CN106977149A - A kind of rectangular slab of stone formula modelled after an antique and its preparation technology - Google Patents

A kind of rectangular slab of stone formula modelled after an antique and its preparation technology Download PDF

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Publication number
CN106977149A
CN106977149A CN201710281474.1A CN201710281474A CN106977149A CN 106977149 A CN106977149 A CN 106977149A CN 201710281474 A CN201710281474 A CN 201710281474A CN 106977149 A CN106977149 A CN 106977149A
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stone
cement
agent
parts
rectangular slab
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CN201710281474.1A
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费宏伟
杨国荣
戴学武
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Individual
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like
    • C04B2111/542Artificial natural stone

Abstract

The invention discloses a kind of rectangular slab of stone formula modelled after an antique and its preparation technology, including following mass parts:25~35 parts of steel gray 300~500 parts, 200~400 parts of water, 400~500 parts of ore in sand form, 600~800 parts of building stones, 70~150 parts of pigment, 15~20 parts of cement additire and cement additive.Its preparation method includes:Steel gray clay standby, capstock preparation, underlying material preparation, the demoulding, polishing, grinding, Anti-seeping technology and crystallization treatment.The rectangular slab of stone modelled after an antique prepared by the present invention is in atropurpureus, improves the quality and aesthetic feeling of the rectangular slab of stone modelled after an antique, reduces the consumption of water, cement is saved, manufacturing cost is reduced, while improving the performance of stone material, the preparation method step is simple, through polishing, Anti-seeping technology and crystallization treatment, the hard effect of crystalline substance on rectangular slab of stone surface modelled after an antique is not only increased, the intensity and durability of stone surface, and preparation technology environmental protection is improved, pernicious gas will not be produced, green production can be realized.

Description

A kind of rectangular slab of stone formula modelled after an antique and its preparation technology
Technical field
The present invention relates to antique stone Material Field, more particularly to a kind of rectangular slab of stone formula modelled after an antique and its preparation technology.
Background technology
Now with the development and the improvement of people's living standards of science and technology, as square road surface or the paver of garden, It is desirable to the appearance that it has lithotome.But lithotome resource-constrained after all, so people set in the side of thinking Method produces the artificial stone with natural stone appearance, has on the one hand effectively saved natural resources, on the other hand also increases Sources of supply so that antique stone obtains large-scale application.Although the current rectangular slab of stone modelled after an antique has reached certain regard in appearance Effect is felt, but it can only place and be furnished indoors, and long-time is placed on outdoor, through rainwash, being exposed to the sun of burning sun, wind Drifting dust falls, and irregular pit occurs in its surface, easily hides and receives dirt, not easy cleaning, it is impossible to the need for meeting people.
The content of the invention
Present invention aims at provide a kind of rectangular slab of stone formula modelled after an antique and its preparation for the deficiency present in prior art The technical scheme of technique, the rectangular slab of stone modelled after an antique prepared by the present invention is in atropurpureus, and The Purple Air comes from the east, and implied meaning is very good, also improves modelled after an antique The quality and aesthetic feeling of the rectangular slab of stone, decorative cover are smooth, are easy to cleaning, can be chronically exposed under rainwater and burning sun, service life is carried significantly Height, the preparation method step is simple, and through polishing, Anti-seeping technology and crystallization treatment, the crystalline substance for not only increasing rectangular slab of stone surface modelled after an antique is hard Effect, improves the intensity and durability of stone surface, and preparation technology environmental protection, will not produce pernicious gas, can realize green Color is produced.
In order to solve the above-mentioned technical problem, the present invention is adopted the following technical scheme that:
A kind of rectangular slab of stone formula modelled after an antique, it is characterised in that including following mass parts:Steel gray 300~500 parts, water 200~400 Part, 400~500 parts of ore in sand form, 600~800 parts of building stones, 70~150 parts of pigment, 15~20 parts of cement additire and cement additive 25~35 parts.
It is preferred that, pigment includes black, yellow and green, the ratio of black, yellow and green three kinds of pigment for (0.8~ 1.5):(0.1~0.5):(0.1~0.4).
Further, cement additire includes the first water reducer, retarder, waterproofing agent and antifreezing agent, the first water reducer, slow setting The mass ratio of agent, waterproofing agent and antifreezing agent is (2.5~5.5):(1.2~1.5):(2.5~3.7):(0.8~1.6).
It is preferred that, the first water reducer is sulfamate water reducer, melamine water reducing agent, polycarboxylate water-reducer, methyl One or both of naphthalene water reducer thing mixed above, retarder is in polyalcohol, amido derivative, cellulose, cellulose ether One or more kinds of mixtures, retarder can not only postpone the setting time of cement mortar, and can delay and reduce The exotherm rate of hydrated cementitious and heat, so that stone material avoids temperature stress from triggering crack in forming process, waterproofing agent is height Level aliphatic acid waterproofing agent, antifreezing agent is one or both of natrium nitrosum, carbonate, calcium chloride, ethylene glycol thing mixed above.
Further, cement additive includes the second water reducer, air entraining agent, lubricant and early strength agent, the second water reducer, bleed The mass ratio of agent, lubricant and early strength agent is (2.3~4.7):(1.5~1.9):(0.5~1.2):(1.3~1.8).
It is preferred that, the second water reducer is one kind in coumarone indene resin water reducer, melamine resin water reducer and naphthalene water reducer Or two or more mixtures, air entraining agent is rosin resin air entraining agent, fatty alcohol sulfonate air entraining agent and alkylated aromatic sulfonic acid bleed One kind in agent, early strength agent is one kind in chloride salt early strength agent and Sulfates early strength agent, and early strength agent can improve stone material Density.
It can not only be increased cement under conditions of cement mixing ratio is constant and mixed by the first water reducer and the second water reducer Compound mobility and intensity is not reduced, make to be easier shaping after cement, ore in sand form mixing, easy to operate, and keeping cement to mix In the case that compound mobility and the ratio of mud are constant, the consumption of water and the consumption of cement can be reduced simultaneously, so as to save cement, is reached To the purpose of reduction manufacturing cost, in the case where keeping cement mixture mobility constant, the consumption for only reducing water is not reduced The consumption of cement, then reduce the ratio of mud, so as to improve the density of cement, improves intensity and durability.
The technique for preparing a kind of rectangular slab of stone formula modelled after an antique described above, it is characterised in that comprise the following steps:
A) it is steel gray clay standby
First by steel gray and water using mass ratio as (4~9):(1~5), adds First vertical concrete stirring machine, control The rotating speed of mixer is 15~55r/min, under normal temperature condition within 10~15min of stirring, stirs into pasty state, then uses pneumatic spray Pulp grinder controls the pressure of pneumatic pulp shooting machine for 4~12KPa along mould surface spraying, and the solidifying and setting under normal temperature condition, Gu The change time is 0.5~2.0h;
B) prepared by capstock
First by ore in sand form and cement using mass ratio as (1.0~2.5):(0.5~1.5) is added to second vertical mixer In be mixed evenly, then add pigment, the mass ratio of pigment and cement, ore in sand form is (1.0~2.0):(85~125): The mass ratio of black, yellow and green is (8~15) in (120~165), wherein pigment:(1~5):(1~3), stirring is equal Cement additire is added in even backward second vertical mixer, the weight of cement additire accounts for the 1.0~2.5% of gross weight, At normal temperatures stirring 10~15min within, be then equably sprayed in above-mentioned mould with pneumatic pulp shooting machine, coating thickness be 10~ 20mm, the then solidifying and setting under normal temperature condition, hardening time is 0.7~2.0h;
C) prepared by underlying material
First by ore in sand form, building stones and cement using mass ratio as (0.5~1.2):(0.8~1.5):(0.4~1.1) the is added It is mixed evenly in three vertical mixers, cement additive is then added into the 3rd vertical mixer is stirred, The weight of wherein cement additive is accounted under the 1.2~2.5% of gross weight, normal temperature condition and stirred within 10~15min, is then passed through Manually load in above-mentioned mould, thickness is 60~80mm, 3~7d of natural curing;
D) it is stripped
After steel gray layer, surface layer and bottom in mould reach setting intensity, demoulding processing is carried out;
E) polish
Stone material after the demoulding is lain in a horizontal plane in machine table, roughly ground with stainless-steel grinding brush, control is ground during grinding The rotating speed of grinding machine is 140~180r/min, laterally vertical respectively grinding 2~3 times, steady mobile grinder during grinding, and controls to grind The translational speed of polish-brush horizontal direction is 2~3min/m, untill stone surface is smooth;
F) grind
After corase grind, abrasive brush is changed, in progress, fine lapping is processed, and is 200~300r/ by the adjustment of rotational speed of grinder Min, laterally vertical respectively grinding 3~5 times, the horizontal movement velocity that abrasive brush is controlled during grinding is 4~6min/m, in process of lapping In add water, and sparge pipe is placed in the both sides of abrasive brush moving direction, grinding is rinsed well after terminating with clear water;
G) Anti-seeping technology
After end to be ground, stone material is dried with drying baker, spary anti-fouling agent after drying, first above and below stone material Surface is brushed, and is brushed back and forth along same direction 2~3 times, until the upper and lower surface of anti-fouling agent and stone material is completely attached to, so Sprayed afterwards in the left and right side of stone material, it is 1~3min/m to control speed of the shower nozzle in moving process, along the side of stone material Face S-shaped spraying back and forth, is sprayed 2~3 times, spary is protected after finishing;
H) crystallization treatment
After stone material Anti-seeping technology maintenance 24h, crystal face cure process is carried out to stone surface with crystal hardening accelerator, to stone material table After face is cleaned out, crystal hardening accelerator is sprayed on stone surface, with steel wool uniformly around on abrasive disk, using crystal face processor Sequentially being ground back and forth in stone surface from top to bottom backward from left, the rotating speed for control crystal face processor is 140~ 180r/min, is handled 2~3 times back and forth, finally carries out encapsulation process to stone material with stone material sealant, is rinsed after drying and is used wax-polishing machine Carry out waxing polishing.
It is preferred that, the mass ratio (1.2~1.8) of pigment, cement and ore in sand form in the preparation of step b) capstocks:(95~ 110):(130~155).
It is preferred that, the mass ratio of ore in sand form, building stones and cement in the preparation of step c) underlying materials is (0.8~1.1):(1.0~ 1.4):(0.5~1.0).
The present invention is by adopting the above-described technical solution, have the advantages that:
1st, the rectangular slab of stone modelled after an antique prepared using the present invention is in atropurpureus, and implied meaning that The Purple Air comes from the east is good, improves the matter of the rectangular slab of stone modelled after an antique Amount and aesthetic feeling, decorative cover are smooth, are easy to cleaning, can be chronically exposed under rainwater and burning sun, service life is greatly improved;
2nd, the building stones that the rectangular slab of stone modelled after an antique prepared using the present invention is used in preparation process are from the lithotome reclaimed The leftover pieces produced during processing, ore in sand form is that, through crushing, grinding and be sieved into, this way is greatly saved by leftover pieces Natural resources, and the recycling of resource is realized, and the consumption of raw material is reduced in preparation process, reduce water Consumption, has saved cement, reduces manufacturing cost, while improving the performance of stone material, is easier into after making cement, ore in sand form mixing It is type, easy to operate;
3rd, preparation method step of the invention is simple, through polishing, Anti-seeping technology and crystallization treatment, not only increases bar modelled after an antique The hard effect of crystalline substance on stone surface, improves the intensity and durability of stone surface, and preparation technology environmental protection, will not produce harmful gas Body, can realize green production;
Embodiment
A kind of rectangular slab of stone formula modelled after an antique of the present invention, including following mass parts:Steel gray 300~500 parts, 200~400 parts of water, ore deposit 400~500 parts of sand, 600~800 parts of building stones, 70~150 parts of pigment, 15~20 parts of cement additire and cement additive 25~ 35 parts.
It is preferred that, pigment includes black, yellow and green, the ratio of black, yellow and green three kinds of pigment for (0.8~ 1.5):(0.1~0.5):(0.1~0.4).
Cement additire includes the first water reducer, retarder, waterproofing agent and antifreezing agent, the first water reducer, retarder, waterproof The mass ratio of agent and antifreezing agent is (2.5~5.5):(1.2~1.5):(2.5~3.7):(0.8~1.6), it is preferred that first subtracts Aqua is one or both of sulfamate water reducer, melamine water reducing agent, polycarboxylate water-reducer, methyl naphthalene water reducer Thing mixed above, retarder is one or both of polyalcohol, amido derivative, cellulose, cellulose ether thing mixed above, Retarder can not only postpone the setting time of cement mortar, and can delay and reduce the exotherm rate and Re of hydrated cementitious Amount, so that stone material avoids temperature stress from triggering crack in forming process, waterproofing agent is higher fatty acids waterproofing agent, and antifreezing agent is One or both of natrium nitrosum, carbonate, calcium chloride, ethylene glycol thing mixed above.
Cement additive includes the second water reducer, air entraining agent, lubricant and early strength agent, the second water reducer, air entraining agent, lubrication The mass ratio of agent and early strength agent is (2.3~4.7):(1.5~1.9):(0.5~1.2):(1.3~1.8), it is preferred that second subtracts Aqua is one or both of coumarone indene resin water reducer, melamine resin water reducer and naphthalene water reducer thing mixed above, bleed Agent is one kind in rosin resin air entraining agent, fatty alcohol sulfonate air entraining agent and alkylated aromatic sulfonic acid air entraining agent, and early strength agent is chlorine One kind in salt early strength agent and Sulfates early strength agent, early strength agent can improve the density of stone material.
It can not only be increased cement under conditions of cement mixing ratio is constant and mixed by the first water reducer and the second water reducer Compound mobility and intensity is not reduced, make to be easier shaping after cement, ore in sand form mixing, easy to operate, and keeping cement to mix In the case that compound mobility and the ratio of mud are constant, the consumption of water and the consumption of cement can be reduced simultaneously, so as to save cement, is reached To the purpose of reduction manufacturing cost, in the case where keeping cement mixture mobility constant, the consumption for only reducing water is not reduced The consumption of cement, then reduce the ratio of mud, so as to improve the density of cement, improves intensity and durability.
The technique for preparing a kind of rectangular slab of stone formula modelled after an antique described above, comprises the following steps:
A) it is steel gray clay standby
First by steel gray and water using mass ratio as (4~9):(1~5), adds First vertical concrete stirring machine, control The rotating speed of mixer is 15~55r/min, under normal temperature condition within 10~15min of stirring, stirs into pasty state, then uses pneumatic spray Pulp grinder controls the pressure of pneumatic pulp shooting machine for 4~12KPa along mould surface spraying, and the solidifying and setting under normal temperature condition, Gu The change time is 0.5~2.0h;
B) prepared by capstock
First by ore in sand form and cement using mass ratio as (1.0~2.5):(0.5~1.5) is added to second vertical mixer In be mixed evenly, then add pigment, the mass ratio of pigment and cement, ore in sand form is (1.0~2.0):(85~125): The mass ratio of black, yellow and green is (8~15) in (120~165), wherein pigment:(1~5):(1~3), stirring is equal Cement additire is added in even backward second vertical mixer, the weight of cement additire accounts for the 1.0~2.5% of gross weight, At normal temperatures stirring 10~15min within, be then equably sprayed in above-mentioned mould with pneumatic pulp shooting machine, coating thickness be 10~ 20mm, the then solidifying and setting under normal temperature condition, hardening time is 0.7~2.0h, it is preferred that capstock prepare in pigment, The mass ratio (1.2~1.8) of cement and ore in sand form:(95~110):(130~155);
C) prepared by underlying material
First by ore in sand form, building stones and cement using mass ratio as (0.5~1.2):(0.8~1.5):(0.4~1.1) the is added It is mixed evenly in three vertical mixers, cement additive is then added into the 3rd vertical mixer is stirred, The weight of wherein cement additive is accounted under the 1.2~2.5% of gross weight, normal temperature condition and stirred within 10~15min, is then passed through Manually load in above-mentioned mould, thickness is 60~80mm, 3~7d of natural curing, it is preferred that ore in sand form, stone in underlying material preparation The mass ratio of material and cement is (0.8~1.1):(1.0~1.4):(0.5~1.0);Cement additive volume is to net slurry flowing Influence is as shown in table 1:
Influence of the cement additive volume of table 1 to net slurry flowing
D) it is stripped
After steel gray layer, surface layer and bottom in mould reach setting intensity, demoulding processing is carried out;
E) polish
Stone material after the demoulding is lain in a horizontal plane in machine table, roughly ground with stainless-steel grinding brush, control is ground during grinding The rotating speed of grinding machine is 140~180r/min, laterally vertical respectively grinding 2~3 times, steady mobile grinder during grinding, and controls to grind The translational speed of polish-brush horizontal direction is 2~3min/m, untill stone surface is smooth;
F) grind
After corase grind, abrasive brush is changed, in progress, fine lapping is processed, and is 200~300r/ by the adjustment of rotational speed of grinder Min, laterally vertical respectively grinding 3~5 times, the horizontal movement velocity that abrasive brush is controlled during grinding is 4~6min/m, in process of lapping In add water, and sparge pipe is placed in the both sides of abrasive brush moving direction, grinding is rinsed well after terminating with clear water;
G) Anti-seeping technology
After end to be ground, stone material is dried with drying baker, spary anti-fouling agent after drying, first above and below stone material Surface is brushed, and is brushed back and forth along same direction 2~3 times, until the upper and lower surface of anti-fouling agent and stone material is completely attached to, so Sprayed afterwards in the left and right side of stone material, it is 1~3min/m to control speed of the shower nozzle in moving process, along the side of stone material Face S-shaped spraying back and forth, is sprayed 2~3 times, spary is protected after finishing;
H) crystallization treatment
After stone material Anti-seeping technology maintenance 24h, crystal face cure process is carried out to stone surface with crystal hardening accelerator, to stone material table After face is cleaned out, crystal hardening accelerator is sprayed on stone surface, with steel wool uniformly around on abrasive disk, using crystal face processor Sequentially being ground back and forth in stone surface from top to bottom backward from left, the rotating speed for control crystal face processor is 140~ 180r/min, is handled 2~3 times back and forth, finally carries out encapsulation process to stone material with stone material sealant, is rinsed after drying and is used wax-polishing machine Carry out waxing polishing.
The performance of the rectangular slab of stone modelled after an antique prepared by the present invention is as shown in table 2
The performance parameter of the rectangular slab of stone modelled after an antique of table 2
Embodiment 1
By 500kg is steel gray plus 200kg water passes through under First vertical concrete stirring machine (rotating speed 20r/min) normal temperature condition Within stirring 15 minutes, then by pneumatic pulp shooting machine (pressure is 5~7KPa), being brokenly sprayed on die surface, (die size is long Mistake!Reference source is not found.It is wide:110 mistakes!Reference source is not found.47, unit:Cm), the solidifying and setting under normal temperature condition, Gu Change time 1h.
After 500kg ores in sand form (furvous), 300kg cement, 5kg pigment are mixed, yellow wherein in pigment is 80 parts, black 30 parts of color, 20 parts of green, after addition cement additire is well mixed, by second vertical concrete stirring machine, normal temperature condition Within lower stirring 15 minutes, then equably it is sprayed in above-mentioned mould by pneumatic pulp shooting machine (pressure is 5~7KPa), thickness is 10mm or so, the solidifying and setting under normal temperature condition, hardening time 1h.
After 500kg ores in sand form (furvous), 600kg building stones, 300kg cement mixings, add cement additive and be well mixed Afterwards, by the 3rd vertical concrete stirring machine, within being stirred 15 minutes under normal temperature condition, manually load in above-mentioned mould, it is thick Spend 70mm or so, natural curing three days or so, the demoulding.
Semi-finished product after the demoulding are first disposed into surface deashing by shot-blasting machine, then polishing obtains finished product.
Embodiment 2
By 500kg is steel gray plus 200kg water passes through under First vertical concrete stirring machine (rotating speed 30r/min) normal temperature condition Within stirring 15 minutes, then by pneumatic pulp shooting machine (pressure is 5~7KPa), being brokenly sprayed on die surface, (die size is long Mistake!Reference source is not found.It is wide:110 mistakes!Reference source is not found.47, unit:Cm), the solidifying and setting under normal temperature condition, Gu Change time 1.5h.
After 500kg ores in sand form (furvous), 300kg cement, 5kg pigment are mixed, yellow wherein in pigment is 100 parts, 40 parts of black, 30 parts of green, after addition cement additire is well mixed, by second vertical concrete stirring machine, normal temperature bar Within being stirred 15 minutes under part, then equably it is sprayed in above-mentioned mould by pneumatic pulp shooting machine (pressure is 5~7KPa), thickness is 15mm or so, the solidifying and setting under normal temperature condition, hardening time 1.5h.
After 500kg ores in sand form (furvous), 600kg building stones, 300kg cement mixings, add cement additive and be well mixed Afterwards, by the 3rd vertical concrete stirring machine, within being stirred 15 minutes under normal temperature condition, manually load in above-mentioned mould, it is thick Spend 75mm or so, natural curing three days or so, the demoulding.
Semi-finished product after the demoulding are first disposed into surface deashing by shot-blasting machine, then polishing obtains finished product.
Embodiment 3
By 500kg is steel gray plus 200kg water passes through under First vertical concrete stirring machine (rotating speed 40r/min) normal temperature condition Within stirring 15 minutes, then by pneumatic pulp shooting machine (pressure is 5~7KPa), being brokenly sprayed on die surface, (die size is long Mistake!Reference source is not found.It is wide:110 mistakes!Reference source is not found.47, unit:Cm), the solidifying and setting under normal temperature condition, Gu Change time 2h.
After 500kg ores in sand form (furvous), 300kg cement, 5kg pigment are mixed, yellow wherein in pigment is 120 parts, 50 parts of black, 40 parts of green, after addition cement additire is well mixed, by second vertical concrete stirring machine, normal temperature bar Within being stirred 15 minutes under part, then equably it is sprayed in above-mentioned mould by pneumatic pulp shooting machine (pressure is 5~7KPa), thickness is 20mm or so, the solidifying and setting under normal temperature condition, hardening time 2h.
After 500kg ores in sand form (furvous), 600kg building stones, 300kg cement mixings, add cement additive and be well mixed Afterwards, by the 3rd vertical concrete stirring machine, within being stirred 15 minutes under normal temperature condition, manually load in above-mentioned mould, it is thick Spend 80mm or so, natural curing three days or so, the demoulding.
Semi-finished product after the demoulding are first disposed into surface deashing by shot-blasting machine, then polishing obtains finished product.
The specific embodiment of the present invention is these are only, but the technical characteristic of the present invention is not limited thereto.It is any with this hair Based on bright, to realize essentially identical technique effect, made ground simple change, equivalent substitution or modification etc., all cover Among protection scope of the present invention.

Claims (9)

1. a kind of rectangular slab of stone formula modelled after an antique, it is characterised in that including following mass parts:Steel gray 300~500 parts, 200~400 parts of water, 400~500 parts of ore in sand form, 600~800 parts of building stones, 70~150 parts of pigment, 15~20 parts of cement additire and cement additive 25 ~35 parts.
2. a kind of rectangular slab of stone formula modelled after an antique according to claim 1, it is characterised in that:The pigment include black, yellow and Green, the ratio of black, yellow and green three kinds of pigment is (0.8~1.5):(0.1~0.5):(0.1~0.4).
3. a kind of rectangular slab of stone formula modelled after an antique according to claim 1, it is characterised in that:The cement additire subtracts including first Aqua, retarder, waterproofing agent and antifreezing agent, first water reducer, the retarder, the waterproofing agent and the antifreezing agent Mass ratio is (2.5~5.5):(1.2~1.5):(2.5~3.7):(0.8~1.6).
4. a kind of rectangular slab of stone formula modelled after an antique according to claim 3, it is characterised in that:First water reducer is sulfamic acid One or both of salt water reducer, melamine water reducing agent, polycarboxylate water-reducer, methyl naphthalene water reducer thing mixed above, institute It is one or both of polyalcohol, amido derivative, cellulose, cellulose ether thing mixed above, the waterproof to state retarder Agent is higher fatty acids waterproofing agent, and the antifreezing agent is one or both of natrium nitrosum, carbonate, calcium chloride, ethylene glycol Thing mixed above.
5. a kind of rectangular slab of stone formula modelled after an antique according to claim 1, it is characterised in that:The cement additive subtracts including second Aqua, air entraining agent, lubricant and early strength agent, second water reducer, the air entraining agent, the lubricant and the early strength agent Mass ratio is (2.3~4.7):(1.5~1.9):(0.5~1.2):(1.3~1.8).
6. a kind of rectangular slab of stone formula modelled after an antique according to claim 1, it is characterised in that:Second water reducer is coumarone tree One or both of fat water reducer, melamine resin water reducer and naphthalene water reducer thing mixed above, the air entraining agent is rosin tree One kind in fat air entraining agent, fatty alcohol sulfonate air entraining agent and alkylated aromatic sulfonic acid air entraining agent, the early strength agent is that chloride salt is early One kind in strong agent and Sulfates early strength agent.
7. prepare a kind of technique of rectangular slab of stone formula modelled after an antique as claimed in claim 1, it is characterised in that comprise the following steps:
A) it is steel gray clay standby
First by steel gray and water using mass ratio as (4~9):(1~5), adds First vertical concrete stirring machine, control stirring The rotating speed of machine is 15~55r/min, under normal temperature condition within 10~15min of stirring, stirs into pasty state, then uses pneumatic pulp shooting machine Along mould surface spraying, the pressure of pneumatic pulp shooting machine is controlled for 4~12KPa, and the solidifying and setting under normal temperature condition, during solidification Between be 0.5~2.0h;
B) prepared by capstock
First by ore in sand form and cement using mass ratio as (1.0~2.5):(0.5~1.5) is added in second vertical mixer and mixed Conjunction stirs, and then adds pigment, pigment and cement, the mass ratio of ore in sand form are (1.0~2.0):(85~125):(120~ 165), the mass ratio of black, yellow and green is (8~15) wherein in pigment:(1~5):(1~3), stirs backward Cement additire is added in second vertical mixer, the weight of cement additire accounts for the 1.0~2.5% of gross weight, in normal temperature Within 10~15min of lower stirring, then equably it is sprayed in above-mentioned mould with pneumatic pulp shooting machine, coating thickness is 10~20mm, Then the solidifying and setting under normal temperature condition, hardening time is 0.7~2.0h;
C) prepared by underlying material
First by ore in sand form, building stones and cement using mass ratio as (0.5~1.2):(0.8~1.5):(0.4~1.1) the 3rd is added It is mixed evenly in vertical mixer, cement additive is then added into the 3rd vertical mixer is stirred, wherein The weight of cement additive is accounted under the 1.2~2.5% of gross weight, normal temperature condition and stirred within 10~15min, then by artificial Load in above-mentioned mould, thickness is 60~80mm, 3~7d of natural curing;
D) it is stripped
After steel gray layer, surface layer and bottom in mould reach setting intensity, demoulding processing is carried out;
E) polish
Stone material after the demoulding is lain in a horizontal plane in machine table, is roughly ground with stainless-steel grinding brush, grinder is controlled during grinding Rotating speed be 140~180r/min, laterally vertical each grinding 2~3 times, steady mobile grinder during grinding, and control abrasive brush The translational speed of horizontal direction is 2~3min/m, untill stone surface is smooth;
F) grind
After corase grind, abrasive brush is changed, in progress, fine lapping is processed, and is 200~300r/min by the adjustment of rotational speed of grinder, horizontal To vertical respectively grinding 3~5 times, the horizontal movement velocity that abrasive brush is controlled during grinding is 4~6min/m, is added in process of lapping Water, and sparge pipe is placed in the both sides of abrasive brush moving direction, grinding is rinsed well after terminating with clear water;
G) Anti-seeping technology
After end to be ground, stone material is dried with drying baker, spary anti-fouling agent, the first upper and lower surface in stone material after drying Brushed, brushed back and forth along same direction 2~3 times, until the upper and lower surface of anti-fouling agent and stone material is completely attached to, Ran Hou The left and right side of stone material is sprayed, and it is 1~3min/m to control speed of the shower nozzle in moving process, is come along the side of stone material S-shaped spraying is returned, is sprayed 2~3 times, spary is protected after finishing;
H) crystallization treatment
After stone material Anti-seeping technology maintenance 24h, crystal face cure process is carried out to stone surface with crystal hardening accelerator, it is clear to stone surface After reason is clean, crystal hardening accelerator is sprayed on stone surface, with steel wool uniformly around on abrasive disk, with crystal face processor by first Order is ground back and forth in stone surface from top to bottom backward from left afterwards, and the rotating speed for controlling crystal face processor is 140~180r/ Min, is handled 2~3 times back and forth, finally carries out encapsulation process to stone material with stone material sealant, is rinsed and is carried out after drying with wax-polishing machine Waxing polishing.
8. a kind of preparation technology of rectangular slab of stone formula modelled after an antique according to claim 7, it is characterised in that:Step b) capstock systems The mass ratio (1.2~1.8) of the pigment, the cement and the ore in sand form in standby:(95~110):(130~155).
9. a kind of preparation technology of rectangular slab of stone modelled after an antique according to claim 7, it is characterised in that:In prepared by step c) underlying materials The ore in sand form, the mass ratio of the building stones and the cement be (0.8~1.1):(1.0~1.4):(0.5~1.0).
CN201710281474.1A 2017-04-26 2017-04-26 A kind of rectangular slab of stone formula modelled after an antique and its preparation technology Pending CN106977149A (en)

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Application publication date: 20170725