CN107056458A - Solid waste ecological restoring method and medicament and building, the method for mine solid wastes kind tea tree - Google Patents

Solid waste ecological restoring method and medicament and building, the method for mine solid wastes kind tea tree Download PDF

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Publication number
CN107056458A
CN107056458A CN201710286408.3A CN201710286408A CN107056458A CN 107056458 A CN107056458 A CN 107056458A CN 201710286408 A CN201710286408 A CN 201710286408A CN 107056458 A CN107056458 A CN 107056458A
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parts
solid waste
sulfate
tea tree
innoxious
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许伟琦
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01BSOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
    • A01B79/00Methods for working soil
    • A01B79/02Methods for working soil combined with other agricultural processing, e.g. fertilising, planting
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G17/00Cultivation of hops, vines, fruit trees, or like trees
    • A01G17/005Cultivation methods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B1/00Dumping solid waste
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

Abstract

Field is recycled the present invention relates to the harmless treatment of solid waste, solid waste, and in particular to the innoxious ecological treatment method and reparation medicament of solid waste and the method for planting tea tree with building solid waste, mine solid wastes.A kind of innoxious restoration of the ecosystem agent of solid waste, it is composed of the following components by weight:30 80 parts of urea, 10 50 parts of ammonium nitrate, 100 260 parts of potassium dihydrogen phosphate, 10 20 parts of magnesium sulfate, 5 10 parts of manganese sulfate, 3 10 parts of ferrous sulfate, 38 parts of potassium acid sulfate, 0.3 1 parts of ytterbium nitrate, 5 20 parts of sodium butyrate.It can adjust and stable soil PH, promote growth of tea plant, improve production tea amount;Improve slow release speed and the time of the ability that solid waste fixes nutrient and moisture, regulation nutrient and moisture;Extend the term of validity of nutrient;Influence of the calcium carbonate to tea tree is prevented and treated, tea tree is grown in the building solid waste and Industrial Solid Waste containing large quantities of lime matter.

Description

Solid waste ecological restoring method and medicament and building, the method for mine solid wastes kind tea tree
Technical field
Field is recycled the present invention relates to the harmless treatment of solid waste, solid waste, and in particular to the innoxious ecology of solid waste is repaiied Compound method and renovation agent and the method for planting tea tree with building solid waste, mine solid wastes.
Background technology
Tea tree is liked being grown in mountain region, slope, and illumination is the most important condition of tea tree existence, thus hillside fields is more suitable than Plain Close growth of tea plant.Therefore Tea Production is Hills Important Agricultural pillar industry, is that tea grower shakes off poverty and sets out on the road to prosperity, increases local finance The key industry of income.Tea tree likes warm and moist weather, and growing environment is that soil layer is thick up to more than 1 meter not containing limestone serous, draining Good sand loam, more than content of organic matter 1%-2%, aeration, water penetration or retaining performance are good, acidity-basicity ph value 4.5 ~6.5 are advisable.Orographic condition mainly has height above sea level, hillside fields, slope aspect etc., is typically chosen slope by north preferably.The gradient should not be too big, typically It is required that less than 30 degree.Tea tree do not like it is calcareous, in soil as contain calcium carbonate (active calcium content is more than 0.2%), just have influence on Growth of tea plant, in addition it is gradually dead.
At present, each city modernization construction carry out it is like a raging fire, removed various Old buildings, than as usual bridge, Old highway, aging blocks room, with regard to the various engineering constructions such as factory, generate substantial amounts of building waste.Brick and tile therein, concrete block are all Need after crushing, ability minority is used to regeneration concrete of building the road and produce, a large amount of building solid wastes have to transport from city, It is deposited in the soot of surrounding city, occupies a large amount of soils.Now, country forbids (red using clay brick in urban construction Brick), this clay brick produced when causing a large amount of Old buildings to be removed can not be recycled as materials for wall in city.Fragment of brick, The concrete block that reinforcing bar, cement and stone bond together is even more to be difficult by, and is particularly difficult to biological utilisation.Moreover, because Mixed mud block product is big, and intensity is high, and its is difficult to crush, and actually prior art can not almost be utilized to it.
Resourcization of Mining Solid Waste abbreviation mine solid wastes, refer to exploitation and select the barren rock and mine tailing produced during washup stone.In ore deposit Uncommercial ore body country rock and horsestone produced by the recovery process of mountain are referred to as chats.During ore extraction, Country rock need to be peeled off, barren rock is discharged, the ore adopted also is needed to wash through choosing, upgrade, and discharges mine tailing.Harm to environment:Mining industry Waste is largely stored up, contaminated land, or causes the disasters such as landslide, mud-rock flow;Chip and mine tailing that barren rock weathering is formed, can be by water Wash away and enter waters, be dissolved the water that permeates the ground, air is entered by wind;Have in waste containing the hypertoxic element such as arsenic, cadmium or put Penetrating property element, is directly detrimental to health.Harmless treatment should be carried out to mine wastes, carry out barren rock and mine tailing to eliminate pollution Comprehensive utilization.
The method of processing mine solid wastes is at present:1. hillock, the stable facture in tailingspile:For prevent barren rock and mine tailing by Water washes away and raised and diffusion pollution by wind, can use following stabilization method:
Physical:Sprayed water to fine tailings, covering lime and soil, at the top of bark, rice straw mulching.This method is to copper Mine tailing is maximally efficient.Also it can be in the wind to plant windbreak, and be covered with agstone and sodium silicate mixture.
Plant method:Permanent plant is planted on barren rock or tailings stack.Experiment proves that the calcareous tailingspile of Pb-Zn deposits is suitable to Fescue is planted, the acid tailingspile of Pb-Zn deposits is suitable to plantation reed grass.Britain also found that mining area grows a kind of dogstail naturally, There are resistance high metal content and the ability of resistance to low nutrient, good stabilization and protective effect can be played.
Chemical method:Using chemical reactor (cement, lime, sodium metasilicate etc.) that can be with mine tailing chemical combination, in mine tailing surface shape Into consolidation duricrust.This method cost is higher, and some mine tailings often interlock with layer of sand, and chemical reactor is difficult to select.Chemical method can be same Plant method combines processing mine tailing.After sowing vegetable seeds in tailingspile, applying a small amount of chemicals prevents tailingspile loose sand Fly upward, moisture is kept, in favor of plant growth.The states such as Colorado, Michigan, Missouri, the Nevada in the U.S. are effectively Employ this method.
2. land reconversion method:After mining on destroyed soil, backfill after barren rock, mine tailing, settlement stability, put down It is whole, mulching soil, serike, or build house.Flyash ash disposal area, iron and aluminium ore waste-rock yard of Chinese certain areas etc. are Land reconversion is completed, planting plants are developed production.
These building solid wastes and mine solid wastes, they can use as green material application completely, and without crushing.Nearby Roadside greening, afforestation, slope protecting afforestation greening are carried out using solid waste, it is possible to reduce freight, reduce and take up an area, also beautify City, is the environmentally friendly behavior achieved many things at one stroke, also complies with the circular economy concept of sustainable development.Added particularly in some cement Various curing agents, waterproofing agent, curing agent etc., its concrete being made is difficult to reuse, these curing agents, waterproofing agent, solid Agent is irritant to biology, it more difficult to carry out biological utilisation.In the prior art, needed first building solid waste using the technology of solid waste It is ground into particle even powder.This process and its consumption energy, produce water pollution, noise pollution, dust pollution and air dirty Dye, more endangers the health of operating personnel.And disintegrating process needs to use various size reduction machineries, size reduction machinery involves great expense and machine Tool own loss is big, causes that the fund input of disintegrating process is big, mechanical loss is big, energy consumption is big.
In the prior art there is not yet can either handle building solid waste can handle mine solid waste and promote growth of tea plant again Restoration of the ecosystem agent.Solid waste and mine solid waste, which how will be built, is used for Tea Production, turns waste into wealth, can eliminate solid waste garbage mountain Environmental pollution, tea quality and yield can be improved again into technical barrier urgently to be resolved hurrily.Solving the technical barrier can produce Raw great economic benefit and environmental benefit.
The content of the invention
In order to solve above-mentioned deficiency, it is an object of the invention to provide a kind of innoxious restoration of the ecosystem agent of solid waste, containing big The nutrient of amount, is adjusted and stable soil PH, promotes growth of tea plant, improves production tea amount;Improve the energy that solid waste fixes nutrient and moisture Slow release speed and the time of power, regulation nutrient and moisture;Extend the term of validity of nutrient;Eliminate cement hardener, waterproofing agent, solidification Agent is to biological infringement, influence of the preventing and treating calcium activated to tea tree, enable tea tree in the building solid waste containing a large amount of calcium activateds and Grown on Industrial Solid Waste.
It is a further object of the present invention to provide a kind of innoxious ecological restoring method of solid waste, this method is without crushing, tool There are energy-saving and emission-reduction, reduce water pollution, noise pollution, dust pollution and air pollution, turn waste into wealth for ecological afforestation construction.
The method that solid waste, mine solid wastes plant tea tree is built it is a further object of the present invention to provide a kind of, can be by originally Discarded solid waste, garbage mountain are used, and make it have nutrient and moisture slow-release time long, fighting drought ability heat-preservation ventilating ability By force, high-output stress-resistance;Can be with long-term adjustment, stable soil pH value.Solid waste is turned waste into wealth the growth of suitable tea tree, increase production tea Amount, and reduce water pollution, noise pollution, dust pollution and air pollution.
In order to realize the goal of the invention of the present invention, the present invention is adopted the following technical scheme that:
A kind of innoxious restoration of the ecosystem agent of solid waste, it is composed of the following components by weight:30-80 parts of urea, ammonium nitrate 10-50 parts, 100-260 parts of potassium dihydrogen phosphate, 10-20 parts of magnesium sulfate, 5-10 parts of manganese sulfate, 3-10 parts of ferrous sulfate, hydrogen sulfate 3-8 parts of potassium, 0.3-1 parts of ytterbium nitrate, 5-20 parts of sodium butyrate.
It is preferred that, a kind of innoxious restoration of the ecosystem agent of solid waste is composed of the following components by weight:40-60 parts of urea, 30-50 parts of ammonium nitrate, 150-230 parts of potassium dihydrogen phosphate, 14-18 parts of magnesium sulfate, 6-8 parts of manganese sulfate, 6-10 parts of ferrous sulfate, sulphur 3-8 parts of potassium hydrogen phthalate, 0.5-0.8 parts of ytterbium nitrate, 10-16 parts of sodium butyrate.
Each component can be mixed into renovation agent powder by above-mentioned renovation agent.
Above-mentioned renovation agent can also be dissolved in water and reparation agent solution is made, and 1 kilogram of above-mentioned powder is dissolved in 50-200 and risen in water, system Into solution.
The innoxious ecological restoring method (method 1) of a kind of solid waste, using following steps:
1) the innoxious restoration of the ecosystem agent solution of solid waste is prepared:Following components is well mixed by weight:Urea 30-80 Part, 10-50 parts of ammonium nitrate, 100-260 parts of potassium dihydrogen phosphate, 10-20 parts of magnesium sulfate, 5-10 parts of manganese sulfate, ferrous sulfate 3-10 Part, 3-8 parts of potassium acid sulfate, 0.3-1 parts of ytterbium nitrate, 5-20 parts of sodium butyrate;1 kilogram of said mixture is dissolved in 50-200 and risen in water, Solution for later use is made;
2) step 1 is used) spray solution for preparing irrigates solid waste, and 1 kilogram is repaired 20-100 squares of agent composition sprinkler irrigation The solid waste surface of rice;
3) in the soil layer of one layer of 20-60 cm thick of solid waste surface sediment, for planting plants.
The innoxious ecological restoring method (method 2) of a kind of solid waste, using following steps:
1) the innoxious restoration of the ecosystem agent powder of solid waste is prepared:Following components is well mixed by weight:Urea 30-80 Part, 10-50 parts of ammonium nitrate, 100-260 parts of potassium dihydrogen phosphate, 10-20 parts of magnesium sulfate, 5-10 parts of manganese sulfate, ferrous sulfate 3-10 Part, it is stand-by that powder is made in 3-8 parts of potassium acid sulfate, 0.3-1 parts of ytterbium nitrate, 5-20 parts of sodium butyrate;
2) hole of 2-5 centimetres of diameter is beaten in solid waste heap with drill rod, deep 15-40 centimetres, each 50-150 centimetres of hole interval, By step 1) in prepare renovation agent powder pour into hole, Xiang Dongzhong pour into can by powder drench water;
3) in the soil layer of one layer of 20-60 cm thick of solid waste surface sediment, for planting plants.
It is a kind of to build the method (method 1) that solid waste, mine solid wastes plant tea tree, using following steps:
1) the innoxious restoration of the ecosystem agent solution of solid waste is prepared:Following components is well mixed by weight:Urea 40-60 Part, 30-50 parts of ammonium nitrate, 150-230 parts of potassium dihydrogen phosphate, 14-18 parts of magnesium sulfate, 6-8 parts of manganese sulfate, ferrous sulfate 6-10 Part, 3-8 parts of potassium acid sulfate, 0.5-0.8 parts of ytterbium nitrate, 10-16 parts of sodium butyrate;1 kilogram of said mixture is dissolved in 50-200 and rises water In, solution for later use is made;
2) use step 1) prepare spray solution irrigate building solid waste, mine solid wastes, 1 kilogram repair agent composition sprinkling fill Irrigate 20-100 square metres of solid waste surface;
3) in the soil layer of one layer of 20-60 cm thick of solid waste surface sediment, for planting tea tree.
It is a kind of to build the method (method 2) that solid waste, mine solid wastes plant tea tree, using following steps:
1) the innoxious restoration of the ecosystem agent powder of solid waste is prepared:Following components is well mixed by weight:Urea 40-60 Part, 30-50 parts of ammonium nitrate, 150-230 parts of potassium dihydrogen phosphate, 14-18 parts of magnesium sulfate, 6-8 parts of manganese sulfate, ferrous sulfate 6-10 Part, it is stand-by that powder is made in 3-8 parts of potassium acid sulfate, 0.5-0.8 parts of ytterbium nitrate, 8-16 parts of sodium butyrate;
2) hole of 2-5 centimetres of diameter is beaten in solid waste heap with drill rod, deep 15-40 centimetres, each 50-150 centimetres of hole interval, By step 1) in prepare renovation agent powder pour into hole, Xiang Dongzhong pour into can by powder drench water;
3) in the soil layer of one layer of 20-60 cm thick of solid waste surface sediment, for planting tea tree.
Calcareous, such as calcium carbonate can be contained in herein described solid waste (active calcium content can be more than 0.2%).
Building solid waste, mine solid wastes are particularly easy to containing calcareous, and content height.
During concrete application, the solid waste after being handled with renovation agent can be embedded in soil;Can also be piled into it is variously-shaped, for example Cube, cylinder etc.;It can be used for building river levee.As long as planting plants in the soil around it, effect can be played. Solid waste after processing can be provided for a long term nutrient to plant, and promotion root system of plant is sturdy, and root system of plant is sought connections with solid waste surface, plant With solid waste one entirety of formation, adjacent plant and solid waste form an entirety under the company of climbing of root system, final plant woods and whole Individual solid waste mountain forms an entirety by the connection of root system, extremely firmly, the enhancing of wind resistance antidetonation water resistant stream erosion ability, is difficult hair Raw solid waste mountain landslide, avalanche, spontaneous combustion etc..
Urea, ammonium nitrate can provide substantial amounts of organic matter and available nitrogen to tea tree, in the innoxious restoration of the ecosystem of solid waste The method that method (method 2) and building solid waste, the method (method 2) of mine solid wastes plantation tea tree use landfill ammonium nitrate powder, Go out ammonia using decomposing ammonium nitrate, while adding water and sodium butyrate, accelerated using the Pneumatic pressure power of ammonia in nutrient immersion solid waste In soil, it is easy to later nutrient slowly-released;Pneumatic pressure power is evenly distributed to sodium butyrate the micropore sweetening of the soil of solid waste simultaneously In gap, cross-linked network is formed;Sodium butyrate is fixed on ammonia gas and water and the sealing of other nutrients in micropore in turn again, that is, improves Shelf-life prevents the volatilization of nitrogen from consuming again, is that later nutrient is leached and regulation HP carries out basis.Potassium dihydrogen phosphate, hydrogen sulfate Potassium provides available phosphorus and effective potassium, while keeping soil into acidity, is conducive to growth of tea plant.Magnesium sulfate, manganese sulfate, ferrous sulfate Promote synthesis and the control soil acidity of chlorophyll, be conducive to the growth of tealeaves, tealeaves is light green, full, yield is high, and blade will not Jaundice, is speckless.
The cement built in the concrete block of solid waste contains curing agent, waterproofing agent, curing agent etc., can block in concrete block Micropore, cause nutrient be difficult to immersion leach.Cement and stone micropore itself are just minimum few, the storage of serious restriction nutrient and Transfer.Ytterbium nitrate can adjust immersion leaching velocity of each nutrition composition in concrete block and mineral stone, adjust nutrient Slow-release time, ytterbium nitrate consumption is big, and the rate of release of nutrient is fast.Sodium butyrate is white or off-white powder, there is special milk Butyric acid loses the fat stink of sample, be used as nutrient storage and transfer medium, it is ensured that transferring path it is unimpeded.It is full of in concrete and stone In the micropore of block, enhancing concrete block and stone fix nutrient, the ability of moisture, concrete block and stone is fixed more support Point;And nutrient, moisture are enclosed in micropore, nitrogen volatilization loss is prevented, extends the term of validity of each nutrient, do not lose for a long time Effect.Concrete block and the nutrient of stone deep layer are then transferred to because remote apart from surface it is difficult to be transferred to solid waste surface by micropore In soil, the nutrient of deep layer is evenly transferred in soil by UNICOM's network that sodium butyrate is formed in micropore, plays steady, uniform The effect of transport transfer nutrient.Part sodium butyrate, which is precipitate into from solid waste in soil crack, forms dendritic network, soil and Solid waste formation cross-linked state, strengthens the conglomeration ability and erosion resistance of soil, it is to avoid soil erosion;When the PH of soil changes When, dendritic network shifts acid ion alkali ion into solid waste, so as to keep the pH value of soil stable.Metal ion in solid waste Acid ion alkali ion salt is changed into microorganism to be fixed up, so that the pH value of balanced soil, therefore can be with long-term adjustment P in soil H.
Beneficial effect:A kind of innoxious restoration of the ecosystem agent for solid waste that the present invention is provided, containing substantial amounts of nutrient, regulation is simultaneously Stable soil PH, promotes growth of tea plant, improves production tea amount;Improve the ability that solid waste fixes nutrient and moisture, regulation nutrient and water The slow release speed divided and time;Extend the term of validity of nutrient;Cement hardener, waterproofing agent, curing agent are eliminated to biological infringement, Influence of the calcium carbonate (active calcium content is more than 0.2%) to tea tree is prevented and treated, enables tea tree in the building containing large quantities of lime matter Grown in solid waste and Industrial Solid Waste, the HP of soil is controlled using the metal ion and adsorption capacity of solid waste, so that harmless treatment Solid waste.Avoid pollution of the solid waste heap to environment.
A kind of innoxious ecological restoring method for solid waste that the present invention is provided, technique is simple, is easy to operation, saves manpower thing Power and energy consumption, this method is without crushing, with energy-saving and emission-reduction, reduces water pollution, noise pollution, dust pollution and air pollution, Turn waste into wealth for ecological afforestation construction.
The method that a kind of building solid waste that the present invention is provided, mine solid wastes plant tea tree, can by the discarded solid waste of script, Garbage mountain is used, and makes it have nutrient and moisture slow-release time long, fighting drought ability heat-preservation ventilating ability is strong, anti-adversity ability By force;Can be with long-term adjustment, stable soil pH value.Solid waste is turned waste into wealth the growth of suitable tea tree, increase production tea amount, and reduce water Pollution, noise pollution, dust pollution and air pollution.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of innoxious restoration of the ecosystem agent of solid waste, it is composed of the following components by weight:70 parts of urea, ammonium nitrate 20 Part, 200 parts of potassium dihydrogen phosphate, 10 parts of magnesium sulfate, 6 parts of manganese sulfate, 5 parts of ferrous sulfate, 7 parts of potassium acid sulfate, 0.8 part of ytterbium nitrate, 15 parts of sodium butyrate.
Embodiment 2
A kind of innoxious restoration of the ecosystem agent of solid waste, it is composed of the following components by weight:35 parts of urea, ammonium nitrate 45 Part, 150 parts of potassium dihydrogen phosphate, 17 parts of magnesium sulfate, 9 parts of manganese sulfate, 10 parts of ferrous sulfate, 5 parts of potassium acid sulfate, 0.4 part of ytterbium nitrate, 18 parts of sodium butyrate.
Embodiment 3
A kind of innoxious restoration of the ecosystem agent of solid waste, it is composed of the following components by weight:50 parts of urea, ammonium nitrate 35 Part, 220 parts of potassium dihydrogen phosphate, 12 parts of magnesium sulfate, 7 parts of manganese sulfate, 8 parts of ferrous sulfate, 4 parts of potassium acid sulfate, 0.9 part of ytterbium nitrate, 6 parts of sodium butyrate.
Embodiment 4
A kind of innoxious restoration of the ecosystem agent of solid waste, it is composed of the following components by weight:60 parts of urea, ammonium nitrate 15 Part, 130 parts of potassium dihydrogen phosphate, 19 parts of magnesium sulfate, 8 parts of manganese sulfate, 4 parts of ferrous sulfate, 6 parts of potassium acid sulfate, 0.5 part of ytterbium nitrate, 10 parts of sodium butyrate.
Embodiment 5
A kind of innoxious restoration of the ecosystem agent of solid waste, it is composed of the following components by weight:55 parts of urea, ammonium nitrate 30 Part, 180 parts of potassium dihydrogen phosphate, 15 parts of magnesium sulfate, 7.5 parts of manganese sulfate, 6.5 parts of ferrous sulfate, 7 parts of potassium acid sulfate, ytterbium nitrate 0.7 Part, 13 parts of sodium butyrate.
Embodiment 6
The innoxious ecological restoring method (method 1) of a kind of solid waste, using following steps:
1) the innoxious restoration of the ecosystem agent solution of solid waste is prepared:Following components is well mixed by weight:80 parts of urea, 30 parts of ammonium nitrate, 250 parts of potassium dihydrogen phosphate, 10 parts of magnesium sulfate, 5 parts of manganese sulfate, 8 parts of ferrous sulfate, 4 parts of potassium acid sulfate, nitric acid 0.9 part of ytterbium, 20 parts of sodium butyrate;1 kilogram of said mixture is dissolved in 185 liters of water, and solution for later use is made;
2) step 1 is used) spray solution for preparing irrigates solid waste, and 1 kilogram is repaired 100 square metres of agent composition sprinkler irrigation Solid waste surface;
3) in the soil layer of one layer of 40 cm thick of solid waste surface sediment, for planting plants.
Embodiment 7
The innoxious ecological restoring method (method 1) of a kind of solid waste, using following steps:
1) the innoxious restoration of the ecosystem agent solution of solid waste is prepared:Following components is well mixed by weight:55 parts of urea, 20 parts of ammonium nitrate, 200 parts of potassium dihydrogen phosphate, 20 parts of magnesium sulfate, 8 parts of manganese sulfate, 9 parts of ferrous sulfate, 6 parts of potassium acid sulfate, nitric acid 0.6 part of ytterbium, 16 parts of sodium butyrate;1 kilogram of said mixture is dissolved in 150 liters of water, and solution for later use is made;
2) step 1 is used) spray solution for preparing irrigates solid waste, and 1 kilogram is repaired 80 square metres of agent composition sprinkler irrigation Solid waste surface;
3) in the soil layer of one layer of 30 cm thick of solid waste surface sediment, Chinese rose is planted in soil.Compared to the moon with area Season, identical growth number of days, the Chinese rose growing way of the present embodiment is vigorous, and stem is sturdy to lodge, and Post flowering, fragrance is denseer, blooms Number of days extend 20%.
Embodiment 8
The innoxious ecological restoring method (method 1) of a kind of solid waste, using following steps:
1) the innoxious restoration of the ecosystem agent solution of solid waste is prepared:Following components is well mixed by weight:45 parts of urea, 15 parts of ammonium nitrate, 140 parts of potassium dihydrogen phosphate, 13 parts of magnesium sulfate, 7 parts of manganese sulfate, 4 parts of ferrous sulfate, 7 parts of potassium acid sulfate, nitric acid 0.4 part of ytterbium, 9 parts of sodium butyrate;1 kilogram of said mixture is dissolved in 60 liters of water, and solution for later use is made;
2) step 1 is used) spray solution for preparing irrigates solid waste, and 1 kilogram is repaired 35 square metres of agent composition sprinkler irrigation Solid waste surface;
3) in the soil layer of one layer of 50 cm thick of solid waste surface sediment, for planting plants.
Embodiment 9
The innoxious ecological restoring method (method 2) of a kind of solid waste, using following steps:
1) the innoxious restoration of the ecosystem agent powder of solid waste is prepared:Following components is well mixed by weight:33 parts of urea, 42 parts of ammonium nitrate, 160 parts of potassium dihydrogen phosphate, 12 parts of magnesium sulfate, 6 parts of manganese sulfate, 4 parts of ferrous sulfate, 7 parts of potassium acid sulfate, nitric acid 1 part of ytterbium, 18 parts of sodium butyrate, is made powder stand-by;
2) hole of 2 centimetres of diameter, deep 35 centimetres, each 65 centimetres of hole interval, by step 1 are beaten in solid waste heap with drill rod) The renovation agent powder of middle preparation is poured into hole, and Xiang Dongzhong pours into the water that powder can drench;
3) in the soil layer of one layer of 25 cm thick of solid waste surface sediment, velvet grass is planted in soil.Compared to area Velvet grass, identical growth number of days, the velvet grass growing way of the present embodiment is vigorous, and blade is higher by average 2.4 centimetres, cauline leaf It is sturdy to lodge.
Embodiment 10
The innoxious ecological restoring method (method 2) of a kind of solid waste, using following steps:
1) the innoxious restoration of the ecosystem agent powder of solid waste is prepared:Following components is well mixed by weight:77 parts of urea, 40 parts of ammonium nitrate, 230 parts of potassium dihydrogen phosphate, 11 parts of magnesium sulfate, 9 parts of manganese sulfate, 6 parts of ferrous sulfate, 5 parts of potassium acid sulfate, nitric acid 0.4 part of ytterbium, 11 parts of sodium butyrate, is made powder stand-by;
2) hole of 5 centimetres of diameter, deep 18 centimetres, each 135 centimetres of hole interval, by step 1 are beaten in solid waste heap with drill rod) The renovation agent powder of middle preparation is poured into hole, and Xiang Dongzhong pours into the water that powder can drench;
3) in the soil layer of one layer of 50 cm thick of solid waste surface sediment, willow is planted in soil.Willow grows vigorous, willow Root has fertilizer, and tree root wraps solid waste growth, tree and solid waste one entirety of formation.It is more stable, wind loading rating and water resistant stream Impact capacity is all greatly improved.Illustrate that the suitable shore protection of product that the application is provided builds slope, for administering river course.
Embodiment 11
The innoxious ecological restoring method (method 2) of a kind of solid waste, using following steps:
1) the innoxious restoration of the ecosystem agent powder of solid waste is prepared:Following components is well mixed by weight:60 parts of urea, 16 parts of ammonium nitrate, 120 parts of potassium dihydrogen phosphate, 12 parts of magnesium sulfate, 7 parts of manganese sulfate, 8 parts of ferrous sulfate, 4 parts of potassium acid sulfate, nitric acid 0.6 part of ytterbium, 12 parts of sodium butyrate, is made powder stand-by;
2) hole of 4 centimetres of diameter, deep 30 centimetres, each 100 centimetres of hole interval, by step 1 are beaten in solid waste heap with drill rod) The renovation agent powder of middle preparation is poured into hole, and Xiang Dongzhong pours into the water that powder can drench;
3) in the soil layer of one layer of 35 cm thick of solid waste surface sediment, for planting plants.
Embodiment 12
It is a kind of to build the method (method 1) that solid waste, mine solid wastes plant tea tree, using following steps:
1) the innoxious restoration of the ecosystem agent solution of solid waste is prepared:Following components is well mixed by weight:46 parts of urea, 39 parts of ammonium nitrate, 170 parts of potassium dihydrogen phosphate, 15 parts of magnesium sulfate, 6 parts of manganese sulfate, 9 parts of ferrous sulfate, 5 parts of potassium acid sulfate, nitric acid 0.6 part of ytterbium, 12 parts of sodium butyrate;1 kilogram of said mixture is dissolved in 60 liters of water, and solution for later use is made;
2) step 1 is used) spray solution for preparing irrigates the hybrid reactors of building solid waste and mine solid wastes, and 1 kilogram of renovation agent is mixed The solid waste surface of 90 square metres of compound sprinkler irrigation;
3) in the soil layer of one layer of 45 cm thick of solid waste surface sediment, for planting tea tree.
Embodiment 13
It is a kind of to build the method (method 1) that solid waste, mine solid wastes plant tea tree, using following steps:
1) the innoxious restoration of the ecosystem agent solution of solid waste is prepared:Following components is well mixed by weight:60 parts of urea, 50 parts of ammonium nitrate, 210 parts of potassium dihydrogen phosphate, 16 parts of magnesium sulfate, 8 parts of manganese sulfate, 9 parts of ferrous sulfate, 7 parts of potassium acid sulfate, nitric acid 0.6 part of ytterbium, 15 parts of sodium butyrate;1 kilogram of said mixture is dissolved in 100 liters of water, and solution for later use is made;
2) step 1 is used) spray solution for preparing irrigates mine solid wastes, and 1 kilogram is repaired 50 squares of agent composition sprinkler irrigation The solid waste surface of rice;
3) in the soil layer of one layer of 30 cm thick of solid waste surface sediment, for planting tea tree.
Embodiment 14
It is a kind of to build the method (method 1) that solid waste, mine solid wastes plant tea tree, using following steps:
1) the innoxious restoration of the ecosystem agent solution of solid waste is prepared:Following components is well mixed by weight:58 parts of urea, 43 parts of ammonium nitrate, 190 parts of potassium dihydrogen phosphate, 15 parts of magnesium sulfate, 6 parts of manganese sulfate, 6 parts of ferrous sulfate, 4 parts of potassium acid sulfate, nitric acid 0.5 part of ytterbium, 13 parts of sodium butyrate;1 kilogram of said mixture is dissolved in 150 liters of water, and solution for later use is made;
2) step 1 is used) spray solution for preparing irrigates building solid waste, and 1 kilogram is repaired 30 squares of agent composition sprinkler irrigation The solid waste surface of rice;
3) in the soil layer of one layer of 55 cm thick of solid waste surface sediment, for planting tea tree.
Embodiment 15
It is a kind of to build the method (method 2) that solid waste, mine solid wastes plant tea tree, using following steps:
1) the innoxious restoration of the ecosystem agent powder of solid waste is prepared:Following components is well mixed by weight:57 parts of urea, 35 parts of ammonium nitrate, 210 parts of potassium dihydrogen phosphate, 17 parts of magnesium sulfate, 7 parts of manganese sulfate, 8 parts of ferrous sulfate, 7 parts of potassium acid sulfate, nitric acid 0.6 part of ytterbium, 9 parts of sodium butyrate, is made powder stand-by;
2) hole of 4 centimetres of diameter is beaten in building solid waste heap with drill rod, deep 40 centimetres, each 70 centimetres of hole interval will be walked Rapid 1) the middle renovation agent powder prepared is poured into hole, and Xiang Dongzhong pours into the water that powder can drench;
3) in the soil layer of one layer of 30 cm thick of solid waste surface sediment, for planting tea tree.
Embodiment 16
It is a kind of to build the method (method 2) that solid waste, mine solid wastes plant tea tree, using following steps:
1) the innoxious restoration of the ecosystem agent powder of solid waste is prepared:Following components is well mixed by weight:45 parts of urea, 45 parts of ammonium nitrate, 180 parts of potassium dihydrogen phosphate, 15 parts of magnesium sulfate, 6 parts of manganese sulfate, 7 parts of ferrous sulfate, 5 parts of potassium acid sulfate, nitric acid 0.7 part of ytterbium, 15 parts of sodium butyrate, is made powder stand-by;
2) hole of 3 centimetres of diameter is beaten in mine solid wastes heap with drill rod, deep 25 centimetres, each 60 centimetres of hole interval will be walked Rapid 1) the middle renovation agent powder prepared is poured into hole, and Xiang Dongzhong pours into the water that powder can drench;
3) in the soil layer of one layer of 50 cm thick of solid waste surface sediment, for planting tea tree.
Embodiment 17
It is a kind of to build the method (method 2) that solid waste, mine solid wastes plant tea tree, using following steps:
1) the innoxious restoration of the ecosystem agent powder of solid waste is prepared:Following components is well mixed by weight:50 parts of urea, 40 parts of ammonium nitrate, 195 parts of potassium dihydrogen phosphate, 16 parts of magnesium sulfate, 8 parts of manganese sulfate, 10 parts of ferrous sulfate, 4 parts of potassium acid sulfate, nitric acid 0.5 part of ytterbium, 12 parts of sodium butyrate, is made powder stand-by;
2) hole of 2 centimetres of diameter is beaten in building solid waste and mine solid wastes hybrid reactor with drill rod, it is deep 20 centimetres, between each hole Every 140 centimetres, by step 1) in prepare renovation agent powder pour into hole, Xiang Dongzhong pour into can by powder drench water;
3) in the soil layer of one layer of 40 cm thick of solid waste surface sediment, for planting tea tree.
Built in the various embodiments described above containing substantial amounts of calcium carbonate, calcium silicates etc. in solid waste and mine solid wastes, and in soil Acid group combine after form substantial amounts of acive calcium ion, it is dead that calcium ion can influence growth of tea plant to even result in tea tree.And this reality Apply tea tree in example healthy and strong, tea leaf quality height, fast growth.Efficiently solve the subalimentation of tea tree.
Contrast experiment 1:
Reference examples 1
Tea tree is planted using with the same procedure of embodiment 15, step, different places is not containing sodium butyrate.
Reference examples 2
Tea tree is planted using with the same procedure of embodiment 15, step, different places is not containing ytterbium nitrate.
Reference examples 3
Tea tree is planted using with the same procedure of embodiment 15, step, different places is not containing ytterbium nitrate, butyric acid Sodium.
Reference examples 4
Tea tree is planted using with the same procedure of embodiment 15, step, different places is not containing ammonium nitrate.
Respectively to above-mentioned each group at 60 days 45 days 30 days 15 days, 1000 grams of the soil of 15 centimetres of depths is selected, soil is determined The content of nitrogen in earth.According to national standard《GB/T22923-2008 Nitrogens, phosphorus, the automatic analyzer determination method of potassium》In " 3.2 nitrogen The measure of content " detects the content of nitrogen.
Nitrogen analysis Nitrogen content (mg) at 15 days Nitrogen content (mg) at 30 days Nitrogen content (mg) at 45 days Nitrogen content (mg) at 60 days
Embodiment 15 393 471 572 593
Reference examples 1 252 329 378 411
Reference examples 2 161 192 217 236
Reference examples 3 159 184 203 215
Reference examples 4 268 347 416 483
Table 1
Nitrogen content is just very high at the 15th day in the soil of Application Example 15, and the amplification of nitrogen content reduces and tended to after 45 days Steadily, illustrate that ammonium nitrate, sodium butyrate, ytterbium nitrate are shared, nutrient can be made to be quickly transferred in soil, and it is laggard to form stationary value Enter sustained release state.
The soil nitrogen content of the 15th day of embodiment 15 is just very high to be compared with reference examples 4, illustrates that urea decomposes the gas produced Dynamic pressure, which has, accelerates Nutrient retranslocation into soil, and is formed after stationary value into sustained release state.
The nitrogen content of reference examples 1,2,3 and embodiment 15 is compared, illustrates that ytterbium nitrate has effects that to promote nutrient to leach, but There is no sodium butyrate to shift the collaboration of nutrient function, its later stage nutrient leaches slack-off, the amplification reduction of nitrogen content.
Reference examples 1 are compared pair with embodiment 15, and reference examples 1 are in 4 times measure, although the nitrogen content in soil is in increase, But amplification gradually weakens, and the increasing degree of embodiment 15 is very stable, illustrates that sodium butyrate uniformly passes the nutrient of concrete deep layer It is delivered in soil, plays a part of steady, uniform transport transfer nutrient.It is the nutrient consumption because upper soll layer that amplification, which is successively decreased, Complete, the nutrient of depths uniformly unimpeded can not be passed out.
Reference examples 2 are compared pair with embodiment 15, reference examples 2 in 4 times measure, nitrogen content in soil always than relatively low, Illustrate that ytterbium nitrate can adjust immersion leaching velocity of each nutrition composition in concrete block, adjust the slow-release time of nutrient.
Reference examples 3 are compared pair with embodiment 15, it is known that when renovation agent does not contain ytterbium nitrate, sodium butyrate, and nutrient can not be from mixed Smoothly be sustained in solidifying soil in soil, although in the presence of ammonium nitrate produces Pneumatic pressure power, can not effectively and rapidly by Nutrients release is into soil.
Acid Rain experiment (anti-soil acidification experiment) is done to above-mentioned soil, first, burning of plant straws collects flue gas, water Flue gas is washed, PH5.1 smoke solution is obtained;Drenched with rain with smoke solution simulation wash away each Application Example 15 and reference examples 1,2,3, 4 soil, the every square metre of 5L smoke solution that drench with rain records the erosion effect drenched with rain to soil, pH value is measured two days later.
The erosion resistance of reference examples 1 and 3 is worst, and pH value is minimum, and experimental example 15, reference examples 2 and the Anti-erosion of reference examples 4 Ability is all very strong, and has all recovered PH, and it is slower that reference examples 2 are recovered.Illustrate that sodium butyrate can precipitate into soil from concrete In earth, strengthen the conglomeration ability and erosion resistance of soil, it is to avoid soil erosion;When the PH of soil changes, sodium butyrate is acid Basic ion is shifted into solid waste, so as to keep the pH value of soil stable.
Comparability test 2
Test example 1,30 plants of tea tree is planted using the method and condition of embodiment 12.
Test example 2,30 plants of tea tree is planted using the method and condition of embodiment 16.
Reference examples 1:Tea tree is planted using with the identical method of embodiment 12 and condition, difference is prepared by reference examples 1 Innoxious restoration of the ecosystem agent solution do not contain ammonium nitrate, ytterbium nitrate, sodium butyrate.Plant 30 plants of tea tree.
Reference examples 2:Tea tree is planted using with the identical method of embodiment 16 and condition, difference is prepared by reference examples 2 Innoxious restoration of the ecosystem agent do not contain ammonium nitrate, ytterbium nitrate, sodium butyrate.Plant 30 plants of tea tree.
Solid waste in test example and reference examples contains substantial amounts of calcium ion.
Growth of tea plant situation Tea tree survives quantity Tea growth speed Tea quality
Test example 1 It is healthy and strong 30 Hurry up, blade it is light green Blade is big, thick
Test example 2 It is healthy and strong 30 Hurry up, blade it is light green Blade is big, thick
Reference examples 1 It is short and small 15 Slowly, leaf roll Blade is thin, curling
Reference examples 2 It is short and small 12 Slowly, leaf is yellow, leaf roll Blade is thin, spottiness
Table 2
Test example 1,2 is compared to understanding with reference examples 1,2, and the application can eliminate influence of the calcium ion to tea tree, make tea The healthy and strong growth of tree, the quality of tealeaves is high, and fast growth, yield is high.
It the above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair The limitation of the present invention, protection scope of the present invention should be defined by claim limited range.For the art For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change Enter and retouch and also should be regarded as protection scope of the present invention.

Claims (5)

1. the innoxious Ecological Disposal agent of a kind of solid waste, it is characterised in that by weight including following components:30-80 parts of urea, 10-50 parts of ammonium nitrate, 100-260 parts of potassium dihydrogen phosphate, 10-20 parts of magnesium sulfate, 5-10 parts of manganese sulfate, 3-10 parts of ferrous sulfate, 3-8 parts of potassium acid sulfate, 0.3-1 parts of ytterbium nitrate, 5-20 parts of sodium butyrate.
2. a kind of innoxious Ecological Disposal agent of solid waste according to claim 1, it is characterised in that:Each component can be mixed Close uniform into inorganic agent powder.
3. a kind of innoxious Ecological Disposal agent of solid waste according to claim 1, it is characterised in that:Can be molten by each component Processing agent solution is made in water, 1 kilogram of above-mentioned powder is dissolved in 50-200 and risen in water, and solution is made.
4. a kind of innoxious Ecological Disposal agent of solid waste according to claim 1,3, the side for harmless treatment solid waste Method, it is characterised in that use following steps:
1) the innoxious Ecological Disposal agent solution of solid waste is prepared:It is well mixed including following components by weight:Urea 30-80 Part, 10-50 parts of ammonium nitrate, 100-260 parts of potassium dihydrogen phosphate, 10-20 parts of magnesium sulfate, 5-10 parts of manganese sulfate, ferrous sulfate 3-10 Part, 3-8 parts of potassium acid sulfate, 0.3-1 parts of ytterbium nitrate, 5-20 parts of sodium butyrate;1 kilogram of said mixture is dissolved in 50-200 and risen in water, Solution for later use is made;
2) step 1 is used) spray solution for preparing irrigates solid waste, 1 kilogram of 20-100 square metres of processing agent composition sprinkler irrigation Solid waste surface;
3) in the soil layer of one layer of 20-60 cm thick of solid waste surface sediment, for planting plants.
5. a kind of build the method that solid waste, mine solid wastes plant tea tree, it is characterised in that uses following steps:
1) the innoxious Ecological Disposal agent solution of solid waste is prepared:Following components is well mixed by weight:40-60 parts of urea, 30-50 parts of ammonium nitrate, 150-230 parts of potassium dihydrogen phosphate, 14-18 parts of magnesium sulfate, 6-8 parts of manganese sulfate, 6-10 parts of ferrous sulfate, sulphur 3-8 parts of potassium hydrogen phthalate, 0.5-0.8 parts of ytterbium nitrate, 10-16 parts of sodium butyrate;1 kilogram of said mixture is dissolved in 50-200 and risen in water, system Into solution for later use;
2) use step 1) prepare spray solution irrigate building solid waste, mine solid wastes, 1 kilogram processing agent composition sprinkler irrigation 20-100 square metres of solid waste surface;
3) in the soil layer of one layer of 20-60 cm thick of solid waste surface sediment, for planting tea tree.
CN201710286408.3A 2017-04-27 2017-04-27 Solid waste ecological restoring method and medicament and building, the method for mine solid wastes kind tea tree Pending CN107056458A (en)

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CN113647308A (en) * 2021-08-17 2021-11-16 中煤浙江生态环境发展有限公司 Re-greening repair backfill material

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Publication number Priority date Publication date Assignee Title
CN113647308A (en) * 2021-08-17 2021-11-16 中煤浙江生态环境发展有限公司 Re-greening repair backfill material
CN113647308B (en) * 2021-08-17 2023-03-14 中煤浙江生态环境发展有限公司 Re-greening repair backfill material

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Application publication date: 20170818