CN107033776A - A kind of metal antirusting agent of high-wear resistance - Google Patents
A kind of metal antirusting agent of high-wear resistance Download PDFInfo
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- CN107033776A CN107033776A CN201710220758.XA CN201710220758A CN107033776A CN 107033776 A CN107033776 A CN 107033776A CN 201710220758 A CN201710220758 A CN 201710220758A CN 107033776 A CN107033776 A CN 107033776A
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Abstract
The invention discloses a kind of metal antirusting agent of high-wear resistance, its raw material includes methyl-silicone oil, polyethylene glycol, citric acid, modified filler, modified antirust agent, wear-resisting toughening modifying auxiliary agent, polyacrylic acid, calgon, sodium benzoate, lauryl sodium sulfate, triethanolamine, silica gel, BTA, sodium olefin sulfonate, sodium metasilicate, natrium nitrosum, dimethyl silicone polymer, dialkyldithiocarbamacompositions sodium, AEO, ammonium molybdate, DBSA, triethylene tetramine and deionized water.The metal antirusting agent of the present invention has excellent anti-wear performance, and good antirust property.
Description
Technical field
The present invention relates to the technical field of antirust agent, more particularly to a kind of metal antirusting agent of high-wear resistance.
Background technology
The derusting of metallic article, antirust problem are always the major issue of relevant surfaces treatment industry technical staff.
As metallic article, some equipment construction bad environments, serious wear, for metal surface antirust agent wear-resisting requirement very
Height, but the demand when anti-wear performance of metal antirusting agent can not meet actual use in currently available technology, therefore need badly and set
A kind of metal antirusting agent of high-wear resistance is counted to solve the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of metal antirusting agent of high-wear resistance,
With excellent anti-wear performance, and good antirust property.
A kind of metal antirusting agent of high-wear resistance proposed by the present invention, its raw material includes by weight：Methyl-silicone oil 6-
12 parts, 3-9 parts of polyethylene glycol, 4-8 parts of citric acid, 6-12 parts of modified filler, modified 4-8 parts of antirust agent, wear-resisting toughening modifying help
5-15 parts of agent, 4-8 parts of polyacrylic acid, 1-3 parts of calgon, 2-6 parts of sodium benzoate, 3-9 parts of lauryl sodium sulfate, three second
4-8 parts of hydramine, 4-8 parts of silica gel, 2-5 parts of BTA, 1-6 parts of sodium olefin sulfonate, 1-4 parts of sodium metasilicate, natrium nitrosum 2-5
Part, 2-8 parts of dimethyl silicone polymer, 4-9 parts of dialkyldithiocarbamacompositions sodium, 3-9 parts of AEO, molybdic acid
2-8 parts of ammonium, 3-6 parts of DBSA, 4-8 parts of triethylene tetramine, 10-20 parts of deionized water.
Preferably, the raw material of modified filler includes by weight：1-8 parts of calcium stearate, 2-8 parts of nano-zinc borate, hard charcoal
Black 1-6 parts, 3-9 parts of magnesium hydroxide, 1-6 parts of wood fiber powder, 2-7 parts of hollow glass micropearl, 1-3 parts of silicon powder, metering system
4-9 parts of acid esters, 2-5 parts of silane resin acceptor kh-550,3-8 parts of silicone oil.
Preferably, modified filler is prepared by following technique：Calcium stearate and nano-zinc borate are well mixed,
50-60 DEG C of sealing stirring at low speed 10-25min, is then mixed with white carbon, wood fiber powder, hollow glass micropearl and silicon powder
Uniformly, 45-55 DEG C of sealing stirring at low speed 5-10min, adds magnesium hydroxide, methacrylate, silane resin acceptor kh-550
It is well mixed with silicone oil, 135-140 DEG C is warming up to, stirring at low speed 10-20min, discharging is cooled to room temperature and obtains modified filler.
Preferably, the raw material of modified antirust agent includes by weight：20-50 parts of nano aluminum nitride, 2-8 parts of aluminium hydroxide,
3-9 parts of trimethylolethane, 1-5 parts of polyisobutene, 2-6 parts of nonyl phenol, 1-3 parts of gaultherolin, tricresyl phosphate 2-6
Part, 3-9 parts of methacrylate, 2-6 parts of calcium silicates, 2-4 parts of lubricant, 4-8 parts of silane coupler KH-560.
Preferably, modified antirust agent is prepared by following technique：Nano aluminum nitride is put into calcining furnace in 750-850
1-5h is calcined at DEG C, is cooled down, is put into 10-12% hydrochloric acid solutions and soaks 2-4h, filtering is taken out, drying is cleaned with clear water, is crushed
Into 150-350 mesh powder, then with aluminium hydroxide, trimethylolethane, polyisobutene, nonyl phenol, gaultherolin, phosphoric acid
Front three phenyl ester, methacrylate, calcium silicates, lubricant and silane coupler KH-560 are well mixed, grinding, produce modified anti-
Rust agent.
Preferably, the raw material of wear-resisting toughening modifying auxiliary agent includes by weight：4-8 parts of starch, 5-15 parts of distilled water, Malaysia
1-8 parts of acid anhydrides, 2-5 parts of ammonium persulfate, 3-6 parts of styrene, 4-8 parts of aluminium chloride, 2-5 parts of sodium hydroxide, nano silicon 3-6
Part, 1-5 parts of bentonite, 4-8 parts of tossa, 3-9 parts of Silane coupling reagent KH-570.
Preferably, wear-resisting toughening modifying auxiliary agent is prepared by following technique：Under nitrogen protection, by starch, distilled water
It is well mixed with maleic anhydride, 80-90 DEG C is then heated to, 10-30min is incubated, ammonium persulfate is then added and is well mixed, stir
Mix addition styrene after 5-15min to be well mixed, then stir 50-70min in 850-1250r/min rotating speeds, then heat to
85-95 DEG C, 40-50h is extracted, then in vacuum drying oven, 65-75 DEG C dries to constant weight, and is cooled to room temperature and obtains material a；By chlorine
Change aluminium, sodium hydroxide and water well mixed, stir, be stored at room temperature 10-20d and obtain material a, then added into material a
Nano silicon, bentonite and tossa, are stored at room temperature 2-6d, then add silane coupler KH-560 and material a and mix
Close uniform, 1-3h is stirred in 1500-2500r/min rotating speeds, then heat to 100-120 DEG C, dry 2-5h, be cooled to after room temperature
Crush and wear-resisting toughening modifying auxiliary agent is made.
A kind of metal antirusting agent of high-wear resistance proposed by the present invention, its raw material includes methyl-silicone oil, polyethylene glycol, lemon
Lemon acid, modified filler, modified antirust agent, wear-resisting toughening modifying auxiliary agent, polyacrylic acid, calgon, sodium benzoate, dodecane
Base sodium sulphate, triethanolamine, silica gel, BTA, sodium olefin sulfonate, sodium metasilicate, natrium nitrosum, polydimethylsiloxanes
Alkane, dialkyldithiocarbamacompositions sodium, AEO, ammonium molybdate, DBSA, triethylene tetramine and
Deionized water with modified filler, is modified antirust agent and wear-resisting wherein using methyl-silicone oil, polyethylene glycol and citric acid as antirust base-material
Toughening modifying auxiliary agent is reinforcement modified materials, with polyacrylic acid, calgon, sodium benzoate, lauryl sodium sulfate, three ethanol
Amine, silica gel, BTA, sodium olefin sulfonate, sodium metasilicate, natrium nitrosum, dimethyl silicone polymer, dialkyl dithio ammonia
Base sodium formate, AEO, ammonium molybdate, DBSA, triethylene tetramine and deionized water are auxiliary agent, are led to
The cooperation of antirust base-material, reinforcement modified materials and auxiliary agent is crossed, obtained metal antirusting agent has excellent anti-wear performance.Wherein, change
Property filler by the way that calcium stearate and nano-zinc borate are well mixed, stirring at low speed is sealed, then with white carbon, wood fibre
Powder, hollow glass micropearl and silicon powder are well mixed, seal stirring at low speed, add magnesium hydroxide, methacrylate, silane
Coupling agent KH-550 and silicone oil are well mixed, heating, stirring at low speed, and discharging is cooled to room temperature and obtains modified filler, applies to this
In the preparation of invention metal antirusting agent, the anti-wear performance of metal antirusting agent of the present invention is effectively increased.Wherein, modified antirust agent leads to
Cross nano aluminum nitride being put into calcining furnace and calcine, cooling is put into hydrochloric acid solution and soaked, and filtering is taken out, and is cleaned and dried with clear water
It is dry, powder is ground into, then with aluminium hydroxide, trimethylolethane, polyisobutene, nonyl phenol, gaultherolin, tricresyl phosphate
Toluene ester, methacrylate, calcium silicates, lubricant and silane coupler KH-560 are well mixed, grinding, produce modified antirust
In agent, the metal antirusting agent for applying to the present invention, the rustless property of metal antirusting agent of the present invention is effectively increased.Wherein, it is wear-resisting
Toughening modifying auxiliary agent is incubated, so by under nitrogen protection, starch, distilled water and maleic anhydride being well mixed, then heated up
Afterwards add ammonium persulfate be well mixed, after stirring add styrene be well mixed, be followed by stirring for, then heat up, extract, then in
In vacuum drying oven, dry to constant weight, be cooled to room temperature and obtain material a；Aluminium chloride, sodium hydroxide and water are well mixed, stirring is equal
It is even, it is stored at room temperature and obtains material a, nano silicon, bentonite and tossa is then added into material a, is stored at room temperature,
Then add silane coupler KH-560 and material a to be well mixed, then stirring heats up, and dries, and is cooled to after room temperature system of crushing
Wear-resisting toughening modifying auxiliary agent is obtained, the wearability that metal antirusting agent of the present invention is effectively increased in metal antirusting agent of the present invention is applied to
Energy and toughness, impart the excellent anti-wear performance of metal antirusting agent of the present invention.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
In embodiment, the parts by weight of methyl-silicone oil can be 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts；
The parts by weight of polyethylene glycol can for 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts,
8.5 parts, 9 parts；The parts by weight of citric acid can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；Change
Property filler parts by weight can be 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts；The parts by weight of modified antirust agent can be 4
Part, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of wear-resisting toughening modifying auxiliary agent can for 5 parts,
6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The parts by weight of polyacrylic acid can for 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of calgon can for 1 part, 1.5 parts, 2 parts,
2.5 parts, 3 parts；The parts by weight of sodium benzoate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；
The parts by weight of lauryl sodium sulfate can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The parts by weight of triethanolamine can be with
For 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of silica gel can for 4 parts, 4.5 parts, 5
Part, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of BTA can for 2 parts, 2.5 parts, 3 parts, 3.5 parts,
4 parts, 4.5 parts, 5 parts；The parts by weight of sodium olefin sulfonate can for 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts；The parts by weight of sodium metasilicate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Nitrous
The parts by weight of sour sodium can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of dimethyl silicone polymer can
Think 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The parts by weight of dialkyldithiocarbamacompositions sodium can for 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts；The parts by weight of AEO can be
3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The parts by weight of ammonium molybdate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；
The parts by weight of DBSA can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight of triethylene tetramine
It can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts to measure part；The parts by weight of deionized water can be
10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts.
Embodiment 1
A kind of metal antirusting agent of high-wear resistance proposed by the present invention, its raw material includes by weight：Methyl-silicone oil 9
Part, 6 parts of polyethylene glycol, 6 parts of citric acid, 9 parts of modified filler, modified 6 parts of antirust agent, 10 parts of wear-resisting toughening modifying auxiliary agent, poly- third
6 parts of olefin(e) acid, 2 parts of calgon, 4 parts of sodium benzoate, 6 parts of lauryl sodium sulfate, 6 parts of triethanolamine, 6 parts of silica gel, benzo
3.5 parts of triazole, 3.5 parts of sodium olefin sulfonate, 2.5 parts of sodium metasilicate, 3.5 parts of natrium nitrosum, 5 parts of dimethyl silicone polymer, two
6.5 parts of alkyl nabam, 6 parts of AEO, 5 parts of ammonium molybdate, 4.5 parts of DBSA,
6 parts of triethylene tetramine, 15 parts of deionized water.
Wherein, modified filler is prepared by following technique：By weight by 4.5 parts of calcium stearates and 5 parts of nano boric acids
Zinc is well mixed, and stirring at low speed 17.5min are sealed at 55 DEG C, then with 3.5 parts of white carbons, 3.5 parts of wood fiber powders, 4.5 parts
Hollow glass micropearl and 2 parts of silicon powders are well mixed, 50 DEG C of sealing stirring at low speed 7.5min, add 6 parts of magnesium hydroxides, 6.5
Part methacrylate, 3.5 parts of silane resin acceptor kh-550s and 5.5 parts of silicone oil are well mixed, and are warming up to 137.5 DEG C, low speed is stirred
15min is mixed, is discharged, is cooled to room temperature and obtains modified filler.
Wherein, modified antirust agent is prepared by following technique：30 parts of nano aluminum nitrides are put into calcining furnace by weight
In 3h is calcined at 800 DEG C, cool down, be put into 11% hydrochloric acid solution and soak 3h, filtering take out, with clear water clean drying, crush
Into 250 mesh powder, then with 5 parts of aluminium hydroxides, 6 portions of trimethylolethanes, 3 portions of polyisobutene, 4 portions of nonyl phenols, 2 portions of bigcatkin willows
Sour methyl esters, 4 parts of tricresyl phosphates, 6 parts of methacrylates, 4 parts of calcium silicates, 3 parts of lubricants and 6 parts of silane coupler KH-
560 are well mixed, and grinding produces modified antirust agent.
Wherein, wear-resisting toughening modifying auxiliary agent is prepared by following technique：Under nitrogen protection, by weight by 6 parts of shallow lakes
Powder, 10 parts of distilled water and 4.5 parts of maleic anhydrides are well mixed, and are then heated to 85 DEG C, are incubated 20min, then add 3.5 parts of mistakes
Ammonium sulfate is well mixed, and adding 4.5 parts of styrene after stirring 10min is well mixed, and is then stirred in 1050r/min rotating speeds
60min, then heats to 90 DEG C, extracts 45h, then in vacuum drying oven, 70 DEG C dry to constant weight, and are cooled to room temperature and obtain material
a；6 parts of aluminium chloride, 3.5 parts of sodium hydroxides and water are well mixed, stirred, 15d is stored at room temperature and obtains material a, Ran Houxiang
4.5 parts of nano silicons, 3 parts of bentonites and 6 parts of tossas are added in material a, 4d is stored at room temperature, 6 parts of silicon are then added
Alkane coupling agent KH-560 and material a is well mixed, and 2h is stirred in 2000r/min rotating speeds, then heats to 110 DEG C, dries 3.5h,
It is cooled to crush after room temperature and wear-resisting toughening modifying auxiliary agent is made.
Embodiment 2
A kind of metal antirusting agent of high-wear resistance proposed by the present invention, its raw material includes by weight：Methyl-silicone oil 6
Part, 9 parts of polyethylene glycol, 4 parts of citric acid, 12 parts of modified filler, modified 4 parts of antirust agent, 15 parts of wear-resisting toughening modifying auxiliary agent, poly- third
4 parts of olefin(e) acid, 3 parts of calgon, 2 parts of sodium benzoate, 9 parts of lauryl sodium sulfate, 4 parts of triethanolamine, 8 parts of silica gel, benzo
2 parts of triazole, 6 parts of sodium olefin sulfonate, 1 part of sodium metasilicate, 5 parts of natrium nitrosum, 2 parts of dimethyl silicone polymer, dialkyl disulfides
For 9 parts of carbamic acid sodium, 3 parts of AEO, 8 parts of ammonium molybdate, 3 parts of DBSA, triethylene tetramine 8
Part, 10 parts of deionized water.
Wherein, modified filler is prepared by following technique：By weight by 1 part of calcium stearate and 8 parts of nano-zinc borates
It is well mixed, stirring at low speed 25min is sealed at 50 DEG C, it is then micro- with 1 part of white carbon, 6 parts of wood fiber powders, 2 parts of hollow glass
Pearl and 3 parts of silicon powders are well mixed, 45 DEG C of sealing stirring at low speed 10min, add 3 parts of magnesium hydroxides, 9 parts of methacrylic acids
Ester, 2 parts of silane resin acceptor kh-550s and 8 parts of silicone oil are well mixed, and are warming up to 135 DEG C, stirring at low speed 20min, discharging is cooled to
Room temperature obtains modified filler.
Wherein, modified antirust agent is prepared by following technique：20 parts of nano aluminum nitrides are put into calcining furnace by weight
In 1h is calcined at 850 DEG C, cool down, be put into 12% hydrochloric acid solution and soak 2h, filtering take out, with clear water clean drying, crush
Into 350 mesh powder, then with 2 parts of aluminium hydroxides, 9 portions of trimethylolethanes, 1 portion of polyisobutene, 6 portions of nonyl phenols, 1 portion of bigcatkin willow
Sour methyl esters, 6 parts of tricresyl phosphates, 3 parts of methacrylates, 6 parts of calcium silicates, 2 parts of lubricants and 8 parts of silane coupler KH-
560 are well mixed, and grinding produces modified antirust agent.
Wherein, wear-resisting toughening modifying auxiliary agent is prepared by following technique：Under nitrogen protection, by weight by 4 parts of shallow lakes
Powder, 15 parts of distilled water and 1 part of maleic anhydride are well mixed, and are then heated to 90 DEG C, are incubated 10min, then add 5 parts of persulfuric acid
Ammonium is well mixed, and adding 6 parts of styrene after stirring 5min is well mixed, and then stirs 70min, Ran Housheng in 850r/min rotating speeds
Temperature extracts 50h, then in vacuum drying oven, 65 DEG C dry to constant weight, and are cooled to room temperature and obtain material a to 85 DEG C；By 8 parts of chlorinations
Aluminium, 2 parts of sodium hydroxides and water are well mixed, stir, are stored at room temperature 20d and obtain material a, and 3 parts are then added into material a
Nano silicon, 5 parts of bentonites and 4 parts of tossas, are stored at room temperature 6d, then add 3 parts of silane coupler KH-560 and
Material a is well mixed, and 1h is stirred in 2500r/min rotating speeds, then heats to 120 DEG C, dries 2h, is cooled to after room temperature system of crushing
Obtain wear-resisting toughening modifying auxiliary agent.
Embodiment 3
A kind of metal antirusting agent of high-wear resistance proposed by the present invention, its raw material includes by weight：Methyl-silicone oil 12
Part, 3 parts of polyethylene glycol, 8 parts of citric acid, 6 parts of modified filler, modified 8 parts of antirust agent, 5 parts of wear-resisting toughening modifying auxiliary agent, polypropylene
8 parts of acid, 1 part of calgon, 6 parts of sodium benzoate, 3 parts of lauryl sodium sulfate, 8 parts of triethanolamine, 4 parts of silica gel, benzo three
5 parts of nitrogen azoles, 1 part of sodium olefin sulfonate, 4 parts of sodium metasilicate, 2 parts of natrium nitrosum, 8 parts of dimethyl silicone polymer, dialkyl dithio
4 parts of carbamic acid sodium, 9 parts of AEO, 2 parts of ammonium molybdate, 6 parts of DBSA, 4 parts of triethylene tetramine,
20 parts of deionized water.
Wherein, modified filler is prepared by following technique：By weight by 8 parts of calcium stearates and 2 parts of nano-zinc borates
It is well mixed, stirring at low speed 10min is sealed at 60 DEG C, it is then micro- with 6 parts of white carbons, 1 part of wood fiber powder, 7 parts of hollow glass
Pearl and 1 part of silicon powder are well mixed, 55 DEG C of sealing stirring at low speed 5min, add 9 parts of magnesium hydroxides, 4 parts of methacrylates,
5 parts of silane resin acceptor kh-550s and 3 parts of silicone oil are well mixed, and are warming up to 140 DEG C, stirring at low speed 10min, discharging is cooled to room
Temperature obtains modified filler.
Wherein, modified antirust agent is prepared by following technique：50 parts of nano aluminum nitrides are put into calcining furnace by weight
In 5h is calcined at 750 DEG C, cool down, be put into 10% hydrochloric acid solution and soak 4h, filtering take out, with clear water clean drying, crush
Into 150 mesh powder, then with 8 parts of aluminium hydroxides, 3 portions of trimethylolethanes, 5 portions of polyisobutene, 2 portions of nonyl phenols, 3 portions of bigcatkin willows
Sour methyl esters, 2 parts of tricresyl phosphates, 9 parts of methacrylates, 2 parts of calcium silicates, 4 parts of lubricants and 4 parts of silane coupler KH-
560 are well mixed, and grinding produces modified antirust agent.
Wherein, wear-resisting toughening modifying auxiliary agent is prepared by following technique：Under nitrogen protection, by weight by 8 parts of shallow lakes
Powder, 5 parts of distilled water and 8 parts of maleic anhydrides are well mixed, and are then heated to 80 DEG C, are incubated 30min, then add 2 parts of persulfuric acid
Ammonium is well mixed, and adding 3 parts of styrene after stirring 15min is well mixed, and then stirs 50min in 1250r/min rotating speeds, then
95 DEG C are warming up to, 40h is extracted, then in vacuum drying oven, 75 DEG C dry to constant weight, and are cooled to room temperature and obtain material a；By 4 parts of chlorine
Change aluminium, 5 parts of sodium hydroxides and water well mixed, stir, be stored at room temperature 10d and obtain material a, then add 6 into material a
Part nano silicon, 1 part of bentonite and 8 parts of tossas, are stored at room temperature 2d, then add 9 parts of silane coupler KH-560
It is well mixed with material a, 3h is stirred in 1500r/min rotating speeds, 100 DEG C are then heated to, 5h is dried, is cooled to after room temperature and crushes
Wear-resisting toughening modifying auxiliary agent is made.
Embodiment 4
A kind of metal antirusting agent of high-wear resistance proposed by the present invention, its raw material includes by weight：Methyl-silicone oil 7
Part, 8 parts of polyethylene glycol, 5 parts of citric acid, 11 parts of modified filler, modified 5 parts of antirust agent, 12 parts of wear-resisting toughening modifying auxiliary agent, poly- third
5 parts of olefin(e) acid, 2.5 parts of calgon, 3 parts of sodium benzoate, 8 parts of lauryl sodium sulfate, 5 parts of triethanolamine, 7 parts of silica gel, benzene
And 3 parts of triazole, 5 parts of sodium olefin sulfonate, 2 parts of sodium metasilicate, 4 parts of natrium nitrosum, 3 parts of dimethyl silicone polymer, dialkyl group two
8 parts of thiocarbamic acid sodium, 4 parts of AEO, 7 parts of ammonium molybdate, 4 parts of DBSA, triethylene tetramine 7
Part, 12 parts of deionized water.
Wherein, modified filler is prepared by following technique：By weight by 2 parts of calcium stearates and 7 parts of nano-zinc borates
It is well mixed, stirring at low speed 20min is sealed at 52 DEG C, it is then micro- with 2 parts of white carbons, 5 parts of wood fiber powders, 3 parts of hollow glass
Pearl and 2.5 parts of silicon powders are well mixed, 48 DEG C of sealing stirring at low speed 12min, add 4 parts of magnesium hydroxides, 8 parts of methacrylic acids
Ester, 3 parts of silane resin acceptor kh-550s and 7 parts of silicone oil are well mixed, and are warming up to 136 DEG C, stirring at low speed 18min, discharging is cooled to
Room temperature obtains modified filler.
Wherein, modified antirust agent is prepared by following technique：30 parts of nano aluminum nitrides are put into calcining furnace by weight
In 2h is calcined at 820 DEG C, cool down, be put into 11.5% hydrochloric acid solution and soak 2.5h, filtering take out, with clear water clean drying,
320 mesh powder are ground into, then with 3 parts of aluminium hydroxides, 8 parts of trimethylolethanes, 2 parts of polyisobutene, 5 parts of nonyl phenols, 1.5
Part gaultherolin, 5 parts of tricresyl phosphates, 4 parts of methacrylates, 5 parts of calcium silicates, 2.5 parts of lubricants and 7 parts of silane idols
Join agent KH-560 to be well mixed, grinding produces modified antirust agent.
Wherein, wear-resisting toughening modifying auxiliary agent is prepared by following technique：Under nitrogen protection, by weight by 5 parts of shallow lakes
Powder, 12 parts of distilled water and 2 parts of maleic anhydrides are well mixed, and are then heated to 88 DEG C, are incubated 15min, then add 4 parts of persulfuric acid
Ammonium is well mixed, and adding 5 parts of styrene after stirring 8min is well mixed, and then stirs 65min, Ran Housheng in 880r/min rotating speeds
Temperature extracts 48h, then in vacuum drying oven, 68 DEG C dry to constant weight, and are cooled to room temperature and obtain material a to 88 DEG C；By 7 parts of chlorinations
Aluminium, 3 parts of sodium hydroxides and water are well mixed, stir, are stored at room temperature 18d and obtain material a, and 4 parts are then added into material a
Nano silicon, 4 parts of bentonites and 5 parts of tossas, are stored at room temperature 5d, then add 4 parts of silane coupler KH-560 and
Material a is well mixed, and 1.5h is stirred in 2200r/min rotating speeds, then heats to 115 DEG C, dries 3h, is cooled to after room temperature and is crushed
Wear-resisting toughening modifying auxiliary agent is made.
Embodiment 5
A kind of metal antirusting agent of high-wear resistance proposed by the present invention, its raw material includes by weight：Methyl-silicone oil 11
Part, 4 parts of polyethylene glycol, 7 parts of citric acid, 7 parts of modified filler, modified 7 parts of antirust agent, 8 parts of wear-resisting toughening modifying auxiliary agent, polypropylene
7 parts of acid, 1.5 parts of calgon, 5 parts of sodium benzoate, 4 parts of lauryl sodium sulfate, 7 parts of triethanolamine, 5 parts of silica gel, benzo
4 parts of triazole, 2 parts of sodium olefin sulfonate, 3 parts of sodium metasilicate, 3 parts of natrium nitrosum, 7 parts of dimethyl silicone polymer, dialkyl disulfides
For 5 parts of carbamic acid sodium, 8 parts of AEO, 3 parts of ammonium molybdate, 5 parts of DBSA, triethylene tetramine 5
Part, 18 parts of deionized water.
Wherein, modified filler is prepared by following technique：By weight by 7 parts of calcium stearates and 3 parts of nano-zinc borates
It is well mixed, stirring at low speed 15min is sealed at 58 DEG C, it is then micro- with 5 parts of white carbons, 2 parts of wood fiber powders, 6 parts of hollow glass
Pearl and 1.5 parts of silicon powders are well mixed, 52 DEG C of sealing stirring at low speed 8min, add 8 parts of magnesium hydroxides, 5 parts of methacrylic acids
Ester, 4 parts of silane resin acceptor kh-550s and 4 parts of silicone oil are well mixed, and are warming up to 139 DEG C, stirring at low speed 12min, discharging is cooled to
Room temperature obtains modified filler.
Wherein, modified antirust agent is prepared by following technique：40 parts of nano aluminum nitrides are put into calcining furnace by weight
In 4h is calcined at 780 DEG C, cool down, be put into 10.5% hydrochloric acid solution and soak 3.5h, filtering take out, with clear water clean drying,
180 mesh powder are ground into, then with 7 parts of aluminium hydroxides, 4 parts of trimethylolethanes, 4 parts of polyisobutene, 3 parts of nonyl phenols, 2.5
Part gaultherolin, 3 parts of tricresyl phosphates, 8 parts of methacrylates, 3 parts of calcium silicates, 3.5 parts of lubricants and 5 parts of silane idols
Join agent KH-560 to be well mixed, grinding produces modified antirust agent.
Wherein, wear-resisting toughening modifying auxiliary agent is prepared by following technique：Under nitrogen protection, by weight by 7 parts of shallow lakes
Powder, 8 parts of distilled water and 7 parts of maleic anhydrides are well mixed, and are then heated to 82 DEG C, are incubated 25min, then add 3 parts of persulfuric acid
Ammonium is well mixed, and adding 4 parts of styrene after stirring 12min is well mixed, and then stirs 55min in 1220r/min rotating speeds, then
92 DEG C are warming up to, 42h is extracted, then in vacuum drying oven, 72 DEG C dry to constant weight, and are cooled to room temperature and obtain material a；By 5 parts of chlorine
Change aluminium, 4 parts of sodium hydroxides and water well mixed, stir, be stored at room temperature 12d and obtain material a, then add 5 into material a
Part nano silicon, 2 parts of bentonites and 7 parts of tossas, are stored at room temperature 3d, then add 8 parts of silane coupler KH-560
It is well mixed with material a, 2.5h is stirred in 1800r/min rotating speeds, 105 DEG C are then heated to, 4h is dried, is cooled to powder after room temperature
It is broken that wear-resisting toughening modifying auxiliary agent is made.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of metal antirusting agent of high-wear resistance, it is characterised in that its raw material includes by weight：Methyl-silicone oil 6-12
Part, 3-9 parts of polyethylene glycol, 4-8 parts of citric acid, 6-12 parts of modified filler, modified 4-8 parts of antirust agent, wear-resisting toughening modifying auxiliary agent
5-15 parts, 4-8 parts of polyacrylic acid, 1-3 parts of calgon, 2-6 parts of sodium benzoate, 3-9 parts of lauryl sodium sulfate, three ethanol
4-8 parts of amine, 4-8 parts of silica gel, 2-5 parts of BTA, 1-6 parts of sodium olefin sulfonate, 1-4 parts of sodium metasilicate, natrium nitrosum 2-5
Part, 2-8 parts of dimethyl silicone polymer, 4-9 parts of dialkyldithiocarbamacompositions sodium, 3-9 parts of AEO, molybdic acid
2-8 parts of ammonium, 3-6 parts of DBSA, 4-8 parts of triethylene tetramine, 10-20 parts of deionized water.
2. the metal antirusting agent of high-wear resistance according to claim 1, it is characterised in that the raw material of modified filler is by weight
Amount part includes：1-8 parts of calcium stearate, 2-8 parts of nano-zinc borate, 1-6 parts of white carbon, 3-9 parts of magnesium hydroxide, wood fiber powder 1-
6 parts, 2-7 parts of hollow glass micropearl, 1-3 parts of silicon powder, 4-9 parts of methacrylate, 2-5 parts of silane resin acceptor kh-550, silicon
It is oily 3-8 parts.
3. the metal antirusting agent of high-wear resistance according to claim 1 or 2, it is characterised in that modified filler is by as follows
It is prepared by technique：Calcium stearate and nano-zinc borate are well mixed, stirring at low speed 10-25min is sealed at 50-60 DEG C, so
It is well mixed afterwards with white carbon, wood fiber powder, hollow glass micropearl and silicon powder, 45-55 DEG C of sealing stirring at low speed 5-
10min, adds magnesium hydroxide, methacrylate, silane resin acceptor kh-550 and silicone oil and is well mixed, be warming up to 135-
140 DEG C, stirring at low speed 10-20min, discharging is cooled to room temperature and obtains modified filler.
4. the metal antirusting agent of the high-wear resistance according to claim any one of 1-3, it is characterised in that modified antirust agent
Raw material include by weight：20-50 parts of nano aluminum nitride, 2-8 parts of aluminium hydroxide, 3-9 parts of trimethylolethane, polyisobutene
1-5 parts, 2-6 parts of nonyl phenol, 1-3 parts of gaultherolin, 2-6 parts of tricresyl phosphate, 3-9 parts of methacrylate, silicic acid
2-6 parts of calcium, 2-4 parts of lubricant, 4-8 parts of silane coupler KH-560.
5. the metal antirusting agent of the high-wear resistance according to claim any one of 1-4, it is characterised in that modified antirust agent
Prepared by following technique：Nano aluminum nitride is put into calcining furnace and calcines 1-5h at 750-850 DEG C, cools down, is put into 10-
2-4h is soaked in 12% hydrochloric acid solution, filtering is taken out, and is cleaned drying with clear water, 150-350 mesh powder is ground into, then with hydrogen-oxygen
Change aluminium, trimethylolethane, polyisobutene, nonyl phenol, gaultherolin, tricresyl phosphate, methacrylate, silicic acid
Calcium, lubricant and silane coupler KH-560 are well mixed, grinding, produce modified antirust agent.
6. the metal antirusting agent of the high-wear resistance according to claim any one of 1-5, it is characterised in that wear-resisting toughness reinforcing changes
The raw material of property auxiliary agent includes by weight：4-8 parts of starch, 5-15 parts of distilled water, 1-8 parts of maleic anhydride, 2-5 parts of ammonium persulfate,
3-6 parts of styrene, 4-8 parts of aluminium chloride, 2-5 parts of sodium hydroxide, 3-6 parts of nano silicon, 1-5 parts of bentonite, tossa
4-8 parts, 3-9 parts of Silane coupling reagent KH-570.
7. the metal antirusting agent of the high-wear resistance according to claim any one of 1-6, it is characterised in that wear-resisting toughness reinforcing changes
Property auxiliary agent is prepared by following technique：Under nitrogen protection, starch, distilled water and maleic anhydride are well mixed, Ran Housheng
Temperature is incubated 10-30min to 80-90 DEG C, then adds ammonium persulfate and is well mixed, and styrene mixing is added after stirring 5-15min
Uniformly, then stir 50-70min in 850-1250r/min rotating speeds, then heat to 85-95 DEG C, extract 40-50h, then in
In vacuum drying oven, 65-75 DEG C dries to constant weight, and is cooled to room temperature and obtains material a；Aluminium chloride, sodium hydroxide and water are well mixed,
Stir, be stored at room temperature 10-20d and obtain material a, nano silicon, bentonite and jute are then added into material a fine
Dimension, is stored at room temperature 2-6d, then adds silane coupler KH-560 and material a and is well mixed, in 1500-2500r/min rotating speeds
1-3h is stirred, 100-120 DEG C is then heated to, 2-5h is dried, is cooled to after room temperature and crushes obtained wear-resisting toughening modifying auxiliary agent.
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| CN109181529A (en) * | 2018-08-17 | 2019-01-11 | 南京力同重工机械有限公司 | A kind of steel member impregnating fluid and preparation method thereof |
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Application publication date: 20170811 |