CN106953058A - 锂离子电池隔膜 - Google Patents
锂离子电池隔膜 Download PDFInfo
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- CN106953058A CN106953058A CN201710229774.5A CN201710229774A CN106953058A CN 106953058 A CN106953058 A CN 106953058A CN 201710229774 A CN201710229774 A CN 201710229774A CN 106953058 A CN106953058 A CN 106953058A
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 9
- 239000012528 membrane Substances 0.000 claims abstract description 8
- 229920000098 polyolefin Polymers 0.000 claims abstract description 8
- 239000004744 fabric Substances 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 10
- 229910052744 lithium Inorganic materials 0.000 abstract description 10
- 239000004745 nonwoven fabric Substances 0.000 abstract description 8
- 238000004880 explosion Methods 0.000 abstract 1
- 230000004888 barrier function Effects 0.000 description 14
- 238000005516 engineering process Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/44—Fibrous material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/463—Separators, membranes or diaphragms characterised by their shape
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cell Separators (AREA)
Abstract
本发明涉及电池技术领域,尤其涉及一种锂离子电池隔膜,包括无纺布层、聚烯烃多孔膜,所述无纺布层的上部和下部分别带有沟槽,所述聚烯烃多孔膜压合在无纺布层的上下两侧,所述无妨布层的表面均布有微孔,孔隙率为80%,无纺布层的厚度为3‑6μm。本电池隔膜将无纺布层的上下表面先压制一定深度的沟槽,这样即使是在高温下该隔膜热膨胀现象非常的小,仍然可以保持其形状,不会存在爆炸的隐患,提高了锂电池的安全性能,同时3um的无纺布层厚度能显著改善隔膜的热稳定性和机械性能。
Description
技术领域
本发明涉及电池技术领域,尤其涉及一种锂离子电池隔膜。
背景技术
在锂电池的结构中,隔膜是关键的内层组件之一。隔膜的性能决定了电池的界面结构、内阻等,直接影响电池的容量、循环以及安全性能等特性,性能优异的隔膜对提高电池的综合性能具有重要的作用。隔膜的主要作用是使电池的正、负极分隔开来,防止两极接触而短路,此外还具有能使电解质离子通过的功能。隔膜材质是不导电的,其物理化学性质对电池的性能有很大的影响。电池的种类不同,采用的隔膜也不同。现有技术中的锂电池隔离膜往往由于技术不够成熟,常常会出锂电池爆炸的问题,其主要原因是锂电池在耐高温方面存在很大的不足。
发明内容
本发明的目的在于克服上述技术的不足,而提供一种锂离子电池隔膜,耐高温,透气性能佳。
本发明为实现上述目的,采用以下技术方案:
一种锂离子电池隔膜,其特征在于:包括无纺布层、聚烯烃多孔膜,所述无纺布层的上部和下部分别带有沟槽,所述聚烯烃多孔膜压合在无纺布层的上下两侧,所述无妨布层的表面均布有微孔,孔隙率为80%,无纺布层的厚度为3-6μm。本电池隔膜将无纺布层的上下表面先压制一定深度的沟槽,这样即使是在高温下该隔膜热膨胀现象非常的小,仍然可以保持其形状,不会存在爆炸的隐患,提高了锂电池的安全性能,同时3um的无纺布层厚度能显著改善隔膜的热稳定性和机械性能。
优选地,所述沟槽深度为1μm-3μm。
本发明的有益效果是:相对于现有技术,本电池隔膜将无纺布层的上下表面先压制一定深度的沟槽,这样即使是在高温下该隔膜热膨胀现象非常的小,仍然可以保持其形状,不会存在爆炸的隐患,提高了锂电池的安全性能,同时3um的无纺布层厚度能显著改善隔膜的热稳定性和机械性能。
附图说明
图1为本发明的结构示意图。
具体实施方式
下面结合附图及较佳实施例详细说明本发明的具体实施方式。如图1所示,一种锂离子电池隔膜,包括无纺布层1、聚烯烃多孔膜2,所述无纺布层的上部和下部分别带有沟槽3,所述聚烯烃多孔膜压合在无纺布层的上下两侧,所述无妨布层的表面均布有微孔,孔隙率为80%,无纺布层的厚度为3-6μm。所述沟槽深度为1μm-3μm。本隔膜不仅具有液态锂电池电芯的高电压、长循环寿命、放电电压平稳以及清洁无污染的特点。而且消除了液态锂电池存在的爆炸的安全隐患,同时外形更灵活、方便,重量更轻巧。
本电池隔膜将无纺布层的上下表面先压制一定深度的沟槽,这样即使是在高温下该隔膜热膨胀现象非常的小,仍然可以保持其形状,不会存在爆炸的隐患,提高了锂电池的安全性能,同时3um的无纺布层厚度能显著改善隔膜的热稳定性和机械性能。
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。
Claims (2)
1.一种锂离子电池隔膜,其特征在于:包括无纺布层、聚烯烃多孔膜,所述无纺布层的上部和下部分别带有沟槽,所述聚烯烃多孔膜压合在无纺布层的上下两侧,所述无妨布层的表面均布有微孔,孔隙率为80%,无纺布层的厚度为3-6μm。
2.根据权利要求1所述的锂离子电池隔膜,其特征在于:所述沟槽深度为1μm-3μm。
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102983300A (zh) * | 2011-09-05 | 2013-03-20 | 索尼公司 | 隔膜和非水电解质电池 |
CN103117369A (zh) * | 2013-02-01 | 2013-05-22 | 深圳中兴创新材料技术有限公司 | 一种复合电池隔膜 |
CN204361159U (zh) * | 2014-09-24 | 2015-05-27 | 浙江西凯新能源开发有限公司 | 一种锂电池隔膜 |
WO2015154320A1 (zh) * | 2014-04-10 | 2015-10-15 | 佛山市金辉高科光电材料有限公司 | 一种新型改性无纺布锂离子电池隔膜及其制备方法 |
CN204857823U (zh) * | 2015-07-16 | 2015-12-09 | 浙江中金铝业有限公司 | 锂电池隔膜 |
CN105772371A (zh) * | 2016-04-29 | 2016-07-20 | 宁德卓高新材料科技有限公司 | 采用微凹版辊改善隔膜波浪边的方法及其微凹版辊 |
CN106233500A (zh) * | 2014-05-20 | 2016-12-14 | 帝人株式会社 | 非水系二次电池用隔膜、其制造方法及非水系二次电池 |
CN205828500U (zh) * | 2016-07-22 | 2016-12-21 | 江西冠德新材科技股份有限公司 | 一种超薄型动力电池隔膜 |
-
2017
- 2017-04-10 CN CN201710229774.5A patent/CN106953058A/zh active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102983300A (zh) * | 2011-09-05 | 2013-03-20 | 索尼公司 | 隔膜和非水电解质电池 |
CN103117369A (zh) * | 2013-02-01 | 2013-05-22 | 深圳中兴创新材料技术有限公司 | 一种复合电池隔膜 |
WO2015154320A1 (zh) * | 2014-04-10 | 2015-10-15 | 佛山市金辉高科光电材料有限公司 | 一种新型改性无纺布锂离子电池隔膜及其制备方法 |
CN106233500A (zh) * | 2014-05-20 | 2016-12-14 | 帝人株式会社 | 非水系二次电池用隔膜、其制造方法及非水系二次电池 |
CN204361159U (zh) * | 2014-09-24 | 2015-05-27 | 浙江西凯新能源开发有限公司 | 一种锂电池隔膜 |
CN204857823U (zh) * | 2015-07-16 | 2015-12-09 | 浙江中金铝业有限公司 | 锂电池隔膜 |
CN105772371A (zh) * | 2016-04-29 | 2016-07-20 | 宁德卓高新材料科技有限公司 | 采用微凹版辊改善隔膜波浪边的方法及其微凹版辊 |
CN205828500U (zh) * | 2016-07-22 | 2016-12-21 | 江西冠德新材科技股份有限公司 | 一种超薄型动力电池隔膜 |
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