CN107028255A - High temperature resistant, fire-retardant, anti-cutting, anti-cut gloves and preparation method thereof - Google Patents
High temperature resistant, fire-retardant, anti-cutting, anti-cut gloves and preparation method thereof Download PDFInfo
- Publication number
- CN107028255A CN107028255A CN201710444649.6A CN201710444649A CN107028255A CN 107028255 A CN107028255 A CN 107028255A CN 201710444649 A CN201710444649 A CN 201710444649A CN 107028255 A CN107028255 A CN 107028255A
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- Prior art keywords
- gloves
- inner bag
- fire
- cutting
- high temperature
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Classifications
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01505—Protective gloves resistant to mechanical aggressions, e.g. cutting. piercing
- A41D19/01511—Protective gloves resistant to mechanical aggressions, e.g. cutting. piercing made of wire-mesh, e.g. butchers' gloves
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01529—Protective gloves with thermal or fire protection
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/08—Organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D06M2101/36—Aromatic polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Abstract
The present invention provides a kind of high temperature resistant, it is fire-retardant, anti-cutting, it is anti-to cut gloves and preparation method thereof, high temperature resistant, it is fire-retardant, anti-cutting, it is anti-to cut gloves, including protective coat, it is arranged at the gloves inner bag in the protective coat, the protective coat is formed by covering yarn through knitting device, the covering yarn is wound around by outsourcing portion and is made on yarn core, the outsourcing portion is formed by aramid fiber through knitting device, the outer surface in the outsourcing portion has fire resistant latex coating, wire braid is compounded with the inside of the protective coat, the yarn core is long glass fiber, the gloves inner bag is the double-decker being made up of high temperature resistant silica gel, filled with inert gas in the cavity of the gloves inner bag, the gloves inner bag is mutually fixedly connected with the madial wall of the protective coat, with good high temperature resistant, skidproof effect, and protect the hand of user not to be burned, and by adding wire so that gloves have good anti-cutting is anti-to cut effect, and improve gloves service life.
Description
Technical field
The present invention relates to a kind of high temperature resistant, fire-retardant, anti-cutting, prevent cutting gloves and preparation method thereof.
Background technology
High temperature resistant of the prior art, fire-retardant, anti-cutting, it is anti-cut gloves, generally made from fire resistance fibre with completely cut off heat to
Human body is transmitted, and protects operating personnel's hand, but existing high temperature resistant, fire-retardant, anti-cutting, anti-cut gloves and there is following defect：
Due to the insufficient strength of fire resistance fibre, gloves are easily damaged, prevent cutting effect without good anti-cutting；
Existing high temperature resistant, fire-retardant, anti-cutting, it is anti-cut gloves and can not prevent heat radiation, and operator is easy in operation
Burnt by high temperature hot gas；
Existing high temperature resistant, fire-retardant, anti-cutting, it is anti-cut gloves and can not be worked in high temperature fluid, such as high-temperature water, due to existing height
Warm gloves are formed by fire resistance fibre braiding, therefore cause high temperature fluid to penetrate into phenomenon.
The content of the invention
It is an object of the invention to overcome defect present in prior art there is provided a kind of high temperature resistant, fire-retardant, anti-cutting, prevent
Gloves are cut, prevent cutting effect with high intensity, good anti-cutting, the anti-of gloves is substantially increased using the heat reflection effect of wire
Hot property, prevents that operator's hand from being burnt, in addition by setting inner bag to play the effect of secondary seal, can apply to high temperature
Operation in fluid.
To achieve the above object, the technical scheme is that there is provided a kind of high temperature resistant, fire-retardant, anti-cutting, preventing cutting gloves,
Including protective coat, the gloves inner bag being arranged in the protective coat, the protective coat is formed by covering yarn through knitting device,
The covering yarn is wound around by outsourcing portion and is made on yarn core, and the outsourcing portion is formed by aramid fiber through knitting device, described
The outer surface in outsourcing portion, which has, is compounded with wire braid, the yarn on the inside of fire resistant latex coating, the protective coat
Core is long glass fiber, and the gloves inner bag is in the double-decker being made up of high temperature resistant silica gel, the cavity of the gloves inner bag
Filled with inert gas, the gloves inner bag is mutually fixedly connected with the madial wall of the protective coat.
It is further improved to be：The long glass fiber is oxide glass constituent, the quality hundred converted by oxide
Point than representing with following compositions, i.e. phosphorus pentoxide 0.01~3%, silica 52~62%, aluminum oxide 10~16%,
Diboron trioxide 0~8%, magnesia 0~5%, calcium oxide 16~30%, alkali metal are Li and Na and K oxide
Resultant 0~2%.
It is further improved to be：The fire resistant latex coating includes following mass fraction raw material：Oiliness polyurethane 100
Part, 10-20 parts of solid, 40-60 parts of phosphate flame retardant of cyclisation, 30-40 parts of methyl ethyl ketone, 8-16 parts of latex powder.
It is further improved to be：The aramid fiber is modification of aramid fiber, and aramid fiber surface modified method is included such as
Lower step：
1）, aramid fiber beam is put into extraction device, be then 60~80 DEG C in temperature using 16~48h of acetone extraction
1~3h is dried in baking oven, the aramid fiber after slurry processing is obtained；
2）, the aramid fiber that chloride reagent and step one are handled is added in glass reactor, then closed reactor is placed on
Gamma-ray irradiation processing is carried out under 60Co irradiation bombs；Aramid fiber is then taken out, is placed into extraction device, using N, N- diformazans
Base formamide extracts 2~4h；Temperature is then placed in dry 1~3h in 150 DEG C of baking ovens；
3）, the aramid fiber that handles step 2 immerse in grafting agent, 0.1~3h is reacted under normal temperature and pressure；Then nothing is used
Water-ethanol rinses 10~30min；1~3h of re-dry, completes a kind of aramid fiber surface modified method.
It is further improved to be：Bonded admittedly by high-temperature plastic between the gloves inner bag and the wire braid
It is fixed.
It is further improved to be：The wire is metal aluminum foil silk.
It is further improved to be：The finger section and palmar hand of the protective coat are provided with some anti-skid bulges, described
Anti-skid bulge is that high-temperature plastic is raised.
A kind of high temperature resistant, fire-retardant, anti-cutting, the anti-preparation method for cutting gloves are also provided based on the same inventive concept present invention,
It is characterized in that：Comprise the following steps：
S1：Covering yarn is made using modification of aramid fiber, wire and long glass fiber；
S2：Covering yarn is woven into the blank for making protective coat using loom, then blank is cut, sewed outside formation protection
Set；
S3：High temperature resistant silica gel is processed into gloves inner bag using injection machine, is reserved on gloves inner bag and is filled with filling for inert gas
Stomata；
S4：In the outer application high-temperature plastic of gloves inner bag, gloves inner bag is fixed in protective coat；
S5：Inert gas is filled with into gloves inner bag by air-filled pore, then air-filled pore is sealed；
S6：It is by dotting machine that high-temperature plastic is raised in finger section and palmar hand the formation high-temperature plastic of protective coat；
S7：By the high temperature resistant after shaping, fire-retardant, anti-cutting, prevent cutting packaging and storage after gloves drying.
The advantages of the present invention are：Gloves are woven using aramid fiber and formed with good fire-retardant effect
Really, the emulsion coating that the fire resistant latex coating on surface is specifically formulated using this present invention is so that outer shell fabric can not only have
Effect reflection high temperature heat radiation heat, also with good water vapour permeability, high-temperature resistant result is very good, and outer shell fabric feel is soft
Soft, snugness of fit is strong, is acted during wearing more flexible.And latex corrugation more preferable grip can be provided, it is tear-proof, resistance to light
Micro- anti-puncture effect, fire-retardant and anti-cutting effect is provided using wire braid；
In addition by gloving into double-decker, protective coat not only improves the strong of gloves while high temperature resistant attribute is ensured
Spend, and have good anti-cutting is anti-to cut effect, not cracky, gloves inner bag is made of high temperature resistant silica gel, and in inner bag
Inert gas is inside filled with, anti-flaming effect is played using inert gas, and can enable the operator to grasp in high temperature fluid
Make, prevent high temperature fluid from penetrating into inside gloves.
Further improved effect is：By being modified processing to aramid fiber, improve aramid fiber and applied with latex
Surface bonding strength between layer, handles aramid fiber, and be used as grafting using chloride reagent using gamma-rays high-energy irradiation
Agent.Under x ray irradiation x effect, a chlorine atom in chloride reagent can be reacted with fiber surface phenyl ring, so that
Fiber surface produces acyl chlorides active group, based on this progress grafting processing, it is possible to achieve the increase of aramid fiber surface group, from
And increase the surface-active of aramid fiber；In addition, under the effect of irradiation of ray, chloride reagent can be to the table of aramid fiber
Face carries out oxide etch, improves the roughness of fiber surface, further the surface-active of increase aramid fiber.
Embodiment
With reference to embodiment, the embodiment to the present invention is further described.
The following examples are only intended to illustrate the technical solution of the present invention more clearly, and can not limit the present invention with this
Protection domain.
A kind of high temperature resistant, fire-retardant, anti-cutting, it is anti-cut gloves, including protective coat, the gloves that are arranged in the protective coat
Inner bag, the protective coat is formed by covering yarn through knitting device, and the covering yarn is wound around by outsourcing portion and is made on yarn core,
The outsourcing portion is formed by aramid fiber through knitting device, and the outer surface in the outsourcing portion has fire resistant latex coating, described anti-
Wire braid is compounded with the inside of shield overcoat, the yarn core is long glass fiber, and the gloves inner bag is by high temperature resistant silicon
Filled with inert gas in the double-decker that glue is made, the cavity of the gloves inner bag, the gloves inner bag and the protective coat
Madial wall be mutually fixedly connected.
It is connected firmly in order that obtaining between gloves inner bag and protective coat, and does not destroy the sealing of gloves inner bag, from
And inert gas seepage can be effectively prevented, bonded admittedly by high-temperature plastic between the gloves inner bag and the protective coat
It is fixed.
It is preferred embodiment that the wire is metal aluminum foil silk, and the heat reflection effect of aluminium foil is more in the present embodiment
By, therefore substantially increase the thermal radiation resistant ability of gloves.
When carrying out high-temperature operation for the convenience of the users, take away object when prevent object is slipped from causing danger phenomenon, it is described
The finger section and palmar hand of protective coat are provided with some anti-skid bulges, and the anti-skid bulge is that high-temperature plastic is raised.
The long glass fiber is oxide glass constituent, and the mass percent converted by oxide is represented with following
Composition, i.e. phosphorus pentoxide 2%, silica 55%, aluminum oxide 15%, diboron trioxide 7%, magnesia 4%, calcium oxide
18%th, alkali metal is the resultant 1% of Li and Na and K oxide.The long glass fiber silk being made of above-mentioned formula can
The B component evaporation capacity for causing environmental problem is reduced, meanwhile, in the case where manufacturing ramuscule glass fibre, it will not be dropped because of fracture of wire etc.
Low fabrication yield and high-grade glass fiber can be obtained, can effectively suppress because near bushing nozzle produce crystallization it is different
Thing and the fracture of wire occurred.Glass fiber physical strength after shaping is good.
The fire resistant latex coating includes following mass fraction raw material：100 parts of oiliness polyurethane, 15 parts of solid, ring
Change 50 parts of phosphate flame retardant, 35 parts of methyl ethyl ketone, 10 parts of latex powder.So that outer shell fabric not only can effectively reflect high temperature
Heat radiation heat, also with good water vapour permeability, high-temperature resistant result is very good, and outer shell fabric is soft, comfortable and easy to wear
Property it is strong, acted during wearing more flexible.And latex corrugation can provide more preferable grip, tear-proof, resistance to slight anti-puncture effect
Really, fire-retardant and anti-cutting effect is provided using wire braid；
The aramid fiber is modification of aramid fiber, and aramid fiber surface modified method comprises the following steps：
1）, aramid fiber beam is put into extraction device, be then 60~80 DEG C in temperature using 16~48h of acetone extraction
1~3h is dried in baking oven, the aramid fiber after slurry processing is obtained；
2）, the aramid fiber that chloride reagent and step one are handled is added in glass reactor, then closed reactor is placed on
Gamma-ray irradiation processing is carried out under 60Co irradiation bombs；Aramid fiber is then taken out, is placed into extraction device, using N, N- diformazans
Base formamide extracts 2~4h；Temperature is then placed in dry 1~3h in 150 DEG C of baking ovens；
3）, the aramid fiber that handles step 2 immerse in grafting agent, 0.1~3h is reacted under normal temperature and pressure；Then nothing is used
Water-ethanol rinses 10~30min；1~3h of re-dry, completes a kind of aramid fiber surface modified method.
By being modified processing to aramid fiber, the surface improved between aramid fiber and emulsion coating is combined by force
Degree, handles aramid fiber, and be used as grafting agent using chloride reagent using gamma-rays high-energy irradiation.In x ray irradiation x effect
Under, a chlorine atom in chloride reagent can be reacted with fiber surface phenyl ring, so as to produce acyl chlorides in fiber surface
Active group, based on this progress grafting processing, it is possible to achieve the increase of aramid fiber surface group, so as to increase aramid fiber
Surface-active；In addition, under the effect of irradiation of ray, chloride reagent can carry out oxide etch to the surface of aramid fiber,
The roughness of fiber surface is improved, further the surface-active of increase aramid fiber.
A kind of high temperature resistant, fire-retardant, anti-cutting, the anti-preparation method for cutting gloves of above-described embodiment, comprise the following steps：
S1：Covering yarn is made using aramid fiber, wire and long glass fiber；
S2：Covering yarn is woven into the blank for making protective coat using loom, then blank is cut, sewed outside formation protection
Set；
S3：High temperature resistant silica gel is processed into gloves inner bag using injection machine, is reserved on gloves inner bag and is filled with filling for inert gas
Stomata；
S4：In the outer application high-temperature plastic of gloves inner bag, gloves inner bag is fixed in protective coat；
S5：Inert gas is filled with into gloves inner bag by air-filled pore, then air-filled pore is sealed；
S6：It is by dotting machine that high-temperature plastic is raised in finger section and palmar hand the formation high-temperature plastic of protective coat；
S7：By the high temperature resistant after shaping, fire-retardant, anti-cutting, prevent cutting packaging and storage after gloves drying.
Technique effect and index：1st, high temperature resistant grade, 100 DEG C >=15s of heat resistance；
2nd, with good anti-anti- and resistance to cut index；
3rd, flame retardant rating, >=3 grades.
With：Army and police's security protection, is holding bucket, uniform crime and processing accident；Personal security in machinery manufacturing industry
Personnel protection etc. in protection, mechanical hazard protective, chemical industry manufacturing industry.
Based on preceding solution：The long glass fiber be oxide glass constituent in phosphorus pentoxide 0.01~
3%th, silica 52~62%, aluminum oxide 10~16%, diboron trioxide 0~8%, magnesia 0~5%, calcium oxide 16~
30%th, alkali metal is the resultant 0~2% of Li and Na and K oxide.As long as can be real in the range of this at this
Apply the object of the invention.
As long as the fire resistant latex coating includes following mass fraction raw material can reach this hair in following scope
Improving eyesight：100 parts of oiliness polyurethane, 10-20 parts of solid, 40-60 parts of phosphate flame retardant of cyclisation, methyl ethyl ketone 30-40
Part, 8-16 parts of latex powder.
The general principle and principal character and its advantage of the present invention has been shown and described above, the technical staff of the industry should
The understanding, the present invention is not limited to the above embodiments, the original for simply illustrating the present invention described in above-described embodiment and explanation
Reason, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes and improvements
It all fall within the protetion scope of the claimed invention, the claimed scope of the invention is by appended claims and its equivalent circle
It is fixed.
Claims (8)
1. a kind of high temperature resistant, fire-retardant, anti-cutting, anti-cut gloves, it is characterised in that：Including protective coat, it is arranged at outside the protection
Gloves inner bag in set, the protective coat is formed by covering yarn through knitting device, and the covering yarn is wound around by outsourcing portion
It is made on yarn core, the outsourcing portion is formed by aramid fiber through knitting device, the outer surface in the outsourcing portion has fire resistant latex
Wire braid is compounded with the inside of coating, the protective coat, the yarn core is long glass fiber, and the gloves inner bag is
Filled with inert gas in the double-decker being made up of high temperature resistant silica gel, the cavity of the gloves inner bag, the gloves inner bag and institute
The madial wall for stating protective coat is mutually fixedly connected.
2. silica 52~62%, aluminum oxide 10~16%, diboron trioxide 0~8%, magnesia 0~5%, calcium oxide 16
~30%, alkali metal is the resultant 0~2% of Li and Na and K oxide.
3. high temperature resistant as claimed in claim 1, fire-retardant, anti-cutting, anti-cut gloves, it is characterised in that：The fire resistant latex is applied
Layer includes following mass fraction raw material：100 parts of oiliness polyurethane, 10-20 parts of solid, cyclisation 40-60 parts of phosphate flame retardant,
30-40 parts of methyl ethyl ketone, 8-16 parts of latex powder.
4.1）, aramid fiber beam is put into extraction device, be then 60~80 DEG C in temperature using 16~48h of acetone extraction
Baking oven in dry 1~3h, obtain slurry processing after aramid fiber；
2）, the aramid fiber that chloride reagent and step one are handled is added in glass reactor, then closed reactor is placed on
Gamma-ray irradiation processing is carried out under 60Co irradiation bombs；Aramid fiber is then taken out, is placed into extraction device, using N, N- diformazans
Base formamide extracts 2~4h；Temperature is then placed in dry 1~3h in 150 DEG C of baking ovens；
3）, the aramid fiber that handles step 2 immerse in grafting agent, 0.1~3h is reacted under normal temperature and pressure；Then nothing is used
Water-ethanol rinses 10~30min；1~3h of re-dry, completes a kind of aramid fiber surface modified method.
5. high temperature resistant as claimed in claim 1, fire-retardant, anti-cutting, anti-cut gloves, it is characterised in that：The gloves inner bag and institute
State and be adhesively fixed by high-temperature plastic between wire braid.
6. high temperature resistant as claimed in claim 1, fire-retardant, anti-cutting, anti-cut gloves, it is characterised in that：The wire is metal
Aluminium foil fibre.
7. high temperature resistant as claimed in claim 1, fire-retardant, anti-cutting, anti-cut gloves, it is characterised in that：The hand of the protective coat
Finger portion and palmar hand are provided with some anti-skid bulges, and the anti-skid bulge is that high-temperature plastic is raised.
8. a kind of high temperature resistant, fire-retardant, anti-cutting, the anti-preparation method for cutting gloves, it is characterised in that：Comprise the following steps：
S1：Covering yarn is made using modification of aramid fiber, wire and long glass fiber；
S2：Covering yarn is woven into the blank for making protective coat using loom, then blank is cut, sewed outside formation protection
Set；
S3：High temperature resistant silica gel is processed into gloves inner bag using injection machine, is reserved on gloves inner bag and is filled with filling for inert gas
Stomata；
S4：In the outer application high-temperature plastic of gloves inner bag, gloves inner bag is fixed in protective coat；
S5：Inert gas is filled with into gloves inner bag by air-filled pore, then air-filled pore is sealed；
S6：It is by dotting machine that high-temperature plastic is raised in finger section and palmar hand the formation high-temperature plastic of protective coat；
S7：By the high temperature resistant after shaping, fire-retardant, anti-cutting, prevent cutting packaging and storage after gloves drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710444649.6A CN107028255A (en) | 2017-06-13 | 2017-06-13 | High temperature resistant, fire-retardant, anti-cutting, anti-cut gloves and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710444649.6A CN107028255A (en) | 2017-06-13 | 2017-06-13 | High temperature resistant, fire-retardant, anti-cutting, anti-cut gloves and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107028255A true CN107028255A (en) | 2017-08-11 |
Family
ID=59542155
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|---|---|---|---|
| CN201710444649.6A Pending CN107028255A (en) | 2017-06-13 | 2017-06-13 | High temperature resistant, fire-retardant, anti-cutting, anti-cut gloves and preparation method thereof |
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| CN (1) | CN107028255A (en) |
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| CN109105985A (en) * | 2018-09-23 | 2019-01-01 | 南通嘉得利安全用品有限公司 | A kind of proximity gloves |
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| CN109105985A (en) * | 2018-09-23 | 2019-01-01 | 南通嘉得利安全用品有限公司 | A kind of proximity gloves |
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Application publication date: 20170811 |
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| RJ01 | Rejection of invention patent application after publication |