CN107057515A - A kind of red lead phenolic aldehyde protective paint coating - Google Patents
A kind of red lead phenolic aldehyde protective paint coating Download PDFInfo
- Publication number
- CN107057515A CN107057515A CN201710440658.8A CN201710440658A CN107057515A CN 107057515 A CN107057515 A CN 107057515A CN 201710440658 A CN201710440658 A CN 201710440658A CN 107057515 A CN107057515 A CN 107057515A
- Authority
- CN
- China
- Prior art keywords
- red lead
- phenolic aldehyde
- protective paint
- aldehyde protective
- paint coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C09D161/14—Modified phenol-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2234—Oxides; Hydroxides of metals of lead
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
Abstract
The invention discloses a kind of red lead phenolic aldehyde protective paint coating, the invention belongs to chemical technology field, its formula is characterized in：It is made up of long oil rosin modified phenolic resin, red lead, dibutyl tin laurate, toluene, fine titanium dioxide powder, ultra-fine lignite wax micro mist, barium sulfate, diolein, triethanolamine.The finished product of the present invention can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing and ship, bridge, the surface of all kinds of outdoor indoor hardware equipment, be the coating that its work is protected.The present invention has micron order and the dual coarse structure of nanoscale simultaneously, so just having the super-hydrophobic self-cleaning function of lotus leaf effect, after product using the present invention, the surface long term of object need not manually be cleaned and returned newly from overcoating brush, save substantial amounts of manpower and materials, simultaneously also do not corroded by wind and rain, the service life of 3 times of common red lead phenolic aldehyde protective paints, strictly a kind of service life for a long time and excellent performance super-hydrophobic red lead phenolic aldehyde protective paint coating.
Description
Technical field
The invention belongs to chemical field, the present invention relates to a kind of protective paint coating, and in particular to be a kind of red lead phenolic aldehyde
Protective paint coating.
Background technology
Red lead phenolic aldehyde protective paint coating is that one kind can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing, ship
The protective coating for the structure such as the anti-planktonic organism in bottom, deck be anti-wear.But the red lead phenolic aldehyde of prior art protection lacquer coat does not have
There is hydrophobic self-cleaning function, manually to clean and be returned newly from overcoating brush in short term, service life is not long, wastes manpower and materials.
The content of invention
The purpose of the present invention is：There is provided it is a kind of there is self-cleaning function, need not manually clean for a long time and from overcoating brush return newly,
A large amount of manpower and materials can be saved, not by erosion by wind and rain, service life is permanent and super-hydrophobic red lead phenolic aldehyde protective paint of excellent performance
Coating.
To achieve the above object, the technical solution adopted in the present invention is a kind of red lead phenolic aldehyde protective paint coating, and it is formulated
It is characterized in：By long oil rosin modified phenolic resin, red lead, dibutyl tin laurate, toluene, fine titanium dioxide powder
(0.5um~0.85um particle diameters), ultra-fine lignite wax micro mist (18nm~65nm particle diameters), barium sulfate, diolein, three ethanol
Amine composition.
The percentage by weight of its component is：
Beneficial effects of the present invention：The present invention is fine titanium dioxide powder (0.5um~0.85um particle diameters), ultra-fine lignite wax
The peptizaiton that micro mist (18nm~65nm particle diameters) is risen by dispersant diolein, is highly dispersed in red lead phenolic aldehyde and prevents
In vernix, distributive law is more than 97%, after the finished product using the present invention, the super-hydrophobic self-cleaning table of paint film formation tool lotus leaf effect
Face, the paint film sample of multiple red lead phenolic aldehyde protective paints is determined with half ball, and the contact angle of its paint film sample and water is at 150 °
More than；Moreover, the observation that sample is carried out by using electron microscope, finds its surface while having micron order and nanoscale dual
Coarse structure.The present invention finished product can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing and ship, bridge,
The surface of all kinds of outdoor indoor hardware equipment, makes the surface of object have the super-hydrophobic self-cleaning function of lotus leaf effect, can for a long time not
Need artificial cleaning and returned newly from overcoating brush, save substantial amounts of manpower and materials, and do not corroded by wind and rain, 3 times common
The service life of red lead phenolic aldehyde protective paint, is that a kind of service life is permanent and super-hydrophobic red lead phenolic aldehyde protective paint of excellent performance is applied
Material.
Embodiment
The following examples are that the present invention is made further to prove, the invention is not restricted to this.
Embodiment one
A kind of red lead phenolic aldehyde protective paint coating, its component and weight proportion are as follows：
Embodiment two
A kind of red lead phenolic aldehyde protective paint coating, its component and weight proportion are as follows：
Embodiment three
A kind of red lead phenolic aldehyde protective paint coating, its component and weight proportion are as follows：
Finished product obtained by the three above embodiment of the present invention is respectively coated on three pieces of slides, surveyed with half ball
The contact angle of fixed these three samples and water：
1st, the contact angle of the slide sample of embodiment one and water is 151.2 °
2nd, the contact angle of the slide sample of embodiment two and water is 153.1 °
3rd, the contact angle of the slide sample of embodiment three and water is 152.3 °
The sample of three above embodiment is determined with half ball, finished product its surface wettability of the present invention is all showed
For superhydrophobic characteristic.
A kind of red lead phenolic aldehyde protective paint coating of the present invention, applies in western district of Guangdong, Duo Jia advertising companies has been supplied, at it
Used on the surface of outdoor large advertisement metal structure skeleton；Made comparisons with common ethene protective paint, product institute of the invention
Super-hydrophobic self-cleaning function with lotus leaf effect, makes the surface of metal structure not by erosion by wind and rain, and permanent light is such as new, saves
Substantial amounts of manpower and materials, product of the invention has the service life of 3 times of common red lead phenolic aldehyde protective paints, and strictly one kind is used
Life-span is permanent and super-hydrophobic red lead phenolic aldehyde protective paint coating of excellent performance.
Claims (2)
1. a kind of red lead phenolic aldehyde protective paint coating, it is characterised in that：The percentage by weight of the formula each component is：Long oil rosin
Phenol-formaldehyde resin modified 40%--52%, red lead 7%--23%, dibutyl tin laurate 5%--24%, toluene 18%--
28%th, fine titanium dioxide powder 5%--25%, ultra-fine lignite wax micro mist 4%--26%, barium sulfate 3%--22%, the oleic acid of glycerine two
Ester 4%--24%, triethanolamine 2%--23%.
2. a kind of red lead phenolic aldehyde protective paint coating according to claim 1, it is characterized in that：Fine titanium dioxide powder 0.5um
~0.85um particle diameters, ultra-fine lignite wax micro mist 18nm~65nm particle diameters, the scattered work risen by dispersant diolein
With being highly dispersed in red lead phenolic aldehyde protective paint, distributive law is more than 97%, using after this finished product, paint film formation tool lotus leaf effect
The super-hydrophobic self-cleaning surface answered, the paint film sample of multiple red lead phenolic aldehyde protective paints is determined with half ball, its paint film sample and water
Contact angle more than 150 °.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710440658.8A CN107057515A (en) | 2017-06-01 | 2017-06-01 | A kind of red lead phenolic aldehyde protective paint coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710440658.8A CN107057515A (en) | 2017-06-01 | 2017-06-01 | A kind of red lead phenolic aldehyde protective paint coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107057515A true CN107057515A (en) | 2017-08-18 |
Family
ID=59595442
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710440658.8A Pending CN107057515A (en) | 2017-06-01 | 2017-06-01 | A kind of red lead phenolic aldehyde protective paint coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107057515A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408990A (en) * | 2013-08-14 | 2013-11-27 | 东莞市明天纳米科技有限公司 | Nanoparticle super-hydrophobic self-cleaning wall paint and preparation method thereof |
| CN103409028A (en) * | 2013-07-29 | 2013-11-27 | 复旦大学 | Photocatalytic type self-repairing super-hydrophobic coating and preparation method thereof |
| CN104592853A (en) * | 2014-12-10 | 2015-05-06 | 成都拜迪新材料有限公司 | Preparation method for water-based phenolic red lead rusted antirust primer |
-
2017
- 2017-06-01 CN CN201710440658.8A patent/CN107057515A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103409028A (en) * | 2013-07-29 | 2013-11-27 | 复旦大学 | Photocatalytic type self-repairing super-hydrophobic coating and preparation method thereof |
| CN103408990A (en) * | 2013-08-14 | 2013-11-27 | 东莞市明天纳米科技有限公司 | Nanoparticle super-hydrophobic self-cleaning wall paint and preparation method thereof |
| CN104592853A (en) * | 2014-12-10 | 2015-05-06 | 成都拜迪新材料有限公司 | Preparation method for water-based phenolic red lead rusted antirust primer |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20170818 |