CN107057476A - A kind of multi-functional chlorinated rubber deck of ship paint - Google Patents

A kind of multi-functional chlorinated rubber deck of ship paint Download PDF

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Publication number
CN107057476A
CN107057476A CN201710465360.2A CN201710465360A CN107057476A CN 107057476 A CN107057476 A CN 107057476A CN 201710465360 A CN201710465360 A CN 201710465360A CN 107057476 A CN107057476 A CN 107057476A
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CN
China
Prior art keywords
paint
chlorinated rubber
resin
deck
pla
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Pending
Application number
CN201710465360.2A
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Chinese (zh)
Inventor
王欣
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Individual
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Individual
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Priority to CN201710465360.2A priority Critical patent/CN107057476A/en
Publication of CN107057476A publication Critical patent/CN107057476A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D115/00—Coating compositions based on rubber derivatives
    • C09D115/02—Rubber derivatives containing halogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of chlorinated rubber deck of ship paint, it is made up of modified chlorinated rubber resin, organic siliconresin, elastic resin, zinc oxide, titanium dioxide, phthalocyanine green, PLA and dimethylbenzene, and the weight ratio of each component is 20 40：5‑20：5‑10：5‑15：15‑30：5‑10：10‑30：5‑10.

Description

A kind of multi-functional chlorinated rubber deck of ship paint
Technical field
The present invention relates to a kind of deck of ship paint, more particularly to a kind of chlorinated rubber deck of ship paint.
Background technology
Deck of ship paint major requirement is water-fast, wear-resisting, sun-proof, people from deck having to priming paint on good adhesive force, ship Member walk about, mechanical cargo transport is very frequent, loading unloading when often collide, therefore deck paint must have good wearability and Abrasion resistance, some domestic deck paint functions are all relatively simple, and wearability is much of that, and retractility is again inadequate, due to deck Paint is long-term all in the scope shined upon, and the temperature at noon is again especially high, and deck paint surface will be because of contractility, and surface is just It can split, so reduce the service life of paint, accelerate the destruction of paint, deepwater steam can be rotten from the gap split Lose on beneath steel plate, cause to paint the corrosion of ground from the inside to surface, accelerate metal rusting etc. to seriously endanger, cause ocean to be transported The massive losses of defeated industry and culture fishery.
Following Chinese patent discloses a variety of deck of ship paints：
But the most direct method that prior art solves deck paint damage is to increase the application thickness of deck paint and frequently repair to apply Dress, substantially takes application in 1 year and repairs once, so add the use of paint, also result in the cost increase of personnel's construction, Also severe contamination ocean.
The content of the invention
All it is single performance, some adhesive force is bad, some elasticity because of the deck of ship paint that current manufacturer produces Bad, what is had is not wear-resisting, having because noon temperature is too high and ftracture across the sea, and such deck paint is often less than 1 year just Again brush once, cause construction cost raising, also pollute ocean.The present invention provides a kind of new deck paint, the deck Paint is made up of a variety of modified resins, by the function of modified resin, is increased the compactness of paint, is prevented vapor, sunlight to oil The permeability and transmittance on surface are painted, increases guarantor's light color retention rate of paint, because elastic resin plays telescopic action in paint, When having the transport vehicle to be travelled on surface, paint can shrink according to the road weight of vehicle, so greatly reduce and ground by vehicle tyre The destruction wiped and caused, adds the life-span of paint, because containing fire resistant resin in paint, and such ship is travelled on ocean, Will not be due to noon sun direct projection, the temperature on deck is too high, and produces cracking phenomena, because PLA is contained in the inside, adds oil The wearability of paint, greatly improves the service life of paint.
The present invention provides a kind of multi-functional chlorinated rubber deck paint, its by modified chlorinated rubber resin, organic siliconresin, Elastic resin, zinc oxide, titanium dioxide, phthalocyanine green, PLA and dimethylbenzene composition, the weight ratio of each component is 20-40：5-20： 5-10：5-15：15-30：5-10：10-30：5-10.
It is preferred that, the weight ratio of each component is 25-35：10-15：10-15：7.5-12.5：20-25：7-8：15-25：7- 8。
Most preferably, the weight ratio of each component is 30：12.5：7.5：10：22.5：7.5：20：7.5.
Its preparation method, step is as follows：
First by modified chlorinated rubber resin, organic siliconresin, elastic resin be added together first it is miscible, then add titanium dioxide and phthalocyanine Green high speed is disperseed, and enters back into grinder grinding, zinc oxide, PLA, 30 points of dimethylbenzene high-speed stirred are added after fineness is qualified Zhong Hou, after examining viscosity qualified, stops stirring, packaging and storage after equitemperature lowers.
Title term of the present invention is explained below：
The paint that deck paint ship deck is used
Modified chlorinated rubber resin is the white powder obtained by natural rubber is after chlorination
Organic siliconresin is the polysiloxane of highly cross-linked network structure
Elastic resin is hydroxyl straight chain alkyd resin
Zinc oxide is a kind of oxide of zinc
Titanium dioxide is titanium dioxide
Phthalocyanine green is coloring pigment
PLA is using lactic acid as main raw polymer
Dimethylbenzene is diluent
The main application of the deck paint of the present invention：Apply in ship deck, the protection of marine steel body panel
The application method of deck paint of the present invention is as follows：
Bung is opened, electricity consumption handle paint stirring is uniform, stirred in the diluent for adding appropriate, placement does 10 minutes, just It can construct, can brush Tu, roller Tu, spray Tu.If film thickness requires too thick, just using without gas blowout Tu.
The multi-functional chlorinated rubber deck paint of the present invention, is made up of a variety of modified resins, by the function of modified resin, Increase the compactness of paint, prevent vapor, sunlight to the permeability and transmittance of painted surface, guarantor's light guarantor's color of increase paint Rate, because elastic resin plays telescopic action in paint, when there is transport vehicle to be travelled on surface, paints traveling of the meeting according to vehicle Weight is shunk, and is so greatly reduced the destruction for being rubbed and being caused by vehicle tyre, the life-span of paint is added, because containing in paint There is fire resistant resin, such ship is travelled on ocean, will not be due to noon sun direct projection, the temperature on deck is too high, and produces Cracking phenomena, because PLA is contained in the inside, adds the wearability of paint, greatly improves the service life of paint.
Hereinafter beneficial effects of the present invention are further illustrated with experimental data：
Recipe determination is tested：
According to the different qualities of material, 4 kinds of formulas are designed：
(1) recipe determination is tested：
According to the different qualities of material, 4 kinds of formulas are designed：
Formula 1 Formula 2 Formula 3 Formula 4
Modified chlorinated rubber resin 20 40 30
Organic siliconresin 5 45 12.5
Elastic resin 10 5 25 7.5
Zinc oxide 5 15 10 10
Titanium dioxide 30 15 5 22.5
Phthalocyanine green 5 10 7.5
PLA 20
Dimethylbenzene 5 10 7.5
Chlorinated rubber resin 30
Silica flour 5 10 5
Acetone 15 10
Screening experiment：
The selection result see the table below：
Formula 1 Formula 2 Formula 3 Formula 4
Viscosity 80KU 80KU 80KU 80KU
Wearability（500g/500r） 100 100 80 60
Salt spray resistance 500 hours 600 hours 600 hours 800 hours
Resistance to salt water 48 hours 72 hours 72 hours 96 hours
Resistance to diesel oil（0# diesel oil） 48 72 72 120
As a result show, be formulated 4 best results.
(2) contrast experiment：
It is the contrast and experiment carried out with prior art below：
As a result show, best results of the present invention.
The present invention and prior art main difference is that, present invention adds PLA, it can play anti-skidding, wear-resisting Effect.
The present invention's has the advantages that, in ocean, because the coating is using modified chlorinated rubber as matrix resin, increase The compactness of paint, prevents the infiltration of sunlight and aqueous vapor, the contractility of paint is added by elastic resin, reduce paint Loss, in addition the paint also have resistant to elevated temperatures function, heatproof can reach surface temperature more than 200 degree, considerably increase paint Service life.
Embodiment：
Following embodiments are used for the formula and preparation technology for illustrating the present invention, but it can not constitute to the scope of the present invention and appoint What is limited.
Embodiment 1
A kind of deck of ship paint, by modified chlorinated rubber resin, organic siliconresin, elastic resin, zinc oxide, titanium dioxide, phthalocyanine Green, PLA and dimethylbenzene composition, the weight ratio of each component is 30：12.5：7.5：10：22.5：7.5：20：7.5.
Its preparation method, step is as follows：
First by modified chlorinated rubber resin, organic siliconresin, elastic resin be added together first it is miscible, then add titanium dioxide and phthalocyanine Green high speed is disperseed, and enters back into grinder grinding, zinc oxide, PLA, 30 points of dimethylbenzene high-speed stirred are added after fineness is qualified Zhong Hou, after examining viscosity qualified, stops stirring, packaging and storage after equitemperature lowers.
Products obtained therefrom is tested by laboratory, meets following technical indicator
Embodiment 2
With modified chlorinated rubber resin：Organic siliconresin：Elastic resin：Zinc oxide：Titanium dioxide：Phthalocyanine green：PLA：Dimethylbenzene =40：5：5：10：20：7：8：5 proportioning, is weighed respectively：Modified chlorinated rubber resin 40kg, organic siliconresin 5kg, elasticity tree Fat 5kg, zinc oxide 10kg, titanium dioxide 20kg, phthalocyanine green 7kg, PLA 8kg, dimethylbenzene 5kg, first by modified chlorinated rubber Resin, organic siliconresin, elastic resin are added together first miscible, then add titanium dioxide and phthalocyanine green scattered at a high speed, enter back into grinding Machine is ground, and zinc oxide, PLA, dimethylbenzene high-speed stirred are added after fineness is qualified after 30 minutes, after examining viscosity qualified, Stop stirring, packaging and storage after equitemperature lowers.
Products obtained therefrom is tested by laboratory, meets following technical indicator
Embodiment 3
With modified chlorinated rubber resin：Organic siliconresin：Elastic resin：Zinc oxide：Titanium dioxide：Phthalocyanine green：PLA：Dimethylbenzene =30：15：5：5：20：7：8：10 proportioning, is weighed respectively：Modified chlorinated rubber resin 30kg, organic siliconresin 15kg, elasticity Resin 5kg, zinc oxide 5kg, titanium dioxide 20kg, phthalocyanine green 7kg, PLA 8kg, dimethylbenzene 10kg, first by modified chlorinated rubber Gum resin, organic siliconresin, elastic resin are added together first miscible, then add titanium dioxide and phthalocyanine green scattered at a high speed, enter back into and grind Grinding machine is ground, and zinc oxide, PLA, dimethylbenzene high-speed stirred are added after fineness is qualified after 30 minutes, through examining viscosity qualified Afterwards, stirring, packaging and storage after equitemperature lowers are stopped.
Products obtained therefrom is tested by laboratory, meets following technical indicator
Embodiment 4
With modified chlorinated rubber resin：Organic siliconresin：Elastic resin：Zinc oxide：Titanium dioxide：Phthalocyanine green：PLA：Dimethylbenzene =25：15：5：5：20：7：13：10 proportioning, is weighed respectively：Modified chlorinated rubber resin 25kg, organic siliconresin 15kg, elasticity Resin 5kg, zinc oxide 5kg, titanium dioxide 20kg, phthalocyanine green 7kg, PLA 13kg, dimethylbenzene 10kg, first by modified chlorinated rubber Gum resin, organic siliconresin, elastic resin are added together first miscible, then add titanium dioxide and phthalocyanine green scattered at a high speed, enter back into and grind Grinding machine is ground, and zinc oxide, PLA, dimethylbenzene high-speed stirred are added after fineness is qualified after 30 minutes, through examining viscosity qualified Afterwards, stirring, packaging and storage after equitemperature lowers are stopped.
Products obtained therefrom is tested by laboratory, meets following technical indicator
Embodiment 5
With modified chlorinated rubber resin：Organic siliconresin：Elastic resin：Zinc oxide：Titanium dioxide：Phthalocyanine green：PLA：Dimethylbenzene =35：10：5：5：16：7：15：7 proportioning, is weighed respectively：Modified chlorinated rubber resin 35kg, organic siliconresin 10kg, elasticity Resin 5kg, zinc oxide 5kg, titanium dioxide 16kg, phthalocyanine green 7kg, PLA 15kg, dimethylbenzene 7kg, first by modified chlorinated rubber Gum resin, organic siliconresin, elastic resin are added together first miscible, then add titanium dioxide and phthalocyanine green scattered at a high speed, enter back into and grind Grinding machine is ground, and zinc oxide, PLA powder, dimethylbenzene high-speed stirred are added after fineness is qualified after 30 minutes, through examining viscosity to close After lattice, stop stirring, packaging and storage after equitemperature lowers.

Claims (2)

1. a kind of chlorinated rubber deck of ship paint, it is characterized in that by modified chlorinated rubber resin, organic siliconresin, elastic resin, Zinc oxide, titanium dioxide, phthalocyanine green, PLA and dimethylbenzene composition, the weight ratio of each component is 20-40：5-20：5-10：5-15： 15-30：5-10：10-30：5-10.
2. the preparation method of the deck of ship paint described in claim 1, it is characterized in that：Methods described step is as follows：
First by modified chlorinated rubber resin, organic siliconresin, elastic resin be added together first it is miscible, then add titanium dioxide and phthalocyanine Green high speed is disperseed, and enters back into grinder grinding, zinc oxide, PLA, 30 points of dimethylbenzene high-speed stirred are added after fineness is qualified Zhong Hou, after examining viscosity qualified, stops stirring, packaging and storage after equitemperature lowers.
CN201710465360.2A 2017-06-19 2017-06-19 A kind of multi-functional chlorinated rubber deck of ship paint Pending CN107057476A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710465360.2A CN107057476A (en) 2017-06-19 2017-06-19 A kind of multi-functional chlorinated rubber deck of ship paint

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CN201710465360.2A CN107057476A (en) 2017-06-19 2017-06-19 A kind of multi-functional chlorinated rubber deck of ship paint

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Publication Number Publication Date
CN107057476A true CN107057476A (en) 2017-08-18

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104946129A (en) * 2015-07-24 2015-09-30 上海海悦涂料有限公司 Polysiloxane heat-reflective topcoat and preparation method thereof
CN105017867A (en) * 2015-07-29 2015-11-04 广西梧州龙鱼漆业有限公司 Ship bottom antirust paint
CN105315796A (en) * 2014-06-23 2016-02-10 天津中油渤星工程科技有限公司 Chlorinated rubber coating used for marine environment and production method
CN105807200A (en) * 2016-05-13 2016-07-27 南京工业大学 Solar cell and electroluminescent device general testing device
CN106118392A (en) * 2016-07-14 2016-11-16 苏州天键衡电子信息科技有限公司 A kind of efficiently hull bottom antibiotic paint and preparation thereof and application process

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105315796A (en) * 2014-06-23 2016-02-10 天津中油渤星工程科技有限公司 Chlorinated rubber coating used for marine environment and production method
CN104946129A (en) * 2015-07-24 2015-09-30 上海海悦涂料有限公司 Polysiloxane heat-reflective topcoat and preparation method thereof
CN105017867A (en) * 2015-07-29 2015-11-04 广西梧州龙鱼漆业有限公司 Ship bottom antirust paint
CN105807200A (en) * 2016-05-13 2016-07-27 南京工业大学 Solar cell and electroluminescent device general testing device
CN106118392A (en) * 2016-07-14 2016-11-16 苏州天键衡电子信息科技有限公司 A kind of efficiently hull bottom antibiotic paint and preparation thereof and application process

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Application publication date: 20170818

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