g/L) odor detection threshold (ODTi)；Peace treaty
0.1- about 100,000 (μ g/L) standard equilibration headspace concentration
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14290307.9 | 2014-10-14 | ||
| EP14290307 | 2014-10-14 | ||
| PCT/EP2015/051047 WO2016058710A1 (en) | 2014-10-14 | 2015-01-21 | Malodor reducing compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107072911A true CN107072911A (en) | 2017-08-18 |
| CN107072911B CN107072911B (en) | 2020-12-29 |
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| CN201580052656.0A Active CN107072911B (en) | 2014-10-14 | 2015-01-21 | Malodor reducing compositions |
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| EP (1) | EP3206660B1 (en) |
| JP (1) | JP6742305B2 (en) |
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| CN (1) | CN107072911B (en) |
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| MX (2) | MX2017003343A (en) |
| WO (1) | WO2016058710A1 (en) |
| ZA (1) | ZA201701647B (en) |
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| CN111432851A (en) * | 2017-11-22 | 2020-07-17 | 弗门尼舍有限公司 | Use of volatile ingredients to limit or eliminate perception of malodour |
| CN111918678A (en) * | 2018-03-29 | 2020-11-10 | 山本香料株式会社 | Odor conversion agent for kitchen waste and odor conversion method for kitchen waste |
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| JP6404266B2 (en) * | 2016-05-27 | 2018-10-10 | 山本香料株式会社 | Odor modulating agent and odor modulating method |
| EP3290086B1 (en) * | 2016-09-06 | 2022-07-27 | Wella Operations US, LLC | Gel network hair treatment compositions with reduced odour |
| EP3290085A1 (en) | 2016-09-06 | 2018-03-07 | Noxell Corporation | Hair colouring or bleaching composition with reduced odour |
| GB201615581D0 (en) * | 2016-09-14 | 2016-10-26 | Givauden Sa | Improvements in or relating to organic compounds |
| FR3063908B1 (en) | 2017-03-17 | 2021-07-30 | Jafer Entpr R&D Sl | USE OF A COMPOSITION CONTAINING 1,8-PARA-MENTHENETHIOL AND 3-MERCAPTOHEXYL ACETATE AS AN ODOR MASKER |
| KR102486015B1 (en) | 2018-04-06 | 2023-01-05 | 주식회사 엘지생활건강 | Composition with excellent activity to remove offensive odor and method to remove offensive odor by using the same |
| CN117999057A (en) * | 2021-10-20 | 2024-05-07 | 弗门尼舍有限公司 | Improved perfume compositions comprising sulfur-containing fragrance precursor compounds |
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Also Published As
| Publication number | Publication date |
|---|---|
| JP6742305B2 (en) | 2020-08-19 |
| CN107072911B (en) | 2020-12-29 |
| ZA201701647B (en) | 2018-05-30 |
| BR112017006180B1 (en) | 2020-11-17 |
| MX2017003343A (en) | 2017-06-21 |
| JP2017533745A (en) | 2017-11-16 |
| BR112017006180A2 (en) | 2017-12-26 |
| US20170290757A1 (en) | 2017-10-12 |
| US11103435B2 (en) | 2021-08-31 |
| KR20170066420A (en) | 2017-06-14 |
| EP3206660A1 (en) | 2017-08-23 |
| MX2020001969A (en) | 2020-03-24 |
| EP3206660B1 (en) | 2021-03-31 |
| WO2016058710A1 (en) | 2016-04-21 |
| KR102342562B1 (en) | 2021-12-23 |
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