CN106928789A - A kind of painting high covering power environment protection interior wall sealing wax and preparation method thereof - Google Patents

A kind of painting high covering power environment protection interior wall sealing wax and preparation method thereof Download PDF

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Publication number
CN106928789A
CN106928789A CN201710157500.XA CN201710157500A CN106928789A CN 106928789 A CN106928789 A CN 106928789A CN 201710157500 A CN201710157500 A CN 201710157500A CN 106928789 A CN106928789 A CN 106928789A
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CN
China
Prior art keywords
parts
interior wall
covering power
wall sealing
sealing wax
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Pending
Application number
CN201710157500.XA
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Chinese (zh)
Inventor
胡中源
董立志
程璐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Chenyang Industry and Trade Group Co Ltd
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Priority to CN201710157500.XA priority Critical patent/CN106928789A/en
Publication of CN106928789A publication Critical patent/CN106928789A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of painting high covering power environment protection interior wall sealing wax and preparation method thereof, it is related to technical field of coatings, in parts by weight, raw material is made up of following component:Aqueous net taste resin:100 300 parts, Opacifying polymers tiny balloon:50 150 parts, band anchoring group dispersant:1 10 parts, association thickener:1 10 parts, defoamer:16 parts, preservative:26 parts, wetting agent:15 parts, titanium dioxide:100 280 parts, filler:190 540 parts, water:10 250 parts;Blended stirring is prepared from.The present invention has zero VOC, and covering power is good, easily construction, the resistance to shampooing of resistant, and a construction reaches preferable decorative effect, the features such as prepare convenient, environmental protection.

Description

A kind of painting high covering power environment protection interior wall sealing wax and preparation method thereof
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of a painting high covering power environment protection interior wall sealing wax and its system Preparation Method.
Background technology
The characteristics of interior wall sealing wax has easy construction, performance protrusion, safety and environmental protection, accounts for governance in inner wall decoration at home Status, its market share is more than 70%.Common interior wall sealing wax to reach preferable effect construction technology for a bottom two sides, it is necessary to Construction three times.Present cost of labor more and more higher, and construct three times, can also extend owner moves in the time, develops one Only apply to brush one times and can just reach decorative effect interior wall sealing wax with very realistic meaning.
Reach one time and brush the interior wall sealing wax of the construction effect that can have just reached, it is necessary to two aspects of solution are asked Topic, 1, with superpower base ability, can just cover the defect of ground for one time, this requires that dry film contrast ratio at least reaches 0.98 More than.2nd, with fine richness, there can be preferable decorative effect when beneath defect is covered.
The contrast ratio of conventional interior wall sealing wax certified products is 0.90, Grade A 0.93, high-class product 0.95, then up covering power is just It is difficult to lifted, be extremely difficult to 0.98 and more than, it is impossible to reach one time and cover in ground defect.Somewhat by a large amount of titanium dioxides of addition Covering power is improved Deng filler, although so ground can be covered with one time, because powder is too many, viscosity increase, it is necessary to plus More water, influence surface effect.
The content of the invention
The technical problem to be solved in the present invention is directed to above-mentioned the deficiencies in the prior art, there is provided a kind of painting high covering power Environment protection interior wall sealing wax and preparation method thereof, the present invention has zero VOC, and covering power is good, easily construction, the resistance to shampooing of resistant, one time Construction reaches preferable decorative effect, the features such as prepare convenient, environmental protection.
In order to solve the above technical problems, the technical solution used in the present invention is:Apply in high covering power environmental protection for a kind of one time Wall sealing wax, raw material in parts by weight, is made up of following component:Aqueous net taste resin:100-300 parts, Opacifying polymers are hollow Microballoon:50-150 parts, band anchoring group dispersant:1-10 parts, association thickener:1-10 parts, defoamer:1-6 parts, anti-corrosion Agent:2-6 parts, wetting agent:1-5 parts, titanium dioxide:100-280 parts, filler:190-540 parts, water:10-250 parts;Blended stirring It is prepared from.
Preferably, raw material in parts by weight, is made up of following component:Aqueous net taste resin:It is 150-280 parts, opaque poly- Compound tiny balloon:80-150 parts, band anchoring group dispersant:3-8 parts, association thickener:3-8 parts, defoamer:2-5 parts, Preservative:2-4 parts, wetting agent:1-3 parts, titanium dioxide:120-250 parts, filler:230-400 parts, water:20-200 parts;It is blended Stirring is prepared from.
Preferably, described filler is 4000 mesh calcined kaolins, 1250 mesh calcined kaolins, 6000 mesh alumina silicate, 800 mesh One or more in wollastonite, diatomite, can more preferably eliminate side angle light, so as to reach more preferable construction effect.The titanium white Powder is rutile ore type, and using chloridising production.
Preferably, described filler includes 4000 mesh calcined kaolins:50-200 parts, 1250 mesh calcined kaolins:50-100 Part, 6000 mesh alumina silicate:30-80 parts, 800 mesh wollastonites:30-80 parts, diatomite:30-80 parts.
Preferably, described filler includes 4000 mesh calcined kaolins:80-150 parts, 1250 mesh calcined kaolins:50-80 Part, 6000 mesh alumina silicate:30-60 parts, 800 mesh wollastonites:40-60 parts, diatomite:30-50 parts.
Preferably, the aqueous net taste resin is large arch dam aqueous acetic acid ethylene-acrylate, and it leads in building-up process Control polymerization speed is crossed, so as to control particle diameter and viscosity, the bulky grain that particle diameter is 0.5 micron is ultimately formed, and synthesizing By three vacuum diaphragm purified treatments in journey, free monomer is few, and smell is light, Gu contain that 70%, and mechanicalness can be reached Can be excellent, filling material grinding can be participated in.
Preferably, the Opacifying polymers tiny balloon is styrene hollow microsphere.Using microballoon inner air/polymerization The difference of refractive index between thing interface, can scatter when light passes through, so that this polymer microballoon is provided with good light and hides Gai Xing.
Preferably, the dispersant is polyacrylic acid sodium salt copolymer analog, the modified polypropene acid solution for having anchoring group One kind in class, modified polycarboxylic acid salt, can prevent bridge flocculation, can to greatest extent improve the dispersiveness of titanium dioxide, from And lift covering power.
Preferably, the thickener is the one kind in polyurethane thickener, association type hydroxyethyl cellulose.Association type is thickened Agent, can improve shearing force during construction, so as to increase film thickness when single pass is constructed, improve paint film richness.
The present invention provides a kind of preparation method of painting high covering power environment protection interior wall sealing wax, including:
Step 1:First add 20%(Weight)Aqueous net taste resin, Opacifying polymers tiny balloon and water, with speed 1000rpm stirs 10min, to stirring;
Step 2:Preservative, wetting agent, dispersant and defoamer are sequentially added, is mixed, 10min is stirred with speed 1000rpm, extremely Stir;
Step 3:Titanium dioxide and filler are added, less than 50 microns are ground under vacuum state;
Step 4:Remaining aqueous net taste resin and thickener are added, appropriate viscosity is adjusted to, 10min are stirred with speed 1000rpm, To stirring.
Compared with prior art, the beneficial effects of the invention are as follows:
Paint film of the present invention has zero VOC, and covering power is good, easily construction, the resistance to shampooing of resistant, and a construction reaches preferably dress Decorations effect, labor and material saving, with by dicoration, feature, the feature of environmental protection.
Specific embodiment
With reference to specific embodiment, the present invention is further detailed explanation.
Embodiment 1
A kind of painting high covering power environment protection interior wall sealing wax that the present embodiment 1 is provided, by weight, is made up of following component:
Aqueous net taste resin:250 parts, Opacifying polymers tiny balloon:120 parts, defoamer:4 parts, preservative:3 parts, wetting Agent:2 parts, band anchoring group dispersant:6 parts, titanium dioxide:180 parts, 4000 mesh calcined kaolins:100 parts, the calcining of 1250 mesh is high Ridge soil:50 parts, 6000 mesh alumina silicate:30 parts, 800 mesh wollastonites:50 parts, diatomite:40 parts, association thickener:5 parts, water: 160 parts.
It is above-mentioned it is a kind of one time painting high covering power environment protection interior wall sealing wax preparation method be:
Step 1:First add 20%(Weight)Aqueous net taste resin, Opacifying polymers tiny balloon and water, with speed 1000rpm stirs 10min, to stirring;
Step 2:Preservative, wetting agent, dispersant and defoamer are sequentially added, is mixed, 10min is stirred with speed 1000rpm, extremely Stir;
Step 3:Titanium dioxide and filler are added, less than 50 microns are ground under vacuum state;
Step 4:Remaining aqueous net taste resin and thickener are added, appropriate viscosity is adjusted to, 10min are stirred with speed 1000rpm, To stirring.
The performance test results of a time painting high covering power environment protection interior wall sealing wax of above-mentioned gained are as shown in table 1:
The performance test results of 1 embodiment of table 1
Can be drawn from testing result, paint film of the present invention has a zero VOC, contrast ratio reach 0.98 and more than, covering power is good, holds The features such as easily construction, resistant resistance to shampooing, while can construct for one time and reach the bottom two sides of common interior wall sealing wax brushing one, construct three Time effect.
Embodiment 2
A kind of painting high covering power environment protection interior wall sealing wax that the present embodiment 2 is provided, by weight, is made up of following component:
Aqueous net taste resin:220 parts, Opacifying polymers tiny balloon:130 parts, defoamer:4 parts, preservative:3 parts, wetting Agent:2 parts, band anchoring group dispersant:6 parts, titanium dioxide:220 parts, 4000 mesh calcined kaolins:120 parts, the calcining of 1250 mesh is high Ridge soil:60 parts, 6000 mesh alumina silicate:30 parts, 800 mesh wollastonites:50 parts, diatomite:40 parts, association thickener:5 parts, water: 110 parts.
A time preparation method for painting high covering power environment protection interior wall sealing wax of the present embodiment is repeated no more with embodiment 1.
The performance test results of a time painting high covering power environment protection interior wall sealing wax of above-mentioned gained are as shown in table 2:
The performance test results of 2 embodiment of table 2
Can be drawn from testing result, paint film of the present invention has a zero VOC, contrast ratio reach 0.98 and more than, covering power is good, holds The features such as easily construction, resistant resistance to shampooing, while can construct for one time and reach the bottom two sides of common interior wall sealing wax brushing one, construct three Time effect.
Embodiment 3
A kind of painting high covering power environment protection interior wall sealing wax that the present embodiment 3 is provided, by weight, is made up of following component:
Aqueous net taste resin:250 parts, Opacifying polymers tiny balloon:150 parts, defoamer:5 parts, preservative:3 parts, wetting Agent:2 parts, band anchoring group dispersant:8 parts, titanium dioxide:250 parts, 4000 mesh calcined kaolins:100 parts, the calcining of 1250 mesh is high Ridge soil:50 parts, 6000 mesh alumina silicate:30 parts, 800 mesh wollastonites:50 parts, diatomite:40 parts, association thickener:5 parts, water: 47 parts.
A time preparation method for painting high covering power environment protection interior wall sealing wax of the present embodiment is repeated no more with embodiment 1.
The performance test results of a time painting high covering power environment protection interior wall sealing wax of above-mentioned gained are as shown in table 3:
The performance test results of 3 embodiment of table 3
Can be drawn from testing result, paint film of the present invention has a zero VOC, contrast ratio reach 0.98 and more than, covering power is good, holds The features such as easily construction, resistant resistance to shampooing, while can construct for one time and reach the bottom two sides of common interior wall sealing wax brushing one, construct three Time effect.
In addition to the implementation, the present invention can also have other embodiment.All use equivalents or equivalent transformation shape Into technical scheme, all fall within the protection domain of application claims.
Can be drawn from testing result, paint film of the present invention has a zero VOC, contrast ratio reach 0.98 and more than, covering power It is good, easily construction, the features such as resistant resistance to shampooing, at the same can construct for one time be reach the bottom two sides of common interior wall sealing wax brushing one, The effect that construction is three times.
Embodiment 2
The painting high covering power environment protection interior wall sealing wax that the present embodiment 2 is provided, by weight, is made up of following component:
Aqueous net taste resin:220 parts, Opacifying polymers tiny balloon:130 parts, defoamer:4 parts, preservative:3 parts, wetting Agent:2 parts, band anchoring group dispersant:6 parts, titanium dioxide:220 parts, 4000 mesh calcined kaolins:120 parts, the calcining of 1250 mesh is high Ridge soil:60 parts, 6000 mesh alumina silicate:30 parts, 800 mesh wollastonites:50 parts, diatomite:40 parts, association thickener:5 parts, water: 110 parts.
A time preparation method for painting high covering power environment protection interior wall sealing wax of the present embodiment is repeated no more with embodiment 1.
The performance test results of a time painting high covering power environment protection interior wall sealing wax of above-mentioned gained are as shown in table 2:
The performance test results of 2 embodiment of table 2
Can be drawn from testing result, paint film of the present invention has a zero VOC, contrast ratio reach 0.98 and more than, covering power is good, holds The features such as easily construction, resistant resistance to shampooing, while can construct for one time and reach the bottom two sides of common interior wall sealing wax brushing one, construct three Time effect.
Embodiment 3
The painting high covering power environment protection interior wall sealing wax that the present embodiment 3 is provided, by weight, is made up of following component:
Aqueous net taste resin:250 parts, Opacifying polymers tiny balloon:150 parts, defoamer:5 parts, preservative:3 parts, wetting Agent:2 parts, band anchoring group dispersant:8 parts, titanium dioxide:250 parts, 4000 mesh calcined kaolins:100 parts, the calcining of 1250 mesh is high Ridge soil:50 parts, 6000 mesh alumina silicate:30 parts, 800 mesh wollastonites:50 parts, diatomite:40 parts, association thickener:5 parts, water: 47 parts.
A time preparation method for painting high covering power environment protection interior wall sealing wax of the present embodiment is repeated no more with embodiment 1.
The performance test results of a time painting high covering power environment protection interior wall sealing wax of above-mentioned gained are as shown in table 3:
The performance test results of 3 embodiment of table 3
Can be drawn from testing result, paint film of the present invention has a zero VOC, contrast ratio reach 0.98 and more than, covering power is good, holds The features such as easily construction, resistant resistance to shampooing, while can construct for one time and reach the bottom two sides of common interior wall sealing wax brushing one, construct three Time effect.
In addition to the implementation, the present invention can also have other embodiment.All use equivalents or equivalent transformation shape Into technical scheme, all fall within the protection domain of application claims.

Claims (10)

1. high covering power environment protection interior wall sealing wax is applied a kind of one time, it is characterised in that:Raw material in parts by weight, by following component group Into:
Aqueous net taste resin:100-300 parts, Opacifying polymers tiny balloon:50-150 parts, band anchoring group dispersant:1- 10 parts, association thickener:1-10 parts, defoamer:1-6 parts, preservative:2-6 parts, wetting agent:1-5 parts, titanium dioxide:100- 280 parts, filler:190-540 parts, water:10-250 parts;Blended stirring is prepared from.
2. high covering power environment protection interior wall sealing wax is applied a kind of one time according to claim 1, it is characterised in that:Raw material is with weight Part meter, is made up of following component:
Aqueous net taste resin:150-280 parts, Opacifying polymers tiny balloon:80-150 parts, band anchoring group dispersant:3-8 Part, association thickener:3-8 parts, defoamer:2-5 parts, preservative:2-4 parts, wetting agent:1-3 parts, titanium dioxide:120-250 Part, filler:230-400 parts, water:20-200 parts;Blended stirring is prepared from.
3. high covering power environment protection interior wall sealing wax is applied a kind of one time according to claim 1 and 2, it is characterised in that described to fill out Expect to be the one kind in 4000 mesh calcined kaolins, 1250 mesh calcined kaolins, 6000 mesh alumina silicate, 800 mesh wollastonites, diatomite Or it is several, the titanium dioxide is rutile ore type, and using chloridising production.
4. high covering power environment protection interior wall sealing wax is applied a kind of one time according to claim 3, it is characterised in that described filler bag Include 4000 mesh calcined kaolins:50-200 parts, 1250 mesh calcined kaolins:50-100 parts, 6000 mesh alumina silicate:30-80 parts, 800 mesh wollastonites:30-80 parts, diatomite:30-80 parts.
5. high covering power environment protection interior wall sealing wax is applied a kind of one time according to claim 3, it is characterised in that described filler bag Include 4000 mesh calcined kaolins:80-150 parts, 1250 mesh calcined kaolins:50-80 parts, 6000 mesh alumina silicate:30-60 parts, 800 Mesh wollastonite:40-60 parts, diatomite:30-50 parts.
6. high covering power environment protection interior wall sealing wax is applied a kind of one time according to claim 1, it is characterised in that described aqueous net Taste resin be large arch dam aqueous acetic acid ethylene-acrylate, 0.5 micron of particle diameter, and in building-up process by three vacuum every Film purified treatment.
7. high covering power environment protection interior wall sealing wax is applied a kind of one time according to claim 1, it is characterised in that described opaque Polymer hollow microsphere is styrene hollow microsphere.
8. high covering power environment protection interior wall sealing wax is applied a kind of one time according to claim 1, it is characterised in that the dispersant For have anchoring group polyacrylic acid sodium salt copolymer analog, modified polypropene acid solution class, modified polycarboxylic acid salt in one kind.
9. high covering power environment protection interior wall sealing wax is applied a kind of one time according to claim 1, it is characterised in that the thickener It is the one kind in polyurethane thickener, association type hydroxyethyl cellulose.
10. a kind of a time according to claim any one of 1-9 applies the preparation method of high covering power environment protection interior wall sealing wax, its It is characterised by, methods described includes:
Step 1:First add 20%(Weight)Aqueous net taste resin, Opacifying polymers tiny balloon and water, with speed 1000rpm stirs 10min, to stirring;
Step 2:Preservative, wetting agent, dispersant and defoamer are sequentially added, is mixed, 10min is stirred with speed 1000rpm, extremely Stir;
Step 3:Titanium dioxide and filler are added, less than 50 microns are ground under vacuum state;
Step 4:Remaining aqueous net taste resin and thickener are added, appropriate viscosity is adjusted to, 10min are stirred with speed 1000rpm, To stirring.
CN201710157500.XA 2017-03-16 2017-03-16 A kind of painting high covering power environment protection interior wall sealing wax and preparation method thereof Pending CN106928789A (en)

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CN201710157500.XA CN106928789A (en) 2017-03-16 2017-03-16 A kind of painting high covering power environment protection interior wall sealing wax and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710157500.XA CN106928789A (en) 2017-03-16 2017-03-16 A kind of painting high covering power environment protection interior wall sealing wax and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115368796A (en) * 2022-08-17 2022-11-22 龙牌涂料(北京)有限公司 High-color-reduction-degree and high-brightness water-based projection curtain paint

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Publication number Priority date Publication date Assignee Title
CN115368796A (en) * 2022-08-17 2022-11-22 龙牌涂料(北京)有限公司 High-color-reduction-degree and high-brightness water-based projection curtain paint
CN115368796B (en) * 2022-08-17 2023-10-20 龙牌涂料(北京)有限公司 High-color-reduction-degree high-brightness water-based projection curtain paint

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