CN106967358A - A kind of LED UV woodenware matte finish paints and preparation method thereof - Google Patents

A kind of LED UV woodenware matte finish paints and preparation method thereof Download PDF

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Publication number
CN106967358A
CN106967358A CN201710074035.3A CN201710074035A CN106967358A CN 106967358 A CN106967358 A CN 106967358A CN 201710074035 A CN201710074035 A CN 201710074035A CN 106967358 A CN106967358 A CN 106967358A
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CN
China
Prior art keywords
led
woodenware
mattes
acrylic resin
rotating speed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710074035.3A
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Chinese (zh)
Inventor
周凌云
全中华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Jiaxin Materials Technology Co Ltd
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Hunan Jiaxin Materials Technology Co Ltd
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Priority to CN201710074035.3A priority Critical patent/CN106967358A/en
Publication of CN106967358A publication Critical patent/CN106967358A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention discloses a kind of LED UV woodenware matte finish paints, by weight percentage, it is prepared from by the raw material of following component:Epoxy acrylic resin 10% 25%;Aliphatic polyamines ester acrylic resin 10% 25%;Two functional acrylic resins 5% 15%;Reactive diluent 35 50%;Light trigger 1% 5%;Mute powder 1% 6%;Auxiliary agent 0.1% 1%.A kind of LED UV woodenware matte finish paints that the present invention is provided, can accelerate curing rate, environmental protection, to human body non-hazardous, and obtained LED UV woodenware mattes finish paints are limited without workpiece type shape, and finish paint good toughness, industrial prospect is wide.

Description

A kind of LED-UV woodenware mattes finish paint and preparation method thereof
Technical field
The present invention relates to finish paint preparation field, especially a kind of LED-UV woodenware mattes finish paint and preparation method thereof.
Background technology
Traditional mercury lamp solidification does not adapt to life from market plane, energy-conservation, easy construction and environmental requirement all angles Force of labor develops the requirement with the epoch.Traditional mercury lamp solidifies high energy consumption, equipment high investment, can only be confined to flat board using base material, resistance to In hot substrate, existing market has been substantially saturated, and profit significantly declines.Under this historical background, Rong Jia R&D teams, which are absorbed in, grinds Study carefully removable cold light source curing technology, obtain successfully and by it smoothly applied to surfacing processing.So make market plane without Limitation expands, in original base than mercury lamp energy-conserving and environment-protective, may move, without heat radiation, traditional mercury lamp can not deeply can reach The field arrived:Traditional-family fits up, special-shaped furniture surface processing, energy-conservation.Normal temperature rapid curing, unlike heat cure heated substrate and Surrounding space, will also evaporate removing dilution solvent or water consume takes big energy, and product is substantially free of volatile organic solvent, no Air pollution can be caused, harm to the human body and fire risk is also reduced, production efficiency is high, and energy consumption is low, and photocuring is set Standby, investment technology is relatively low, easily realizes production line balance, and area of mill site is small, can save great amount of investment.Without solvent, Pollution is reduced, resource is saved, considers most economical.
As countries in the world ecological environmental protection is paid attention to, strict legislation is carried out to atmosphere pollution and is limited, photocuring product Superiority.The U.S., Europe, Japan and other countries are used as one of reduction VOC emission important means using photocuring technology.China Increase to environmental improvement and protection, this is without suspected of photocuring product offer opportunity, it is believed that, with national development, society enters Step, harmonious co-existence between man and nature, environmental protection photocuring industry is bound to all enter with day, thriving.
The content of the invention
In view of this, it is an object of the invention to provide a kind of LED-UV woodenware mattes finish paint and preparation method thereof, solidification Speed is fast, environmental protection, and obtained LED-UV woodenware mattes finish paint is limited without workpiece type shape.
The technical scheme is that:A kind of LED-UV woodenware mattes finish paint, by weight percentage, by following component Raw material is prepared from:
Epoxy acrylic resin 10%-25%;
Aliphatic polyamines ester acrylic resin 10%-25%;
Two functional acrylic resins 5%-15%;
Reactive diluent 35-50%;
Light trigger 1%-5%;
Mute powder 1%-6%;
Auxiliary agent 0.1%-1%.
Preferably, a kind of LED-UV woodenware mattes finish paint, by weight percentage, is prepared by the raw material of following component Form:
Epoxy acrylic resin 15%-20%;
Aliphatic polyamines ester acrylic resin 20%-25%;
Two functional acrylic resins 5%-10%;
Reactive diluent 40-45%;
Light trigger 3%-5%;
Mute powder 1%-3%;
Auxiliary agent 0.5%-1%.
Preferably, the light trigger is benzoin and derivative or benzil and derivative or hydroxyalkyl phenones or amine alkane One or more combination in base benzophenone or acyl group oxidation of ketones thing or benzophenone or thioxanthone or iron arene.
Preferably, the auxiliary agent is the one or more combination in levelling agent or defoamer or anti-settling agent.
A kind of preparation method of LED-UV woodenware mattes finish paint, comprises the following steps:
(1)Start dispersion machine and adjust rotating speed to 1000-1200 revs/min, the epoxy acrylic is sequentially added under this rotating speed In resin, aliphatic polyamines ester acrylic resin, two functional acrylic resins, stir 15-20 minutes;
(2)Dispersing speed is adjusted to 1000-1200 revs/min, the mute powder and reactive diluent are added under this rotating speed, it is high Speed stirring 5-10 minutes;
(3)Dispersing speed is adjusted to 1000 revs/min, the light trigger, 5-10 points of moderate-speed mixer are added under this rotating speed Clock, until paint liquid fineness reaches 15-30um;
(4)Dispersing speed is adjusted to 800-1000 revs/min, the auxiliary agent is added under this rotating speed, is stirred 10-20 minutes, Produce.
Compared with prior art, the present invention has the advantages that:A kind of LED-UV woodenware mattes that the present invention is provided Finish paint, can accelerate curing rate, environmental protection, to human body non-hazardous, and obtained LED-UV woodenware matte finish paints are without work Part type shape is limited, and finish paint good toughness, industrial prospect is wide.
Embodiment
With reference to embodiment, the present invention will be further described.
Embodiment 1
A kind of LED-UV woodenware mattes finish paint, by weight percentage, is prepared from by the raw material of following component, such as table 1:
Table 1
Epoxy acrylic resin 10%
Aliphatic polyamines ester acrylic resin 25%
Two functional acrylic resins 5%
Reactive diluent 40%
Light trigger 3%
Mute powder 1%
Defoamer 0.5%
Levelling agent 0.3%
Anti-settling agent 0.2%
Above-mentioned light trigger is benzoin and derivative or benzil and derivative or hydroxyalkyl phenones or amine alkyl phenones or acyl One or more combination in base oxidation of ketones thing or benzophenone or thioxanthone or iron arene.
Auxiliary agent is the one or more combination in levelling agent or defoamer or anti-settling agent.
A kind of preparation method for the LED-UV woodenware matte finish paints being formulated described in use embodiment 1, comprises the following steps:
(1)Start dispersion machine and adjust rotating speed to 1000-1200 revs/min, the epoxy acrylic is sequentially added under this rotating speed In resin, aliphatic polyamines ester acrylic resin, two functional acrylic resins, stir 15-20 minutes;
(2)Dispersing speed is adjusted to 1000-1200 revs/min, the mute powder and reactive diluent are added under this rotating speed, it is high Speed stirring 5-10 minutes;
(3)Dispersing speed is adjusted to 1000 revs/min, the light trigger, 5-10 points of moderate-speed mixer are added under this rotating speed Clock, until paint liquid fineness reaches 15-30um;
(4)Dispersing speed is adjusted to 800-1000 revs/min, the auxiliary agent is added under this rotating speed, is stirred 10-20 minutes, Produce.
Embodiment 2
A kind of LED-UV woodenware mattes finish paint, by weight percentage, is prepared from by the raw material of following component, such as table 2:
Table 2
Epoxy acrylic resin 20%
Aliphatic polyamines ester acrylic resin 25%
Two functional acrylic resins 5%
Reactive diluent 40%
Light trigger 3%
Mute powder 3%
Defoamer 0.3%
Levelling agent 0.2%
Anti-settling agent 0.5%
Above-mentioned light trigger is benzoin and derivative or benzil and derivative or hydroxyalkyl phenones or amine alkyl phenones or acyl One or more combination in base oxidation of ketones thing or benzophenone or thioxanthone or iron arene.
Auxiliary agent is the one or more combination in levelling agent or defoamer or anti-settling agent.
A kind of preparation method for the LED-UV woodenware matte finish paints being formulated described in use embodiment 2, comprises the following steps:
(1)Start dispersion machine and adjust rotating speed to 1000-1200 revs/min, the epoxy acrylic is sequentially added under this rotating speed In resin, aliphatic polyamines ester acrylic resin, two functional acrylic resins, stir 15-20 minutes;
(2)Dispersing speed is adjusted to 1000-1200 revs/min, the mute powder and reactive diluent are added under this rotating speed, it is high Speed stirring 5-10 minutes;
(3)Dispersing speed is adjusted to 1000 revs/min, the light trigger, 5-10 points of moderate-speed mixer are added under this rotating speed Clock, until paint liquid fineness reaches 15-30um;
(4)Dispersing speed is adjusted to 800-1000 revs/min, the auxiliary agent is added under this rotating speed, is stirred 10-20 minutes, Produce.
Embodiment 3
A kind of LED-UV woodenware mattes finish paint, by weight percentage, is prepared from by the raw material of following component, such as table 3:
Table 3
Epoxy acrylic resin 10%
Aliphatic polyamines ester acrylic resin 10%
Two functional acrylic resins 5%
Reactive diluent 40%
Light trigger 3%
Mute powder 1%
Defoamer 0.5%
Levelling agent 0.3%
Anti-settling agent 0.2%
Above-mentioned light trigger is benzoin and derivative or benzil and derivative or hydroxyalkyl phenones or amine alkyl phenones or acyl One or more combination in base oxidation of ketones thing or benzophenone or thioxanthone or iron arene.
Auxiliary agent is the one or more combination in levelling agent or defoamer or anti-settling agent.
A kind of preparation method for the LED-UV woodenware matte finish paints being formulated described in use embodiment 3, comprises the following steps:
(1)Start dispersion machine and adjust rotating speed to 1000-1200 revs/min, the epoxy acrylic is sequentially added under this rotating speed In resin, aliphatic polyamines ester acrylic resin, two functional acrylic resins, stir 15-20 minutes;
(2)Dispersing speed is adjusted to 1000-1200 revs/min, the mute powder and reactive diluent are added under this rotating speed, it is high Speed stirring 5-10 minutes;
(3)Dispersing speed is adjusted to 1000 revs/min, the light trigger, 5-10 points of moderate-speed mixer are added under this rotating speed Clock, until paint liquid fineness reaches 15-30um;
(4)Dispersing speed is adjusted to 800-1000 revs/min, the auxiliary agent is added under this rotating speed, is stirred 10-20 minutes, Produce.
Embodiment 4
A kind of LED-UV woodenware mattes finish paint, by weight percentage, is prepared from by the raw material of following component, such as table 4:
Table 4
Epoxy acrylic resin 25%
Aliphatic polyamines ester acrylic resin 25%
Two functional acrylic resins 15%
Reactive diluent 40%
Light trigger 3%
Mute powder 3%
Defoamer 0.3%
Levelling agent 0.2%
Anti-settling agent 0.5%
Above-mentioned light trigger is benzoin and derivative or benzil and derivative or hydroxyalkyl phenones or amine alkyl phenones or acyl One or more combination in base oxidation of ketones thing or benzophenone or thioxanthone or iron arene.
Auxiliary agent is the one or more combination in levelling agent or defoamer or anti-settling agent.
A kind of preparation method for the LED-UV woodenware matte finish paints being formulated described in use embodiment 4, comprises the following steps:
(1)Start dispersion machine and adjust rotating speed to 1000-1200 revs/min, the epoxy acrylic is sequentially added under this rotating speed In resin, aliphatic polyamines ester acrylic resin, two functional acrylic resins, stir 15-20 minutes;
(2)Dispersing speed is adjusted to 1000-1200 revs/min, the mute powder and reactive diluent are added under this rotating speed, it is high Speed stirring 5-10 minutes;
(3)Dispersing speed is adjusted to 1000 revs/min, the light trigger, 5-10 points of moderate-speed mixer are added under this rotating speed Clock, until paint liquid fineness reaches 15-30um;
(4)Dispersing speed is adjusted to 800-1000 revs/min, the auxiliary agent is added under this rotating speed, is stirred 10-20 minutes, Produce.
The performance test results contrast of LED-UV woodenware mattes finish paint and commercially available prod made from above-described embodiment 1-4 is as follows Table 5;
Table 5
As can be seen from the above table, a kind of LED-UV woodenware mattes finish paint that the present invention is provided and preparation method thereof, can accelerate solid Change speed, environmental protection, to human body non-hazardous, and obtained LED-UV woodenware mattes finish paint is limited without workpiece type shape, finish paint Good toughness, industrial prospect is wide.
The above embodiments are only the preferred embodiments of the present invention, it is impossible to the interest field of the present invention is limited with this, because This, modification, equivalent variations, improvement for being made according to scope of the present invention patent etc. still belong to the scope that the present invention is covered.

Claims (5)

1. a kind of LED-UV woodenware mattes finish paint, it is characterised in that by weight percentage, prepared by the raw material of following component and Into:
Epoxy acrylic resin 10%-25%;
Aliphatic polyamines ester acrylic resin 10%-25%;
Two functional acrylic resins 5%-15%;
Reactive diluent 35-50%;
Light trigger 1%-5%;
Mute powder 1%-6%;
Auxiliary agent 0.1%-1%.
2. a kind of LED-UV woodenware mattes finish paint according to claim 1, it is characterised in that by weight percentage, by The raw material of following component is prepared from:
Epoxy acrylic resin 15%-20%;
Aliphatic polyamines ester acrylic resin 20%-25%;
Two functional acrylic resins 5%-10%;
Reactive diluent 40-45%;
Light trigger 3%-5%;
Mute powder 1%-3%;
Auxiliary agent 0.5%-1%.
3. a kind of LED-UV woodenware mattes finish paint according to claim 1 or 2, it is characterised in that the light trigger is Benzoin and derivative or benzil and derivative or hydroxyalkyl phenones or amine alkyl phenones or acyl group oxidation of ketones thing or hexichol first One or more combination in ketone or thioxanthone or iron arene.
4. a kind of LED-UV woodenware mattes finish paint according to claim 1 or 2, it is characterised in that the auxiliary agent is levelling One or more combination in agent or defoamer or anti-settling agent.
5. a kind of preparation method of LED-UV woodenware mattes finish paint as described in claim any one of 1-4, it is characterised in that bag Include following steps:
(1)Start dispersion machine and adjust rotating speed to 1000-1200 revs/min, the epoxy acrylic is sequentially added under this rotating speed In resin, aliphatic polyamines ester acrylic resin, two functional acrylic resins, stir 15-20 minutes;
(2)Dispersing speed is adjusted to 1000-1200 revs/min, the mute powder and reactive diluent are added under this rotating speed, it is high Speed stirring 5-10 minutes;
(3)Dispersing speed is adjusted to 1000 revs/min, the light trigger, 5-10 points of moderate-speed mixer are added under this rotating speed Clock, until paint liquid fineness reaches 15-30um;
(4)Dispersing speed is adjusted to 800-1000 revs/min, the auxiliary agent is added under this rotating speed, is stirred 10-20 minutes, Produce.
CN201710074035.3A 2017-02-10 2017-02-10 A kind of LED UV woodenware matte finish paints and preparation method thereof Pending CN106967358A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710074035.3A CN106967358A (en) 2017-02-10 2017-02-10 A kind of LED UV woodenware matte finish paints and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710074035.3A CN106967358A (en) 2017-02-10 2017-02-10 A kind of LED UV woodenware matte finish paints and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106967358A true CN106967358A (en) 2017-07-21

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111423809A (en) * 2020-04-13 2020-07-17 上海君子兰新材料股份有限公司 L ED-UV spraying matte finish paint and preparation method thereof
CN114395306A (en) * 2022-01-20 2022-04-26 安徽中紫智涂科技有限公司 Water-based UV (ultraviolet) photocuring woodware coating, photocuring method and application

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CN103122204A (en) * 2013-02-05 2013-05-29 江苏宏泰高分子材料有限公司 Solvent-free metal preservative UV (ultraviolet) paint and preparation method thereof
CN103627300A (en) * 2013-11-12 2014-03-12 惠州市长润发涂料有限公司 Ultraviolet (UV) laser roller coating woodware matt finish
CN104130670A (en) * 2014-08-20 2014-11-05 崇州市美涂士涂料科技有限公司 Solvent-free UV vacuum spraying under-coating paint and preparation method thereof
CN106118447A (en) * 2016-08-23 2016-11-16 佛山阳光逸采涂料科技有限公司 A kind of UV LED low-yield solidification household coating and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103122204A (en) * 2013-02-05 2013-05-29 江苏宏泰高分子材料有限公司 Solvent-free metal preservative UV (ultraviolet) paint and preparation method thereof
CN103627300A (en) * 2013-11-12 2014-03-12 惠州市长润发涂料有限公司 Ultraviolet (UV) laser roller coating woodware matt finish
CN104130670A (en) * 2014-08-20 2014-11-05 崇州市美涂士涂料科技有限公司 Solvent-free UV vacuum spraying under-coating paint and preparation method thereof
CN106118447A (en) * 2016-08-23 2016-11-16 佛山阳光逸采涂料科技有限公司 A kind of UV LED low-yield solidification household coating and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111423809A (en) * 2020-04-13 2020-07-17 上海君子兰新材料股份有限公司 L ED-UV spraying matte finish paint and preparation method thereof
CN111423809B (en) * 2020-04-13 2022-02-11 上海君子兰新材料股份有限公司 LED-UV spraying matte finish paint and preparation method thereof
CN114395306A (en) * 2022-01-20 2022-04-26 安徽中紫智涂科技有限公司 Water-based UV (ultraviolet) photocuring woodware coating, photocuring method and application

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Application publication date: 20170721

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