CN106981496B - Output amplifier and production method for frame transfer Visible-light CCD - Google Patents

Output amplifier and production method for frame transfer Visible-light CCD Download PDF

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Publication number
CN106981496B
CN106981496B CN201710216550.0A CN201710216550A CN106981496B CN 106981496 B CN106981496 B CN 106981496B CN 201710216550 A CN201710216550 A CN 201710216550A CN 106981496 B CN106981496 B CN 106981496B
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gate medium
drain area
drain
layer
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CN106981496A (en
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张故万
伍明娟
罗春林
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CETC 44 Research Institute
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/148Charge coupled imagers
    • H01L27/14831Area CCD imagers
    • H01L27/1485Frame transfer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/148Charge coupled imagers
    • H01L27/14806Structural or functional details thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/148Charge coupled imagers
    • H01L27/14806Structural or functional details thereof
    • H01L27/14812Special geometry or disposition of pixel-elements, address lines or gate-electrodes

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Electromagnetism (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Solid State Image Pick-Up Elements (AREA)

Abstract

The invention discloses a kind of output amplifier for frame transfer Visible-light CCD, the output amplifier is made of substrate layer, two source-drain areas, three gate mediums, source and drain polysilicon electrode, three phosphorosilicate glass layers, barrier layer, metallic aluminum and ground;The invention also discloses the production methods of aforementioned output amplifier;The method have the benefit that: a kind of output amplifier and production method for frame transfer Visible-light CCD is proposed, the program can effectively improve the quality of frame transfer Visible-light CCD.

Description

Output amplifier and production method for frame transfer Visible-light CCD
Technical field
The present invention relates to a kind of CCD technology more particularly to a kind of output amplifiers and system for frame transfer Visible-light CCD Make method.
Background technique
Frame transfer Visible-light CCD is a kind of important CCD type, the amplifier one on common frame transfer Visible-light CCD As be made of substrate layer, two source-drain areas, three gate mediums, source and drain polysilicon electrode, metallic aluminum and ground, structure such as Fig. 2 Shown, for the prior art in production, there are the following problems: 1) prior art generally uses thermal diffusion doping process to be formed Source-drain area and ground, the characteristic based on thermal diffusion doping process is it is found that the longitudinal diffusion speed of thermal diffusion doping process and laterally expansion It is almost the same to dissipate speed, when amplifier grid length size is smaller, is easy to cause Punchthrough, amplifier is made to fail, in production grid When the lesser amplifier of long size, needs to design some structures for preventing Punchthrough in the amplifier, considerably increase grid length The manufacture difficulty of the lesser amplifier of size;2) prior art is generally existed using wet corrosion technique when making metallic aluminum Electrode is etched on metallic aluminum, the operational characteristic based on wet corrosion technique is it is found that longitudinal corrosion of wet corrosion technique is fast Rate and lateral encroaching rate are almost the same, when corroding metallic aluminum downwards, although having the protection of photoresist, corrosive liquid in transverse direction Also it will do it lateral encroaching, so that the metallic aluminum narrowed thickness at stepped locations, since metallic aluminum is generally using vapor deposition work Skill is formed, be at the stepped locations on device, below metallic aluminum at step chamfering it is empty, corrosive liquid easily infiltrates into So that metallic aluminum is occurred broken strip at stepped locations, the direct current reliability of device is made to be difficult to be guaranteed;3) metallic aluminum is direct It is contacted with silicon materials, since aluminium is spread fastly in silicon, readily diffuses into PN junction position, especially shallow junction PN junction, easy occurring source Junction spiking is leaked, causes PN junction to fail, cannot be imaged so as to cause CCD, component failure is caused to be scrapped.
Summary of the invention
For the problems in background technique, the invention proposes a kind of output amplifier for frame transfer Visible-light CCD, Its innovation is: the output amplifier is by substrate layer, two source-drain areas, three gate mediums, source and drain polysilicon electrode, three phosphorus Silica glass layer, barrier layer, metallic aluminum and ground composition;The source-drain area is formed in the surface layer on the upside of substrate layer, two source and drain Spaced apart between area, the source-drain area positioned at left side is denoted as left source-drain area, and the source-drain area positioned at right side is denoted as right source-drain area; The gate medium is formed on the upper surface of substrate layer;First gate medium is located at the left side of left source-drain area, the right side of the first gate medium End covers the left end of left source-drain area;Second gate medium is between left source-drain area and right source-drain area, the left end of the second gate medium The right end of left source-drain area is covered, the right end of the second gate medium covers the left end of right source-drain area, the first gate medium and second gate It is spaced between medium;Third gate medium is located at the right of right source-drain area, and the left end of third gate medium is by the right side of right source-drain area End covering, it is spaced between the second gate medium and third gate medium;The source and drain polysilicon electrode is layered in second gate medium Upper surface middle part;First phosphorosilicate glass layer is layered on the upper surface of the first gate medium;Second phosphorosilicate glass layer is layered in On the upper surface of two gate mediums, source and drain polysilicon electrode is wrapped in interior by the second phosphorosilicate glass layer;Third phosphorosilicate glass layer stackup On the upper surface of third gate medium;The barrier layer covers the exposed part of source-drain area, gate medium and phosphorosilicate glass layer;Institute Metallic aluminum is stated to be covered on the outer surface on barrier layer;It is formed in the periphery of substrate layer describedly.
The principle of aforementioned schemes is: existing frame transfer Visible-light CCD output amplifier there are aiming at the problem that, this hair Bright to propose a kind of new output amplifier structure, in this structure, inventor is provided with phosphorus silicon glass on three gate mediums Glass layer, wherein, can be effective after being provided with phosphorosilicate glass layer in source and drain polysilicon electrode is wrapped in by the second phosphorosilicate glass layer Improve stepped locations at body structure surface smoothness, improve the climbing capacity of surface metal, in addition, phosphorosilicate glass layer be conducive to it is miscellaneous The sucking of matter can effectively improve functional reliability of the device in wet environment especially to the sucking of sodium ion;Meanwhile Inventor metallic aluminum is isolated with rectangular structure with barrier layer, barrier layer also on metallic aluminum following settings barrier layer It is possible to prevente effectively from metallic aluminum causes to puncture to lower section silicon structure, device yield is improved.
Based on aforementioned schemes, the invention also provides following preferred embodiments: the barrier layer is by the first titanium for stacking gradually Layer, titanium nitride layer and the second titanium layer are constituted.In early-stage study, inventor uses the double-layer structure of titanium nitride layer and titanium layer Barrier layer (titanium nitride layer upper, titanium layer is under) finds that metallic aluminum there are aliquation phenomenon, is found through analysis in scribing, rises Layer phenomenon is since the adhesion between aluminium and titanium nitride is poor, and under the stress in scribing, aliquation occurs in aluminium, by more Secondary test discovery, then increase by one first titanium layer in metallic aluminum and titanium nitride layer, it can effectively improve metallic aluminum and lower layer's knot There is aluminium aliquation situation in the adhesion of structure when can effectively avoid scribing.
Based on aforementioned structure, the invention also provides a kind of production of output amplifier for frame transfer Visible-light CCD Method, the structure of the output amplifier is as previously mentioned, specific production method are as follows:
1) substrate layer is provided;
2) production ground;
3) source-drain area is made;
4) gate medium is made;
5) polysilicon electrode is made;
6) phosphorosilicate glass layer is made;
7) surface gettering is handled;
8) barrier layer is made;
9) metallic aluminum is made;
During step 2) makes ground, it is doped using ion implantation technology;The process of step 3) production source-drain area In, it is doped using ion implantation technology;In step 6), first in structural body surface deposition phosphorosilicate glass, then to phosphorus silicon glass Glass performs etching to form three phosphorosilicate glass layers, quarter when performing etching to phosphorosilicate glass layer, between adjacent phosphorosilicate glass layer The width of borrosion hole is up big and down small;In step 9), first in structural body surface deposition metallic aluminium, dry plasma etch pair is then used Metallic aluminium performs etching to form metallic aluminum.
From the point of view of overall process flow, preceding method is roughly the same with prior art, and innovative point therein has: 1, making It during ground and source-drain area, has been all made of ion implantation technology and has been doped, based on the prior art it is found that ion implantation technology Concentration and junction depth control precision it is all higher, and almost without horizontal proliferation, can effectively solve described in background technology the 1) Point problem can effectively improve production efficiency in addition, the operating efficiency of ion implantation technology is also higher;2, phosphorus silicon glass is increased Glass layer making step, the purpose for making phosphorosilicate glass layer are as previously described;3, it joined surface gettering processing step, gettering processing can The heavy metal ion such as Fe, Ni, Cu, the Cr that may introduce in technical process are drawn into nucleated areas, to reduce CCD product Dark current;4, when performing etching to phosphorosilicate glass layer, keep the width of the etched hole between adjacent phosphorosilicate glass layer up big and down small, It forms one kind " the rim of a bowl " structure and is conducive to contact of the metal with hole to reduce the gradient of surface texture, reduce climbing for metallic aluminium Slope difficulty and contact resistance;5, barrier layer making step is increased, purpose is as previously described;6, it when making metallic aluminum, uses Dry plasma etch performs etching metallic aluminium, and dry plasma etch guarantees device it is possible to prevente effectively from there is broken strip situation Part quality.
Experiment proves that compared with existing processing technology, after structure and manufacture craft of the invention, the direct current of product Qualification rate is promoted by original 70% or so to 95% or more, exchange qualification rate namely product be imaged zero defect qualification rate from 20% or so originally is promoted to 70% or so, is improved more than 3 times, and the dark current of product is reduced close to 1 times, in the batch of product Stability and consistency are better than original product between batch.
The method have the benefit that: propose a kind of output amplifier and system for frame transfer Visible-light CCD Make method, the program can effectively improve the quality of frame transfer Visible-light CCD.
Detailed description of the invention
Fig. 1, structural schematic diagram of the invention;
The structural schematic diagram of Fig. 2, the prior art;
Title corresponding to each label is respectively as follows: substrate layer 1, source-drain area 2, gate medium 3, source and drain polysilicon electrode in figure 4, phosphorosilicate glass layer 5, barrier layer 6, metallic aluminum 7.
Specific embodiment
A kind of output amplifier for frame transfer Visible-light CCD, innovation are: the output amplifier is by substrate layer 1, two source-drain areas, 2, three gate mediums 3,4, three phosphorosilicate glass layers 5 of source and drain polysilicon electrode, barrier layer 6,7 and of metallic aluminum Ground composition;The source-drain area 2 is formed in the surface layer of 1 upside of substrate layer, spaced apart between two source-drain areas 2, is located at The source-drain area 2 in left side is denoted as left source-drain area, and the source-drain area 2 positioned at right side is denoted as right source-drain area;The gate medium 3 is formed in substrate On the upper surface of layer 1;First gate medium 3 is located at the left side of left source-drain area, and the right end of the first gate medium 3 is by the left end of left source-drain area Covering;Second gate medium 3 is between left source-drain area and right source-drain area, and the left end of the second gate medium 3 is by the right end of left source-drain area Covering, the right end of the second gate medium 3 cover the left end of right source-drain area, between the first gate medium 3 and the second gate medium 3 there are Every;Third gate medium 3 is located at the right of right source-drain area, and the left end of third gate medium 3 covers the right end of right source-drain area, second gate It is spaced between medium 3 and third gate medium 3;The source and drain polysilicon electrode 4 is layered in the upper surface of the second gate medium 3 Portion;First phosphorosilicate glass layer 5 is layered on the upper surface of the first gate medium 3;Second phosphorosilicate glass layer 5 is layered in the second gate medium On 3 upper surface, source and drain polysilicon electrode 4 is wrapped in interior by the second phosphorosilicate glass layer 5;Third phosphorosilicate glass layer 5 is layered in On the upper surface of three gate mediums 3;The barrier layer 6 covers the exposed part of source-drain area 2, gate medium 3 and phosphorosilicate glass layer 5; The metallic aluminum 7 is covered on the outer surface on barrier layer 6;It is formed in the periphery of substrate layer 1 describedly.
Further, the barrier layer 6 is made of the first titanium layer, titanium nitride layer and the second titanium layer stacked gradually.
A kind of production method of the output amplifier for frame transfer Visible-light CCD, the output amplifier is by substrate layer 1, two source-drain areas, 2, three gate mediums 3,4, three phosphorosilicate glass layers 5 of source and drain polysilicon electrode, barrier layer 6,7 and of metallic aluminum Ground composition;The source-drain area 2 is formed in the surface layer of 1 upside of substrate layer, spaced apart between two source-drain areas 2, is located at The source-drain area 2 in left side is denoted as left source-drain area, and the source-drain area 2 positioned at right side is denoted as right source-drain area;The gate medium 3 is formed in substrate On the upper surface of layer 1;First gate medium 3 is located at the left side of left source-drain area, and the right end of the first gate medium 3 is by the left end of left source-drain area Covering;Second gate medium 3 is between left source-drain area and right source-drain area, and the left end of the second gate medium 3 is by the right end of left source-drain area Covering, the right end of the second gate medium 3 cover the left end of right source-drain area, between the first gate medium 3 and the second gate medium 3 there are Every;Third gate medium 3 is located at the right of right source-drain area, and the left end of third gate medium 3 covers the right end of right source-drain area, second gate It is spaced between medium 3 and third gate medium 3;The source and drain polysilicon electrode 4 is layered in the upper surface of the second gate medium 3 Portion;First phosphorosilicate glass layer 5 is layered on the upper surface of the first gate medium 3;Second phosphorosilicate glass layer 5 is layered in the second gate medium On 3 upper surface, source and drain polysilicon electrode 4 is wrapped in interior by the second phosphorosilicate glass layer 5;Third phosphorosilicate glass layer 5 is layered in On the upper surface of three gate mediums 3;The barrier layer 6 covers the exposed part of source-drain area 2, gate medium 3 and phosphorosilicate glass layer 5; The metallic aluminum 7 is covered on the outer surface on barrier layer 6;It is formed in the periphery of substrate layer 1 describedly;
It is characterized by: the described method includes:
1) substrate layer 1 is provided;
2) production ground;
3) source-drain area 2 is made;
4) gate medium 3 is made;
5) polysilicon electrode 4 is made;
6) phosphorosilicate glass layer 5 is made;
7) surface gettering is handled;
8) barrier layer 6 is made;
9) metallic aluminum 7 is made;
During step 2) makes ground, it is doped using ion implantation technology;The process of step 3) production source-drain area 2 In, it is doped using ion implantation technology;In step 6), first in structural body surface deposition phosphorosilicate glass, then to phosphorus silicon glass Glass performs etching to form three phosphorosilicate glass layers 5, when performing etching to phosphorosilicate glass layer 5, between adjacent phosphorosilicate glass layer 5 The width of etched hole is up big and down small;In step 9), first in structural body surface deposition metallic aluminium, dry plasma etch is then used Metallic aluminium is performed etching to form metallic aluminum 7.

Claims (3)

1. a kind of output amplifier for frame transfer Visible-light CCD, it is characterised in that: the output amplifier is by substrate layer (1), two source-drain areas (2), three gate mediums (3), source and drain polysilicon electrode (4), three phosphorosilicate glass layers (5), barrier layers (6), metallic aluminum (7) and ground composition;The source-drain area (2) is formed in the surface layer on the upside of substrate layer (1), two source-drain areas (2) spaced apart between, the source-drain area (2) positioned at left side is denoted as left source-drain area, and the source-drain area (2) positioned at right side is denoted as the right side Source-drain area;The gate medium (3) is formed on the upper surface of substrate layer (1);First gate medium (3) is located at a left side for left source-drain area The right end on side, the first gate medium (3) covers the left end of left source-drain area;Second gate medium (3) is located at left source-drain area and right source and drain Between area, the left end of the second gate medium (3) covers the right end of left source-drain area, and the right end of the second gate medium (3) is by right source-drain area Left end covering, it is spaced between the first gate medium (3) and the second gate medium (3);Third gate medium (3) is located at right source-drain area The right, the left end of third gate medium (3) covers the right end of right source-drain area, the second gate medium (3) and third gate medium (3) it Between it is spaced;The source and drain polysilicon electrode (4) is layered in the upper surface middle part of the second gate medium (3);First phosphorosilicate glass Layer (5) is layered on the upper surface of the first gate medium (3);Second phosphorosilicate glass layer (5) is layered in the upper table of the second gate medium (3) On face, source and drain polysilicon electrode (4) is wrapped in interior by the second phosphorosilicate glass layer (5);Third phosphorosilicate glass layer (5) is layered in third On the upper surface of gate medium (3);The barrier layer (6) is by the exposed portion of source-drain area (2), gate medium (3) and phosphorosilicate glass layer (5) Divide covering;The metallic aluminum (7) is covered on the outer surface of barrier layer (6);It is formed in the periphery of substrate layer (1) describedly.
2. the output amplifier according to claim 1 for frame transfer Visible-light CCD, it is characterised in that: the blocking Layer (6) is made of the first titanium layer, titanium nitride layer and the second titanium layer stacked gradually.
3. a kind of production method of the output amplifier for frame transfer Visible-light CCD, the output amplifier is by substrate layer (1), two source-drain areas (2), three gate mediums (3), source and drain polysilicon electrode (4), three phosphorosilicate glass layers (5), barrier layers (6), metallic aluminum (7) and ground composition;The source-drain area (2) is formed in the surface layer on the upside of substrate layer (1), two source-drain areas (2) spaced apart between, the source-drain area (2) positioned at left side is denoted as left source-drain area, and the source-drain area (2) positioned at right side is denoted as the right side Source-drain area;The gate medium (3) is formed on the upper surface of substrate layer (1);First gate medium (3) is located at a left side for left source-drain area The right end on side, the first gate medium (3) covers the left end of left source-drain area;Second gate medium (3) is located at left source-drain area and right source and drain Between area, the left end of the second gate medium (3) covers the right end of left source-drain area, and the right end of the second gate medium (3) is by right source-drain area Left end covering, it is spaced between the first gate medium (3) and the second gate medium (3);Third gate medium (3) is located at right source-drain area The right, the left end of third gate medium (3) covers the right end of right source-drain area, the second gate medium (3) and third gate medium (3) it Between it is spaced;The source and drain polysilicon electrode (4) is layered in the upper surface middle part of the second gate medium (3);First phosphorosilicate glass Layer (5) is layered on the upper surface of the first gate medium (3);Second phosphorosilicate glass layer (5) is layered in the upper table of the second gate medium (3) On face, source and drain polysilicon electrode (4) is wrapped in interior by the second phosphorosilicate glass layer (5);Third phosphorosilicate glass layer (5) is layered in third On the upper surface of gate medium (3);The barrier layer (6) is by the exposed portion of source-drain area (2), gate medium (3) and phosphorosilicate glass layer (5) Divide covering;The metallic aluminum (7) is covered on the outer surface of barrier layer (6);It is formed in the periphery of substrate layer (1) describedly;
It is characterized by: the described method includes:
1) substrate layer (1) is provided;
2) production ground;
3) source-drain area (2) are made;
4) gate medium (3) are made;
5) polysilicon electrode (4) are made;
6) phosphorosilicate glass layer (5) are made;
7) surface gettering is handled;
8) barrier layer (6) are made;
9) metallic aluminum (7) are made;
During step 2) makes ground, it is doped using ion implantation technology;Step 3) makes the process of source-drain area (2) In, it is doped using ion implantation technology;In step 6), first in structural body surface deposition phosphorosilicate glass, then to phosphorus silicon glass Glass performs etching to form three phosphorosilicate glass layers (5), when being performed etching to phosphorosilicate glass layer (5), adjacent phosphorosilicate glass layer (5) Between etched hole width it is up big and down small;It is then dry using plasma first in structural body surface deposition metallic aluminium in step 9) Method etching performs etching metallic aluminium to form metallic aluminum (7).
CN201710216550.0A 2017-04-05 2017-04-05 Output amplifier and production method for frame transfer Visible-light CCD Active CN106981496B (en)

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Publication number Priority date Publication date Assignee Title
CN110335882B (en) * 2019-06-25 2021-05-07 中国电子科技集团公司第四十四研究所 Pixel structure capable of improving frame transfer CCD (Charge coupled device) responsivity

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010068244A1 (en) * 2008-12-10 2010-06-17 Eastman Kodak Company Method of fabricating image sensors with lateral overflow drains
CN202948931U (en) * 2012-11-06 2013-05-22 宁波比亚迪半导体有限公司 Power device for improving morphology of diffusion region
CN103972253A (en) * 2013-01-25 2014-08-06 索尼公司 Semiconductor device and method of manufacturing semiconductor device
CN106449689A (en) * 2016-11-11 2017-02-22 中国电子科技集团公司第四十四研究所 A frame-transfer visible light CCD with a polyimide cushion layer

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010068244A1 (en) * 2008-12-10 2010-06-17 Eastman Kodak Company Method of fabricating image sensors with lateral overflow drains
CN202948931U (en) * 2012-11-06 2013-05-22 宁波比亚迪半导体有限公司 Power device for improving morphology of diffusion region
CN103972253A (en) * 2013-01-25 2014-08-06 索尼公司 Semiconductor device and method of manufacturing semiconductor device
CN106449689A (en) * 2016-11-11 2017-02-22 中国电子科技集团公司第四十四研究所 A frame-transfer visible light CCD with a polyimide cushion layer

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