CN106928872A - A kind of EVA inorganic agents of good frost resistance - Google Patents
A kind of EVA inorganic agents of good frost resistance Download PDFInfo
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- CN106928872A CN106928872A CN201710258718.4A CN201710258718A CN106928872A CN 106928872 A CN106928872 A CN 106928872A CN 201710258718 A CN201710258718 A CN 201710258718A CN 106928872 A CN106928872 A CN 106928872A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/02—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
- C09D193/04—Rosin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2433/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
The present invention relates to a kind of EVA inorganic agents of good frost resistance, the preparing raw material of the EVA inorganic agents includes following components by weight：22~26 parts of 545~560 parts of toluene, 58~63 parts of butanone, 154~163 parts of ethyl ester, 26~31 parts of methyl methacrylate, 18~25 parts of 24 essence of HR, 5~6.5 parts of thermoplastic styrene butadiene rubber, 6~9 parts of EVA260,3~6 parts of cis-butenedioic anhydride, 1.5~3 parts of benzoyl peroxide and terpene phenol resin.EVA inorganic agents obtained in formula of the invention are still substantially absent from gel situation in subzero 10 degrees centigrade, good mobility is also equipped with order to constructing operation, possesses good anti-freezing property, its anti-freezing property is effectively lifted, properties of product stabilization, the winter productions for being adapted to more areas are used, and disclosure satisfy that the use requirement of more conglomerate, and EVA surfaces and the bonding effect of adhesive using the inorganic agent is effectively lifted.
Description
Technical field
The present invention relates to a kind of EVA inorganic agents, a kind of EVA inorganic agents of good frost resistance are particularly related to.
Background technology
The features such as EVA expanded materials have low production cost, light weight, elastic good, ventilative, handling ease, easy coloring and
It is widely used.It is poor with the affinity between highly polar adhesive but the polarity of EVA is weak, need to be surface-treated.Mesh
It is preceding generally to be synthesized at EVA surfaces using monomer graft modification SBS such as methyl methacrylate (MMA), acrylic acid (AA) in the industry
The method for managing agent solves the adhesion problem of EVA material, although can reach preferable treatment effect, but this kind of inorganic agent is present
The poor weak point of anti-freezing property, its gel easy at low temperature is not suitable for use in winter, causes this kind of EVA inorganic agents
Use limited by larger.
The content of the invention
The present invention provides a kind of EVA inorganic agents of good frost resistance, to overcome the existing EVA inorganic agents for commonly using to deposit
Anti-freezing property it is poor, the easy gel of use in winter uses limited problem.
The present invention is adopted the following technical scheme that：
A kind of EVA inorganic agents of good frost resistance, the preparing raw material of the EVA inorganic agents includes following components by weight：First
545~560 parts of benzene, 58~63 parts of butanone, 154~163 parts of ethyl ester, 26~31 parts of methyl methacrylate, HR-24 essence 18~
25 parts, 5~6.5 parts of thermoplastic styrene butadiene rubber, 6~9 parts of EVA260,3~6 parts of cis-butenedioic anhydride, 1.5~3 parts of benzoyl peroxide and terpene
22~26 parts of alkene phenol resin.
Specifically, the preparation of the EVA inorganic agents preferably following four kinds of prescriptions：
First, the preparing raw material of the EVA inorganic agents is made up of following components by weight：550 parts of toluene, 60 parts of butanone, second
160 parts of ester, 30 parts of methyl methacrylate, 20 parts of HR-24 essence, 5.6 parts of thermoplastic styrene butadiene rubber, 7 parts of EVA260, cis-butenedioic anhydride 4
24 parts of part, 2 parts of benzoyl peroxide and terpene phenol resin.
Second, the preparing raw material of the EVA inorganic agents is made up of following components by weight：555 parts of toluene, butanone 62
It is part, 157 parts of ethyl ester, 28 parts of methyl methacrylate, 23 parts of HR-24 essence, 6 parts of thermoplastic styrene butadiene rubber, 8 parts of EVA260, suitable
25 parts of 5 parts of acid anhydride, 2.5 parts of benzoyl peroxide and terpene phenol resin.
Third, the preparing raw material of the EVA inorganic agents is made up of following components by weight：545 parts of toluene, butanone 63
It is part, 163 parts of ethyl ester, 26 parts of methyl methacrylate, 25 parts of HR-24 essence, 5 parts of thermoplastic styrene butadiene rubber, 6 parts of EVA260, suitable
22 parts of 6 parts of acid anhydride, 1.5 parts of benzoyl peroxide and terpene phenol resin.
Fourth, the preparing raw material of the EVA inorganic agents is made up of following components by weight：560 parts of toluene, butanone 58
Part, 154 parts of ethyl ester, 31 parts of methyl methacrylate, 18 parts of HR-24 essence, 6.5 parts of thermoplastic styrene butadiene rubber, 9 parts of EVA260,
26 parts of 3 parts of cis-butenedioic anhydride, 3 parts of benzoyl peroxide and terpene phenol resin.
Further with improvement, the preparing raw material of the EVA inorganic agents is made up of following components by weight：Carbon black 15~18
Part, 1~2 part of zinc oxide, 16~20 parts of isocyanates, 20~23 parts of MEA, 35~40 parts of rosin resin, dichloromethane 60
~66 parts, 545~560 parts of toluene, 58~63 parts of butanone, 154~163 parts of ethyl ester, 26~31 parts of methyl methacrylate, HR-
24 18~25 parts of essence, 5~6.5 parts of thermoplastic styrene butadiene rubber, 6~9 parts of EVA260,3~6 parts of cis-butenedioic anhydride, benzoyl peroxide
1.5~3 parts and 22~26 parts of terpene phenol resin.
Specifically, the preparation of the EVA inorganic agents preferably following four kinds of prescriptions：
First, the preparing raw material of the EVA inorganic agents is made up of following components by weight：17 parts of carbon black, 1.5 parts of zinc oxide,
19 parts of isocyanates, 22 parts of MEA, 37 parts of rosin resin, 62 parts of dichloromethane, 550 parts of toluene, 60 parts of butanone, ethyl ester
160 parts, 30 parts of methyl methacrylate, 20 parts of HR-24 essence, 5.6 parts of thermoplastic styrene butadiene rubber, 7 parts of EVA260, cis-butenedioic anhydride 4
24 parts of part, 2 parts of benzoyl peroxide and terpene phenol resin.
Second, the preparing raw material of the EVA inorganic agents is made up of following components by weight：16 parts of carbon black, zinc oxide 2
Part, 17 parts of isocyanates, 21 parts of MEA, 38 parts of rosin resin, 64 parts of dichloromethane, 557 parts of toluene, 62 parts of butanone, second
It is 155 parts of ester, 27 parts of methyl methacrylate, 22 parts of HR-24 essence, 5.3 parts of thermoplastic styrene butadiene rubber, 7.7 parts of EVA260, suitable
25 parts of 5 parts of acid anhydride, 2.7 parts of benzoyl peroxide and terpene phenol resin.
Third, the preparing raw material of the EVA inorganic agents is made up of following components by weight：18 parts of carbon black, zinc oxide 1
Part, 16 parts of isocyanates, 23 parts of MEA, 35 parts of rosin resin, 66 parts of dichloromethane, 560 parts of toluene, 63 parts of butanone, second
163 parts of ester, 26 parts of methyl methacrylate, 18 parts of HR-24 essence, 6.5 parts of thermoplastic styrene butadiene rubber, 6 parts of EVA260, cis-butenedioic anhydride 6
22 parts of part, 3 parts of benzoyl peroxide and terpene phenol resin.
Fourth, the preparing raw material of the EVA inorganic agents is made up of following components by weight：15 parts of carbon black, zinc oxide 2
Part, 20 parts of isocyanates, 20 parts of MEA, 40 parts of rosin resin, 60 parts of dichloromethane, 545 parts of toluene, 58 parts of butanone, second
154 parts of ester, 31 parts of methyl methacrylate, 25 parts of HR-24 essence, 5 parts of thermoplastic styrene butadiene rubber, 9 parts of EVA260, cis-butenedioic anhydride 3
26 parts of part, 3 parts of benzoyl peroxide and terpene phenol resin.
From the above-mentioned description of this invention, compared to the prior art, the invention has the advantages that：It is of the invention to match somebody with somebody
The obtained EVA inorganic agents in side are still substantially absent from gel situation at subzero 10 DEG C or so, be also equipped with good mobility so as to
In constructing operation, possesses good anti-freezing property, its anti-freezing property is effectively lifted, properties of product stabilization is adapted to more
The winter production in area is used, and disclosure satisfy that the use requirement of more conglomerate, and the EVA surfaces using the inorganic agent and adhesive
Bonding effect is effectively lifted.
Specific embodiment
Implementation method one
The preparing raw material of the EVA inorganic agents of present embodiment is made up of following components by weight：550 parts of toluene, butanone 60
Part, 160 parts of ethyl ester, 30 parts of methyl methacrylate, 20 parts of HR-24 essence, 5.6 parts of thermoplastic styrene butadiene rubber, 7 parts of EVA260,
24 parts of 4 parts of cis-butenedioic anhydride, 2 parts of benzoyl peroxide and terpene phenol resin.EVA inorganic agents are subzero obtained in the formula of present embodiment
2 DEG C or so are still substantially absent from gel situation.
Implementation method two
The preparing raw material of the EVA inorganic agents of present embodiment is made up of following components by weight：555 parts of toluene, butanone 62
It is part, 157 parts of ethyl ester, 28 parts of methyl methacrylate, 23 parts of HR-24 essence, 6 parts of thermoplastic styrene butadiene rubber, 8 parts of EVA260, suitable
25 parts of 5 parts of acid anhydride, 2.5 parts of benzoyl peroxide and terpene phenol resin.EVA inorganic agents are subzero obtained in the formula of present embodiment
2 DEG C or so are still substantially absent from gel situation.
Implementation method three
The preparing raw material of the EVA inorganic agents of present embodiment is made up of following components by weight：545 parts of toluene, butanone 63
It is part, 163 parts of ethyl ester, 26 parts of methyl methacrylate, 25 parts of HR-24 essence, 5 parts of thermoplastic styrene butadiene rubber, 6 parts of EVA260, suitable
22 parts of 6 parts of acid anhydride, 1.5 parts of benzoyl peroxide and terpene phenol resin.EVA inorganic agents are at 0 DEG C obtained in the formula of present embodiment
Left and right is still substantially absent from gel situation.
Implementation method four
The preparing raw material of the EVA inorganic agents of present embodiment is made up of following components by weight：560 parts of toluene, butanone 58
Part, 154 parts of ethyl ester, 31 parts of methyl methacrylate, 18 parts of HR-24 essence, 6.5 parts of thermoplastic styrene butadiene rubber, 9 parts of EVA260,
26 parts of 3 parts of cis-butenedioic anhydride, 3 parts of benzoyl peroxide and terpene phenol resin.EVA inorganic agents are at 0 DEG C obtained in the formula of present embodiment
Left and right is still substantially absent from gel situation.
Implementation method five
The preparing raw material of the EVA inorganic agents of present embodiment is made up of following components by weight：17 parts of carbon black, zinc oxide
1.5 parts, 19 parts of isocyanates, 22 parts of MEA, 37 parts of rosin resin, 62 parts of dichloromethane, 550 parts of toluene, 60 parts of butanone,
It is 160 parts of ethyl ester, 30 parts of methyl methacrylate, 20 parts of HR-24 essence, 5.6 parts of thermoplastic styrene butadiene rubber, 7 parts of EVA260, suitable
24 parts of 4 parts of acid anhydride, 2 parts of benzoyl peroxide and terpene phenol resin.EVA inorganic agents are subzero 10 obtained in the formula of present embodiment
DEG C or so be still substantially absent from gel situation.
Implementation method six
The preparing raw material of the EVA inorganic agents of present embodiment is made up of following components by weight：16 parts of carbon black, zinc oxide 2
Part, 17 parts of isocyanates, 21 parts of MEA, 38 parts of rosin resin, 64 parts of dichloromethane, 557 parts of toluene, 62 parts of butanone, second
It is 155 parts of ester, 27 parts of methyl methacrylate, 22 parts of HR-24 essence, 5.3 parts of thermoplastic styrene butadiene rubber, 7.7 parts of EVA260, suitable
25 parts of 5 parts of acid anhydride, 2.7 parts of benzoyl peroxide and terpene phenol resin.EVA inorganic agents are subzero obtained in the formula of present embodiment
8 DEG C or so are still substantially absent from gel situation.
Implementation method seven
The preparing raw material of the EVA inorganic agents of present embodiment is made up of following components by weight：18 parts of carbon black, zinc oxide 1
Part, 16 parts of isocyanates, 23 parts of MEA, 35 parts of rosin resin, 66 parts of dichloromethane, 560 parts of toluene, 63 parts of butanone, second
163 parts of ester, 26 parts of methyl methacrylate, 18 parts of HR-24 essence, 6.5 parts of thermoplastic styrene butadiene rubber, 6 parts of EVA260, cis-butenedioic anhydride 6
22 parts of part, 3 parts of benzoyl peroxide and terpene phenol resin.EVA inorganic agents obtained in the formula of present embodiment are on subzero 6 DEG C of left sides
The right side is still substantially absent from gel situation.
Implementation method eight
The preparing raw material of the EVA inorganic agents of present embodiment is made up of following components by weight：15 parts of carbon black, zinc oxide 2
Part, 20 parts of isocyanates, 20 parts of MEA, 40 parts of rosin resin, 60 parts of dichloromethane, 545 parts of toluene, 58 parts of butanone, second
154 parts of ester, 31 parts of methyl methacrylate, 25 parts of HR-24 essence, 5 parts of thermoplastic styrene butadiene rubber, 9 parts of EVA260, cis-butenedioic anhydride 3
26 parts of part, 3 parts of benzoyl peroxide and terpene phenol resin.EVA inorganic agents obtained in the formula of present embodiment are on subzero 5 DEG C of left sides
The right side is still substantially absent from gel situation.
Specific embodiment of the invention is above are only, but design concept of the invention is not limited thereto, it is all to utilize this
Design carries out the change of unsubstantiality to the present invention, all should belong to the behavior for invading the scope of the present invention.
Claims (10)
1. EVA inorganic agents of a kind of good frost resistance, it is characterised in that the preparing raw material of the EVA inorganic agents is included by weight
Following components：545~560 parts of toluene, 58~63 parts of butanone, 154~163 parts of ethyl ester, 26~31 parts of methyl methacrylate,
18~25 parts of HR-24 essence, 5~6.5 parts of thermoplastic styrene butadiene rubber, 6~9 parts of EVA260,3~6 parts of cis-butenedioic anhydride, benzoyl peroxide first
22~26 parts of 1.5~3 parts of acyl and terpene phenol resin.
2. a kind of EVA inorganic agents of good frost resistance as claimed in claim 1, it is characterised in that the preparation of the EVA inorganic agents
Raw material is made up of following components by weight：550 parts of toluene, 60 parts of butanone, 160 parts of ethyl ester, 30 parts of methyl methacrylate,
20 parts of HR-24 essence, 5.6 parts of thermoplastic styrene butadiene rubber, 7 parts of EVA260,4 parts of cis-butenedioic anhydride, 2 parts of benzoyl peroxide and terpene phenolic
24 parts of resin.
3. a kind of EVA inorganic agents of good frost resistance as claimed in claim 1, it is characterised in that the preparation of the EVA inorganic agents
Raw material is made up of following components by weight：555 parts of toluene, 62 parts of butanone, 157 parts of ethyl ester, 28 parts of methyl methacrylate,
23 parts of HR-24 essence, 6 parts of thermoplastic styrene butadiene rubber, 8 parts of EVA260,5 parts of cis-butenedioic anhydride, 2.5 parts of benzoyl peroxide and terpene phenolic
25 parts of resin.
4. a kind of EVA inorganic agents of good frost resistance as claimed in claim 1, it is characterised in that the preparation of the EVA inorganic agents
Raw material is made up of following components by weight：545 parts of toluene, 63 parts of butanone, 163 parts of ethyl ester, 26 parts of methyl methacrylate,
25 parts of HR-24 essence, 5 parts of thermoplastic styrene butadiene rubber, 6 parts of EVA260,6 parts of cis-butenedioic anhydride, 1.5 parts of benzoyl peroxide and terpene phenolic
22 parts of resin.
5. a kind of EVA inorganic agents of good frost resistance as claimed in claim 1, it is characterised in that the preparation of the EVA inorganic agents
Raw material is made up of following components by weight：560 parts of toluene, 58 parts of butanone, 154 parts of ethyl ester, 31 parts of methyl methacrylate,
18 parts of HR-24 essence, 6.5 parts of thermoplastic styrene butadiene rubber, 9 parts of EVA260,3 parts of cis-butenedioic anhydride, 3 parts of benzoyl peroxide and terpene phenolic
26 parts of resin.
6. a kind of EVA inorganic agents of good frost resistance as claimed in claim 1, it is characterised in that the preparation of the EVA inorganic agents
Raw material is made up of following components by weight：15~18 parts of carbon black, 1~2 part of zinc oxide, 16~20 parts of isocyanates, Dan Yi
20~23 parts of hydramine, 35~40 parts of rosin resin, 60~66 parts of dichloromethane, 545~560 parts of toluene, 58~63 parts of butanone, second
154~163 parts of ester, 26~31 parts of methyl methacrylate, 18~25 parts of HR-24 essence, 5~6.5 parts of thermoplastic styrene butadiene rubber,
22~26 parts of 6~9 parts of EVA260,3~6 parts of cis-butenedioic anhydride, 1.5~3 parts of benzoyl peroxide and terpene phenol resin.
7. a kind of EVA inorganic agents of good frost resistance as claimed in claim 6, it is characterised in that the preparation of the EVA inorganic agents
Raw material is made up of following components by weight：17 parts of carbon black, 1.5 parts of zinc oxide, 19 parts of isocyanates, 22 parts of MEA,
37 parts of rosin resin, 62 parts of dichloromethane, 550 parts of toluene, 60 parts of butanone, 160 parts of ethyl ester, 30 parts of methyl methacrylate, HR-
24 20 parts of essence, 5.6 parts of thermoplastic styrene butadiene rubber, 7 parts of EVA260,4 parts of cis-butenedioic anhydride, 2 parts of benzoyl peroxide and terpene phenol resin
24 parts.
8. a kind of EVA inorganic agents of good frost resistance as claimed in claim 6, it is characterised in that the preparation of the EVA inorganic agents
Raw material is made up of following components by weight：16 parts of carbon black, 2 parts of zinc oxide, 17 parts of isocyanates, 21 parts of MEA, pine
38 parts of botany bar gum, 64 parts of dichloromethane, 557 parts of toluene, 62 parts of butanone, 155 parts of ethyl ester, 27 parts of methyl methacrylate, HR-24
22 parts of essence, 5.3 parts of thermoplastic styrene butadiene rubber, 7.7 parts of EVA260,5 parts of cis-butenedioic anhydride, 2.7 parts of benzoyl peroxide and terpene phenolic tree
25 parts of fat.
9. a kind of EVA inorganic agents of good frost resistance as claimed in claim 6, it is characterised in that the preparation of the EVA inorganic agents
Raw material is made up of following components by weight：18 parts of carbon black, 1 part of zinc oxide, 16 parts of isocyanates, 23 parts of MEA, pine
35 parts of botany bar gum, 66 parts of dichloromethane, 560 parts of toluene, 63 parts of butanone, 163 parts of ethyl ester, 26 parts of methyl methacrylate, HR-24
18 parts of essence, 6.5 parts of thermoplastic styrene butadiene rubber, 6 parts of EVA260,6 parts of cis-butenedioic anhydride, 3 parts of benzoyl peroxide and terpene phenol resin 22
Part.
10. a kind of EVA inorganic agents of good frost resistance as claimed in claim 6, it is characterised in that the system of the EVA inorganic agents
Standby raw material is made up of following components by weight：15 parts of carbon black, 2 parts of zinc oxide, 20 parts of isocyanates, 20 parts of MEA,
40 parts of rosin resin, 60 parts of dichloromethane, 545 parts of toluene, 58 parts of butanone, 154 parts of ethyl ester, 31 parts of methyl methacrylate, HR-
24 25 parts of essence, 5 parts of thermoplastic styrene butadiene rubber, 9 parts of EVA260,3 parts of cis-butenedioic anhydride, 3 parts of benzoyl peroxide and terpene phenol resin 26
Part.
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Cited By (4)
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| CN110684422A (en) * | 2019-09-18 | 2020-01-14 | 广东多正树脂科技有限公司 | Single-component rubber treating agent and preparation method thereof |
| CN110684422B (en) * | 2019-09-18 | 2021-06-25 | 广东多正树脂科技有限公司 | Single-component rubber treating agent and preparation method thereof |
| CN110564345A (en) * | 2019-09-27 | 2019-12-13 | 福建华夏蓝新材料科技有限公司 | Water-based EVA (ethylene-vinyl acetate) treating agent and preparation method thereof |
| CN110564345B (en) * | 2019-09-27 | 2021-03-09 | 福建华夏蓝新材料科技有限公司 | Water-based EVA (ethylene-vinyl acetate) treating agent and preparation method thereof |
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