CN1858140A - Environment friendly chloroprene rubber grafting glue without tribenzene - Google Patents
Environment friendly chloroprene rubber grafting glue without tribenzene Download PDFInfo
- Publication number
- CN1858140A CN1858140A CN 200610035856 CN200610035856A CN1858140A CN 1858140 A CN1858140 A CN 1858140A CN 200610035856 CN200610035856 CN 200610035856 CN 200610035856 A CN200610035856 A CN 200610035856A CN 1858140 A CN1858140 A CN 1858140A
- Authority
- CN
- China
- Prior art keywords
- weight portions
- chloroprene rubber
- environment friendly
- glue
- tribenzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention discloses the recipe of no-benzene environment friendly chloroprene rubber grafting glue. The chloroprene rubber grafting glue consists of butanone 10-35 weight portions, ethyl acetate 10-25 weight portions, methyl cyclohexane 10-15 weight portions, dimethyl carbonate 5-10 weight portions, grafted chloroprene rubber 5-15 weight portions, YH792 type thermoplastic elastomer 1-2.5 weight portions, MMA 1-10 weight portions, MAA 0.1-0.2 weight portions, composite initiator 0.01-0.02 weight portions and antioxidant BHT 0.1-0.4 weight portions. The present invention has good use effect, strong adhesion force, low cost and other advantages.
Description
Technical field
The present invention relates to a kind of tackiness agent, more specifically saying so relates to a kind of graft type chlorine dibutyl glue kinds glue.
Background technology
Chlorine dibutyl glue kinds (being called for short CR) grafting agent uses quite extensive in life, as shoemaking, tire, case and bag etc.Existing tackiness agent mainly adopts chloroprene rubber, resin etc. to make solvent, be used for the viscose glue in the shoemaking, and existing oil price is constantly soaring, the raw materials cost of producing organic solvent also increases much, and the most dependence on import of chloroprene rubber, in addition because adopt contains benzene raw materials, thereby bring certain influence more, exist in the pollution potential safety hazard for manufacturing operator such as shoemaking personnel healthy.
So people have adopted the feedstock production that does not contain " triphen ", as application number be 97118384, the applying date be on October 23rd, 1997, denomination of invention for not contain the graft neoprene adhesive of " triphen " and the patent application of manufacturing process thereof, it relates to a kind of graft type neoprene adhesive.Contain neoprene rubber, mixed solvent, methyl methacrylate, initiator, Resorcinol, 2,6 ditertiary butyl p cresol, tert butyl phenolic resin, said initiator is an oxidation-reduction initiator, and by dibenzoyl peroxide and N, the N-xylidene(s) is formed; Mixed solvent is made up of ethyl acetate, acetone, 120 ↑ [#] gasoline, butanone or ethyl acetate, hexanaphthene, 120 ↑ [#] gasoline, butanone.Above-mentioned patent has the higher defective of cost equally.
Summary of the invention
The objective of the invention is in order to solve above-mentioned deficiency, and provide a kind of environmental protection that has, the environment friendly chloroprene rubber grafting glue without tribenzene that bonding force is strong, cost is low.
The technical solution that the present invention adopts in order to reach above-mentioned effect is as follows:
The production formula of this nothing triphen environment friendly chloroprene rubber class (CR) Graft Adhesive, it is characterized in that, it is made of following set of dispense ratio, butanone 10-35 part, vinyl acetic monomer 10-25 part, methylcyclohexane 10-15 part, methylcarbonate 5-10 part, chlorine dibutyl glue kinds CR2442 graft type neoprene sheet 5-15 part, YH792 thermoplastic elastomer-1.5 methyl methacrylate MMA 1-10 part, methacrylic acid MAA 0.1-0.2 part, compound initiator 0.01-0.02 part, antioxidant BHT 0.1-0.4 part.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is:
The solvent system that product of the present invention uses belongs to real no triphen environmental protection system, and use range is wide, uses homemade neoprene sheet and SBS import substitution chloroprene rubber, and production cost is low, and excellent generalization values is arranged.
Embodiment
The production formula of this nothing triphen environment friendly chloroprene rubber class (CR) Graft Adhesive, constitute (weight part) by following set of dispense ratio, butanone-30 part, vinyl acetic monomer-25 part, methylcyclohexane-15 part, methylcarbonate-10 part, chlorine dibutyl glue kinds (CR) 2442 graft type neoprene sheets-13.5 part, YH792 type thermoplastic elastomer 1-2.5 part methyl methacrylate (MMA)-9.85 part, methacrylic acid MAA-0.15 part, compound initiator-0.015 part, antioxidant BHT-0.3 part.
Product of the present invention different with routine on organic solvent uses, methylcyclohexane and methylcarbonate have been introduced, in technical process, also use compound monomer and initiator, make finished product on performance, basic difference be arranged, and bonding effect is better with chlorine dibutyl glue kinds (CR) Graft Adhesive of routine.
This graft type neoprene latex, used the home-made neoprene sheet to replace import chloroprene rubber on the high side, and the part neoprene sheet replaced with SBS, adopted chlorine dibutyl glue kinds (CR)/SBS/MAA/MMA quaternary grafted method, and with compound initiator initiation reaction, make final product have high chromaticness and stronger shearing resistance, reduced production cost widely.
Product of the present invention is widely used in shoe industry, case and bag industry, to EVA/EVA, and EVA/TPR, EVA/Rubber, the stickup of materials such as PVC/Rubber all has stronger effect.Its technical parameter is: viscosity 3500～4000cps, solid content about 17.5%.
Claims (1)
1, the production formula of a kind of no triphen environment friendly chloroprene rubber class (CR) Graft Adhesive, it is characterized in that it constitutes (weight part) by following set of dispense ratio: butanone 10-35 part, vinyl acetic monomer 10-25 part, methylcyclohexane 10-15 part, methylcarbonate 5-10 part, chlorine dibutyl glue kinds (CR) 2442 graft type neoprene sheet 5-15 parts, YH792 type thermoplastic elastomer 1-2.5 part methyl methacrylate MMA 1-10 part, methacrylic acid MAA 0.1-0.2 part, compound initiator 0.01-0.02 part, antioxidant BHT 0.1-0.4 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610035856 CN1858140A (en) | 2006-06-09 | 2006-06-09 | Environment friendly chloroprene rubber grafting glue without tribenzene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610035856 CN1858140A (en) | 2006-06-09 | 2006-06-09 | Environment friendly chloroprene rubber grafting glue without tribenzene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1858140A true CN1858140A (en) | 2006-11-08 |
Family
ID=37297098
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200610035856 Pending CN1858140A (en) | 2006-06-09 | 2006-06-09 | Environment friendly chloroprene rubber grafting glue without tribenzene |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1858140A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850975A (en) * | 2012-09-28 | 2013-01-02 | 广东多正化工科技有限公司 | Aliphatic carbonate modified multivariant copolymerization grafted neoprene adhesive and preparation method of neoprene adhesive |
| CN104087200A (en) * | 2014-07-01 | 2014-10-08 | 中科院广州化学有限公司南雄材料生产基地 | Triphenyl-free chloroprene rubber adhesive and preparation method thereof |
| WO2016038448A1 (en) | 2014-09-12 | 2016-03-17 | Arkema France | Method for preparing a grafted and unsaturated synthetic rubber |
| CN105602476A (en) * | 2014-11-21 | 2016-05-25 | 奥克化学扬州有限公司 | Solvent composition used for polychloroprene solvent adhesive, composition containing polychloroprene solvent adhesive and polychloroprene solvent adhesive |
-
2006
- 2006-06-09 CN CN 200610035856 patent/CN1858140A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850975A (en) * | 2012-09-28 | 2013-01-02 | 广东多正化工科技有限公司 | Aliphatic carbonate modified multivariant copolymerization grafted neoprene adhesive and preparation method of neoprene adhesive |
| CN102850975B (en) * | 2012-09-28 | 2015-02-18 | 广东多正化工科技有限公司 | Aliphatic carbonate modified multivariant copolymerization grafted neoprene adhesive and preparation method of neoprene adhesive |
| CN104087200A (en) * | 2014-07-01 | 2014-10-08 | 中科院广州化学有限公司南雄材料生产基地 | Triphenyl-free chloroprene rubber adhesive and preparation method thereof |
| WO2016038448A1 (en) | 2014-09-12 | 2016-03-17 | Arkema France | Method for preparing a grafted and unsaturated synthetic rubber |
| CN105602476A (en) * | 2014-11-21 | 2016-05-25 | 奥克化学扬州有限公司 | Solvent composition used for polychloroprene solvent adhesive, composition containing polychloroprene solvent adhesive and polychloroprene solvent adhesive |
| CN105602476B (en) * | 2014-11-21 | 2017-10-10 | 江苏奥克化学有限公司 | Solvent compositions for neoprene solvent adhesive, the neoprene solvent glue composition comprising it and neoprene solvent adhesive |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103509159B (en) | The graft-modification method of low gel fraction solution polymerized butadiene styrene rubber | |
| US8662125B2 (en) | Modified gel particles and rubber composition | |
| DE102012213041A1 (en) | Rubber composition for a tire and pneumatic tire | |
| EP1939221A3 (en) | A method for producing functionalized cis-1,4polydienes having high cis-1,4-linkage content and high functionality | |
| RU2742276C2 (en) | Sealing gels, method of their production and their use in sealing compounds for self-sealing tires | |
| CN101177599A (en) | Aromatic hydrocarbon-free environment-protection chloroprene rubber adhesive with high adhesive strength | |
| EP2177374A1 (en) | Rubber mixtures with functionalised diene rubbers and micro gels, a method for producing and using the same | |
| CN101029163A (en) | Production of high-performance polyisoprene water latex, its gloves and related products | |
| EP2389295A1 (en) | Rubber mixtures containing silane and having possibly functionalized diene rubbers and microgels, a method for the production thereof, and use thereof | |
| CN1858140A (en) | Environment friendly chloroprene rubber grafting glue without tribenzene | |
| TW201842141A (en) | Sealing compounds | |
| Sakdapipanich et al. | Natural rubber: Biosynthesis, structure, properties and application | |
| TW201842140A (en) | Extended sealing gels, process for production thereof and use thereof in sealing compounds for self-sealing tyres | |
| CN102863934A (en) | Method for preparing heat-resistant modified water-based chloroprene rubber adhesive and application | |
| US7473472B2 (en) | Adhesive composition for the direct joining of a pre-gelled polyester or vinyl ester to raw rubber | |
| CN105440975B (en) | A kind of styrene-butadiene latex adhesive and preparation method thereof | |
| KR101899268B1 (en) | Transparent, tough and heatproof rubber composition comprising neodymium-catalyzed isoprene component, and manufacturing process for the same | |
| CN103524977B (en) | A kind of organic-silicon-modified thermoplastic elastomer (TPE) | |
| CN104470958B (en) | Chloroprene rubber, its preparation method and chloroprene rubber composition and its sulfide | |
| CN108129719A (en) | Rubber composition for tire tread and preparation method thereof | |
| KR100997278B1 (en) | Graft copolymer for transparent thermoplastic polyurethane resin, preparation method thereof, and polyurethane resin composition containing the same | |
| US6393655B1 (en) | Rubber products having better abrasion resistance | |
| CN103819635A (en) | Star-shaped hydrogenated butadiene styrene block copolymer, and preparation method and application thereof | |
| CN106928872A (en) | A kind of EVA inorganic agents of good frost resistance | |
| CN115232372B (en) | Sole composite material with wear resistance, wet skid resistance and high adhesive force performance and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Open date: 20061108 |