CN107027833A - A kind of plant promoter - Google Patents

A kind of plant promoter Download PDF

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Publication number
CN107027833A
CN107027833A CN201710436690.9A CN201710436690A CN107027833A CN 107027833 A CN107027833 A CN 107027833A CN 201710436690 A CN201710436690 A CN 201710436690A CN 107027833 A CN107027833 A CN 107027833A
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CN
China
Prior art keywords
sericine
plant promoter
water hyacinth
gardenoside
present
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Pending
Application number
CN201710436690.9A
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Chinese (zh)
Inventor
朱潜荣
朱梅
朱建文
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GUANGXI SHANYUN BIOCHEMISTRY TECHNOLOGY Co Ltd
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GUANGXI SHANYUN BIOCHEMISTRY TECHNOLOGY Co Ltd
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Priority to CN201710436690.9A priority Critical patent/CN107027833A/en
Publication of CN107027833A publication Critical patent/CN107027833A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/10Animals; Substances produced thereby or obtained therefrom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40Liliopsida [monocotyledons]

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Microbiology (AREA)
  • Pest Control & Pesticides (AREA)
  • Biotechnology (AREA)
  • Mycology (AREA)
  • Virology (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of plant promoter, the weight proportion of the plant promoter each component is:Gardenoside is 2~5 parts, and water hyacinth extract is 1~3 part, 3~6 parts of sericine.Sericine as the raw material of plant promoter, i.e., is applied to plant promoter field by the present invention first using sericine, has widened the application field of sericine, improves the economic value of sericine.In addition, sericine of the present invention can be that obtained sericine is reclaimed from silk gum waste liquid using conventional method, the discharge of silk gum waste water can be reduced, environmental pollution is reduced.The plant promoter has good water solubility simultaneously, and hestening rooting and crop yield effect are notable, the high advantage of natural content.

Description

A kind of plant promoter
Technical field
The present invention relates to a kind of plant promoter.
Background technology
China is the country for planting Sang Yangcan earliest in the world, and away from the present, oneself has more than 7,000 years.Bombyx-mori Silk Proteins matter content is up to 98%, the sericin that it is covered in outside silk-fibroin by 70-80% silk-fibroin and 20-30% is constituted.Existing enterprise's life During production, sericine can be taken as Fei Qi Wu Sui discharge of wastewater to fall in filature and concise process, be not only With the huge waste of raw material, and cause very big pressure to water environment pollution.Counted according to Zhong Shang industrial research institute, National about 150,000 tons of silk yield in 2015, about 3-4 ten thousand tons sericines are discharged, and the waste of raw material and environment are dirty Dye is startling.
At present, the widely used hormone and growth regulator for promoting plant establishment is many both at home and abroad, mainly there is indoles second Acid(IAA), indolebutyric acid(IBA), methyl α-naphthyl acetate(NAA), gibberellin(Gibberellin), the basic element of cell division(Cytokinins)、 Abscisic acid(ABA)And the serial root-inducing powders of ABT etc..Existing disclosed plant hormone has following weak point:
(1)Poorly water-soluble.Such as heteroauxin, indolebutyric acid, methyl α-naphthyl acetate, most of gibberellin, ABT root-inducing powders are all insoluble in Water is slightly soluble in water.Need to be diluted with water again after first being dissolved with alcohol when using, or be allowed into salt with alkali and be dissolved in water, this Use cost is not only increased, and increases configuration step.
(2)Natural content is low, it is difficult to be separated to the quantity of enough applications.Such as 3 tons cauliflower blades only extract 3 milligrams Heteroauxin, content is part per billion, and per kilogram soybean contains 14 milligrams of abscisic acid, and content is 14/1000000ths, cell point The content for splitting the zeatin of one of element is about 1/100000000th.
(3)Rooting efficiency is not good, especially to the difficult rare or endangered species of some cuttage root-takings, commonly uses the life of plant hormone Root rate is low, promotes root growth and development effect not good.
Apply for and obtain the patent of invention of mandate before the applicant of present patent application《Plant increasing agent and its preparation side Method and its application that vegetable plants are increased production》(The patent No. 201210238833.2), extracted using Gardenoside and water hyacinth Thing is mixed, its good water solubility, and significantly, natural content is high, can effectively solve the problem that existing for hestening rooting and crop yield effect A series of problems for promoting plant establishment hormone and growth regulator presence of the compositions such as heteroauxin, indolebutyric acid, methyl α-naphthyl acetate. If can combine sericin with above-mentioned patent, the application field of sericine can not only be widened, silk gum egg is improved The economic value of white matter, and the discharge of silk gum waste water can be reduced, reduce environmental pollution.
The content of the invention
The technical problem to be solved in the present invention is:A kind of plant yield-increasing using sericine as one of primary raw material is provided Agent, can not only widen the application field of sericine, and can reduce pollution of the silk gum waste water to environment, while the plant Thing increasing agent has good water solubility, and significantly, the high advantage of natural content is solved above-mentioned existing for hestening rooting and crop yield effect There is problem present in technology.
Solving the technical scheme of above-mentioned technical problem is:A kind of plant promoter, the weight proportion of its each component is:
2~5 parts of Gardenoside, 1~3 part of water hyacinth extract, 3~6 parts of sericine;
Described Gardenoside is the Gardenoside that high-purity gardenoside, i.e. purity are more than or equal to 98%;
Described sericine is the sericine that purity is more than or equal to 90%.
Described sericine is that obtained sericine is reclaimed from silk gum waste liquid using conventional method.
A kind of plant promoter of the present invention, it is prepared using following methods,
(1)The preparation of water hyacinth extract:Water hyacinth:Ethanol is 1 by weight:10~15, by water hyacinth be put into 50~60 DEG C, Mass percentage concentration is extracts in 75~85% ethanol solution, after extraction 1.5~2 hours, then with power is 120~150W Ultrasonic wave carries out 30~40min ultrasonic wave extraction, and centrifugation is removed slag and obtains water hyacinth crude extract, water hyacinth crude extract again according to Secondary process thin-layer chromatography and silica gel column chromatography separating purification, the water hyacinth for obtaining moisture content≤7% by vacuum concentration after purification are carried Take thing;
(2)The preparation of plant promoter:By weight, by 3~6 parts of sericine, 2~5 parts of Gardenoside and step(1)It is made 1~3 part of well mixed preparation of water hyacinth extract obtain plant promoter.
One of present invention plants plant promoter, and it has the advantages that:
1. sericine is applied to plant first and is increased by the present invention using raw material of the sericine as plant promoter Is produced from agent field, the application field of sericine has been widened, the economic value of sericine is improved.In addition, of the present invention Sericine can be that obtained sericine is reclaimed from silk gum waste liquid using conventional method, can reduce silk gum give up The discharge of water, reduces environmental pollution.From the angle of the manufacturing enterprises such as filature, production cost can be saved for enterprise, simultaneously Solve the problems, such as the discharge of wastewater of enterprise.
2. good water solubility, hestening rooting and crop yield effect are notable:Increasing agent of the present invention is the cape jasmine by integration of drinking and medicinal herbs Water-soluble extractive Gardenoside and wild water hyacinth water-soluble extractive, sericine composition, Gardenoside and water hyacinth Water-soluble extractive belong to water-soluble plant hormone, with excellent water solubility, the water solubility of sericine is also fine, meets Water can dissolve rapidly, configure extremely easy to use, entering water 1 minute can be entirely molten, adapts to the application of all kinds of soil, to soil not Any side effect can be produced.Increasing agent of the present invention is not only notable to hestening rooting and crop yield effect, moreover it is possible to lift greengrocery The ability of plant disease-resistant insect pest.
3. natural content is high:The component Gardenoside of increasing agent of the present invention belongs to natural phytohormone, cape jasmine fruit it is natural Content reaches more than 4~6%, is the natural content highest plant hormone found so far, than high thousand times of other plant hormone-content More than;The content of another component water hyacinth extract is also higher, and raw material water hyacinth is also readily obtained.
4. cost is low:If every gram of price of plant promoter of the present invention is identical with ABT1 root-inducing powders, but in configuration solution When every gram of ABT1 root-inducing powder must add the ethanol of 500ml 95%, water otherwise can not be dissolved in entirely, the negative of user had so both been added Load, adds time and the step of configuration solution again, and plant promoter of the present invention is directly dissolved in water, it is not necessary to which other auxiliary are molten Agent, reduces cost.And the water hyacinth used in the present invention is wild, the production cost of plant promoter reduce further.
5. preparation technology is simple, easy to use, it is easy to promote the use of:The preparation technology of plant promoter of the present invention is simple, Seed soaking, seed dressing, root dipping, heading and foliage dressing that increasing agent may be directly applied to during crop-planting, increasing agent is direct Add water and be configured to suitable concentration and can be used, it is easy to use, using in extensive range, it is easy to promote the use of.
6. environmental protection, reduces environmental pollution:One of raw materials of the present invention sericine can be using conventional Method reclaims obtained sericine from silk gum waste liquid, can reduce the discharge of silk gum waste liquid, favourable to environmental protection, this Another raw material of invention is water hyacinth, and pollution of the water hyacinth at present in China's water body is very big, and country is also for processing Very big cost has been spent in this kind of pollution, and the present invention just can effectively utilize water hyacinth, turned waste into wealth, both reduced The pollution of environment, protects environment again, has also saved the cost that a part is used to handle water hyacinth pollution to country.And this hair Bright main component is sericine, Gardenoside and water hyacinth extract, does not use other chemical fertilizer compositions, is adapted to each The application of class soil, any side effect will not be produced to soil, reduced the pollution of soil, also protected soil environment.
Brief description of the drawings
Fig. 1:Use the capsicum design sketch of the present invention.
Fig. 2:The capsicum design sketch of the present invention is not used.
Fig. 3:Use the rape design sketch of the present invention.
Fig. 4:The rape design sketch of the present invention is not used.
Fig. 5:Use the pawpaw design sketch of the present invention(The usage amount of the present invention is more).
Fig. 6:Use the pawpaw design sketch of the present invention(The usage amount of the present invention is less).
Fig. 7:The pawpaw design sketch of the present invention is not used.
Embodiment
Embodiment 1:A kind of plant promoter, the weight proportion of its each component is:
2~5 parts of Gardenoside, 1~3 part of water hyacinth extract, 3~6 parts of sericine.
The preferred high-purity gardenoside of Gardenoside described in the present embodiment, i.e. purity are more than or equal to 98% Gardenoside.
Described sericine is the sericine that purity is more than or equal to 90%.
The weight proportion of each component is as shown in the table in embodiment 1:
In the present embodiment, described sericine is that obtained sericin is reclaimed from silk gum waste liquid using conventional method Matter, the general technological process of described conventional method is:Silk reeling wastewater recovery → filtering → UF membrane purification → film concentration → spray Mist it is dry purity more than 90% sericine finished product.As one kind conversion, sericine of the present invention can also It is sericine directly isolated from Bombyx-mori Silk Proteins.
Embodiment 2:Plant promoter described in embodiment 1, it is prepared using following methods:
(1)The preparation of water hyacinth extract:Water hyacinth:Ethanol is 1 by weight:10, water hyacinth is put into 50 DEG C, quality percentage Concentration is extracts in 80% ethanol solution, after extracting 1.5 hours, then the ultrasonic wave for being 120W with power carries out 30min ultrasound Ripple is extracted, and centrifugation, which is removed slag, obtains water hyacinth crude extract, and water hyacinth crude extract sequentially passes through thin-layer chromatography and silica gel column layer again Analysis is isolated and purified, and obtains moisture content≤7%, the water hyacinth extract of purity >=90% by vacuum concentration after purification;It is concentrated in vacuo Condition be:Vacuum:- 0.07~-0.09Mpa, temperature:52~55 DEG C, in thin-layer chromatography separation process, solvent is By acetone and chloroform by volume 1:9~12 compositions;In silica gel column chromatography separation process, mobile phase be by acetone and hexane by Volume ratio 1:6~10 compositions.
(2)The preparation of plant promoter:By weight, by 3~6 parts of sericine, 2~5 parts of Gardenoside and water hyacinth 1~3 part of well mixed preparation of extract obtains plant promoter.
In the present embodiment, described Gardenoside can be prepared using any means, as long as obtained Gardenoside purity is more than Equal to 98%.
In the present embodiment, pass through step(1)The water hyacinth extract prepared, with reference to UV-VIS, IR, MS and NMR etc. Method carries out Preliminary Identification to compound.As a result show, the compound may be 6- acetyl -4,6- dimethyl -2,4- hexamethylene two The isomer of ketenes or cyclic diolefine ketone.
The application that plant promoter of the present invention increases production to vegetable plants, is to be used for described plant promoter One, two, three, four in seed soaking, seed dressing, root dipping, heading or foliage dressing in vegetable plants planting process or In five processes, the usage amount of plant promoter is:
1. soak seed:The use of plant promoter concentration of aqueous solution is 10~20 mg/kg, seed is 10~20 mg/kg's with concentration The weight of plant promoter compares 1:2;
2. dress seed:The use of plant promoter concentration of aqueous solution is 15~25 mg/kg;Seed is 15~25 mg/kg's with concentration The weight of plant promoter compares 1:1;
3. root dipping:The use of plant promoter concentration of aqueous solution is 20~80 mg/kg;Root and the plant that concentration is 20~80 mg/kg The weight of thing increasing agent compares 1:4;
4. ear:The use of plant promoter concentration of aqueous solution is 50~100 mg/kg;The blade face of plant is sprayed directly on when using On fringe, usage amount is determined according to actual conditions;
5. foliage dressing:The use of plant promoter concentration of aqueous solution is 20~40 mg/kg;Typically directly sprayed in crop flowers Blade face is spilt, usage amount is determined according to actual conditions.
Described vegetable plants refer to cucumber, pawpaw, capsicum, fresh kidney beans, peanut and rape, certain plant yield-increasing of the present invention Agent can be also used for the fertilising of other vegetable plants, or for other class crops for example:Wheat and the fertilising of cotton, equal energy Reach good effect of increasing production.
Experiment is proved:After increasing agent of the present invention, cucumber production promoting 40% or so, pawpaw volume increase 50% or so, rape yield increasing 50% or so, capsicum volume increase 30% or so, moreover it is possible to lift the ability of vegetable plants disease and insect resistance.
Contrast test 1:Effect of increasing production for cucumber
Arranged using random district's groups, use plant promoter of the present invention(The mg/kg of increasing agent concentration of aqueous solution 10~20)To cucumber kind Son immersion 1h, is contrasted, the ratio between seed soaking liquid measure and seed weight are 2 with clear water immersion 1h:1, immersion 4 times is repeated, all harvest The fresh production of meter, carries out statistical analysis.Result of the test shows that plant promoter of the present invention can significantly improve the fresh yield of cucumber, volume increase 37.7%.Production-increasing function, which is mainly, significantly increases fruit number, and next adds single fruit weight.The straight fruit of fresh cucumbers can also be dramatically increased Rate, so as to improve the commodity value of cucumber.There is certain resistance to cucumber downy mildew, it is possible to decrease the incidence of disease 9%.
Contrast test 2:Effect of increasing production for pawpaw
It is 10mg/kg plant promoters of the present invention with concentration, immersion pawpaw seed 3h;It is 25mg/kg plants of the present invention with concentration Increasing agent is in foliage-spray 1 time after pawpaw knot one week of melon, if clear water check experiment.Harvesting metering in batches after maturation, all After harvest is finished, statistical analysis is carried out to yield.It can be seen that from yield result, plant promoter has preferable volume increase to pawpaw Effect, facilitation is restarted to the single pod of pawpaw, and main efficacy results are increase total outputs.Volume increase more than 45%, to pawpaw resistance against diseases There is enhanced trend.
Contrast test 3:For improving yield of hot pepper
10 days after capsicum first flower, sprayed respectively with 20mg/kgABT4 root-inducing powders and 20mg/kg plant promoters of the present invention respectively The blade face for spilling capsicum compares experiment.Harvested respectively after maturation, the result control of two kinds of processing:With the capsicum of ABT4 root-inducing powders Volume increase 7.5%, 30.1% is increased production with the capsicum of plant promoter of the present invention.
Contrast test 4:For rape seed soaking
Rape seed half an hour is soaked respectively with 10mg/kgABT4 root-inducing powders, 10mg/kg plant promoters of the present invention then to broadcast Kind, the ratio between seed soaking liquid measure and seed weight are 2:1.The seedling of the latter's processing is bigger than the former, Ye great, dark green oily tender, and without red Leaf.

Claims (3)

1. a kind of plant promoter, it is characterised in that:The weight proportion of its each component is:
2~5 parts of Gardenoside, 1~3 part of water hyacinth extract, 3~6 parts of sericine;
Described Gardenoside is the Gardenoside that high-purity gardenoside, i.e. purity are more than or equal to 98%;
Described sericine is the sericine that purity is more than or equal to 90%.
2. a kind of plant promoter as claimed in claim 1, it is characterised in that:Described sericine is to use routine side Method reclaims obtained sericine from silk gum waste liquid.
3. a kind of plant promoter as claimed in claim 1 or 2, it is characterised in that:It is prepared using following methods,
(1)The preparation of water hyacinth extract:Water hyacinth:Ethanol is 1 by weight:10~15, by water hyacinth be put into 50~60 DEG C, Mass percentage concentration is extracts in 75~85% ethanol solution, after extraction 1.5~2 hours, then with power is 120~150W Ultrasonic wave carries out 30~40min ultrasonic wave extraction, and centrifugation is removed slag and obtains water hyacinth crude extract, water hyacinth crude extract again according to Secondary process thin-layer chromatography and silica gel column chromatography separating purification, the water hyacinth for obtaining moisture content≤7% by vacuum concentration after purification are carried Take thing;
(2)The preparation of plant promoter:By weight, by 3~6 parts of sericine, 2~5 parts of Gardenoside and step(1)It is made 1~3 part of well mixed preparation of water hyacinth extract obtain plant promoter.
CN201710436690.9A 2017-06-12 2017-06-12 A kind of plant promoter Pending CN107027833A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020035361A1 (en) * 2018-08-17 2020-02-20 Amsilk Gmbh Use of a structural polypeptide for plant coating

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101041486A (en) * 2007-04-24 2007-09-26 无锡迪威勒普科技有限公司 Method for treatment and comprehensive utilization of silk production waste water
JP2010254596A (en) * 2009-04-22 2010-11-11 Yamaka Seiren:Kk Plant additive
CN102771520A (en) * 2012-07-11 2012-11-14 广西山云生化科技有限公司 Plant yield increasing agent, preparation method thereof and applications in increasing yield of vegetable plants
CN104058876A (en) * 2014-07-14 2014-09-24 丹东中天柞蚕生物科技有限公司 Sericin multi-effect liquid bioorganic fertilizer and production method
CN104058877A (en) * 2014-07-14 2014-09-24 丹东中天柞蚕生物科技有限公司 Biological organic compound fertilizer of sericin protein and manufacturing method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101041486A (en) * 2007-04-24 2007-09-26 无锡迪威勒普科技有限公司 Method for treatment and comprehensive utilization of silk production waste water
JP2010254596A (en) * 2009-04-22 2010-11-11 Yamaka Seiren:Kk Plant additive
CN102771520A (en) * 2012-07-11 2012-11-14 广西山云生化科技有限公司 Plant yield increasing agent, preparation method thereof and applications in increasing yield of vegetable plants
CN104058876A (en) * 2014-07-14 2014-09-24 丹东中天柞蚕生物科技有限公司 Sericin multi-effect liquid bioorganic fertilizer and production method
CN104058877A (en) * 2014-07-14 2014-09-24 丹东中天柞蚕生物科技有限公司 Biological organic compound fertilizer of sericin protein and manufacturing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020035361A1 (en) * 2018-08-17 2020-02-20 Amsilk Gmbh Use of a structural polypeptide for plant coating
CN115956563A (en) * 2018-08-17 2023-04-14 阿姆西尔克有限公司 Use of structural polypeptides in plant coatings

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RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170811