CN107151383A - A kind of high-strength abrasion-proof fiberglass - Google Patents
A kind of high-strength abrasion-proof fiberglass Download PDFInfo
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- CN107151383A CN107151383A CN201710336980.6A CN201710336980A CN107151383A CN 107151383 A CN107151383 A CN 107151383A CN 201710336980 A CN201710336980 A CN 201710336980A CN 107151383 A CN107151383 A CN 107151383A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/47—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes fibre-reinforced plastics, e.g. glass-reinforced plastics
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of high-strength abrasion-proof fiberglass, wear-resisting glass fibre reinforced plastic component includes 15 25 parts of polypropylene, 10 20 parts of epoxy resin, 10 30 parts of nano-ceramic particle, 28 parts of silane coupler, 5 10 parts of cyclohexanone, 26 parts of zirconium oxide, 15 25 parts of anti-wear agent by weight.Preparation technology of the present invention is simple, preparation process is environment friendly and pollution-free, and obtained fiberglass anti-wear performance is good, while also having corrosion-resistant, resistant to elevated temperatures advantage, can extend the service life of glass fibre reinforced plastic cable.
Description
Technical field
The present invention relates to wear-resisting glass fibre reinforced plastic preparing technical field, specially a kind of high-strength abrasion-proof fiberglass.
Background technology
Fiberglass, i.e. fiber-reinforced plastic, refer generally to use unsaturated polyester resin, epoxy resin and phenolic resin as matrix resin,
Make the reinforced plastics of reinforcing material, also known as fiberglass reinforced plastics with glass fibre or its product.Fiberglass has light weight
And hard, non-conductive, high mechanical strength, recycle less, the advantages of corrosion-resistant, thus be widely used in the every field in industry.
Fiberglass can be divided into unsaturated polyester (UP) glass steel, fiber glass epoxy, phenolic fiberglass reinforced plastics according to the difference of matrix.By being made
Resin matrix kind is different, therefore characteristically there is also very big difference for fiberglass.And cable is generally required now
Underground is embedded in, its corrosion resistance, anti-wear performance are poor.
The content of the invention
It is an object of the invention to provide a kind of high-strength abrasion-proof fiberglass, with asking for solving to propose in above-mentioned background technology
Topic.
To achieve the above object, the present invention provides following technical scheme：A kind of high-strength abrasion-proof fiberglass, wear-resisting glass fibre reinforced plastic
Component includes 15-25 parts of polypropylene by weight, 10-20 parts of epoxy resin, 10-30 parts of nano-ceramic particle, silane coupled
2-8 parts of agent, 5-10 parts of cyclohexanone, 2-6 parts of zirconium oxide, 15-25 parts of anti-wear agent.
It is preferred that, the anti-wear agent component includes sour 10-20 parts of the sodium polymer of ureaformaldehyde, styrene-acrylic emulsion 10- by weight
2-10 parts of 30 parts, 2-8 parts of triethyl citrate, 2-10 parts of polysiloxanes, 5-12 parts of nano aluminium oxide and nano-sized iron oxide.
It is preferred that, composition proportion preferably is：20 parts of polypropylene, 15 parts of epoxy resin, 20 parts of nano-ceramic particle, silane
5 parts of coupling agent, 8 parts of cyclohexanone, 4 parts of zirconium oxide, 20 parts of anti-wear agent.
It is preferred that, its preparation method comprises the following steps：
A, will polypropylene, epoxy resin, silane coupler, cyclohexanone mix after add reactor in be heated to while stirring melting
State, obtains mixture A；
B, addition nano-ceramic particle, zirconium oxide in mixture A, add after mixing and are ground in ball mill, drum's speed of rotation is
100-300 revs/min, Ball-milling Time is 10min-20min, obtains mixture B；
C, anti-wear agent is added in mixture B, extrusion molding in double screw extruder is added after mixing, wear-resisting glass fibre reinforced plastic is obtained.
Compared with prior art, the beneficial effects of the invention are as follows：Preparation technology of the present invention is simple, preparation process is environmentally friendly without dirt
Dye, obtained fiberglass anti-wear performance is good, while also having corrosion-resistant, resistant to elevated temperatures advantage, can extend glass fibre reinforced plastic cable
Service life；In addition, the anti-wear agent added in the present invention have densification, microdilatancy, decrement, diminishing, plasticising, enhancing, it is impervious prevent
The advantage of water, freeze proof anti-carbonation, improves glass fibre reinforced plastic cable impact-resisting wear-resisting ability, further extends its service life.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model that the present invention is protected
Enclose.
The present invention provides following technical scheme：A kind of high-strength abrasion-proof fiberglass, wear-resisting glass fibre reinforced plastic component is by weight
Including 15-25 parts of polypropylene, 10-20 parts of epoxy resin, 10-30 parts of nano-ceramic particle, 2-8 parts of silane coupler, cyclohexanone
5-10 parts, 2-6 parts of zirconium oxide, 15-25 parts of anti-wear agent；Anti-wear agent component includes the sour sodium polymer 10-20 of ureaformaldehyde by weight
Part, 10-30 parts of styrene-acrylic emulsion, 2-8 parts of triethyl citrate, 2-10 parts of polysiloxanes, 5-12 parts of nano aluminium oxide and nanometer
2-10 parts of iron oxide.
Embodiment one：
Wear-resisting glass fibre reinforced plastic component includes 15 parts of polypropylene, 10 parts of epoxy resin, 10 parts of nano-ceramic particle, silane by weight
2 parts of coupling agent, 5 parts of cyclohexanone, 2 parts of zirconium oxide, 15 parts of anti-wear agent；Anti-wear agent component includes the sour sodium polymerization of ureaformaldehyde by weight
10 parts of thing, 10 parts of styrene-acrylic emulsion, 2 parts of triethyl citrate, 2 parts of polysiloxanes, 5 parts of nano aluminium oxide and nano-sized iron oxide 2
Part.
The preparation method of the present embodiment comprises the following steps：
A, will polypropylene, epoxy resin, silane coupler, cyclohexanone mix after add reactor in be heated to while stirring melting
State, obtains mixture A；
B, addition nano-ceramic particle, zirconium oxide in mixture A, add after mixing and are ground in ball mill, drum's speed of rotation is
100 revs/min, Ball-milling Time is 10min, obtains mixture B；
C, anti-wear agent is added in mixture B, extrusion molding in double screw extruder is added after mixing, wear-resisting glass fibre reinforced plastic is obtained.
Embodiment two：
Wear-resisting glass fibre reinforced plastic component includes polipropene 25 part, 20 parts of epoxy resin, 30 parts of nano-ceramic particle, silane by weight
8 parts of coupling agent, 10 parts of cyclohexanone, 6 parts of zirconium oxide, 25 parts of anti-wear agent；Anti-wear agent component includes the sour sodium of ureaformaldehyde and gathered by weight
20 parts of compound, 30 parts of styrene-acrylic emulsion, 8 parts of triethyl citrate, 10 parts of polysiloxanes, 12 parts of nano aluminium oxide and nano oxidized
10 parts of iron.
The preparation method of the present embodiment comprises the following steps：
A, will polypropylene, epoxy resin, silane coupler, cyclohexanone mix after add reactor in be heated to while stirring melting
State, obtains mixture A；
B, addition nano-ceramic particle, zirconium oxide in mixture A, add after mixing and are ground in ball mill, drum's speed of rotation is
300 revs/min, Ball-milling Time is 20min, obtains mixture B；
C, anti-wear agent is added in mixture B, extrusion molding in double screw extruder is added after mixing, wear-resisting glass fibre reinforced plastic is obtained.
Embodiment three：
Wear-resisting glass fibre reinforced plastic component includes 17 parts of polypropylene, 12 parts of epoxy resin, 14 parts of nano-ceramic particle, silane by weight
3 parts of coupling agent, 6 parts of cyclohexanone, 3 parts of zirconium oxide, 16 parts of anti-wear agent；Anti-wear agent component includes the sour sodium polymerization of ureaformaldehyde by weight
12 parts of thing, 14 parts of styrene-acrylic emulsion, 3 parts of triethyl citrate, 3 parts of polysiloxanes, 6 parts of nano aluminium oxide and nano-sized iron oxide 3
Part.
The preparation method of the present embodiment comprises the following steps：
A, will polypropylene, epoxy resin, silane coupler, cyclohexanone mix after add reactor in be heated to while stirring melting
State, obtains mixture A；
B, addition nano-ceramic particle, zirconium oxide in mixture A, add after mixing and are ground in ball mill, drum's speed of rotation is
120 revs/min, Ball-milling Time is 12min, obtains mixture B；
C, anti-wear agent is added in mixture B, extrusion molding in double screw extruder is added after mixing, wear-resisting glass fibre reinforced plastic is obtained.
Example IV：
Wear-resisting glass fibre reinforced plastic component includes 22 parts of polypropylene, 18 parts of epoxy resin, 28 parts of nano-ceramic particle, silane by weight
7 parts of coupling agent, 8 parts of cyclohexanone, 5 parts of zirconium oxide, 22 parts of anti-wear agent；Anti-wear agent component includes the sour sodium polymerization of ureaformaldehyde by weight
18 parts of thing, 28 parts of styrene-acrylic emulsion, 7 parts of triethyl citrate, 8 parts of polysiloxanes, 10 parts of nano aluminium oxide and nano-sized iron oxide 9
Part.
The preparation method of the present embodiment comprises the following steps：
A, will polypropylene, epoxy resin, silane coupler, cyclohexanone mix after add reactor in be heated to while stirring melting
State, obtains mixture A；
B, addition nano-ceramic particle, zirconium oxide in mixture A, add after mixing and are ground in ball mill, drum's speed of rotation is
280 revs/min, Ball-milling Time is 18min, obtains mixture B；
C, anti-wear agent is added in mixture B, extrusion molding in double screw extruder is added after mixing, wear-resisting glass fibre reinforced plastic is obtained.
Embodiment five：
Wear-resisting glass fibre reinforced plastic component includes 22 parts of polypropylene, 16 parts of epoxy resin, 25 parts of nano-ceramic particle, silane by weight
6 parts of coupling agent, 6 parts of cyclohexanone, 5 parts of zirconium oxide, 22 parts of anti-wear agent；Anti-wear agent component includes the sour sodium polymerization of ureaformaldehyde by weight
16 parts of thing, 25 parts of styrene-acrylic emulsion, 3 parts of triethyl citrate, 6 parts of polysiloxanes, 10 parts of nano aluminium oxide and nano-sized iron oxide 5
Part.
The preparation method of the present embodiment comprises the following steps：
A, will polypropylene, epoxy resin, silane coupler, cyclohexanone mix after add reactor in be heated to while stirring melting
State, obtains mixture A；
B, addition nano-ceramic particle, zirconium oxide in mixture A, add after mixing and are ground in ball mill, drum's speed of rotation is
250 revs/min, Ball-milling Time is 16min, obtains mixture B；
C, anti-wear agent is added in mixture B, extrusion molding in double screw extruder is added after mixing, wear-resisting glass fibre reinforced plastic is obtained.
Embodiment six：
Wear-resisting glass fibre reinforced plastic component includes sour 15 parts of the sodium polymer of ureaformaldehyde, 20 parts of styrene-acrylic emulsion, triethyl citrate 5 by weight
Part, 6 parts of polysiloxanes, 9 parts of nano aluminium oxide and 6 parts of nano-sized iron oxide；Anti-wear agent component includes ureaformaldehyde acid by weight
15 parts of sodium polymer, 20 parts of styrene-acrylic emulsion, 5 parts of triethyl citrate, 6 parts of polysiloxanes, 8 parts of nano aluminium oxide and nano oxygen
Change 6 parts of iron.
The preparation method of the present embodiment comprises the following steps：
A, will polypropylene, epoxy resin, silane coupler, cyclohexanone mix after add reactor in be heated to while stirring melting
State, obtains mixture A；
B, addition nano-ceramic particle, zirconium oxide in mixture A, add after mixing and are ground in ball mill, drum's speed of rotation is
200 revs/min, Ball-milling Time is 15min, obtains mixture B；
C, anti-wear agent is added in mixture B, extrusion molding in double screw extruder is added after mixing, wear-resisting glass fibre reinforced plastic is obtained.
Experimental example：
Fiberglass made from various embodiments of the present invention is subjected to anti-abrasion strength, compression strength with fiberglass made from conventional method
With experiment of having worn and torn, data such as following table is obtained：
| Anti-abrasion strength（h(kg/m2） | Compression strength（Mpa） | Wear rate（%） | |
| Conventional method | 6.2 | 42.6 | 6.9 |
| Embodiment one | 10.2 | 69.2 | 2.5 |
| Embodiment two | 10.5 | 69.5 | 2.5 |
| Embodiment three | 10.1 | 69.8 | 2.4 |
| Example IV | 10.0 | 69.6 | 2.8 |
| Embodiment five | 10.6 | 68.9 | 2.6 |
| Embodiment six | 10.9 | 70.5 | 2.1 |
From above table data, wear-resisting glass fibre reinforced plastic prepared by embodiment six can reach optimum performance.
Preparation technology of the present invention is simple, preparation process is environment friendly and pollution-free, and obtained fiberglass anti-wear performance is good, while also having
There is corrosion-resistant, resistant to elevated temperatures advantage, the service life of glass fibre reinforced plastic cable can be extended；In addition, the anti-wear agent added in the present invention
There is densification, microdilatancy, decrement, diminishing, plasticising, enhancing, impervious waterproof, freeze proof anti-carbonation, fiberglass electricity is improved
Cable impact-resisting wear-resisting ability, further extends its service life.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (4)
1. a kind of high-strength abrasion-proof fiberglass, it is characterised in that：Wear-resisting glass fibre reinforced plastic component includes polypropylene 15-25 by weight
Part, 10-20 parts of epoxy resin, 10-30 parts of nano-ceramic particle, 2-8 parts of silane coupler, 5-10 parts of cyclohexanone, zirconium oxide 2-6
Part, 15-25 parts of anti-wear agent.
2. a kind of high-strength abrasion-proof fiberglass according to claim 1, it is characterised in that：The anti-wear agent component is by weight
Number includes sour 10-20 parts of the sodium polymer of ureaformaldehyde, 10-30 parts of styrene-acrylic emulsion, 2-8 parts of triethyl citrate, polysiloxanes 2-10
2-10 parts of part, 5-12 parts of nano aluminium oxide and nano-sized iron oxide.
3. a kind of high-strength abrasion-proof fiberglass according to claim 1, it is characterised in that：It is preferred that composition proportion be：It is poly-
It is 20 parts of propylene, 15 parts of epoxy resin, 20 parts of nano-ceramic particle, 5 parts of silane coupler, 8 parts of cyclohexanone, 4 parts of zirconium oxide, wear-resisting
20 parts of agent.
4. realize a kind of preparation method of high-strength abrasion-proof fiberglass described in claim 1, it is characterised in that：Its preparation method
Comprise the following steps：
A, will polypropylene, epoxy resin, silane coupler, cyclohexanone mix after add reactor in be heated to while stirring melting
State, obtains mixture A；
B, addition nano-ceramic particle, zirconium oxide in mixture A, add after mixing and are ground in ball mill, drum's speed of rotation is
100-300 revs/min, Ball-milling Time is 10min-20min, obtains mixture B；
C, anti-wear agent is added in mixture B, extrusion molding in double screw extruder is added after mixing, wear-resisting glass fibre reinforced plastic is obtained.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710336980.6A CN107151383A (en) | 2017-05-14 | 2017-05-14 | A kind of high-strength abrasion-proof fiberglass |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710336980.6A CN107151383A (en) | 2017-05-14 | 2017-05-14 | A kind of high-strength abrasion-proof fiberglass |
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| CN201710336980.6A Pending CN107151383A (en) | 2017-05-14 | 2017-05-14 | A kind of high-strength abrasion-proof fiberglass |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109776959A (en) * | 2018-12-29 | 2019-05-21 | 安徽天康(集团)股份有限公司 | A kind of wear-resisting middle-high voltage power cable of insulation |
| CN113429659A (en) * | 2021-07-12 | 2021-09-24 | 安徽瑞丰管业有限公司 | Production process of high-wear-resistance glass steel tube |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292612A (en) * | 2014-05-27 | 2015-01-21 | 安徽宁国市高新管业有限公司 | High-strength wear resistant glass fiber reinforced plastic |
-
2017
- 2017-05-14 CN CN201710336980.6A patent/CN107151383A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292612A (en) * | 2014-05-27 | 2015-01-21 | 安徽宁国市高新管业有限公司 | High-strength wear resistant glass fiber reinforced plastic |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109776959A (en) * | 2018-12-29 | 2019-05-21 | 安徽天康(集团)股份有限公司 | A kind of wear-resisting middle-high voltage power cable of insulation |
| CN113429659A (en) * | 2021-07-12 | 2021-09-24 | 安徽瑞丰管业有限公司 | Production process of high-wear-resistance glass steel tube |
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