CN107033635A - A kind of building coating for purifying air and its preparation method and application - Google Patents
A kind of building coating for purifying air and its preparation method and application Download PDFInfo
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- CN107033635A CN107033635A CN201611035021.2A CN201611035021A CN107033635A CN 107033635 A CN107033635 A CN 107033635A CN 201611035021 A CN201611035021 A CN 201611035021A CN 107033635 A CN107033635 A CN 107033635A
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- parts
- mixture
- illite
- building coating
- cumarin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
Abstract
The invention discloses a kind of building coating for purifying air and its preparation method and application, the building coating is made up of the raw material below according to parts by weight：41 49 parts of illite, 6 14 parts of methyl α-naphthyl acetate, 3 11 parts of cumarin, 22 30 parts of 1,2 propane diols, 8 16 parts of Lygodium japonicum.Illite is crushed, the processing of naphthalene acid solution heating stirring is added, mixture A is made；By cumarin, 1, mixture B is made in 2 propane diols, Lygodium japonicum mixing heated sealed stirring；Mixture A and mixture B Hybrid Heatings are stirred, add that deionized water is ultrasonically treated, be down to room temperature produces.Building coating produced by the present invention, can not only remove formaldehyde and peculiar smell, improve air quality, but also the effect with release anion, purification air, reusable, to people's nonhazardous, non-corrosiveness, performance is stable, preparation method is simple to operate, environment friendly and pollution-free, is easy to industrialized production.
Description
Technical field
The present invention relates to building material technical field, specifically a kind of building coating for purifying air and preparation method thereof and
Using.
Background technology
There is different degrees of VOC emission after existing interior decoration, the health of serious threat people.With society's hair
Exhibition, economic progress, people more focus on the features such as health, comfortableness, the feature of environmental protection, the aesthetic property of house decorative material.
Illite is a kind of common clay mineral, and the mother's ﹑ potassium feldspar weathering of Chang Youbai clouds is formed, and is originated in argillaceous rocks,
Or formed by other mineral alterations.It is often the middle transition mineral to form other clay minerals.Illite is the one of China
Plant new mineral.Domestic that Erie's stone ore is initially found in ferryboat head village of agger township, Antu, Jilin Province illite resource is enriched very much,
Resource reserve is verified more than 1.4 hundred million tons, prospective reserves surpasses 200,000,000 tons, belonged to single super-huge chiltern illite mineral deposit.
Illite has rich potassium, high alumina, low iron and the superior chemistry such as smooth, bright, fine and smooth, heat-resisting, physical property.She
Sharp stone can freely discharge anion and far infrared.Many researchs have shown that there is pole by the illite of processing in the world in recent years
Strong fungistatic effect, and a variety of harmful heavy metals of absorption and pernicious gas of energy.But illite is and it in the prior art
Its a variety of raw material complex role with identical effect, single illite is adsorbed with toxic gas DeGrain, existing
Technology is to its complex disposal process, and cost is high, it is impossible to meet needs.
The content of the invention
Formaldehyde and peculiar smell, release anion, the building coating for purifying air are removed it is an object of the invention to provide a kind of
And its preparation method and application, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides following technical scheme：
A kind of building coating for purifying air, is made up of the raw material below according to parts by weight：41-49 parts of illite, naphthalene second
Sour 6-14 parts, 3-11 parts of cumarin, 22-30 parts of 1,2- propane diols, 8-16 parts of Lygodium japonicum.
It is used as further scheme of the invention：The building coating of the purification air, by below according to the raw material of parts by weight
Composition：43-47 parts of illite, 8-12 parts of methyl α-naphthyl acetate, 5-9 parts of cumarin, 24-28 parts of 1,2- propane diols, 10-14 parts of Lygodium japonicum.
It is used as further scheme of the invention：The building coating of the purification air, by below according to the raw material of parts by weight
Composition：45 parts of illite, 10 parts of methyl α-naphthyl acetate, 7 parts of cumarin, 26 parts of 1,2- propane diols, 12 parts of Lygodium japonicum.
Another object of the present invention is to provide a kind of preparation method for the building coating for purifying air, comprises the steps of：
1) 30% ethanol of 11.5 times of methyl α-naphthyl acetate and its quality is mixed, naphthalene acid solution is made；Illite is crushed, mistake
100 mesh sieves, add naphthalene acid solution, insert in reactor and the stir process 1.3h at a temperature of 92 DEG C, mixture A is made；
2) cumarin, 1,2-PD, Lygodium japonicum are mixed, stir process 40-45min are sealed at a temperature of 67 DEG C,
Mixture B is made；
3) mixture A is mixed with mixture B, then in 200 DEG C of stir process 1.5h, then adds illite quality
2.8 times of deionized water, is heated to 86 DEG C and at such a temperature ultrasonically treated 48min, and ultrasonic power is 900W, is being down to room temperature
Produce building coating.
Another object of the present invention is to provide application of the building coating in air-treatment.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention is handled using methyl α-naphthyl acetate illite, then is interacted with cumarin, 1,2-PD, Lygodium japonicum
Obtained building coating, can not only remove formaldehyde and peculiar smell, improve air quality, but also empty with release anion, purification
The effect of gas.The coating of the present invention is not lost, i.e. reusable after used coating is calcined again, does not result in and builds
Building refuse.The present invention is to people's nonhazardous, non-corrosiveness, and performance is stable, with high absorption adhesion, can quick adsorption purification
Formaldehyde, gas with foreign flavor in air, it is quick in the case that visible ray or light are very weak, efficiently, enduringly eliminate first
Aldehyde, gas with foreign flavor, purification efficiency are higher, and purifying formaldehyde efficiency reaches 87-96%, and toluene purification efficiency reaches 58-68%, purification
Effect persistence is higher, and purifying formaldehyde effect persistence reaches 82-92%, and toluene clean-up effect persistence reaches 46-56%.This
Invention green and healthy are pollution-free, can discharge anion in air, and anion average increase is 80-108/cm3, pure and fresh sky
Gas.Preparation method of the present invention is simple to operate, environment friendly and pollution-free, is easy to industrialized production.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of building coating for purifying air is made up of the raw material below according to parts by weight：Erie
41 parts of stone, 6 parts of methyl α-naphthyl acetate, 3 parts of cumarin, 22 parts of 1,2- propane diols, 8 parts of Lygodium japonicum.
11.5 times of 30% ethanol of methyl α-naphthyl acetate and its quality is mixed, naphthalene acid solution is made；Illite is crushed, mistake
100 mesh sieves, add naphthalene acid solution, insert in reactor and the stir process 1.3h at a temperature of 92 DEG C, mixture A is made.
Cumarin, 1,2-PD, Lygodium japonicum are mixed, stir process 40min is sealed at a temperature of 67 DEG C, mixture B is made.Will
Mixture A is mixed with mixture B, then in 200 DEG C of stir process 1.5h, then add 2.8 times of illite quality go from
Sub- water, is heated to 86 DEG C and at such a temperature ultrasonically treated 48min, and ultrasonic power is 900W, and building painting is produced being down to room temperature
Material.
Embodiment 2
In the embodiment of the present invention, a kind of building coating for purifying air is made up of the raw material below according to parts by weight：Erie
49 parts of stone, 14 parts of methyl α-naphthyl acetate, 1 part of coumarin 1,30 parts of 1,2- propane diols, 16 parts of Lygodium japonicum.
11.5 times of 30% ethanol of methyl α-naphthyl acetate and its quality is mixed, naphthalene acid solution is made；Illite is crushed, mistake
100 mesh sieves, add naphthalene acid solution, insert in reactor and the stir process 1.3h at a temperature of 92 DEG C, mixture A is made.
Cumarin, 1,2-PD, Lygodium japonicum are mixed, stir process 45min is sealed at a temperature of 67 DEG C, mixture B is made.Will
Mixture A is mixed with mixture B, then in 200 DEG C of stir process 1.5h, then add 2.8 times of illite quality go from
Sub- water, is heated to 86 DEG C and at such a temperature ultrasonically treated 48min, and ultrasonic power is 900W, and building painting is produced being down to room temperature
Material.
Embodiment 3
In the embodiment of the present invention, a kind of building coating for purifying air is made up of the raw material below according to parts by weight：Erie
43 parts of stone, 8 parts of methyl α-naphthyl acetate, 5 parts of cumarin, 24 parts of 1,2- propane diols, 10 parts of Lygodium japonicum.
11.5 times of 30% ethanol of methyl α-naphthyl acetate and its quality is mixed, naphthalene acid solution is made；Illite is crushed, mistake
100 mesh sieves, add naphthalene acid solution, insert in reactor and the stir process 1.3h at a temperature of 92 DEG C, mixture A is made.
Cumarin, 1,2-PD, Lygodium japonicum are mixed, stir process 42min is sealed at a temperature of 67 DEG C, mixture B is made.Will
Mixture A is mixed with mixture B, then in 200 DEG C of stir process 1.5h, then add 2.8 times of illite quality go from
Sub- water, is heated to 86 DEG C and at such a temperature ultrasonically treated 48min, and ultrasonic power is 900W, and building painting is produced being down to room temperature
Material.
Embodiment 4
In the embodiment of the present invention, a kind of building coating for purifying air is made up of the raw material below according to parts by weight：Erie
47 parts of stone, 12 parts of methyl α-naphthyl acetate, 9 parts of cumarin, 28 parts of 1,2- propane diols, 14 parts of Lygodium japonicum.
11.5 times of 30% ethanol of methyl α-naphthyl acetate and its quality is mixed, naphthalene acid solution is made；Illite is crushed, mistake
100 mesh sieves, add naphthalene acid solution, insert in reactor and the stir process 1.3h at a temperature of 92 DEG C, mixture A is made.
Cumarin, 1,2-PD, Lygodium japonicum are mixed, stir process 42min is sealed at a temperature of 67 DEG C, mixture B is made.Will
Mixture A is mixed with mixture B, then in 200 DEG C of stir process 1.5h, then add 2.8 times of illite quality go from
Sub- water, is heated to 86 DEG C and at such a temperature ultrasonically treated 48min, and ultrasonic power is 900W, and building painting is produced being down to room temperature
Material.
Embodiment 5
In the embodiment of the present invention, a kind of building coating for purifying air is made up of the raw material below according to parts by weight：Erie
45 parts of stone, 10 parts of methyl α-naphthyl acetate, 7 parts of cumarin, 26 parts of 1,2- propane diols, 12 parts of Lygodium japonicum.
11.5 times of 30% ethanol of methyl α-naphthyl acetate and its quality is mixed, naphthalene acid solution is made；Illite is crushed, mistake
100 mesh sieves, add naphthalene acid solution, insert in reactor and the stir process 1.3h at a temperature of 92 DEG C, mixture A is made.
Cumarin, 1,2-PD, Lygodium japonicum are mixed, stir process 42min is sealed at a temperature of 67 DEG C, mixture B is made.Will
Mixture A is mixed with mixture B, then in 200 DEG C of stir process 1.5h, then add 2.8 times of illite quality go from
Sub- water, is heated to 86 DEG C and at such a temperature ultrasonically treated 48min, and ultrasonic power is 900W, and building painting is produced being down to room temperature
Material.
Comparative example 1
In addition to methyl α-naphthyl acetate is not contained, its material content and preparation process are consistent with embodiment 5.
Comparative example 2
In addition to Lygodium japonicum is not contained, its material content and preparation process are consistent with embodiment 5.
Comparative example 3
In addition to methyl α-naphthyl acetate and Lygodium japonicum is not contained, its material content and preparation process are consistent with embodiment 5.
Embodiment 6
Embodiment 1-5 and comparative example 1-3 coating are respectively used on the indoor wall that certain newly builds up, then carried out indoor
Formaldehyde in air, peculiar smell material carry out formaldehyde, the detection of toluene purification efficiency and formaldehyde, the detection of toluene clean-up effect persistence
(commission national building materials industrial technology supervision research center), detection establishing criteria JC/T 1074-2008《Indoor air cleaning
Change function coating material purifying property》.
Experimental condition：Sample size 200g, temperature (20 ± 2) DEG C, relative humidity (50 ± 10) %, lighting time：48h.Inspection
Survey result as shown in table 1.
Table 1
The data in table 1, building coating of the invention is under the interaction of each raw material to formaldehyde in air, peculiar smell
Material purifying formaldehyde efficiency, purifying formaldehyde effect persistence, toluene purification efficiency, the testing result of toluene clean-up effect persistence
Meet standard JC/T 1074-2008《Function of purifying indoor air coating material purifying property》In " I classes material " technical indicator
It is required that.
Anion-generating capacity detection (commission Building wood is carried out to room air to embodiment 1-5 and comparative example 1-3 coating
Expect industrial environment inspection center), detection establishing criteria JC/T 1016-2006《The method of testing of material anion-generating capacity》.Survey
Method for testing is that 100g samples are positioned over into 0.25m3Closed bin in, closed 24h produces negative aeroion tester (Air with the U.S.
Ion Counter).Testing result is as shown in table 2.Testing conditions：T=25 DEG C of temperature, relative humidity RH=60%；Detection time
Number：16 times.
Table 2
The data in table 2, building coating of the invention averagely increases under the interaction of each raw material to anion
Dosage is >=80/cm3。
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It may be appreciated other embodiment.
Claims (5)
1. a kind of building coating for purifying air, it is characterised in that be made up of the raw material below according to parts by weight：Illite 41-
49 parts, 6-14 parts of methyl α-naphthyl acetate, 3-11 parts of cumarin, 22-30 parts of 1,2- propane diols, 8-16 parts of Lygodium japonicum.
2. the building coating of purification air according to claim 1, it is characterised in that by below according to the raw material of parts by weight
Composition：43-47 parts of illite, 8-12 parts of methyl α-naphthyl acetate, 5-9 parts of cumarin, 24-28 parts of 1,2- propane diols, 10-14 parts of Lygodium japonicum.
3. the building coating of purification air according to claim 1, it is characterised in that by below according to the raw material of parts by weight
Composition：45 parts of illite, 10 parts of methyl α-naphthyl acetate, 7 parts of cumarin, 26 parts of 1,2- propane diols, 12 parts of Lygodium japonicum.
4. it is a kind of as described in claim 1-3 is any purification air building coating preparation method, it is characterised in that by with
Lower step composition：
1) 30% ethanol of 11.5 times of methyl α-naphthyl acetate and its quality is mixed, naphthalene acid solution is made；Illite is crushed, 100 are crossed
Mesh sieve, adds naphthalene acid solution, inserts in reactor and the stir process 1.3h at a temperature of 92 DEG C, mixture A is made；
2) cumarin, 1,2-PD, Lygodium japonicum are mixed, stir process 40-45min is sealed at a temperature of 67 DEG C, be made
Mixture B；
3) mixture A is mixed with mixture B, then in 200 DEG C of stir process 1.5h, then adds illite quality 2.8
Deionized water again, is heated to 86 DEG C and at such a temperature ultrasonically treated 48min, ultrasonic power is 900W, is being down to room temperature i.e.
Obtain building coating.
5. application of the building coating as described in claim 1-3 is any in air-treatment.
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| CN201611035021.2A CN107033635A (en) | 2016-11-23 | 2016-11-23 | A kind of building coating for purifying air and its preparation method and application |
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| CN201611035021.2A CN107033635A (en) | 2016-11-23 | 2016-11-23 | A kind of building coating for purifying air and its preparation method and application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880669A (en) * | 2017-12-20 | 2018-04-06 | 承德人和矿业有限责任公司 | Functional paint |
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| KR100407898B1 (en) * | 2000-07-18 | 2003-12-01 | 김명식 | liquid illite coating material for structure's surface |
| CN1912479A (en) * | 2006-07-21 | 2007-02-14 | 中山大学 | Application of nuclear element in air anion generation material |
| CN104725022A (en) * | 2015-03-18 | 2015-06-24 | 陈广田 | Illite composite paint |
| CN105272061A (en) * | 2015-11-14 | 2016-01-27 | 蒋文兰 | Illite color coating powder with air purifying function |
| CN105712697A (en) * | 2016-01-22 | 2016-06-29 | 福建科福材料有限公司 | Sanitary ceramics slip and preparation technology thereof |
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2016
- 2016-11-23 CN CN201611035021.2A patent/CN107033635A/en active Pending
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|---|---|---|---|---|
| KR100407898B1 (en) * | 2000-07-18 | 2003-12-01 | 김명식 | liquid illite coating material for structure's surface |
| CN1912479A (en) * | 2006-07-21 | 2007-02-14 | 中山大学 | Application of nuclear element in air anion generation material |
| CN104725022A (en) * | 2015-03-18 | 2015-06-24 | 陈广田 | Illite composite paint |
| CN105272061A (en) * | 2015-11-14 | 2016-01-27 | 蒋文兰 | Illite color coating powder with air purifying function |
| CN105712697A (en) * | 2016-01-22 | 2016-06-29 | 福建科福材料有限公司 | Sanitary ceramics slip and preparation technology thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880669A (en) * | 2017-12-20 | 2018-04-06 | 承德人和矿业有限责任公司 | Functional paint |
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Application publication date: 20170811 |