CN107022239A - Environment-friendly water-based scratch resistance dumb paint - Google Patents
Environment-friendly water-based scratch resistance dumb paint Download PDFInfo
- Publication number
- CN107022239A CN107022239A CN201710079467.3A CN201710079467A CN107022239A CN 107022239 A CN107022239 A CN 107022239A CN 201710079467 A CN201710079467 A CN 201710079467A CN 107022239 A CN107022239 A CN 107022239A
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- parts
- scratch resistance
- agent
- emulsion
- acrylic emulsion
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of environment-friendly water-based scratch resistance dumb paint, it includes the component of following parts by weight：26~35 parts of acrylic emulsion A, 20~29 parts of acrylic emulsion B, 15~24 parts of Polyurethane emulsion, 0.5~3 part of wetting agent, 0.5~3 part of defoamer, 0.5~3 part of levelling agent, 0.5~3 part of wax powder, 10~20 parts of pigment, 0.5~4 part of dispersant, 0.5~3 part of scratch resistance agent, 0.5~3 part of thickener, 0.5~4 part of pH adjusting agent；Wherein acrylic emulsion A is that Shanghai is the modern acrylic emulsion of alliance 7410 in Shanghai towards the acrylic emulsions of industry TR 803, acrylic emulsion B is multiplied.This water-based ink has pollution-free, environmentally friendly reliable, and solvent is aqueous low, ink noresidue on packaging material, non-toxic, easily reclaims, the advantages of cheap, and the hardness of film that ink of the invention is obtained through anilox roll is high, and adhesive force is strong, and printing levelability is good.
Description
Technical field
The invention belongs to ink area, tool manikin is related to a kind of environment-friendly water-based scratch resistance dumb paint and preparation method thereof.
Background technology
Gravure ink is a kind of coloured colloid of stabilization, and dispersion be able to will be coated on appropriate mode of printing
On appropriate material, make it that character pattern and color is presented and ceased there is provided line and attraction.
With the progress and development of society, the raising of national life level, class requirement of the society to plastic flexible package is got over
Come higher, demand is increasing, the kind and style of flexible package are increasingly various, and usage amount also increasingly increases, current domestic modeling
Expect the printing 95% of paper flexible package above is by the way of intaglio printing, plastics, paper gravure printing ink contain substantial amounts of
Organic solvent（Account for 50%）, the low boiling such as toluene, ethyl acetate, butanone, high volatilization contain aromatic hydrocarbon, not only poisonous but also inflammable, no
But the residual of organic solvent is easily produced in packaging, and is also the primary pollution source of intaglio printing environmental pollution.Therefore
The production of the gravure inks such as Plastics in China, paper is by regulation systems such as fire service law, labor safety method, the law of food safety
About.Printing packaging manufacturing industry is also faced with environmental protection cry continuous surging and Environmental protective policy, the law of food safety
Deng increasingly severe multiple pincer attack.Therefore it is extremely urgent green base gravure ink that is aqueous low and meeting environmental requirement to be developed again.
The content of the invention
The purpose of the present invention is that there is provided a kind of environment-friendly water-based scratch resistance dumb paint and its preparation side on the basis of existing technology
Method.
The purpose of the present invention can be reached by following measures：
A kind of environment-friendly water-based scratch resistance dumb paint, it includes the component of following parts by weight：26~35 parts of acrylic emulsion A, acrylic acid
20~29 parts of emulsion B, 15~24 parts of Polyurethane emulsion, 0.5~3 part of wetting agent, 0.5~3 part of defoamer, levelling agent 0.5~3
Part, 0.5~3 part of wax powder, 10~20 parts of pigment, 0.5~4 part of dispersant, 0.5~3 part of scratch resistance agent, 0.5~3 part of thickener, pH
0.5~4 part of conditioning agent；Wherein acrylic emulsion A is that Shanghai is upper towards industry TR-803 acrylic emulsions, acrylic emulsion B is multiplied
The acrylic emulsion of Hai Jin alliances 7410.
In a kind of preferred scheme, environment-friendly water-based scratch resistance dumb paint includes the component of following parts by weight：Acrylic emulsion A
27~33 parts, 22~27 parts of acrylic emulsion B, 17~23 parts of Polyurethane emulsion, 0.5~2 part of wetting agent, defoamer 0.5~2
Part, 0.5~2 part of levelling agent, 0.5~2 part of wax powder, 12~18 parts of pigment, 1~4 part of dispersant, 0.5~2 part of scratch resistance agent, thickening
0.5~2 part of agent, 1~4 part of pH adjusting agent.
In another preferred scheme, environment-friendly water-based scratch resistance dumb paint includes the component of following parts by weight：Acrylic emulsion A
28~32 parts, 23~27 parts of acrylic emulsion B, 18~22 parts of Polyurethane emulsion, 0.5~2 part of wetting agent, defoamer 0.5~2
Part, 0.5~2 part of levelling agent, 0.5~2 part of wax powder, 13~17 parts of pigment, 1~3 part of dispersant, 0.5~2 part of scratch resistance agent, thickening
0.5~2 part of agent, 1~3 part of pH adjusting agent.
In a kind of more preferably scheme, environment-friendly water-based scratch resistance dumb paint includes the component of following parts by weight：Acrylic emulsion A
30 parts, 25 parts of acrylic emulsion B, 20 parts of Polyurethane emulsion, 1 part of wetting agent, 1 part of defoamer, 1 part of levelling agent, 1 part of wax powder, face
15 parts of material, 2 parts of dispersant, 1 part of scratch resistance agent, 1 part of thickener, 2 parts of pH adjusting agent.
Polyurethane emulsion in the present invention is selected from connection solidification and learns Polyurethane emulsion, this fertile chemical Polyurethane emulsion, Hubei wound
Prosperous CX-9129G Polyurethanes emulsion, Dongguan HTC HD566 Polyurethanes emulsion or super great chemical industry F-11C Polyurethane emulsions.
Wetting agent in the present invention is selected from Bi Ke chemistry BYK347, Bi Ke chemistry BYK346, Shanghai and wins Supreme Being Tego Do-75;
KL245、Tego Do-75;KL500、Tego Do-75;The KL 270 or modest chemical W469 of moral.
Defoamer in the present invention is selected from Shanghai and wins Supreme Being Tego k3;830、Tego k3;822、Tego k3;482nd, moral is modest
Chemical W-0506, Shanghai sea ease SD670, Bi Ke chemistry BYK-085 or Bi Ke chemistry BYK-071.
Dispersant in the present invention is selected from EFKA4560 or the dispersants of SN 5040.
Levelling agent in the present invention is selected from BYK333, BYK361, Glide 432, Flow 300 or the levellings of Efka 3600
Agent.
Scratch resistance agent in the present invention is selected from BYK378, BYK300 or BYK306.
Thickener in the present invention surpass/is opened up selected from Tao Shi thickeners TT-935, ROHM AND HAAS ACRYSOL ASE-60 or Shen
Good SC-01 thickeners.
Pigment in the present invention is selected from red pigment, yellow uitramarine, blue pigment or black pigment.
A kind of preparation method of above-mentioned environment-friendly water-based scratch resistance dumb paint：First by acrylic emulsion A, acrylic emulsion B and poly-
After the mixing of amine ester emulsion, wax powder and pigment are added, high-speed stirred is uniform, is ground to after being stirred behind fineness≤10 μm, continue to add
Enter wetting agent, defoamer, levelling agent, dispersant, scratch resistance agent and thickener, be eventually adding pH adjusting agent and adjust pH value to 7~9.
In printing process, the transmission and ink amount control of environment-friendly water-based scratch resistance dumb paint are undertaken by anilox roll, because
This needs selects anilox roll according to product requirement, to obtain preferable print distinctness and resolving power.
The present invention can be made under the cooperation of other components environment-friendly water-based resistance to by the mutual synergies of three kinds of emulsions
Scrape the printing levelability of dumb paint, it is adhesive force, hardness, viscosity, low aqueous etc. while reaching preferably effect, experiment is found, is gone
Except any emulsion or emulsion consumption be not in scope of the presently claimed invention, then Expected Results is unable to reach.
Beneficial effects of the present invention：The present invention environment-friendly water-based scratch resistance dumb paint 10 μm of fineness ﹤, solid content be 45 ±
5%, viscosity：25 DEG C apply 4 glasss 50-65 seconds or 25-35 seconds, pH value 7-9.This water-based ink have it is pollution-free, environmentally friendly reliable, it is molten
Agent is aqueous low, ink noresidue on packaging material, non-toxic, easily reclaims, the advantages of cheap, ink of the invention is through net
The hardness of film that line roller is obtained is high, and adhesive force is strong, and printing levelability is good.
Embodiment
Present disclosure is described further with reference to embodiments.But protection scope of the present invention is not limited to following
Each embodiment.
The preparation method of each example ink is：After first acrylic emulsion A, acrylic emulsion B and Polyurethane emulsion are mixed,
Add wax powder and pigment, high-speed stirred is uniform, is ground to after being stirred behind fineness≤10 μm, continuously add wetting agent, defoamer,
Levelling agent, dispersant, scratch resistance agent and thickener, are eventually adding pH adjusting agent and adjust pH value to 7~9.
Embodiment 1
The parts by weight of environment-friendly water-based scratch resistance dumb paint are constituted：Shanghai court multiplies 30 parts of industry TR-803 acrylic emulsions, Shanghai the present
25 parts of 7410 acrylic emulsion of alliance, 20 parts of Dongguan HTC HD566 Polyurethanes emulsion, 1 part of BYK346 wetting agents, W-0506 froth breakings
1 part of agent, 1 part of 300 levelling agents of Flow, 1 part of wax powder, 15 parts of pigment, 2 parts of EFKA4560 dispersants, 1 part of BYK378 scratch resistance agents are opened up
Good 1 part of SC-01 thickeners, 2 parts of pH adjusting agent.
Embodiment 2
The parts by weight of environment-friendly water-based scratch resistance dumb paint are constituted：Shanghai court multiplies 30 parts of industry TR-803 acrylic emulsions, Shanghai the present
25 parts of 7410 acrylic emulsion of alliance, 20 parts of Dongguan HTC HD566 Polyurethanes emulsion, 1 part of BYK346 wetting agents, sea ease SD670 disappears
1 part of infusion, 1 part of 432 levelling agents of Glide, 1 part of wax powder, 15 parts of pigment, 2 parts of EFKA4560 dispersants, BYK378 scratch resistance agents 1
Part, 1 part of ACRYSOL ASE-60 thickeners, 2 parts of pH adjusting agent.
Embodiment 3
The parts by weight of environment-friendly water-based scratch resistance dumb paint are constituted：Shanghai court multiplies 30 parts of industry TR-803 acrylic emulsions, Shanghai the present
25 parts of 7410 acrylic emulsion of alliance, super great 20 parts of chemical industry F-11C Polyurethanes emulsion, 1 part of BYK347 wetting agents, BYK-085 disappears
1 part of infusion, 1 part of BYK361 levelling agents, 1 part of wax powder, 15 parts of pigment, 2 parts of 504 dispersants of SN, 1 part of BYK300 scratch resistance agents, Tao Shi
1 part of TT-935 thickeners, 2 parts of pH adjusting agent.
Embodiment 4
The parts by weight of environment-friendly water-based scratch resistance dumb paint are constituted：Shanghai court multiplies 30 parts of industry TR-803 acrylic emulsions, Shanghai the present
25 parts of 7410 acrylic emulsion of alliance, super great 20 parts of chemical industry F-11C Polyurethanes emulsion, 1 part of BYK347 wetting agents, BYK-071 disappears
1 part of infusion, 1 part of BYK333 levelling agents, 1 part of wax powder, 15 parts of pigment, 2 parts of 504 dispersants of SN, 1 part of BYK306 scratch resistance agents, Tao Shi
1 part of TT-935 thickeners, 2 parts of pH adjusting agent.
Comparative example 1
Shanghai in embodiment 1 is removed towards industry TR-803 acrylic emulsions are multiplied, and by the modern acrylic emulsion of alliance 7410 in Shanghai
Consumption be changed to 55 parts, other be the same as Examples 1.
Comparative example 2
The modern acrylic emulsion of alliance 7410 in Shanghai in embodiment 1 is removed, and Shanghai court is multiplied into industry TR-803 acrylic emulsions
Consumption be changed to 55 parts, other be the same as Examples 1.
Comparative example 3
Shanghai in embodiment 1 is changed to 40 towards the consumption for multiplying industry TR-803 acrylic emulsions, and by the modern alliance 7,410 third in Shanghai
The consumption of olefin(e) acid emulsion is changed to 15 parts, other be the same as Examples 1.
Embodiment 5
10 μm of the fineness ﹤ of embodiment 1-4 environment-friendly water-based scratch resistance dumb paint, solid content is 45 ± 5%, viscosity：25 DEG C apply 4 glasss
50-65 seconds or 25-35 seconds, pH value 7-9.
By the ink obtained by each example by anilox printing in substrate surface, dried after being completed for printing, obtain film, to applying
Film is tested.
The adhesive force of film is with reference to standard GB/T/T9286-1998《The lattice of drawing of paint and varnish paint film are tested》[enter
The stroke lattice tape pull method of row ten is tested, and test result is expressed as 0-5 grades, wherein 0 grade best, 5 grades worst.
The hardness of film is with reference to standard GB/T/T6739-1996《Hardness of film pencil determination method》It is measured, is divided into
Totally 13 grades of 6H to 6B, wherein 6H is most hard, and 6B is most soft.
Film is covered using this resin combination is printed on mylar film, and mylar film is placed under LED after drying
Look after, can't see LED light line good for 0 grade, it can be seen that LED light line is 1 grade poor.
Printing levelability uses visual observations, and smooth even is 0 grade good, and it is 1 grade to have rough or uneven situation.
The ink film that each example is obtained by more than further carries out performance test, as a result such as following table.
| Performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Hardness H | 4 | 3 | 3 | 3 | 1 | 1 | 2 |
| Adhesive force | 2 | 2 | 3 | 2 | 5 | 5 | 4 |
| Print levelability | 0 | 0 | 0 | 0 | 1 | 1 | 1 |
Claims (9)
1. a kind of environment-friendly water-based scratch resistance dumb paint, it is characterised in that it includes the component of following parts by weight：Acrylic emulsion A 26
~35 parts, 20~29 parts of acrylic emulsion B, 15~24 parts of Polyurethane emulsion, 0.5~3 part of wetting agent, 0.5~3 part of defoamer,
0.5~3 part of levelling agent, 0.5~3 part of wax powder, 10~20 parts of pigment, 0.5~4 part of dispersant, 0.5~3 part of scratch resistance agent, thickener
0.5~3 part, 0.5~4 part of pH adjusting agent；Wherein acrylic emulsion A is that Shanghai court multiplies industry TR-803 acrylic emulsions, propylene
Yogurt liquid B is the modern acrylic emulsion of alliance 7410 in Shanghai.
2. environment-friendly water-based scratch resistance dumb paint according to claim 1, it is characterised in that it includes the component of following parts by weight：
27~33 parts of acrylic emulsion A, 22~27 parts of acrylic emulsion B, 17~23 parts of Polyurethane emulsion, 0.5~2 part of wetting agent,
0.5~2 part of defoamer, 0.5~2 part of levelling agent, 0.5~2 part of wax powder, 12~18 parts of pigment, 1~4 part of dispersant, scratch resistance agent
0.5~2 part, 0.5~2 part of thickener, 1~4 part of pH adjusting agent.
3. environment-friendly water-based scratch resistance dumb paint according to claim 2, it is characterised in that it includes the component of following parts by weight：
28~32 parts of acrylic emulsion A, 23~27 parts of acrylic emulsion B, 18~22 parts of Polyurethane emulsion, 0.5~2 part of wetting agent,
0.5~2 part of defoamer, 0.5~2 part of levelling agent, 0.5~2 part of wax powder, 13~17 parts of pigment, 1~3 part of dispersant, scratch resistance agent
0.5~2 part, 0.5~2 part of thickener, 1~3 part of pH adjusting agent.
4. environment-friendly water-based scratch resistance dumb paint according to claim 3, it is characterised in that it includes the component of following parts by weight：
30 parts of acrylic emulsion A, 25 parts of acrylic emulsion B, 20 parts of Polyurethane emulsion, 1 part of wetting agent, 1 part of defoamer, levelling agent 1
Part, 1 part of wax powder, 15 parts of pigment, 2 parts of dispersant, 1 part of scratch resistance agent, 1 part of thickener, 2 parts of pH adjusting agent.
5. the environment-friendly water-based scratch resistance dumb paint according to any one in Claims 1 to 4, it is characterised in that the Polyurethane
Emulsion, which is selected from, joins solidification Polyurethane emulsion, this fertile chemical Polyurethane emulsion, the prosperous CX-9129G Polyurethanes emulsion of Hubei wound, Dongguan
HTC HD566 Polyurethanes emulsion or super great chemical industry F-11C Polyurethane emulsions.
6. the environment-friendly water-based scratch resistance dumb paint according to any one in Claims 1 to 4, it is characterised in that the wetting agent
Supreme Being Tego Do-75 are won selected from Bi Ke chemistry BYK347, Bi Ke chemistry BYK346, Shanghai;KL245、Tego Do-75;KL500、
Tego Do-75;The KL 270 or modest chemical W469 of moral；The defoamer is selected from Shanghai and wins Supreme Being Tego k3;830、Tego k3;
822、Tego k3;482nd, the modest chemical W-0506 of moral, Shanghai sea ease SD670, Bi Ke chemistry BYK-085 or Bi Ke chemistry BYK-
071；The dispersant is selected from EFKA4560 or the dispersants of SN 5040.
7. the environment-friendly water-based scratch resistance dumb paint according to any one in Claims 1 to 4, it is characterised in that the levelling agent
Selected from BYK333, BYK361, Glide 432, Flow 300 or the levelling agents of Efka 3600；The scratch resistance agent be selected from BYK378,
BYK300 or BYK306.
8. the environment-friendly water-based scratch resistance dumb paint according to any one in Claims 1 to 4, it is characterised in that the thickener
Good SC-01 thickeners surpass/are opened up selected from Tao Shi thickeners TT-935, ROHM AND HAAS ACRYSOL ASE-60 or Shen；The pigment choosing
From red pigment, yellow uitramarine, blue pigment or black pigment；The pH value of the ink is 7~9.
9. a kind of preparation method of the environment-friendly water-based scratch resistance dumb paint in Claims 1 to 4 described in any one, it is characterised in that
After first mixing acrylic emulsion A, acrylic emulsion B and Polyurethane emulsion, wax powder and pigment are added, high-speed stirred is uniform, stirs
It is ground to after mixing behind fineness≤10 μm, continuously adds wetting agent, defoamer, levelling agent, dispersant, scratch resistance agent and thickener,
It is eventually adding pH adjusting agent and adjusts pH value to 7~9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710079467.3A CN107022239A (en) | 2017-02-14 | 2017-02-14 | Environment-friendly water-based scratch resistance dumb paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710079467.3A CN107022239A (en) | 2017-02-14 | 2017-02-14 | Environment-friendly water-based scratch resistance dumb paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107022239A true CN107022239A (en) | 2017-08-08 |
Family
ID=59526145
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710079467.3A Withdrawn CN107022239A (en) | 2017-02-14 | 2017-02-14 | Environment-friendly water-based scratch resistance dumb paint |
Country Status (1)
| Country | Link |
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| CN (1) | CN107022239A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111379190A (en) * | 2018-12-28 | 2020-07-07 | 上海杰易森股份有限公司 | Water-based scratch-resistant matte oil and preparation method thereof |
| CN117801664A (en) * | 2023-12-28 | 2024-04-02 | 广东金冠科技股份有限公司 | Scratch-resistant composition, preparation method and application thereof |
-
2017
- 2017-02-14 CN CN201710079467.3A patent/CN107022239A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111379190A (en) * | 2018-12-28 | 2020-07-07 | 上海杰易森股份有限公司 | Water-based scratch-resistant matte oil and preparation method thereof |
| CN117801664A (en) * | 2023-12-28 | 2024-04-02 | 广东金冠科技股份有限公司 | Scratch-resistant composition, preparation method and application thereof |
| CN117801664B (en) * | 2023-12-28 | 2024-05-28 | 广东金冠科技股份有限公司 | Scratch-resistant composition, preparation method and application thereof |
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Application publication date: 20170808 |
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