CN107013882B - A kind of plant lamp turning photoreactivation translucent cover and its application - Google Patents

A kind of plant lamp turning photoreactivation translucent cover and its application Download PDF

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Publication number
CN107013882B
CN107013882B CN201710128649.5A CN201710128649A CN107013882B CN 107013882 B CN107013882 B CN 107013882B CN 201710128649 A CN201710128649 A CN 201710128649A CN 107013882 B CN107013882 B CN 107013882B
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China
Prior art keywords
translucent cover
photoreactivation
plant lamp
light
plant
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CN201710128649.5A
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CN107013882A (en
Inventor
张浩然
邓建昆
雷炳富
刘应亮
陈燕科
黄超荣
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South China Agricultural University
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South China Agricultural University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V3/00Globes; Bowls; Cover glasses
    • F21V3/04Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings
    • F21V3/06Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by the material
    • F21V3/062Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by the material the material being plastics
    • F21V3/0625Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by the material the material being plastics the material diffusing light, e.g. translucent plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature

Abstract

The invention discloses a kind of plant lamps for turning photoreactivation translucent cover and its application.One kind turning photoreactivation translucent cover, is made of high molecule plastic, light diffusing agent and nitride phosphor.It also discloses that this turns the preparation method of photoreactivation translucent cover simultaneously, is mixed after weighing each raw material according to the ratio, extruding pelletization, compression molding after re-dry.Also disclose a kind of plant lamp, being includes described turning photoreactivation translucent cover and the naked fluorescent tube of white light LEDs.Translucent cover of the invention can play the secondary effect for turning light due to being doped with nitride red fluorescent powder, can quickly be assembled into LED plant lamp with T8 type white light LEDs fluorescent tube, meet the needs of photosynthesis of plant.

Description

A kind of plant lamp turning photoreactivation translucent cover and its application
Technical field
The present invention relates to a kind of plant lamps for turning photoreactivation translucent cover and its application.
Background technique
In recent years, plant factor due to be able to achieve crop high-efficiency and continuous growth, without rest plantation the characteristics of and attract attention. Wherein, the illumination system for belonging to one of key technology is more taken seriously.Initially, plant lamp is generally fluorescent lamp or high-pressure sodium Lamp, light quality is fixed to hinder plant factor's development with the shortcomings that energy consumption high photosynthetic efficiency bottom within a very long time.With luminous The invention of diode (LED) and be applied to plant lamp in, the illumination system of plant factor has obtained biggish promotion.Due to plant The light that needs of photosynthesis focus primarily upon blue light and feux rouges, LED plant lamp can be adjusted according to the needs it is blue feux rouges ratio, The spectrum of the two is set more to coincide, to play the effect for promoting plant growth.LED plant lamp can be divided into following two class Type: 1) blue-ray LED and red-light LED are combined;2) UV/blue LED and phosphor combination type.Compared to the former, Hou Zheyou Preparation is simple, and advantage at low cost is popularized in plant factor.However, in UV/blue LED and phosphor combination In type plant light source, the ingredient for regulating and controlling light needs to change the ratio between different fluorescent powders, for actual use bring it is many not Just.
On the whole, it reduces to improve the efficiency of illumination system with cost, from LED plant light source and can mainly build Mode two parts optimize.Firstly, light source part focuses primarily upon the research and development to the multicolor luminous fluorescent powder of single-matrix, reduce Influence between a variety of fluorescent powders, but being used in the fluorescent powder encapsulated on chip all is that disposably, not can be recycled;Its It is secondary, people also proposed it is various build mode to study the effect that do not share the same light to plant, but be easy to make in heuristic process At the waste for building cost.
LED lamp currently on the market requires outfit translucent cover and plays the role of protecting lamp source and make to shine uniform. Meanwhile YAG yellow fluorescent powder is mixed in translucent cover and is also had been reported as secondary light conversion.It can be seen that by light transmission Cover, which carries out corresponding modification, can make LED realize new function, for example LED plant lamp.
Summary of the invention
The purpose of the present invention is to provide a kind of plant lamps for turning photoreactivation translucent cover and its application.
The technical solution used in the present invention is:
One kind turning photoreactivation translucent cover, is made of high molecule plastic, light diffusing agent and nitride phosphor.
The mass ratio of the high molecule plastic, light diffusing agent and nitride phosphor is (88.0~88.9): (10.5~ 11.5): (0.1~1.0).
The high molecule plastic is carbonic ester, and the light diffusing agent is organic siliconresin.
The nitride phosphor is CaAlSiN3:Eu2+
The nitride phosphor average grain diameter is 1.0~5.0 μm.
The nitride phosphor is that preparation is sintered at 1500~1650 DEG C using high temperature solid-state method, and crude product is through gas Stream crushes, after sieving.
A kind of preparation method turning photoreactivation translucent cover is mixed after weighing each raw material according to the ratio, extruding pelletization, Compression molding after re-dry.
The extrusion temperature is 250~260 DEG C, and drying temperature is 100 DEG C.
A kind of plant lamp turns photoreactivation translucent cover and the naked fluorescent tube of white light LEDs including described.
The naked fluorescent tube of the white light LEDs is T8 type.
The beneficial effects of the present invention are:
Translucent cover of the invention can play the secondary effect for turning light due to being doped with nitride red fluorescent powder, white with T8 type Light LED lamp tube can quickly be assembled into LED plant lamp, meet the needs of photosynthesis of plant.
It is specific as follows:
(1) present invention uses nitride CaAlSiN3:Eu2+Fluorescent powder dosage is few, and thermal stability is good, reduces in preparation process The luminous intensity loss generated due to high temperature;
(2) PC/ nitride phosphor composite transparent cover simple process of the present invention, save the cost are conducive to batch The demand of production, gathers around and has broad application prospects;
(3) plant lamp preparation method of the present invention is simple, common lampshade need to be only replaced with above-mentioned PC/ nitride fluorescent Powder composite transparent cover can be obtained;Meanwhile by replacing different doped nitride CaAlSiN3:Eu2+The light transmission of phosphor concentration Cover can quickly play the effect of regulation plant lamp light quality, convenient for being directed to the plantation of Different Crop.
Detailed description of the invention
Fig. 1 is the PC/ nitride phosphor composite transparent cover preparation flow figure of Examples 1 to 6;
Fig. 2 is PC/ nitride phosphor composite transparent cover prepared by embodiment 6 and nitride CaAlSiN3:Eu2+Fluorescence Powder XRD comparison diagram;
Fig. 3 is the exciting light spectrogram (A) of the prepared PC/ nitride phosphor composite transparent cover with concentration of Examples 1 to 6 With launching light spectrogram (B);
Fig. 4 is the EL figure for the T8 type white light LEDs fluorescent tube that Examples 1 to 6 is equipped with PC/ nitride phosphor composite transparent cover.
Specific embodiment
One kind turning photoreactivation translucent cover, is made of high molecule plastic, light diffusing agent and nitride phosphor.
Preferably, the mass ratio of the high molecule plastic, light diffusing agent and nitride phosphor is (88.0~88.9): (10.5~11.5): (0.1~1.0);It is further preferred that the high molecule plastic, light diffusing agent and nitride phosphor Mass ratio be (88.0~88.9): 11:(0.1~1.0).
Preferably, the high molecule plastic is carbonic ester, and the light diffusing agent is organic siliconresin.
Preferably, the nitride phosphor is CaAlSiN3:Eu2+
Preferably, the nitride phosphor average grain diameter is 1.0~5.0 μm.
Preferably, the nitride phosphor is that preparation is sintered at 1500~1650 DEG C using high temperature solid-state method, slightly Product obtains after sieving through air-flow crushing.
A kind of preparation method turning photoreactivation translucent cover is mixed after weighing each raw material according to the ratio, extruding pelletization, Compression molding after re-dry.
Preferably, the extrusion temperature is 250~260 DEG C, and drying temperature is 100 DEG C.
Further, it is described be blended in mix mixed in color machine, extrusion squeezes out in Twin screw extruder, and compression moulding is in mill Compression moulding in machine.
A kind of plant lamp turns photoreactivation translucent cover and the naked fluorescent tube of white light LEDs including described.
Preferably, the naked fluorescent tube of the white light LEDs is T8 type.
Further, the plant lamp is will directly to turn photoreactivation translucent cover to be installed to the naked fluorescent tube top of T8 type white light LEDs It is constituted.
Further, the naked fluorescent tube of T8 type white light LEDs contains 100 white light LEDs patches, and patch is by blue chip And Y3Al5O12:Ce3+Fluorescent powder composition;The naked power of lamp tube of the white light LEDs is 18W.
Mechanism of the invention is further described below:
The present invention is by nitride CaAlSiN3:Eu2+Fluorescent powder is doped to PC material base in such a way that high-temperature fusion is granulated In matter, obtain turning light PC/ nitride phosphor composite transparent cover through compression molding.Utilize CaAlSiN3:Eu2+Fluorescent powder can be high The characteristics of blue light and yellow light are converted into feux rouges by effect, enables the white light of tradition LED after the translucent cover, enhances its feux rouges portion Divide to be transformed into plant lamp.
The contents of the present invention are described in further detail below by way of specific embodiment.
Embodiment 1:
According to weight percentage of each raw material in PC/ nitride phosphor composite transparent cover, by 88.9% PC, 11% organic extension resin and 0.1% nitride CaAlSiN3:Eu2+The proportion of fluorescent powder is uniformly mixed in color machine in mixing, so It is placed on 255 DEG C of high-temperature fusions in double screw extruder to be granulated, obtains the light conversion master batch for being used to prepare translucent cover.By gained master batch It is put into after 100 DEG C of driers remove moisture removal in 2 hours, is prepared in open mill through compression moulding and turn light PC translucent cover.It will turn light PC again Translucent cover is installed to the naked fluorescent tube top of T8 type white light LEDs and obtains LED plant lamp.
Embodiment 2:
Turning the weight percentage in light PC translucent cover according to each raw material, by 88.8% PC, 11% organic extension tree Rouge and 0.2% nitride CaAlSiN3:Eu2+The proportion of fluorescent powder is uniformly mixed in color machine in mixing, and is subsequently placed in twin-screw and squeezes 255 DEG C of high-temperature fusions are granulated in machine out, obtain the light conversion master batch for being used to prepare translucent cover.Gained master batch is put into 100 DEG C of dryings After device removes moisture removal, is prepared in open mill through compression moulding and turn light PC translucent cover.To turn light PC translucent cover again, to be installed to T8 type white The naked fluorescent tube top light LED obtains LED plant lamp.
Embodiment 3:
Turning the weight percentage in light PC translucent cover according to each raw material, by 88.6% PC, 11% organic extension tree Rouge and 0.4% nitride CaAlSiN3:Eu2+The proportion of fluorescent powder is uniformly mixed in color machine in mixing, and is subsequently placed in twin-screw and squeezes 255 DEG C of high-temperature fusions are granulated in machine out, obtain the light conversion master batch for being used to prepare translucent cover.Gained master batch is put into 100 DEG C of dryings After device removes moisture removal, is prepared in open mill through compression moulding and turn light PC translucent cover.To turn light PC translucent cover again, to be installed to T8 type white The naked fluorescent tube top light LED obtains LED plant lamp.
Embodiment 4:
Turning the weight percentage in light PC translucent cover according to each raw material, by 88.4% PC, 11% organic extension tree Rouge and 0.6% nitride CaAlSiN3:Eu2+The proportion of fluorescent powder is uniformly mixed in color machine in mixing, and is subsequently placed in twin-screw and squeezes 255 DEG C of high-temperature fusions are granulated in machine out, obtain the light conversion master batch for being used to prepare translucent cover.Gained master batch is put into 100 DEG C of dryings After device removes moisture removal, is prepared in open mill through compression moulding and turn light PC translucent cover.To turn light PC translucent cover again, to be installed to T8 type white The naked fluorescent tube top light LED obtains LED plant lamp.
Embodiment 5:
Turning the weight percentage in light PC translucent cover according to each raw material, by 88.2% PC, 11% organic extension tree Rouge and 0.8% nitride CaAlSiN3:Eu2+The proportion of fluorescent powder is uniformly mixed in color machine in mixing, and is subsequently placed in twin-screw and squeezes 255 DEG C of high-temperature fusions are granulated in machine out, obtain the light conversion master batch for being used to prepare translucent cover.Gained master batch is put into 100 DEG C of dryings After device removes moisture removal, is prepared in open mill through compression moulding and turn light PC translucent cover.To turn light PC translucent cover again, to be installed to T8 type white The naked fluorescent tube top light LED obtains LED plant lamp.
Embodiment 6:
Turning the weight percentage in light PC translucent cover according to each raw material, by 88% PC, 11% organic extension resin With 1% nitride CaAlSiN3:Eu2+The proportion of fluorescent powder is uniformly mixed in color machine in mixing, and is subsequently placed in double screw extruder In 255 DEG C of high-temperature fusions be granulated, obtain the light conversion master batch for being used to prepare translucent cover.Gained master batch is put into 100 DEG C of driers After moisture removal, is prepared in open mill through compression moulding and turn light PC translucent cover.It will turn light PC translucent cover again and be installed to T8 type white light LEDs Naked fluorescent tube top obtains LED plant lamp.
Examples 1 to 6 to turn light PC translucent cover preparation flow as shown in Fig. 1, prepare that turn light PC saturating as can be seen from Figure 1 The process very simple of light shield is quick, suitable for mass production.
Turn light PC translucent cover and nitride CaAlSiN prepared by embodiment 63:Eu2+Fluorescent powder XRD comparison diagram such as attached drawing 2 It is shown, nitride CaAlSiN can be illustrated in Fig. 23:Eu2+There is no send out during being doped to the front and back of PC material for fluorescent powder Solution estranged or other additional reactions, keep good optical property.
The fluorescence PC translucent cover excitation (A) of various concentration prepared by Examples 1 to 6 and transmitting (B) spectrum such as 3 institute of attached drawing Show, it can be seen that the light absorption range of translucent cover is extensive in Fig. 3, blue yellow part efficiently can be converted into feux rouges, be conducive to The photosynthesis of plant.
Examples 1 to 6 is equipped with the EL figure of the T8 type white light LEDs fluorescent tube of translucent cover as shown in Fig. 4, and Fig. 4 can illustrate: 1) When the fluorescent powder doping concentration of fluorescence PC translucent cover is lower, the white light transformation efficiency issued by fluorescent tube is low, and the white light of transmission contains Amount is high, so that light efficiency is higher;2) when the fluorescent powder doping concentration of fluorescence PC translucent cover is higher, due to the dense arrangement of fluorescent powder White light is caused to penetrate difficult, although feux rouges coverage area is increased, whole light efficiency is reduced.
The optical performance data that the T8 type white light LEDs fluorescent tube of different translucent covers is equipped in Examples 1 to 6 is as shown in table 1 below:
Table 1 is equipped with the T8 type white LED lamp lightpipe optics parameter of different translucent covers
It is available by above-mentioned table 1, the T8 type white light LEDs fluorescent tube of different translucent covers is equipped in Examples 1 to 6, shine face The transformation from cool white light to warm white, and available different types of colour temperature may be implemented in color, meets the need of different situations It wants.

Claims (6)

1. a kind of plant lamp, it is characterised in that: including turning photoreactivation translucent cover and the naked fluorescent tube of white light LEDs;Described turns photoreactivation It is (88.0~88.9) that translucent cover is by high molecule plastic, light diffusing agent and nitride phosphor in mass ratio: (10.5~ 11.5): (0.1~1.0) composition;The high molecule plastic is carbonic ester, and the light diffusing agent is organic siliconresin, described Nitride phosphor be CaAlSiN3:Eu2+
2. a kind of plant lamp according to claim 1, it is characterised in that: the nitride phosphor average grain diameter is 1.0~5.0 μm.
3. a kind of plant lamp according to claim 2, it is characterised in that: the nitride phosphor is solid using high temperature Phase method is sintered preparation at 1500~1650 DEG C, and crude product obtains after sieving through air-flow crushing.
4. a kind of plant lamp according to claim 1, it is characterised in that: described turns photoreactivation translucent cover preparation method It is: is mixed after weighing each raw material according to the ratio, extruding pelletization, compression molding after re-dry.
5. a kind of plant lamp according to claim 4, it is characterised in that: described turns photoreactivation translucent cover preparation method In, extrusion temperature is 250~260 DEG C, and drying temperature is 100 DEG C.
6. a kind of plant lamp according to claim 1, it is characterised in that: the naked fluorescent tube of the white light LEDs is T8 type.
CN201710128649.5A 2017-03-06 2017-03-06 A kind of plant lamp turning photoreactivation translucent cover and its application Active CN107013882B (en)

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