CN107059471A - Anion paper pulp and its anion paper being made up of the paper pulp - Google Patents
Anion paper pulp and its anion paper being made up of the paper pulp Download PDFInfo
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- CN107059471A CN107059471A CN201710164387.8A CN201710164387A CN107059471A CN 107059471 A CN107059471 A CN 107059471A CN 201710164387 A CN201710164387 A CN 201710164387A CN 107059471 A CN107059471 A CN 107059471A
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- anion
- starch
- paper pulp
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
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Abstract
The invention belongs to field of papermaking, it is related to a kind of anion paper pulp and its anion paper being made up of the paper pulp.It solve the existing paper added with anionic additive can not sustained release anion, and the technical problem of quality problems easily occurs for paper quality itself.Anion starch is added with anion paper pulp of the present invention.Paper obtained by the present invention has release high-concentration anion steady in a long-term, emitting far-infrared, purification air, bactericidal, and do not influence into the advantage of paper quality itself, negative ion release paper is used for a long time, can further exciting human cell activity, promote blood circulation of human body and metabolism.
Description
Technical field
The invention belongs to field of papermaking, it is related to a kind of anion paper pulp and its anion paper being made up of the paper pulp.
Background technology
Anion has passed through clinical real for domestic and international medical field expert to the health, longevity and ecological significant impact of people
Trample and verified.Contemporary science has opened bioelectric secret, and each cell of organism is exactly in a micro cell, cell membrane
There is 50-90mv potential difference outside, if " cell battery " cannot get sufficient electric charge supplement, the electric process of body is difficult to continue
Maintain, thus have influence on the normal activity of body, produce aging and early ageing.
Few place is polluted in forest, beach, waterfall, countryside etc., containing substantial amounts of anion air, its concentration is pollution
Serious urban hundred times, herein people can feel with fresh air, breathe happy, relaxation and happiness, it is relaxing, here it is many
The effect that many anion airs are produced.Therefore anion air is referred to as " long-lived element " or " air vitamin " by people.
In medical field, it is the effective means with germ and purification air is killed that anion, which is identified,.Its mechanism mainly exists
After anion is combined with bacterium, bacterium is produced the change of structure or the transfer of energy, cause bacterial death, most final decline is sunken to
Ground.Medical research shows that electronegative particulate makes oxygen content increase in blood in air, is conducive to blood oxygen conveying, absorbs and profit
With with human metabolism is promoted, raising human immunological competence strengthens human body flesh energy, the effect of regulation body function balance.
According to textual criticism, anion is to 7 systems of human body, and nearly more than 30 kinds of diseases, which have, to be suppressed, alleviates and auxiliary therapeutic action, especially to human body
Health-care effect become apparent.Medical research shows that the anion number of maintenance health of people is:1000-2000/cm3, and all
The anion number of city house enclosed area is only:40-50/cm3, body physiological obstacle such as god can be induced in such a case for a long time
Decline through weak, easily tired, resistance etc..
Traditional anion manufacturing process is that anionic additive is added into mixed pulp, for example, Chinese invention patent Shen
It please disclose a kind of anion paper and its preparation technology [application number:200810006931.7], this application is mixed with negative in paper pulp
Ionic additive, obtained paper also has the function of certain release anion, but it still has anion burst size few,
Effective release time is short, and the technical problems such as quality problems easily occur for paper quality itself.
The content of the invention
Regarding the issue above, the present invention provides a kind of anion paper pulp and preparation method thereof.It is above-mentioned to reach
Purpose, present invention employs following technical proposal:A kind of anion paper pulp, wherein added with anion starch.
In above-mentioned anion paper pulp, described anion paper pulp is made using following methods, and shallow lake is put into agitator
Powder and water, stir, add anionic additive, after being sufficiently stirred for obtain anion starch, the anion starch spray into
Anion paper pulp is obtained in paper pulp.
In above-mentioned anion paper pulp, described starch is native starch or converted starch.
In above-mentioned anion paper pulp, described native starch includes appointing in corn, cassava, wheat and farina
Meaning is one or more of.
In above-mentioned anion paper pulp, described anion starch includes starch, 8- that mass fraction is respectively 70-80 parts
The water of 10 parts of anionic additive and 5-30 part.
In above-mentioned anion paper pulp, the anion starch include mass fraction be respectively 75 parts starch, 9 parts negative
Ionic additive and 18 parts of water.
In above-mentioned anion paper pulp, the percentage by weight of described anion starch in anion paper pulp is 1-2%.
In above-mentioned anion paper pulp, described anionic additive includes ancient extra large sedimentary rock, oyster shell whiting or anion and planted
Any one or a few in thing liquid extract solution.
A kind of anion paper, is made up of above-mentioned anion paper pulp.
In above-mentioned anion paper, the percentage by weight of described anion starch in anion paper is 1.2-10%.
Compared with prior art, the advantage of the invention is that:
1st, the paper obtained by the present invention can it is long-term, effectively discharge high-concentration anion, emitting far-infrared, purification is empty
Gas, bactericidal.The present invention is used for a long time, can further exciting human cell activity, promote blood circulation of human body and newly
Old metabolism.
2nd, the present invention is sprayed into paper pulp again by being mixed into anionic additive into starch in Process of Applying Glue, rather than will
Anionic additive is directly mixed in paper pulp so that obtained anion paper can keep the quality of plain paper in itself, no
The quality problems of paper occur.
Embodiment
Reagent used, unless otherwise specified, can be commercially available from routine biochemistry reagent shop in following embodiments.
Embodiment 1
The present embodiment provides a kind of anionic additive component, specifically, and anionic additive component includes Gu Haichen
Product rock.
Wherein, ancient extra large sedimentary rock is ground to powdered.
Ancient sea sedimentary rock --- sea-gull stone, English name:Health.Main component is CaO, SiO2And variable valency metal Fe;
Internal structure has 20-60nm hole, therefore possesses powerful adsorption function;When moisture in air enters micro- inside sea-gull stone
Kong Shi, hydrone is ionized by the electric microfield for iron generation of being appraised at the current rate, and produces natural negative ion, negative oxygen ion concentration is up to 1700/cm3,
Contain a small amount of TiO inside sea-gull stone simultaneously2, therefore with photoelectrocatalysis effect, the harmful bacteria in air, virus can be killed,
According to experiment, sea-gull stone to staphylococcus aureus, Escherichia coli, Candida albicans, withered grass bacterium antibiotic rate be up to 90% with
On.
One of ancient sea sedimentary rock is opal stone, and also known as Ou Po, opal, classification are noncrystalline, belong to opal bijouterie.Egg
Bai Shi has unique natural nano level microcellular structure, has powerful adsorption function, while discharging natural air anion.
The two of ancient sea sedimentary rock are six ring stones, are created on the Ordovician system (away from modern 200,000,000 4 thousand ten thousand years)., can be certainly with clean structure
So emitting far-infrared, normal emittance is up to 0.88, the biological Electricity Functional for having uniqueness.It is that a kind of adsorptivity is powerful, anti-electromagnetism
Ripple, anti-chemotherapy, antitumor, AIDS virus resisting ancient sedimentary rock, six ring stones are rich in calcium, magnesium, sodium, potassium, iron, selenium, zinc, strontium, copper
And nutrient necessary to the human body such as noble metal germanium, and forever discharge anion.
Three attapulgites of ancient sea sedimentary rock, also known as palygorskite (Palygorskite) or ripple thread thin white silk used in ancient China stone, are a kind of link layer
The clay ore of magnesium silicate containing Shuifu County of shape structure.Because attapulgite clay has unique crystal structure, with good
Caking property and stronger adsorption function, and deodorization, the characteristic of purification.
In the present embodiment, ancient extra large sedimentary rock includes following components:In sea-gull stone, opal stone, six ring stones and attapulgite
Any one and it is several.
Embodiment 2
The present embodiment provides a kind of anionic additive component, specifically, and anionic additive component includes Gu Haichen
Product rock and oyster shell whiting.
Wherein, ancient extra large sedimentary rock be ground to it is powdered be well mixed with oyster shell whiting, the quality of the extra large sedimentary rock of Gu and oyster shell whiting
Than for 1:1.
Oyster shell whiting, is oyster shell whiting pulverized powder, and its 95% main component is calcium carbonate, calcium containing small amounts, oxyphie
The calcified materials such as calcium, itself is again porous fibrous double helix construction structure, has effects that absorption, decomposing formaldehyde, while also can
By the toxic gas in air such as:Benzene, TVOC, ammonia etc. are effectively removed.
Embodiment 3
The present embodiment provides a kind of anionic additive component, specifically, and anionic additive component includes Gu Haichen
Product rock, oyster shell whiting and anion vegetation water extract solution.
Wherein, ancient extra large sedimentary rock be ground to it is powdered be well mixed again with oyster shell whiting and anion vegetation water extract solution, Gu
The mass ratio of extra large sedimentary rock, oyster shell whiting and anion vegetation water extract solution is 1:1:2.
Anion vegetation water extract solution, it refines extract solution by using anion plant source and is made.Specifically, it will make a good deal of money
Set (Pachira macrocarpa), Pistacia weinmannifolia (Pistacia weinmannifolia J.Poisson ex Franch.),
Epipremnum aureum (Epipremnum aureum), kaffir lily (Clivia miniata), Begonia argenteo- guttata (Begoniaargenteo-
Guttata), suede cypress (Chamae-cyparispisifera), rubber tree (Ficus elastica Roxb.ex Hornem),
Bracketplant (Chlorophytumcomosum), wandering jew (Zebrinapendula), sweet osmanthus (Osmanthusfra-grans), south
Red deal (Araucariaheterophylla), schefflera (Scheffleraoctophylla), watermelon peel green pepper grass
(Peperomiasandersii) or any one or a few plant in the bamboo palm (Rhapisexcelsa), high-pressure is passed through
The negative high voltage pulse signal that impulse generator is produced obtains liquid extract solution, then is planted anion is made after extract solution concentration
Thing liquid extract solution.
Specifically imposing the method for negative high voltage pulse signal is:The negative pulse that high-voltage pulse generator is produced passes through end one
In root metal probe, the soil on insertion potted plant periphery.The circuit of the high-voltage pulse generator is closed by room micronic dust,
Generator is grounded in itself.There are reliable high voltage insulating materials between flowerpot and ground.
Embodiment 4
The present embodiment provides a kind of anion starch component, specifically, and anion starch component includes starch, embodiment
1-3 any one anionic additive and water.
Wherein, 10 parts of anionic additives and 5 parts of water are added into 70 parts of starch, is well mixed, obtains anion starch.
Embodiment 5
The present embodiment provides a kind of anion starch component, specifically, and anion starch component includes starch, embodiment
1-3 any one anionic additive and water.
Wherein, 8 parts of anionic additives and 30 parts of water are added into 80 parts of starch, is well mixed, obtains anion starch.
Embodiment 6
The present embodiment provides a kind of anion starch component, specifically, and anion starch component includes starch, embodiment
1-3 any one anionic additive and water.
Wherein, 9 parts of anionic additives and 18 parts of water are added into 75 parts of starch, is well mixed, obtains anion starch.
Embodiment 7
The present embodiment provides a kind of anion starch component, specifically, and anion starch component includes starch, embodiment
1-3 any one anionic additive and water.
Wherein, 8 parts of anionic additives and 12 parts of water are added into 80 parts of starch, is well mixed, obtains anion starch.
Embodiment 8
The present embodiment provides a kind of anion starch component, specifically, and anion starch component includes starch, embodiment
1-3 any one anionic additive and water.
Wherein, 10 parts of anionic additives and 10 parts of water are added into 80 parts of starch, is well mixed, obtains anion starch.
Embodiment 9
The present embodiment provides a kind of anion starch component, specifically, and anion starch component includes starch, embodiment
1-3 any one anionic additive and water.
Wherein, 8 parts of anionic additives and 22 parts of water are added into 70 parts of starch, is well mixed, obtains anion starch.
Embodiment 10
The present embodiment provides a kind of anion starch component, specifically, and anion starch component includes starch, embodiment
1-3 any one anionic additive and water.
Wherein, 10 parts of anionic additives and 20 parts of water are added into 70 parts of starch, is well mixed, obtains anion starch.
Embodiment 11
The present embodiment provides a kind of anion starch, and it constitutes the anion starch that component is embodiment 4-10 any one
Component.
Wherein starch is cornstarch.
Embodiment 12
The present embodiment provides a kind of anion starch, and it constitutes the anion starch that component is embodiment 4-10 any one
Component.
Wherein starch is the mixture of cornstarch and tapioca, and the mass ratio of cornstarch and tapioca is 1:1.
Embodiment 13
The present embodiment provides a kind of anion starch, and it constitutes the anion starch that component is embodiment 4-10 any one
Component.
Wherein starch is the mixture of cornstarch, tapioca and wheaten starch, cornstarch, tapioca and wheat
The mass ratio of starch is 1:1:1.
Embodiment 14
The present embodiment provides a kind of anion starch, and it constitutes the anion starch that component is embodiment 4-10 any one
Component.
Wherein starch is the mixture of cornstarch, tapioca, wheaten starch and farina, cornstarch, wood
The mass ratio of sweet potato starch, wheaten starch and farina is 1:1:1:1.
Embodiment 15
The present embodiment provides a kind of anion starch, and it constitutes the anion starch that component is embodiment 4-10 any one
Component.
Wherein starch is corn grafting starch.
Embodiment 16
The present embodiment provides a kind of anion pulp compositions, specifically, including embodiment 4-15 any one anions
Starch and paper pulp.
Wherein, percentage by weight of the anion starch in anion paper pulp is 1%.Made with the anion paper pulp by existing
Paper technique productions day common paper, obtains a kind of anion paper.
Embodiment 17
The present embodiment provides a kind of anion pulp compositions, specifically, including embodiment 4-15 any one anions
Starch and paper pulp.
Wherein, percentage by weight of the anion starch in anion paper pulp is 2%.Made with the anion paper pulp by existing
Paper technique productions day common paper, obtains a kind of anion paper.
Embodiment 18
The present embodiment provides a kind of anion pulp compositions, specifically, including embodiment 4-15 any one anions
Starch and paper pulp.
Wherein, percentage by weight of the anion starch in anion paper pulp is 1.5%.With the anion paper pulp by existing
Paper technology produces day common paper, obtains a kind of anion paper.
Embodiment 19
The present embodiment provides a kind of anion paper, and specifically, it is by embodiment 16-18 any one anion paper pulp systems
.
Wherein percentage by weight of the anion starch in anion paper is 1.2%.
Embodiment 20
The present embodiment provides a kind of anion paper, and specifically, it is by embodiment 16-18 any one anion paper pulp systems
.
Wherein percentage by weight of the anion starch in anion paper is 10%.
Embodiment 21
The present embodiment provides a kind of anion paper, and specifically, it is by embodiment 16-18 any one anion paper pulp systems
.
Wherein percentage by weight of the anion starch in anion paper is 5.6%.
Embodiment 22
A kind of anion paper pulp is present embodiments provided, is obtained by following methods, specifically, is comprised the following steps:
Step one:Fresh maize germ is taken, it is 14% to measure the aqueous mass fraction of maize germ, is cleaned, and is removed
The mechanical admixtures such as sandstone soil;
Step 2:Maize germ is put into the sulfurous aqueous acid that mass fraction is 0.5% to impregnate;
Step 3:After fully extracting, remaining solid is made corn and formed sediment by broken, sieving, precipitation, dry, levigate process
Powder is standby;
Step 4:Cornstarch is added into agitator;
Step 5:Water is added into agitator, is stirred 10 minutes;
Step 6:Anionic additive is added into agitator again, is sufficiently stirred for obtaining corn anion starch after mixing.
Step 7:Corn anion starch is sprayed and obtains anion paper pulp into paper pulp.
Anionic additive is any one or a few of embodiment 1-3, and the production method of paper pulp is compared with each of technology
Paper pulp is planted, here is omitted.
Wherein, in step one to six, the parts by weight of cornstarch, anionic additive and water are respectively 70-80 parts,
8-10 parts and 5-30 parts, can the addition of its reclaimed water be taken the circumstances into consideration to be added portionwise depending on stir, and is added water in starch as common knowledge,
The present embodiment does not do the restriction specifically matched, as long as can stir.
In step 7, spray corn anion starch can use commercially available spray thrower, or using artificial spray, to reach
Mixed uniformly effect.
Embodiment 23
A kind of anion paper pulp is present embodiments provided, substantially the same manner as Example 22, difference is, including following
Step:
Step one:Fresh maize germ is taken, it is 9% to measure the aqueous mass fraction of maize germ, cleans, goes to remove sand
The mechanical admixtures such as stone soil;
Step 2:Maize germ is put into the sulfurous aqueous acid that mass fraction is 0.2% to impregnate;
Step 3:After fully extracting, remaining solid is made corn and formed sediment by broken, sieving, precipitation, dry, levigate process
Powder is standby;
Step 4:Cornstarch is added into agitator;
Step 5:Water is added into agitator, is stirred 20 minutes;
Step 6:Anionic additive is added into agitator again, is sufficiently stirred for obtaining corn anion starch after mixing.
Step 7:Corn anion starch is sprayed and obtains anion paper pulp into paper pulp.
Embodiment 24
A kind of anion paper pulp is present embodiments provided, it is substantially the same manner as Example 22, comprise the following steps:
Step one:Fresh maize germ is taken, it is 12% to measure the aqueous mass fraction of maize germ, is cleaned, and is removed
The mechanical admixtures such as sandstone soil;
Step 2:Maize germ is put into the sulfurous aqueous acid that mass fraction is 0.3% to impregnate;
Step 3:After fully extracting, remaining solid is made corn and formed sediment by broken, sieving, precipitation, dry, levigate process
Powder is standby;
Step 4:Cornstarch is added into agitator;
Step 5:Water is added into agitator, is stirred 15 minutes;
Step 6:Anionic additive is added into agitator again, is sufficiently stirred for obtaining corn anion starch after mixing.
Step 7:Corn anion starch is sprayed and obtains anion paper pulp into paper pulp.
Application examples 1
In Example 7-10 each portion of anion starch, the paper pulp that 65 times of quality are sprayed respectively, anion is made
Paper 1, anion paper 2, anion paper 3 and anion paper 4.5 identical close test casees are taken, chamber 1-5 (about 1m are named as
× 1m × 1m), take anion paper 1, anion paper 2, anion paper 3, anion paper 4 and each 60g of plain paper to be respectively put into 1-5
In number chamber.After 12 hours, negative ion concentration and radiation dose rate in measurement chamber measure result as follows:
Interpretation of result:By 1, the experimental data of 2,3, No. 4 experimental boxs compares respectively at the experimental data of No. 5 experimental boxs can
To learn, it placed the negative ion concentration in the experimental box of anion paper and be significantly higher than bearing in the experimental box that placed common paper
Ion concentration, therefore the present invention has the function of release high-concentration anion;Next placed the radiation in the experimental box of anion paper
Radiation dose rate in close rate and the experimental box that placed common paper is essentially identical, the safety value far below national regulation,
Therefore will not produce the healthy factor of new threat user using this anion paper.
Negative ion concentration detects negative ion concentration detection of the data from Shanghai Anna Environmental Protection Technology Co., Ltd's production difficult to understand
Instrument;Amount of radiation detects far-infrared radiation detector of the data from Jining Luke Testing Equipment Co., Ltd..
Above numerical value, by using the instrument, parallel three experiments are averaged, each Therapy lasted detection 500
Second.
Specific embodiment described herein is only to spirit explanation for example of the invention.Technology neck belonging to of the invention
The technical staff in domain can be made various modifications or supplement to described specific embodiment or be replaced using similar mode
Generation, but without departing from the spiritual of the present invention or surmount scope defined in appended claims.
Claims (10)
1. a kind of anion paper pulp, it is characterised in that:Anion starch is added with this anion paper pulp.
2. anion paper pulp according to claim 1, it is characterised in that described anion paper pulp uses following methods system
, starch and water are put into agitator, is stirred, anionic additive is added, anion starch is obtained after being sufficiently stirred for,
The anion starch, which is sprayed, obtains anion paper pulp in paper pulp.
3. anion paper pulp according to claim 2, it is characterised in that described starch is that native starch or denaturation are formed sediment
Powder.
4. anion paper pulp according to claim 3, it is characterised in that described native starch includes corn, cassava, small
Any one or a few in wheat and farina.
5. anion paper pulp according to claim 1, it is characterised in that described anion starch includes mass fraction point
Starch, 8-10 parts of anionic additive and 5-30 parts of water that Wei be 70-80 parts.
6. anion paper pulp according to claim 5, it is characterised in that the anion starch is distinguished including mass fraction
For 75 parts of starch, 9 parts of anionic additive and 18 parts of water.
7. anion paper pulp according to claim 1, it is characterised in that described anion starch is in anion paper pulp
Percentage by weight be 1-2%.
8. anion paper pulp according to claim 2, it is characterised in that described anionic additive includes ancient sea deposition
Any one or a few in rock, oyster shell whiting or anion vegetation water extract solution.
9. a kind of anion paper, is made up of the anion paper pulp described in claim 1-8.
10. anion paper according to claim 9, it is characterised in that described anion starch is in anion paper
Percentage by weight is 1.2-10%.
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Cited By (1)
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CN108999032A (en) * | 2018-09-07 | 2018-12-14 | 宿州学院 | A kind of preparation method of modified plant fibers filter paper |
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SE526112C2 (en) * | 2003-11-27 | 2005-07-05 | Sveriges Staerkelseproduct Foe | Preparation of semi dry anionic starch, by reacting with alkali metal salt of 3-chloro-2-hydroxypropyl sulfonate or 2,3-epoxypropyl sulfonate in presence of alkali catalyst |
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Application publication date: 20170818 |
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