CN106957928A - A kind of preparation method of snakegourd fructose syrup - Google Patents
A kind of preparation method of snakegourd fructose syrup Download PDFInfo
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- CN106957928A CN106957928A CN201710182447.9A CN201710182447A CN106957928A CN 106957928 A CN106957928 A CN 106957928A CN 201710182447 A CN201710182447 A CN 201710182447A CN 106957928 A CN106957928 A CN 106957928A
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- snakegourd
- fructose syrup
- preparation
- fruit flesh
- rosthornii harms
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- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B50/00—Sugar products, e.g. powdered, lump or liquid sugar; Working-up of sugar
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- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
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- Medicines Containing Plant Substances (AREA)
Abstract
The invention discloses a kind of preparation method of snakegourd fructose syrup, the present invention is extracted using the new fresh fruit flesh of snakegourd or trichosanthes rosthornii Harms as raw material with water, after the de- hardship of centrifugation, activated carbon or macroporous absorbent resin, plus antioxidant, and be concentrated under reduced pressure to obtain snakegourd fructose syrup.The present invention carries out science to the carbohydrate content in the snakegourd or the fruit flesh of trichosanthes rosthornii Harms passed into disuse and extracted to separate, obtained snakegourd fructose syrup purity is high, quality is excellent, strategic material can be provided for sugar industry, the natural fructose syrup product blank with the peculiar fragrant local flavor of snakegourd has also been filled up simultaneously, without bitter taste, mouthfeel is favourable.The preparation method that the present invention is provided can solve snakegourd or trichosanthes rosthornii Harms seasonal yield is big, and discarded fruit flesh is difficult to store, and the problem of polluting environment while developing deep processed product, improves its added value, with important actual application value.
Description
Technical field
The present invention relates to a kind of preparation method of plant dis-medicinal part carbohydrate, and in particular to one kind snakegourd or bilateral Chinese juniper
The method that the fruit flesh in building prepares snakegourd fructose syrup.
Background technology
Snakegourd (Trichosanthes kirilowii Maxim.) or trichosanthes rosthornii Harms building (Trichosanthes
Rosthornii Harms), also known as potyvirus, medicine melon etc., belong to Curcurbitaceae snake gourd.Main product Anhui, Shandong, Henan, Sichuan, Jiangsu
Etc. ground.Snakegourd or trichosanthes rosthornii Harms whole body have very high medical value, and Snakegourd Fruit, PERICARPIUM TRICHOSANTHIS, Chinese Drug Gualouzi and root of Chinese trichosanthes are medicine
Allusion quotation includes kind, is applied well in field of medicaments.Meanwhile, Chinese Drug Gualouzi is also widely used for food service industry, and what is be made stops
Not busy food extensively gets consumer reception.
From whole snakegourd or trichosanthes rosthornii Harms fruit from the point of view of each position accounting, fruit flesh accounting weighs 31~43%, accounts for whole
/ 3rd or so of fruit.According to incompletely statistics, at present national snakegourd or trichosanthes rosthornii Harms up to 50,000,000 mu of cultivated area, root
According to per mu yield value, every mu of ground can produce about 100 kilograms of fruit fleshes (in terms of dry weight).During the Habitat producing of Chinese Drug Gualouzi, largely
Snakegourd or the fruit flesh of trichosanthes rosthornii Harms go out of use, and be poured into irrigation canals and ditches river, this not only causes certain wasting of resources, while
Serious environmental pollution is caused, the normal farming in farmland is harmful to.The main method for alleviating this contradiction is to snakegourd or bilateral
The fruit flesh of snakegourd carries out deep processing and comprehensive utilization.
Detect and find through HPLC-ELSD, fructose and glucose content are high in the fruit flesh of snakegourd or trichosanthes rosthornii Harms, can be used as sugar
The source of energy, but containing a certain amount of bitter substance, influence its mouthfeel and application.The present invention to the snakegourd passed into disuse or
Carbohydrate content in the fruit flesh of trichosanthes rosthornii Harms carries out science and extracts separation, and obtained snakegourd fructose syrup purity is high, and quality is excellent, is
Sugar industry provides strategic material, while it is empty also to have filled up the natural fructose syrup product with the peculiar fragrant local flavor of snakegourd
In vain, no bitter taste, mouthfeel is favourable.And snakegourd or trichosanthes rosthornii Harms seasonal yield can be solved greatly, discarded fruit flesh is difficult to store, and pollutes ring
The problem of border, while developing deep processed product, its added value is improved, with important actual application value.
The content of the invention
Goal of the invention：It is an object of the invention to provide a kind of fruit flesh using snakegourd or trichosanthes rosthornii Harms tool is prepared as raw material
There is the natural fructose syrup of snakegourd peculiar taste, prepared natural fructose syrup can apply to the food industry such as beverage, and
As snakegourd or the deep working method of trichosanthes rosthornii Harms, the fruit flesh of snakegourd or trichosanthes rosthornii Harms in current snakegourd industrial chain quilt can be solved
The problem of discarded, rationally, science, fruit flesh resource easily utilized, resource utilization is improved, while reducing environmental pollution.
Technical scheme：In order to realize the above object the technical scheme that the present invention takes is：
Snakegourd fructose syrup prepared by the fruit flesh of a kind of use snakegourd or trichosanthes rosthornii Harms, it is to be prepared by the following method
Arrive：
(1) the fruit flesh of fresh snakegourd or trichosanthes rosthornii Harms is taken, by fruit flesh and water 1:4~1:12 part by weight is stirred and evenly mixed,
Separation of solid and liquid, forms the grease of superficial layer, middle faint yellow water layer and the solid layer of bottom, takes middle faint yellow water layer；
(2) the faint yellow water layer for taking step (1) to obtain, adds activated carbon, stirs, and stands, and filtrate is collected in filtering；Or mistake
Large pore resin absorption column, collects permeate；
(3) by the filtrate in step (2) or permeate, be concentrated under reduced pressure into pol Brix% for 40~50 when, add 0.5-
Be concentrated under reduced pressure into after 10 ‰ antioxidant pol Brix% for 60~75 when, obtain snakegourd fructose syrup.
Preferably, above-described snakegourd fructose syrup, can be used activated carbon debittering material, step (2)
In activated carbon addition be faint yellow water layer solution 3%~5% (w/V), 45~55 DEG C of whipping temp, time of repose 0.5~
1.5h。
Preferably, above-described snakegourd fructose syrup, it is possible to use macroporous absorbent resin debittering material,
Macroreticular resin in step (2) can be D101 types or AB-8 types, and upper column flow rate is 1 to 4BV/h, the major diameter of post bed
Than for 5~2:1.
Contain bitter substance in snakegourd fruit flesh, the mouthfeel and quality of snakegourd fructose syrup are influenceed, in order to further obtain pure
Degree is high, the snakegourd fructose syrup of Functionality, quality and appealing design, and the present invention screens different debitterized techniques by many experiments, it is determined that using activated carbon
Absorption or macroporous absorbent resin elution, after charcoal absorption or macroporous resin adsorption filtering, can remove bitter substance, work
Skill is simple to operation, and the snakegourd fructose syrup of high purity more than 98% can be obtained simultaneously, and with the distinctive aromatic oxy of snakegourd
Taste, mouthfeel is good.
Preferably, the above-described fruit flesh with snakegourd or trichosanthes rosthornii Harms prepares the preparation side of snakegourd fructose syrup
Method, antioxidant described in step (3) is vitamin C, sodium isoascorbate or citric acid, is added into after antioxidant, can be with
The problems such as effectively solving fructose and glucose long-time heating oxidation deterioration, and can obtain function more fully high-quality snakegourd really
Glucose is starched.
The present invention carries out purity detecting, snakegourd fruit Portugal using high performance liquid chromatograph to the snakegourd fructose syrup prepared
Fructose and glucose content are respectively up to more than 40% based on butt for syrup, and the two summation is up to more than 90%；Through GC-MS points
Analysis, snakegourd fructose syrup contains the distinctive methyl laurate of snakegourd, methyl myristate ester, methyl caprate, linoleic acid, Snakegourd Fruit acid
Deng flavor component, content is 0.5~5%, can improve mouthfeel.
The snakegourd fructose syrup that the present invention is provided can be used for the food industry such as beverage, sweetener processing, it can also be used to medicine
Industry.
Beneficial effect：The fruit flesh using snakegourd or trichosanthes rosthornii Harms that the present invention is provided has snakegourd only as what raw material was prepared
The natural fructose syrup of special local flavor, with advantages below：
(1) present invention is prepared into according to the property of carbohydrate content in the fruit flesh of snakegourd or trichosanthes rosthornii Harms by many experiments
To the fructose syrup that purity is high, quality is excellent, high performance liquid chromatography content detection result shows snakegourd fructose syrup fruit based on butt
Sugar and glucose content are respectively up to more than 40%, and the two summation contains the distinctive laurate first of snakegourd up to more than 90%
The flavor components such as ester, methyl myristate ester, methyl caprate, linoleic acid, Snakegourd Fruit acid, excellent taste, the invention is snakegourd or double
The exploitation of side snakegourd deep processed product provides new direction, and the exploitation for sucrose and fructose syrup again provides new resource.
(2) the natural snakegourd fructose syrup that the present invention is provided, compared with the fructose syrup used in current food processing, tool
There is the distinctive fragrant local flavor of snakegourd, be real meaning in process of production without any food additives of such as compound essence etc.
The natural syrup of justice, green non-pollution.
(3) preparation method of the invention, can be significantly as a kind of snakegourd or the fruit flesh deep processing purification techniques of trichosanthes rosthornii Harms
The comprehensive utilization ratio of snakegourd or trichosanthes rosthornii Harms is improved, environmental pollution is reduced, and preparation method is simple to operation, is suitable for industrializing
Big production, the fruit flesh that can effectively solve snakegourd or trichosanthes rosthornii Harms goes out of use in current snakegourd industrial chain and pollutes asking for environment
Topic, with important actual application value.
Brief description of the drawings
Fig. 1 is the preparation technology flow chart of refined snakegourd fructose syrup；
Fig. 2 is the trichosanthes rosthornii Harms fruit flesh high performance liquid chromatography detection collection of illustrative plates of embodiment 1；
Fig. 3 is the total ion of Ultra Performance Liquid Chromatography-mass spectrometry of the trichosanthes rosthornii Harms fruit flesh charcoal treated of embodiment 1
Stay figure；
Fig. 4 is the snakegourd fructose syrup high performance liquid chromatography detection collection of illustrative plates of embodiment 1；
Fig. 5 is total for Ultra Performance Liquid Chromatography-mass spectrometry of the trichosanthes rosthornii Harms fruit flesh through AB-8 type resin treatments of embodiment 2
Ion stays figure；
Fig. 6 is total for Ultra Performance Liquid Chromatography-mass spectrometry of the trichosanthes rosthornii Harms fruit flesh through D101 type resin treatments of embodiment 3
Ion stays figure.
Specific embodiment
According to following embodiments, the present invention may be better understood.However, as it will be easily appreciated by one skilled in the art that real
Apply specific material proportion, process conditions and its result described by example and be merely to illustrate the present invention, without that will not also should limit
The present invention described in detail in claims processed.
Embodiment 1
A kind of snakegourd fructose syrup, it is to be prepared by the following method to obtain：Process route as shown in Figure 1：
(1) the fruit flesh 5kg (water content about 75%) of fresh trichosanthes rosthornii Harms is taken, as shown in Fig. 2 high performance liquid chromatography detection is really
Fructose and glucose content are respectively up to more than 22% based on butt for flesh, by fruit flesh and water 1:10 part by weight is stirred and evenly mixed,
13000r/min is centrifuged, and separation of solid and liquid obtains the solid layer of surface grease, middle faint yellow water layer and bottom, is taken middle light
Yellow water layer；
(2) the faint yellow water layer for taking step (1) to obtain, the powdered activated carbon (w/V) of addition 3%, stirring, in 45 DEG C of water-baths
40min, is stood, and filtrate is collected in filtering；As shown in figure 3, Ultra Performance Liquid Chromatography-mass spectrometry detection bitter substance
(3.08min, m/z 798.87；3.40min, m/z 557.18；3.94min, m/z 721.37；4.10min, m/z 851.37)
It has been removed.
(3) by the filtrate in step (2), be concentrated under reduced pressure (60 DEG C, vacuum 0.08MPa) to pol Brix% be 42 when,
When (50 DEG C, vacuum 0.08MPa) to the pol that is concentrated under reduced pressure after the vitamin C for adding 10 ‰ is Brix%65, snakegourd fruit Portugal is obtained
Syrup 2.6kg.As shown in figure 4, high performance liquid chromatography detection snakegourd fructose syrup fructose and glucose content difference based on butt
Up to more than 45%, the two summation up to 98%, and containing 2% methyl laurate, methyl myristate ester, methyl caprate,
The flavor components such as linoleic acid, Snakegourd Fruit acid.
Embodiment 2
A kind of snakegourd fructose syrup, it is to be prepared by the following method to obtain：
(1) the fruit flesh 4kg (water content about 75%) of fresh trichosanthes rosthornii Harms is taken, as shown in Fig. 2 high performance liquid chromatography detection is really
Fructose and glucose content are respectively up to more than 22% based on butt for flesh, by fruit flesh and water 1:6 ratio is mixed, 13000r/min from
The heart, separation of solid and liquid takes middle faint yellow water layer；
(2) the faint yellow water layer for taking step (1) to obtain, is concentrated under reduced pressure (60 DEG C, vacuum 0.08MPa) to the 1/ of original volume
After 7, concentrate crosses AB-8 type macroreticular resin chromatographic columns, and upper column flow rate is 2.5BV/h, and the draw ratio of post bed is 4:1, collect and pass through
Liquid.As shown in figure 5, Ultra Performance Liquid Chromatography-mass spectrometry detection bitter substance (3.08min, m/z 798.87；3.40min,
m/z 557.18；3.94min, m/z 721.37；4.10min, m/z 851.37) it has been removed.
(3) by the permeate in step (2), be concentrated under reduced pressure (60 DEG C, vacuum 0.08MPa) to pol Brix% be 45
When, add after 8 ‰ ISOASCORBIC ACID when being concentrated under reduced pressure (50 DEG C, vacuum 0.08MPa) to pol Brix%70, obtain snakegourd really
Glucose starches 2.1kg.High performance liquid chromatography detection snakegourd fructose syrup based on butt fructose and glucose content respectively up to 40%
More than, the two summation up to 95%, and containing 3% methyl laurate, methyl myristate ester, methyl caprate, linoleic acid and
The flavor components such as Snakegourd Fruit acid.
Embodiment 3
A kind of snakegourd fructose syrup, it is to be prepared by the following method to obtain：
(1) the fruit flesh 4kg (water content about 75%) of fresh snakegourd is taken, as shown in Fig. 2 high performance liquid chromatography detection fruit flesh is pressed
Butt meter fructose and glucose content are respectively up to more than 20%, by fruit flesh and water 1:5 ratio is mixed, 13000r/min centrifugations,
Separation of solid and liquid, takes middle faint yellow water layer；
(2) the faint yellow water layer for taking step (1) to obtain, is concentrated under reduced pressure (60 DEG C, vacuum 0.08MPa) to the 1/ of original volume
After 6, concentrate crosses D101 type macroreticular resin chromatographic columns, and upper column flow rate is 3BV/h, and the draw ratio of post bed is 3:1, collect and pass through
Liquid.As shown in fig. 6, Ultra Performance Liquid Chromatography-mass spectrometry detection bitter substance (3.08min, m/z 798.87；3.40min,
m/z 557.18；3.94min, m/z 721.37；4.10min, m/z 851.37) it has been removed.
(3) by the permeate in step (2), be concentrated under reduced pressure (60 DEG C, vacuum 0.08MPa) to Brix% be 40 when, plus
When (50 DEG C, vacuum 0.08MPa) are concentrated under reduced pressure after the citric acid for entering 6 ‰ to Brix%68, snakegourd fructose syrup 2.2kg is obtained.
High performance liquid chromatography detection snakegourd fructose syrup based on butt fructose and glucose content respectively up to more than 40%, the two summation
Up to 95%, and containing the fragrance such as 3% methyl laurate, methyl myristate ester, methyl caprate, linoleic acid and Snakegourd Fruit acid into
Point.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (4)
1. a kind of preparation method of snakegourd fructose syrup, it is characterised in that it comprises the following steps：
(1) the fruit flesh of fresh snakegourd or trichosanthes rosthornii Harms is taken, by fruit flesh and water 1:4~1:12 part by weight is stirred and evenly mixed, then
Separation of solid and liquid, takes middle faint yellow water layer；
(2) the faint yellow water layer for taking step (1) to obtain, adds activated carbon, stirs, and stands, and filtrate is collected in filtering；Or will be yellowish
Color water layer crosses large pore resin absorption column, collects permeate；
(3) by the filtrate in step (2) or permeate, be concentrated under reduced pressure into pol Brix% for 40~50 when, then add 0.5-
Be concentrated under reduced pressure into after 10 ‰ antioxidant pol Brix% for 60~75 when, obtain snakegourd fructose syrup.
2. the preparation method of snakegourd fructose syrup according to claim 1, it is characterised in that：Activity described in step (2)
Charcoal adds 3%~5% that weight is faint yellow water layer liquor capacity, 45~55 DEG C of whipping temp, 0.5~1.5h of time of repose.
3. the method for the preparation method slurry of snakegourd fructose syrup according to claim 1, it is characterised in that：Step (2) institute
The macroreticular resin stated is D101 types or AB-8 types, and upper column flow rate is 1 to 4BV/h, and the draw ratio of post bed is 5~2:1.
4. the preparation method of snakegourd fructose syrup according to claim 1, it is characterised in that：It is anti-described in step (3)
Oxidant is vitamin C, sodium isoascorbate or citric acid.
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| CN201710182447.9A CN106957928A (en) | 2017-03-24 | 2017-03-24 | A kind of preparation method of snakegourd fructose syrup |
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| CN201710182447.9A CN106957928A (en) | 2017-03-24 | 2017-03-24 | A kind of preparation method of snakegourd fructose syrup |
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Citations (6)
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|---|---|---|---|---|
| JP2661698B2 (en) * | 1988-03-11 | 1997-10-08 | ダウ・ケミカル日本株式会社 | Sugar solution purification method |
| CN1611133A (en) * | 2003-10-29 | 2005-05-04 | 北京市农林科学院 | Water melon syrup and its preparing method |
| CN101327244A (en) * | 2008-07-30 | 2008-12-24 | 卢照凯 | Decolored and debitterized Momordica grosvenori extract and preparation method thereof |
| CN102648750A (en) * | 2012-05-07 | 2012-08-29 | 南京中医药大学 | Refine Chinese date cane sugar, Chinese date high fructose syrup and preparation method of refine Chinese date cane sugar and Chinese date high fructose syrup |
| CN102742803A (en) * | 2012-07-20 | 2012-10-24 | 李德祥 | Snake gourd fruit flesh massecuite and preparation method thereof |
| CN103860624A (en) * | 2014-03-26 | 2014-06-18 | 成都理工大学 | Method for removing fructus trichosanthis pulp by assist of biological enzyme |
-
2017
- 2017-03-24 CN CN201710182447.9A patent/CN106957928A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2661698B2 (en) * | 1988-03-11 | 1997-10-08 | ダウ・ケミカル日本株式会社 | Sugar solution purification method |
| CN1611133A (en) * | 2003-10-29 | 2005-05-04 | 北京市农林科学院 | Water melon syrup and its preparing method |
| CN101327244A (en) * | 2008-07-30 | 2008-12-24 | 卢照凯 | Decolored and debitterized Momordica grosvenori extract and preparation method thereof |
| CN102648750A (en) * | 2012-05-07 | 2012-08-29 | 南京中医药大学 | Refine Chinese date cane sugar, Chinese date high fructose syrup and preparation method of refine Chinese date cane sugar and Chinese date high fructose syrup |
| CN102742803A (en) * | 2012-07-20 | 2012-10-24 | 李德祥 | Snake gourd fruit flesh massecuite and preparation method thereof |
| CN103860624A (en) * | 2014-03-26 | 2014-06-18 | 成都理工大学 | Method for removing fructus trichosanthis pulp by assist of biological enzyme |
Non-Patent Citations (1)
| Title |
|---|
| 马艳，等: "药材瓜蒌不同部位的红外光谱分析", 《光散射学报》 * |
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Application publication date: 20170718 |