CN107034420B - Nonmagnetic steel product and its manufacturing method - Google Patents

Nonmagnetic steel product and its manufacturing method Download PDF

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Publication number
CN107034420B
CN107034420B CN201710475061.7A CN201710475061A CN107034420B CN 107034420 B CN107034420 B CN 107034420B CN 201710475061 A CN201710475061 A CN 201710475061A CN 107034420 B CN107034420 B CN 107034420B
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nonmagnetic steel
manufacturing
powder
steel product
green compact
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CN107034420A (en
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陈家坚
朱权利
刘艳肖
刘军
潘永汉
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Guangdong Guangdong Joaquin Polytron Technologies Inc
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/02Making ferrous alloys by powder metallurgy
    • C22C33/0257Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
    • C22C33/0278Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/008Ferrous alloys, e.g. steel alloys containing tin
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)

Abstract

The present invention relates to a kind of nonmagnetic steel product and its manufacturing methods.The manufacturing method of the nonmagnetic steel product includes the following steps:It is prepared by green compact:Fe-Mn prealloy powder is taken, 2~4% activators and 0.3~0.6% graphite is added, adds the binder of the Fe-Mn prealloy powder, activator, graphite total weight 0.5~1.2%, compression moulding after mixing obtains green compact;The activator includes FeB master alloyed powders, wherein the weight percent of the B powder is 15~25%;Sintering:The green compact are sintered, the nonmagnetic steel product is obtained.The use for avoiding the higher raw material of the prices such as copper powder keeps the cost of manufacture of nonmagnetic steel product cheap, while obtaining the nonmagnetic steel product haveing excellent performance, and tensile strength can reach 500MP or more, and elongation is up to 6% or more.

Description

Nonmagnetic steel product and its manufacturing method
Technical field
The present invention relates to powder metallurgical technologies, more particularly to a kind of nonmagnetic steel product and its manufacturing method.
Background technology
The relative permeability μ values of nonmagnetic steel are slightly larger than 1, very weak for magnetization in magnetic field, do not generate magnetic induction substantially Low magnetic steel iron material, therefore visually be referred to as nonmagnetic steel.The requirement of nonmagnetic steel room temperature texture is stable austenite, and iron is plain Body, pearlite and martensitic structure are ferromagnetism at normal temperatures, and high manganese nonmagnetic steel is exactly to expand Fe-C by adding manganese element Austenitic area in alloy phase diagram obtains stable single phase austenite tissue at ambient temperature.
Industrially, high manganese nonmagnetic steel product is obtained generally by casting, and processing hardening is apparent, for required precision height If small part can with the method for powder metallurgy produce can preferably solve the problems, such as this.Manganese because with oxygen affinity is big, fusing point is high, easy The shortcomings of volatilization more difficult carry out alloying, these drawbacks can be solved by being introduced in the form of prealloy, and can ensure material It is magnetic constant.But there are prealloy itself have strong processing hardening characteristic, compressibility be poor, green strength is low, sintering is by force Spend low deficiency.
It is existing to use high manganese prealloy powder with powder metallurgically manufacturing nonmagnetic steel technique, in order to improve the briquettability and burning of powder Density is tied, mainly improves mouldability by the way that the good Cu powder of high-content compressibility is added, while utilizing the effect of its liquid-phase sintering, Sintered density is improved to obtain high-density sintered no magnetic product.Since the price of copper is high, cause the cost of technique high, It cannot be satisfied the demand of market high performance-price ratio.Although and aforementioned elements powder can obtain high-density sintered no magnetic product, nothing The mechanical property of magnet steel is unsatisfactory.
Invention content
Based on this, it is necessary to which for providing, a kind of process is simple, cost-effective, excellent combination property powder metallurgy The manufacturing method of nonmagnetic steel product.
A kind of manufacturing method of nonmagnetic steel product, includes the following steps:
It is prepared by green compact:Fe-Mn prealloy powder is taken, 2~4% activation of the Fe-Mn prealloy powder weight percent are added Agent and 0.3~0.6% graphite add the bonding of the Fe-Mn prealloy powder, activator, graphite total weight 0.5~1.2% Agent, compression moulding after mixing, obtains green compact;
The activator includes FeB master alloyed powders, in the FeB master alloyed powders weight percent of B be 15~ 25%;
The Fe-Mn prealloy powder includes the ingredient of following weight percent:Mn 15~19%, C 0.6~1.2%, Si 0.7~1.0%, S≤0.05%, P≤0.09%, Pb≤0.2%, Sn≤0.2%, surplus Fe;
Sintering:The green compact are sintered, the nonmagnetic steel product is obtained.
The Fe-Mn prealloy powder includes the ingredient of following weight percent in one of the embodiments,:Mn 17~ 19%, C 0.6~0.9%, Si 0.8~1.0%, S≤0.05%, P≤0.09%, Pb≤0.2%, Sn≤0.2%, surplus For Fe.
The Fe-Mn prealloy powder is smelting mixed by A3 steel, mid-carbon fe-mn and high carbon ferromanganese in one of the embodiments, After conjunction, it is prepared using water atomization.The A3 steel is a kind of mild steel, phosphorus content≤0.03%.
The binder is paraffin wax base wax powder in one of the embodiments,.
The nonmagnetic steel product includes the ingredient of following weight percent in one of the embodiments,:Mn 14.31~ 18.56%, C 0.87~1.77%, Si 0.67~0.98%, B 0.1~1%, S≤0.08%, P≤0.09%, Pb≤ 0.2%, Sn≤0.2%, surplus Fe.
The nonmagnetic steel product includes the ingredient of following weight percent in one of the embodiments,:Mn 16~ 18.56%, C 1.1~1.4%, Si 0.7~0.98%, B 0.1~0.5%, S≤0.08%, P≤0.09%, Pb≤ 0.2%, Sn≤0.2%, surplus Fe.
The size distribution of the Fe-Mn prealloy powder is 150~325 mesh in one of the embodiments,.
The density of the green compact is 5.8~6.2g/cm in one of the embodiments,3
The temperature of the sintering is 1200 DEG C~1280 DEG C in one of the embodiments, 1.5~2h of time.
The present invention also provides the nonmagnetic steel products that the manufacturing method of the nonmagnetic steel product manufactures.
Compared with prior art, the invention has the advantages that:
In order to avoid the use of the higher cupric high density powder of cost, while in identical sintered article density 6.9-7.1g/ cm3It is lower to obtain the nonmagnetic steel product with higher force performance, the manufacturing method of nonmagnetic steel product of the invention:First, with not The Fe-Mn prealloy mixed powders that copper is added are main powder, and adjust the ingredient of Fe-Mn prealloy powder, reduce Gao Meng as far as possible Work-hardening capacity of the prealloy powder in pressing process;Secondly, graphite is added and binder realizes the lubrication of alloyed powder, not only Effectively solve the problems, such as that the compressibility of prealloy Fe-Mn prealloy powder and formability are poor, and graphite powder is gone back in sintering process Strengthen the metallurgical binding of high manganese prealloy powder;Coordinate FeB master alloyed powders as activator again, forms liquid at a sintering temperature The activation mutually played.Gained alloy powder compressibility and good moldability as a result, can be pressed into using standard machinery press Type, sintering nonmagnetic steel product size stabilization obtained, density 6.9-7.1g/cm3.Compared with prior art, copper is avoided The use of the higher raw material of the prices such as powder, keeps the cost of manufacture of nonmagnetic steel product cheap, while significantly improving nonmagnetic steel product Mechanical property, tensile strength can reach 500MP or more, and elongation is up to 6% or more.
Compared with prior art, not only nonmagnetic steel product properties is high for the manufacturing method of nonmagnetic steel product of the invention, but also It is simple for process, at low cost, Product Precision is high, can be used for the occasion high to mechanical property requirements, substantially extend existing nonmagnetic steel system The industrial applications range of product.
In addition, avoiding preparing the technology mode of powdered metal parts using the highdensity prealloy powder of cupric, also open up The application of high manganese prealloy powder, has great importance to the popularization of powder metallurgical technique.
Specific implementation mode
The nonmagnetic steel product and its manufacturing method of the present invention are described in further detail below in conjunction with specific embodiment.
For the size distribution of the Fe-Mn prealloy powder used in the embodiment of the present invention for 150~325 mesh, preparation method is as follows:
According to required Fe-Mn prealloy powder ingredients, A3 steel is placed in intermediate frequency furnace after heating fusing according to a certain ratio, is added Enter mid-carbon fe-mn and high carbon ferromanganese;After melting down, with ferrosilicon deoxidation, Fe-Mn prealloy powder is prepared using water atomization.
Paraffin wax base wax powder is purchased from Guangzhou Qing Fanxiang new materials Co., Ltd.
Activator FeB master alloyed powders are purchased from Changsha Tian Jiu metal materials Co., Ltd.
Graphite is the special aquadag of powder metallurgy.
Embodiment 1
A kind of manufacturing method of nonmagnetic steel product (balance weight) of the present embodiment, includes the following steps:
A) first, Fe-Mn prealloy powder is taken, and by the weight percent for accounting for Fe-Mn prealloy powder, 4% activator is added Graphite with 0.3%, adds the paraffin wax base wax powder bonding of the Fe-Mn prealloy powder, activator, graphite total weight 1.2% Agent is stirred evenly spare with mixed powder machine.
Wherein, the activator is FeB master alloyed powders, wherein the weight percent of the B powder is 20%;
Fe-Mn prealloy powder includes the ingredient of following weight percent:Mn 15%, C 1.2%, Si 0.7, S≤ 0.05%, P≤0.09%, Pb≤0.2%, Sn≤0.2%, surplus Fe.
B) it send mixed mixed-powder to standard machinery press compression moulding, the green compact of balance weight is made, density domination exists 5.8g/cm3
C) green compact of compacting are sintered in pushing away boat stove, sintering temperature is 1200 DEG C~1280 DEG C, sintering time 1.5h。
D) deburring processing is polished to sintered green compact, you can.
Gained balance weight includes the ingredient of following weight percent:Mn 14.35%, C 1.47%, Si 0.68%, B 0.8%, S≤0.05%, P≤0.09%, Pb≤0.2%, Sn≤0.2%, surplus Fe.
Embodiment 2
A kind of manufacturing method of nonmagnetic steel product (balance weight) of the present embodiment, includes the following steps:
A) first, Fe-Mn prealloy powder is taken, and by the weight percent for accounting for Fe-Mn prealloy powder, 3% activator is added Graphite with 0.5%, adds the paraffin wax base wax powder bonding of the Fe-Mn prealloy powder, activator, graphite total weight 0.9% Agent is stirred evenly spare with mixed powder machine.
Wherein, the activator is FeB master alloyed powders, wherein the weight percent of the B powder is 15%;
Fe-Mn prealloy powder includes the ingredient of following weight percent:Mn 17%, C 0.9%, Si 1.0, S≤ 0.05%, P≤0.09%, Pb≤0.2%, Sn≤0.2%, surplus Fe.
B) it send mixed mixed-powder to standard machinery press compression moulding, the green compact of balance weight is made, density domination exists 6.0g/cm3
C) green compact of compacting are sintered in pushing away boat stove, sintering temperature is 1200 DEG C~1280 DEG C, sintering time 2h。
D) deburring processing is polished to sintered green compact, you can.
Gained balance weight includes the ingredient of following weight percent:Mn 16.4%, C 1.37%, Si 0.965%, B 0.45%, S≤0.05%, P≤0.09%, Pb≤0.2%, Sn≤0.2%, surplus Fe.
Embodiment 3
A kind of manufacturing method of nonmagnetic steel product (balance weight) of the present embodiment, includes the following steps:
A) first, Fe-Mn prealloy powder is taken, and by the weight percent for accounting for Fe-Mn prealloy powder, 2% activator is added Graphite with 0.6%, adds the paraffin wax base wax powder bonding of the Fe-Mn prealloy powder, activator, graphite total weight 0.5% Agent is stirred evenly spare with mixed powder machine.
Wherein, the activator includes FeB master alloyed powders, wherein the weight percent of the B powder is 25%;
Fe-Mn prealloy powder includes the ingredient of following weight percent:Mn 19%, C 0.6%, Si 0.8, S≤ 0.05%, P≤0.09%, Pb≤0.2%, Sn≤0.2%, surplus Fe.
B) it send mixed mixed-powder to standard machinery press compression moulding, the green compact of balance weight is made, density domination exists 6.2g/cm3
C) green compact of compacting are sintered in pushing away boat stove, sintering temperature is 1200 DEG C~1280 DEG C, sintering time 1.5h。
D) deburring processing is polished to sintered green compact, you can, gained balance weight includes following weight percent Ingredient:Mn 18.5%, C 1.18%, Si 0.78%, B 0.1%, S≤0.05%, P≤0.09%, Pb≤0.2%, Sn ≤ 0.2%, surplus Fe.
Comparative example 1
A kind of nonmagnetic steel product (balance weight) of this comparative example, raw material and manufacture with embodiment 1, difference lies in:It does not use The activator.
Comparative example 2
A kind of nonmagnetic steel product (balance weight) of this comparative example, raw material and manufacture with embodiment 1, difference lies in:It does not use The graphite.
The performance test results of embodiment 1-3 and comparative example 1-2 are as shown in table 1.
Table 1
Each technical characteristic of embodiment described above can be combined arbitrarily, to keep description succinct, not to above-mentioned reality It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited In contradiction, it is all considered to be the range of this specification record.
Several embodiments of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention Range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (10)

1. a kind of manufacturing method of nonmagnetic steel product, which is characterized in that include the following steps:
It is prepared by green compact:It uses Fe-Mn prealloy powder for original washing powder, 2~4% activators and 0.3 of Fe-Mn prealloy powder weight is added ~0.6% graphite adds the binder of the Fe-Mn prealloy powder, activator, graphite total weight 0.5~1.2%, mixing Compression moulding afterwards obtains green compact;
The activator includes FeB master alloyed powders, and the weight percent of B is 15~25% in the FeB master alloyed powders;
The Fe-Mn prealloy powder includes the ingredient of following weight percent:Mn 15~19%, C 0.6~1.2%, Si 0.7 ~1.0%, S≤0.05%, P≤0.09%, Pb≤0.2%, Sn≤0.2%, surplus Fe;
Sintering:The green compact are sintered, the nonmagnetic steel product is obtained.
2. the manufacturing method of nonmagnetic steel product according to claim 1, which is characterized in that the Fe-Mn prealloy powder packet Include the ingredient of following weight percent:Mn 17~19%, C 0.6~0.9%, Si 0.8~1.0%, S≤0.05%, P≤ 0.09%, Pb≤0.2%, Sn≤0.2%, surplus Fe.
3. the manufacturing method of nonmagnetic steel product according to claim 1, which is characterized in that the Fe-Mn prealloy powder by After A3 steel, mid-carbon fe-mn and the smelting mixing of high carbon ferromanganese, it is prepared using water atomization.
4. the manufacturing method of nonmagnetic steel product according to claim 1, which is characterized in that the binder is paraffinic base wax Powder.
5. according to the manufacturing method of claim 1-4 any one of them nonmagnetic steel products, which is characterized in that the nonmagnetic steel system Product include the ingredient of following weight percent:Mn 14.31~18.56%, C 0.87~1.77%, Si 0.67~0.98%, B 0.1~1%, S≤0.08%, P≤0.09%, Pb≤0.2%, Sn≤0.2%, surplus Fe.
6. the manufacturing method of nonmagnetic steel product according to claim 5, which is characterized in that the nonmagnetic steel product includes such as The ingredient of lower weight percent:Mn 16~18.56%, C 1.1~1.4%, Si 0.7~0.98%, B 0.1~0.5%, S ≤ 0.08%, P≤0.09%, Pb≤0.2%, Sn≤0.2%, surplus Fe.
7. according to the manufacturing method of claim 1-4 any one of them nonmagnetic steel products, which is characterized in that the Fe-Mn is pre- The size distribution of alloyed powder is 150~325 mesh.
8. according to the manufacturing method of claim 1-4 any one of them nonmagnetic steel products, which is characterized in that the green compact it is close Degree is 5.8~6.2g/cm3
9. according to the manufacturing method of claim 1-4 any one of them nonmagnetic steel products, which is characterized in that the temperature of the sintering Degree is 1200 DEG C~1280 DEG C, 1.5~2h of time.
10. the nonmagnetic steel product that the manufacturing method of claim 1-9 any one of them nonmagnetic steel products manufactures.
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Publication number Priority date Publication date Assignee Title
CN110756814B (en) * 2018-07-26 2022-08-05 广东美芝制冷设备有限公司 Preparation method of copper-free metallurgical material, balance block and compressor
CN111468711B (en) * 2019-01-23 2022-02-15 广东粤海华金科技股份有限公司 Composite activation sintered non-magnetic steel material and manufacturing method thereof
CN110468342B (en) * 2019-09-10 2021-07-27 温岭市恒丰粉末冶金有限公司 Nonmagnetic balance block processing technology
CN114015942B (en) * 2021-11-04 2022-07-29 广东美芝制冷设备有限公司 Nonmagnetic balance block, preparation method thereof and compressor

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CN106270494B (en) * 2016-09-26 2019-01-15 广东粤海华金科技股份有限公司 Nonmagnetic steel product and its powder metallurgically manufacturing method
CN106312059A (en) * 2016-10-11 2017-01-11 广东粤海华金科技股份有限公司 Powder metallurgy sintering method of non-magnetic steel structural component

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