CN102154932A - Low-specific-gravity stone paper - Google Patents

Low-specific-gravity stone paper Download PDF

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CN102154932A
CN102154932A CN2011100561500A CN201110056150A CN102154932A CN 102154932 A CN102154932 A CN 102154932A CN 2011100561500 A CN2011100561500 A CN 2011100561500A CN 201110056150 A CN201110056150 A CN 201110056150A CN 102154932 A CN102154932 A CN 102154932A
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base paper
weight
paper layer
parts
lithopone
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CN102154932B (en
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崔江
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Dazheng New Material Zhaoqing Co ltd
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Abstract

The invention discloses low-specific-gravity stone paper relating to synthetic paper. The low-specific-gravity stone paper comprises a base paper layer and a coating layer, wherein the coating layer is coated on the base paper layer; the base paper layer comprises 15-30 parts by weight of synthetic resin and 70-85 parts by weight of mixing material, wherein the synthetic resin is polylactic acid, EVA (ethylene vinyl acetate copolymer), PP (polypropylene), PE (poly ehtylene) or a mixture of any two of the polylactic acid, the EVA, the PP and the PE; the mixing material is a hollow glass ball, coal ash or the mixture of the hollow glass ball and the coal ash; and the coating layer comprises 20-40 parts by weight of acrylic resin, 20-40 parts by weight of lithopone and 30-50 parts by weight of deionized water. The low-specific-gravity stone paper has the following benefits: the mixing material is the hollow glass ball or coal ash so that the mixing material has low specific gravity and good dispersity; the lithopone has good covering power, thus the weight of the paper is convenient to reduce, the paper quality is improved, and the manufacturing cost is reduced.

Description

The stone paper that a kind of proportion is little
Technical field
The present invention relates to stone paper, refer to the stone paper that a kind of proportion is little especially.
Background technology
The demand and the consumption figure of paper product constantly increase, and this is relevant with improving constantly of the progress of social civilization and human living standard.The tradition paper technology has following deficiency at least: 1, the main raw material of papermaking is the wood pulp that trees are made, and paper industry has consumed a large amount of valuable forest resources, is a key factor that causes earth ecology unbalance.2, paper industry also consumes the great amount of water resources and the energy.3, wet production is adopted in the production of various paper mostly, produce paper pulp by a series of chemical method and physical method, discharge a large amount of acid, alkali wasteliquid, contaminated soil and water body, the environment that the mankind are depended on for existence suffers to destroy and threatens, and need expend a large amount of inputs to the processing up to standard of acid, alkali wasteliquid, difficulty of governance is big, causes production cost to improve.4, production method complexity, equipment investment is big.
Whole world environmental issue is more and more outstanding, and the forest reserves constantly reduce, and traditional paper and manufacturing technology thereof have been proposed challenge.The synthetic paper of stone paper and so on arises at the historic moment, and is applied to all trades and professions.But the stone paper of producing is heavier than conventional paper at present, thereby the application of stone paper is limited to.Cause the heavy reason of stone paper more, one of them is that stone paper is a main raw material with artificial resin and Paris white, the proportion of Paris white (comprising heavy calcium carbonate and precipitated calcium carbonate powder) is bigger, and Paris white generally accounts for about 75%, causes stone paper proportion to increase.
Summary of the invention
The present invention is intended to the above-mentioned deficiency at traditional paper technology and present stone paper, provides a kind of proportion little stone paper, and its proportion is near traditional paper, and combination property is superior, generally is suitable for or the like.
In order to achieve the above object, finish above-mentioned task, the stone paper that a kind of proportion of the present invention is little adopts following technical scheme.
The little stone paper of structure a kind of proportion of the present invention is made up of base paper layer and coating layer, and coating layer is coated on the base paper layer;
Base paper layer is made up of synthetic resin and spice, and the parts by weight of synthetic resin are 15~30, and the parts by weight of spice are 70~85; Synthetic resin is PLA or EVA or PP or PE or any two kinds combination in them; Spice is hollow glass bead or flyash, or their combination;
The composition of coating layer comprises acrylic acid resin, lithopone and deionized water, and the parts by weight that account for separately are: acrylic acid resin 20~40, lithopone 20~40, deionized water 30~50;
Its procedure of processing is:
, with spice heat baking dehydration, make the percentage by weight of water content wherein be less than or equal to 0.2%, and stir;
Figure 241552DEST_PATH_IMAGE002
, synthetic resin powder mixed with the spice that stirs and stir, carry out banburying again and mediate and handle, and granulation in Granulation Equipments;
Figure 506312DEST_PATH_IMAGE003
, will send into calender through the raw material that granulation is handled and extrude, again by stretch processing, just obtain base paper layer;
Figure 164564DEST_PATH_IMAGE004
, base paper layer is carried out corona treatment, make the surface of base paper layer have certain roughness;
Figure 514774DEST_PATH_IMAGE005
, the acrylic acid resin of coating layer component heated to be dissolved in the deionized water, adds lithopone then and stirs, and makes the coating layered material;
Figure 651095DEST_PATH_IMAGE006
, will pass through
Figure 770360DEST_PATH_IMAGE005
The coating layered material that makes is coated in process
Figure 163296DEST_PATH_IMAGE004
The surface of the base paper layer of handling.
Technique scheme is further set forth:
The granularity of hollow glass bead is that the diameter of particle is for being equal to or less than 1 micron.
The fineness of flyash is equal to or greater than 200 orders.
The fineness of lithopone is equal to or greater than 600 orders.
The thickness of base paper layer is 0.02~2 millimeter.
The stone paper that a kind of proportion of the present invention is little, its beneficial effect is:
One, spice are hollow glass bead or flyash, its light specific gravity, good dispersion, the covering of lithopone might as well, be convenient to alleviate the weight of paper, improve paper quality, reduce manufacturing cost.
Its two, environment-friendly type.Biodegradable, belong to the environment friendly material, can not cause white pollution.
Its three, do not contain heavy metal, do not contain phthalate, can not produce the danger that plasticizer disengages.Can be as culture, food and sanitary paper.
Its four, pliable and tough good, the folding resistance to tearing is good, can be as notebook and textbook with paper etc.
The specific embodiment
Below, introduce the specific embodiment of the present invention.
Embodiment one:
The stone paper that a kind of proportion of the present invention is little is made up of base paper layer and coating layer, and coating layer is coated on the base paper layer.
Base paper layer is made up of synthetic resin and spice, and the parts by weight of synthetic resin are 15, and the parts by weight of spice are 70; Synthetic resin is PLA or EVA or PP or PE or any two kinds combination in them; Spice is hollow glass bead or flyash or their combination.
The composition of coating layer comprises acrylic acid resin, lithopone and deionized water, and the parts by weight that account for separately are: acrylic acid resin 20, lithopone 20, deionized water 30.
Its procedure of processing is:
, with spice heat baking dehydration, make the percentage by weight of water content wherein be less than or equal to 0.2%, and stir;
Figure 940814DEST_PATH_IMAGE002
, synthetic resin powder mixed with the spice that stirs and stir, carry out banburying again and mediate and handle, and granulation in Granulation Equipments;
Figure 914586DEST_PATH_IMAGE003
, will send into calender through the raw material that granulation is handled and extrude, again by stretch processing, just obtain base paper layer;
Figure 478422DEST_PATH_IMAGE004
, base paper layer is carried out corona treatment, make the surface of base paper layer have certain roughness;
Figure 319338DEST_PATH_IMAGE005
, the acrylic acid resin of coating layer component heated to be dissolved in the deionized water, adds lithopone then and stirs, and makes the coating layered material;
Figure 361243DEST_PATH_IMAGE006
, will pass through
Figure 455101DEST_PATH_IMAGE005
The coating layered material that makes is coated in process
Figure 626057DEST_PATH_IMAGE004
The surface of the base paper layer of handling.
The granularity of hollow glass bead is that the diameter of particle is for being equal to or less than 1 micron.
The fineness of flyash is equal to or greater than 200 orders.
The fineness of lithopone is equal to or greater than 600 orders.
The thickness of base paper layer is 0.02~2 millimeter.
Embodiment two:
The little stone paper of structure a kind of proportion of the present invention is made up of base paper layer and coating layer, and coating layer is coated on the base paper layer.
Base paper layer is made up of synthetic resin and spice, and the parts by weight of synthetic resin are 22, and the parts by weight of spice are 77; Synthetic resin is PLA or EVA or PP or PE or any two kinds combination in them; Spice is hollow glass bead or flyash or their combination.
The composition of coating layer comprises acrylic acid resin, lithopone and deionized water, and the parts by weight that account for separately are: acrylic acid resin 30, lithopone 30, deionized water 40.
Its procedure of processing is:
Figure 172576DEST_PATH_IMAGE001
, with spice heat baking dehydration, make the percentage by weight of water content wherein be less than or equal to 0.2%, and stir;
Figure 283751DEST_PATH_IMAGE002
, synthetic resin powder mixed with the spice that stirs and stir, carry out banburying again and mediate and handle, and granulation in Granulation Equipments;
Figure 232116DEST_PATH_IMAGE003
, will send into calender through the raw material that granulation is handled and extrude, again by stretch processing, just obtain base paper layer;
Figure 636290DEST_PATH_IMAGE004
, base paper layer is carried out corona treatment, make the surface of base paper layer have certain roughness;
Figure 607788DEST_PATH_IMAGE005
, the acrylic acid resin of coating layer component heated to be dissolved in the deionized water, adds lithopone then and stirs, and makes the coating layered material;
Figure 991496DEST_PATH_IMAGE006
, will pass through
Figure 558482DEST_PATH_IMAGE005
The coating layered material that makes is coated in process
Figure 572705DEST_PATH_IMAGE004
The surface of the base paper layer of handling.
The granularity of hollow glass bead is that the diameter of particle is for being equal to or less than 1 micron.
The fineness of flyash is equal to or greater than 200 orders.
The fineness of lithopone is equal to or greater than 600 orders.
The thickness of base paper layer is 0.02~2 millimeter.
Embodiment three:
The stone paper that a kind of proportion of the present invention is little is made up of base paper layer and coating layer, and coating layer is coated on the base paper layer.
Base paper layer is made up of synthetic resin and spice, and the parts by weight of synthetic resin are 30, and the parts by weight of spice are 85; Synthetic resin is PLA or EVA or PP or PE or any two kinds combination in them; Spice is hollow glass bead or flyash or their combination.
The composition of coating layer comprises acrylic acid resin, lithopone and deionized water, and the parts by weight that account for separately are: acrylic acid resin 40, lithopone 40, deionized water 50.
Its procedure of processing is:
Figure 535894DEST_PATH_IMAGE001
, with spice heat baking dehydration, make the percentage by weight of water content wherein be less than or equal to 0.2%, and stir;
Figure 723293DEST_PATH_IMAGE002
, synthetic resin powder mixed with the spice that stirs and stir, carry out banburying again and mediate and handle, and granulation in Granulation Equipments;
Figure 583933DEST_PATH_IMAGE003
, will send into calender through the raw material that granulation is handled and extrude, again by stretch processing, just obtain base paper layer;
Figure 142959DEST_PATH_IMAGE004
, base paper layer is carried out corona treatment, make the surface of base paper layer have certain roughness;
Figure 649901DEST_PATH_IMAGE005
, the acrylic acid resin of coating layer component heated to be dissolved in the deionized water, adds lithopone then and stirs, and makes the coating layered material;
Figure 640991DEST_PATH_IMAGE006
, will pass through
Figure 418454DEST_PATH_IMAGE005
The coating layered material that makes is coated in process The surface of the base paper layer of handling.
The granularity of hollow glass bead is that the diameter of particle is for being equal to or less than 1 micron.
The fineness of flyash is equal to or greater than 200 orders.
The fineness of lithopone is equal to or greater than 600 orders.
The thickness of base paper layer is 0.02~2 millimeter.
The above-mentioned specific embodiment only is preferred embodiment of the present invention.The technical staff who it is pointed out that the industry can make some distortion and improvement under the guidance of technical solution of the present invention.These distortion all are the scope of protection of the invention with improvement.

Claims (5)

1. the stone paper that proportion is little is made up of base paper layer and coating layer, and coating layer is coated on the base paper layer; It is characterized in that:
Base paper layer is made up of synthetic resin and spice, and the parts by weight of synthetic resin are 15~30, and the parts by weight of spice are 70~85; Synthetic resin is PLA or EVA or PP or PE or any two kinds combination in them; Spice is hollow glass bead or flyash or their combination;
The composition of coating layer comprises acrylic acid resin, lithopone and deionized water, and the parts by weight that account for separately are: acrylic acid resin 20~40, lithopone 20~40, deionized water 30~50;
Its procedure of processing is:
, with spice heat baking dehydration, make the percentage by weight of water content wherein be less than or equal to 0.2%, and stir;
Figure 892784DEST_PATH_IMAGE002
, synthetic resin powder mixed with the spice that stirs and stir, carry out banburying again and mediate and handle, and granulation in Granulation Equipments;
Figure 29148DEST_PATH_IMAGE003
, will send into calender through the raw material that granulation is handled and extrude, again by stretch processing, just obtain base paper layer;
Figure 556076DEST_PATH_IMAGE004
, base paper layer is carried out corona treatment, make the surface of base paper layer have certain roughness;
Figure 539075DEST_PATH_IMAGE005
, the acrylic acid resin of coating layer component heated to be dissolved in the deionized water, adds lithopone then and stirs, and makes the coating layered material;
Figure 370503DEST_PATH_IMAGE006
, will pass through
Figure 856979DEST_PATH_IMAGE005
The coating layered material that makes is coated in process
Figure 882704DEST_PATH_IMAGE004
The surface of the base paper layer of handling.
2. the little stone paper of a kind of proportion according to claim 1 is characterized in that: the granularity of hollow glass bead is that the diameter of particle is for being equal to or less than 1 micron.
3. the little stone paper of a kind of proportion according to claim 1, it is characterized in that: the fineness of flyash is equal to or greater than 200 orders.
4. according to the little stone paper of a kind of proportion of claim described 1, it is characterized in that: the fineness of lithopone is equal to or greater than 600 orders.
5. according to the little stone paper of a kind of proportion of claim described 1, it is characterized in that: the thickness of base paper layer is 0.02~2 millimeter.
CN201110056150.0A 2011-03-09 2011-03-09 The stone paper that a kind of proportion is little Active CN102154932B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102501474A (en) * 2011-10-20 2012-06-20 夏丽蓉 Short glass fiber PP stone paper and preparation method thereof
CN102898670A (en) * 2012-04-27 2013-01-30 天象集团有限责任公司 Biodegradable environmentally-friendly paper and preparation method thereof
CN102911592A (en) * 2012-05-14 2013-02-06 天象集团有限责任公司 Aqueous coating solution for surface of plastic paper and preparation method thereof
CN108248023A (en) * 2016-12-28 2018-07-06 现代自动车株式会社 Manufacture the method for three-dimensional objects and related three-dimensional objects
CN109024088A (en) * 2018-07-20 2018-12-18 无锡和烁丰新材料有限公司 A kind of formula and its manufacturing process of Ultra-low Specific weight synthetic paper

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01221594A (en) * 1988-02-29 1989-09-05 Nippon Kakoh Seishi Kk Production of cast-coated paper
JP2004149952A (en) * 2002-10-30 2004-05-27 Fuji Photo Film Co Ltd Support for recording material
CN101701433A (en) * 2009-11-18 2010-05-05 蔡茂友 Stone water-free paper-making method and flow
CN101768893A (en) * 2010-01-18 2010-07-07 武汉大学 Stone paper paint, preparation method thereof and stone paper prepared by stone paper paint
CN101831835A (en) * 2010-05-01 2010-09-15 陈美章 Stone papermaking method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01221594A (en) * 1988-02-29 1989-09-05 Nippon Kakoh Seishi Kk Production of cast-coated paper
JP2004149952A (en) * 2002-10-30 2004-05-27 Fuji Photo Film Co Ltd Support for recording material
CN101701433A (en) * 2009-11-18 2010-05-05 蔡茂友 Stone water-free paper-making method and flow
CN101768893A (en) * 2010-01-18 2010-07-07 武汉大学 Stone paper paint, preparation method thereof and stone paper prepared by stone paper paint
CN101831835A (en) * 2010-05-01 2010-09-15 陈美章 Stone papermaking method

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102501474A (en) * 2011-10-20 2012-06-20 夏丽蓉 Short glass fiber PP stone paper and preparation method thereof
CN102501474B (en) * 2011-10-20 2014-11-19 夏丽蓉 Short glass fiber PP stone paper and preparation method thereof
CN102898670A (en) * 2012-04-27 2013-01-30 天象集团有限责任公司 Biodegradable environmentally-friendly paper and preparation method thereof
CN102898670B (en) * 2012-04-27 2014-10-15 天象集团有限责任公司 Biodegradable environmentally-friendly paper and preparation method thereof
CN102911592A (en) * 2012-05-14 2013-02-06 天象集团有限责任公司 Aqueous coating solution for surface of plastic paper and preparation method thereof
CN102911592B (en) * 2012-05-14 2015-10-21 天象集团有限责任公司 For the water-based coating fluid and preparation method thereof on plastic paper surface
CN108248023A (en) * 2016-12-28 2018-07-06 现代自动车株式会社 Manufacture the method for three-dimensional objects and related three-dimensional objects
CN108248023B (en) * 2016-12-28 2022-01-07 现代自动车株式会社 Method for manufacturing a three-dimensional product and related three-dimensional product
CN109024088A (en) * 2018-07-20 2018-12-18 无锡和烁丰新材料有限公司 A kind of formula and its manufacturing process of Ultra-low Specific weight synthetic paper

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