CN106967529A - A kind of gentle inirritative dish washing detergent and preparation method thereof - Google Patents

A kind of gentle inirritative dish washing detergent and preparation method thereof Download PDF

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Publication number
CN106967529A
CN106967529A CN201710214997.4A CN201710214997A CN106967529A CN 106967529 A CN106967529 A CN 106967529A CN 201710214997 A CN201710214997 A CN 201710214997A CN 106967529 A CN106967529 A CN 106967529A
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sodium
dish washing
washing detergent
detergent
deionized water
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CN106967529B (en
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不公告发明人
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Shandong Dashu Life Health Technology Co.,Ltd.
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Hunan Erzhan Intelligent Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Abstract

Dish washing detergent and preparation method thereof is not gently stimulated the invention discloses one kind, the dish washing detergent is made up of the component of following weight percentage：The 20wt% of sodium sulfate of polyethenoxy ether of fatty alcohol 10, Cocoamidopropyl betaine 5 10wt%, the pungent 5wt% of Plantacare 818 1, the 5wt% of cocounut oil acyl hydroxyl second sulphur ester sodium 1, the 5wt% of methyl sodiosul foaliphatate 1, the 2wt% of sodium chloride 0.1, the 0.3wt% of sodium citrate 0.05, the 1wt% of ethanol 0.1, the 0.6wt% of sodium benzoate 0.1, the 0.2wt% of disodium ethylene diamine tetraacetate 0.01, the 2wt% of aloe extract 0.5, the 2wt% of purslane extract 0.5, deionized water surplus.The dish washing detergent, which has, not to stimulate gently, and natural environmental-protective, dirt-removing power are good, antibacterial, and consumption demand is met significantly.

Description

A kind of gentle inirritative dish washing detergent and preparation method thereof
Technical field
The present invention relates to dish washing detergent field, more particularly to a kind of gentle inirritative dish washing detergent and its preparation Method.
Background technology
Dish washing detergent is the dish bowl cleaning agent commonly used in daily life, can effectively remove the greasy dirt on tableware.Conventional meal The main component of tool detergent has sodium alkyl benzene sulfonate, fatty alcohol ether ammonium sulfate, amine-oxides, alkanolamide, solubilizer, thickening Agent, preservative, essence etc., though it is with stronger decontamination ability, has certain alkalescence, often directly contact these products Be irritating to the skin effect, have degreasing to human sebaceous, often cause user's hand skin it is tight, dry, it is coarse even Decortication allergic phenomena.
The content of the invention
Based on this, one of the object of the invention is to provide a kind of gentle inirritative dish washing detergent and preparation method thereof.
The concrete technical scheme for solving above-mentioned technical problem is as follows：
A kind of gentle inirritative dish washing detergent, the dish washing detergent is made up of the component of following weight percentage：
Sodium sulfate of polyethenoxy ether of fatty alcohol 10-20wt%,
Cocoamidopropyl betaine 5-10wt%,
Pungent Plantacare 818 1-5wt%,
Cocounut oil acyl hydroxyl second sulphur ester sodium 1-5wt%,
Methyl sodiosul foaliphatate 1-5wt%,
Sodium chloride 0.1-2wt%,
Sodium citrate 0.05-0.3wt%,
Ethanol 0.1-1wt%,
Sodium benzoate 0.1-0.6wt%,
Disodium ethylene diamine tetraacetate 0.01-0.2wt%,
Aloe extract 0.5-2wt%,
Purslane extract 0.5-2wt%,
Deionized water surplus, citric acid or piece alkali regulation pH6.8-7.0.
It is preferred that, the dish washing detergent is made up of the component of following weight percentage：
Sodium sulfate of polyethenoxy ether of fatty alcohol 13-18wt%,
Cocoamidopropyl betaine 6-9wt%,
Pungent Plantacare 818 1-4wt%,
Cocounut oil acyl hydroxyl second sulphur ester sodium 1-3wt%,
Methyl sodiosul foaliphatate 1-3wt%,
Sodium chloride 0.5-1.5wt%,
Sodium citrate 0.15-0.25wt%,
Ethanol 0.6-0.8wt%,
Sodium benzoate 0.3-0.5wt%,
Disodium ethylene diamine tetraacetate 0.08-0.2wt%,
Aloe extract 1.5-1.8wt%,
Purslane extract 1.5-1.8wt%,
Deionized water surplus, citric acid or piece alkali regulation pH6.8-7.0.
It is preferred that, C is contained in the sodium sulfate of polyethenoxy ether of fatty alcohol12-C14Alkyl chain, the oxirane of alcohol ether puts down Right homopolymerization is 2-3.
It is preferred that, C is contained in the methyl sodiosul foaliphatate14-C16Alkyl chain.
Another object of the present invention is a kind of preparation method of gentle inirritative dish washing detergent of offer, and step is as follows：
Take appropriate amount of deionized water to be heated to 42-45 DEG C, be slowly added to sodium sulfate of polyethenoxy ether of fatty alcohol and stir to complete Dissolving；Pungent Plantacare 818, cocounut oil acyl hydroxyl second sulphur ester sodium, Cocoamidopropyl betaine and fat are sequentially added then at 45-50 DEG C Fatty acid methyl esters sodium sulfonate, and stir respectively to being completely dissolved, it is cooled to 32-35 DEG C；After sequentially add ethanol, ethylenediamine tetra-acetic acid Disodium, sodium citrate and sodium benzoate, add aloe extract and purslane extract, and stir respectively to being completely dissolved；Again Sodium chloride and remaining deionized water are added, citric acid or piece alkali adjust pH to neutrality.
A kind of gentle inirritative dish washing detergent of the present invention and preparation method thereof has advantages below and beneficial Effect：
1) dish washing detergent of the present invention is without sodium alkyl benzene sulfonate, amine-oxides and alkanolamide etc., to skin irritatin Property it is larger, be unfavorable for the component of environmental protection, it is reasonable that it is formulated, while being aided with two kinds of extracts makes its milder, using rear skin not It is tight, dry and coarse, and the feature of environmental protection is good, dirt-removing power is good, antibacterial, and consumption demand is met significantly.
2) dish washing detergent preparation method of the present invention is science, simple, conveniently.
Embodiment
Below with reference to specific embodiment, the present invention will be further described, so that those skilled in the art are clearer The solution present invention, but and it is not so limited the present invention.
Embodiment 1
The present embodiment is related to a kind of gentle inirritative dish washing detergent, dish washing detergent by following weight percentage group It is grouped into：
Sodium sulfate of polyethenoxy ether of fatty alcohol 15wt%,
Cocoamidopropyl betaine 8wt%,
Pungent Plantacare 818 4wt%,
Cocounut oil acyl hydroxyl second sulphur ester sodium 1wt%,
Methyl sodiosul foaliphatate 2wt%,
Sodium chloride 0.7wt%,
Sodium citrate 0.2wt%,
Ethanol 0.8wt%,
Sodium benzoate 0.5wt%,
Disodium ethylene diamine tetraacetate 0.12wt%,
Aloe extract 1.5wt%,
Purslane extract 1.5wt%,
Deionized water surplus, citric acid or piece alkali regulation pH6.8-7.0.
Wherein, C is contained in sodium sulfate of polyethenoxy ether of fatty alcohol12-C14Alkyl chain, the oxirane average polymerization of alcohol ether Spend for 2-3；Contain C in methyl sodiosul foaliphatate14-C16Alkyl chain.
The preparation method of above-mentioned dish washing detergent, step is as follows：
Take appropriate amount of deionized water to be heated to 42-45 DEG C, be slowly added to sodium sulfate of polyethenoxy ether of fatty alcohol and stir to complete Dissolving；Pungent Plantacare 818, cocounut oil acyl hydroxyl second sulphur ester sodium, Cocoamidopropyl betaine and fat are sequentially added then at 45-50 DEG C Fatty acid methyl esters sodium sulfonate, and stir respectively to being completely dissolved, it is cooled to 32-35 DEG C；After sequentially add ethanol, ethylenediamine tetra-acetic acid Disodium, sodium citrate and sodium benzoate, add aloe extract and purslane extract, and stir respectively to being completely dissolved；Again Sodium chloride and remaining deionized water are added, citric acid or piece alkali adjust pH to neutrality.
Embodiment 2
The present embodiment is related to a kind of gentle inirritative dish washing detergent, dish washing detergent by following weight percentage group It is grouped into：
Sodium sulfate of polyethenoxy ether of fatty alcohol 20wt%,
Cocoamidopropyl betaine 5wt%,
Pungent Plantacare 818 2wt%,
Cocounut oil acyl hydroxyl second sulphur ester sodium 2wt%,
Methyl sodiosul foaliphatate 4wt%,
Sodium chloride 1.6wt%,
Sodium citrate 0.1wt%,
Ethanol 0.9wt%,
Sodium benzoate 0.4wt%,
Disodium ethylene diamine tetraacetate 0.16wt%,
Honegsukle flower P.E 0.5wt%,
Purslane extract 0.5wt%,
Deionized water surplus, citric acid or piece alkali regulation pH6.8-7.0.
The preparation method of above-mentioned dish washing detergent is with reference to embodiment 1.
Performance test
First, test objective
Determine the scourability and mildness of detergent obtained by embodiment 1 and embodiment 2.
2nd, content is determined
Dirt-removing power, skin irritation.
Control group dish washing detergent is made up of the component of following weight percentage：
Sodium sulfate of polyethenoxy ether of fatty alcohol 10wt%,
Cocoamidopropyl betaine 2wt%,
Pungent Plantacare 818 1wt%,
Cocounut oil acyl hydroxyl second sulphur ester sodium 1wt%,
Methyl sodiosul foaliphatate 8wt%,
Sodium chloride 0.9wt%,
Sodium citrate 0.4wt%,
Ethanol 0.8wt%,
Sodium benzoate 0.1wt%,
Disodium ethylene diamine tetraacetate 0.12wt%,
Aloe extract 1.5wt%,
Purslane extract 1.5wt%,
Deionized water surplus, citric acid or piece alkali regulation pH6.8-7.0.
Wherein, C is contained in sodium sulfate of polyethenoxy ether of fatty alcohol12-C14Alkyl chain, the oxirane average polymerization of alcohol ether Spend for 2-3；Contain C in methyl sodiosul foaliphatate14-C16Alkyl chain.
3rd, method of testing
1st, the measure of detergency (1)
Assay method：According to dish washing detergent GB9985-2000, Appendix B detergency is determined, and the foam method of method two is carried out Determine.
2nd, skin irritation (1)
Rabbit skin irritation test：Take 6 rabbit, every 2 one group, using left and right sides self-contrast method.24h before experiment Family's rabbit back diamond wool is removed, each 6cm × 8cm of gross area is removed, left side goes to hair-fields to smear 0.5ml detergent (first 2 times a day Group smear embodiment 1 made from detergent, second group of smearing embodiment 2, the 3rd group of smearing control group) made from dishwashing detergent Agent, is covered, immobilization with adhesive tape continues 3h with one layer of glassine paper and two layers of gauze, is removed covering and is coated position with warm water cleaning, Continuous 7 days, the 1h after applicator is removed every time, and coat preceding observation again and record erythema, oedema, blutpunkte, dry skin With pachylosis situation；Right side is coated with distilled water as blank control.After last coating, 1h, 24h, 48h after detergent is removed Visually observed with 72h, erythema and oedema score value occur according to standards of grading record, assassination of going forward side by side swashs intensity evaluation.Evaluation method It is as follows：
The skin wound repair of table 1 scores
Dermoreaction Integration
Erythema and eschar are formed
Without erythema 0
Slight erythema (visible reluctantly) 1
Obvious erythema 2
Moderate-severe erythema 3
Severe erythema (aubergine) to slight eschar is formed 4
Oedema is formed
Without oedema 0
Slight oedema (visible reluctantly) 1
Mild edema (cutaneous protuberance profile understands) 2
Intermediate edema (cutaneous protuberance about 1mm) 3
Severe edema (cutaneous protuberance expands more than 1mm, scope) 4
The skin irritation intensity evaluation of table 2
Stimulus intensity Score value
It is nonirritant 0.0-0.4
Subexcite 0.5-1.9
Medium excitant 2.0-5.0
Intense stimulus 5.1-8.0
3rd, detergency (2) and skin irritation (2)
30 people are divided into three groups, everyone distributes 10 plates for filling artificial greasy dirt, every group uses embodiment 1,2 respectively Cleaned with detergent made from control group, record plate decontamination situation, user use rear hand situation and use feeling. 4th, measurement result
Detergency (1) and skin irritation (1) result are shown in Table 3 and table 4 respectively：As seen from the table：Embodiment 1,2 and control The obtained detergent detergency of group is good, and Examples 1 and 2 are to rabbit no skin irritation, the inadequate visible erythema of control group rabbit, There is minimal irritation；User is preferable using detergency after embodiment 1,2 and control group, uses detergent made from embodiment 1 There is no tight, dry and coarse sensation using rear hand, slightly feel tight using rear hand using detergent made from embodiment 2 And drying, have no coarse, it is tight and dry using detergent hand made from control group, have no coarse.
The detergency of table 3 (1) measurement result
Sample Detergency (dishwashing number)
Embodiment 1 6.5
Embodiment 2 6.0
Control group 6.0
The stimulate the reaction of table 4 is integrated and stimulus intensity evaluation result

Claims (5)

1. a kind of gentle inirritative dish washing detergent, it is characterised in that the dish washing detergent is by following weight percentage Component is constituted：
Sodium sulfate of polyethenoxy ether of fatty alcohol 10-20wt%,
Cocoamidopropyl betaine 5-10wt%,
Pungent Plantacare 818 1-5wt%,
Cocounut oil acyl hydroxyl second sulphur ester sodium 1-5wt%,
Methyl sodiosul foaliphatate 1-5wt%,
Sodium chloride 0.1-2wt%,
Sodium citrate 0.05-0.3wt%,
Ethanol 0.1-1wt%,
Sodium benzoate 0.1-0.6wt%,
Disodium ethylene diamine tetraacetate 0.01-0.2wt%,
Aloe extract 0.5-2wt%,
Purslane extract 0.5-2wt%,
Deionized water surplus, citric acid or piece alkali regulation pH6.8-7.0.
2. a kind of gentle inirritative dish washing detergent according to claim 1, it is characterised in that the dish washing detergent It is made up of the component of following weight percentage：
Sodium sulfate of polyethenoxy ether of fatty alcohol 13-18wt%,
Cocoamidopropyl betaine 6-9wt%,
Pungent Plantacare 818 1-4wt%,
Cocounut oil acyl hydroxyl second sulphur ester sodium 1-3wt%,
Methyl sodiosul foaliphatate 1-3wt%,
Sodium chloride 0.5-1.5wt%,
Sodium citrate 0.15-0.25wt%,
Ethanol 0.6-0.8wt%,
Sodium benzoate 0.3-0.5wt%,
Disodium ethylene diamine tetraacetate 0.08-0.2wt%,
Aloe extract 1.5-1.8wt%,
Purslane extract 1.5-1.8wt%,
Deionized water surplus, citric acid or piece alkali regulation pH6.8-7.0.
3. a kind of gentle inirritative detergent for washing dishware with hand according to claim 1 or 2, it is characterised in that the fat Contain C in fat alcohol polyethenoxy ether sodium sulfate12-C14Alkyl chain, the oxirane average degree of polymerization of alcohol ether is 2-3.
4. a kind of gentle inirritative detergent for washing dishware with hand according to claim 1 or 2, it is characterised in that the fat Contain C in fatty acid methyl esters sodium sulfonate14-C16Alkyl chain.
5. the preparation method of the gentle inirritative dish washing detergent as described in claim any one of 1-4, it is characterised in that step It is rapid as follows：
Take appropriate amount of deionized water to be heated to 42-45 DEG C, be slowly added to sodium sulfate of polyethenoxy ether of fatty alcohol and stir to being completely dissolved； Pungent Plantacare 818, cocounut oil acyl hydroxyl second sulphur ester sodium, Cocoamidopropyl betaine and fatty acid methyl are sequentially added then at 45-50 DEG C Ester sodium sulfonate, and stir respectively to being completely dissolved, it is cooled to 32-35 DEG C；After sequentially add ethanol, disodium ethylene diamine tetraacetate, Sodium citrate and sodium benzoate, add aloe extract and purslane extract, and stir respectively to being completely dissolved；Add chlorine Change sodium and remaining deionized water, citric acid or piece alkali adjust pH to neutrality.
CN201710214997.4A 2017-04-02 2017-04-02 A kind of mildly inirritative dish washing detergent and preparation method thereof Active CN106967529B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110305744A (en) * 2019-06-27 2019-10-08 安徽省华凯轻工科技有限公司 A kind of environment-friendly highly efficient dish washing liquid
CN110699192A (en) * 2018-07-10 2020-01-17 中国医学科学院药用植物研究所 Green tableware detergent and its prepn
CN111349526A (en) * 2020-04-15 2020-06-30 惠州兆婷化妆品有限公司 Kitchen heavy oil stain cleaning agent and preparation method thereof
CN111793529A (en) * 2020-08-10 2020-10-20 訾孟州 Natural composite detergent of high-purity pineapple enzyme and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1191890A (en) * 1997-02-27 1998-09-02 Lg化学株式会社 Compositions of dishwashing detergent
CN1632093A (en) * 2004-11-09 2005-06-29 江苏隆力奇生物科技股份有限公司 Sterilization hand-guarding liquid detergent
CN102250696A (en) * 2011-06-15 2011-11-23 于文 Safe and environment-friendly concentrated special cleaning agent for vegetables and fruits
CN103045400A (en) * 2012-12-18 2013-04-17 广州立白企业集团有限公司 Liquid tableware detergent composition containing natural antibacterial components
CN103540444A (en) * 2013-09-27 2014-01-29 安徽华印机电股份有限公司 Mild non-irritating detergent for skin
CN106085641A (en) * 2016-06-03 2016-11-09 江西草珊瑚消毒用品有限公司 Antibiotic liquid detergent

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1191890A (en) * 1997-02-27 1998-09-02 Lg化学株式会社 Compositions of dishwashing detergent
CN1632093A (en) * 2004-11-09 2005-06-29 江苏隆力奇生物科技股份有限公司 Sterilization hand-guarding liquid detergent
CN102250696A (en) * 2011-06-15 2011-11-23 于文 Safe and environment-friendly concentrated special cleaning agent for vegetables and fruits
CN103045400A (en) * 2012-12-18 2013-04-17 广州立白企业集团有限公司 Liquid tableware detergent composition containing natural antibacterial components
CN103540444A (en) * 2013-09-27 2014-01-29 安徽华印机电股份有限公司 Mild non-irritating detergent for skin
CN106085641A (en) * 2016-06-03 2016-11-09 江西草珊瑚消毒用品有限公司 Antibiotic liquid detergent

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110699192A (en) * 2018-07-10 2020-01-17 中国医学科学院药用植物研究所 Green tableware detergent and its prepn
CN110699192B (en) * 2018-07-10 2023-06-23 中国医学科学院药用植物研究所 Green tableware washing liquid and preparation method thereof
CN110305744A (en) * 2019-06-27 2019-10-08 安徽省华凯轻工科技有限公司 A kind of environment-friendly highly efficient dish washing liquid
CN111349526A (en) * 2020-04-15 2020-06-30 惠州兆婷化妆品有限公司 Kitchen heavy oil stain cleaning agent and preparation method thereof
CN111793529A (en) * 2020-08-10 2020-10-20 訾孟州 Natural composite detergent of high-purity pineapple enzyme and preparation method thereof

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