CN106924079A - 杀菌消毒无水清洗剂 - Google Patents
杀菌消毒无水清洗剂 Download PDFInfo
- Publication number
- CN106924079A CN106924079A CN201710163754.2A CN201710163754A CN106924079A CN 106924079 A CN106924079 A CN 106924079A CN 201710163754 A CN201710163754 A CN 201710163754A CN 106924079 A CN106924079 A CN 106924079A
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- Prior art keywords
- sterilizing
- cleaning agent
- skin
- oil
- anhydrous cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
本发明公开了一种杀菌消毒无水清洗剂,是属于现代小化工产品无水洗手剂生产配制技术领域。由蛇油芦荟油润肤护肤、松油醇甲基硅油爽肤洁肤、豆油甘油去污垢清肤、貂油松油VE强力去污滋润肌肤、白色矿油溶剂油即效杀菌、芦荟油茶树油护肤保湿灭菌、橄榄油蓖麻油广谱持久抑菌组成。本品具有强力杀灭各种病菌病毒,并具有保湿润肤护肤,防裂冻,祛斑杀螨去油污,主要用于突发事故中抗炎救震泥石流断水断电干旱无水的情况下,用于清洁消毒双手,能强效广谱杀灭大肠杆菌、金黄色葡萄球菌、伤寒杆菌、痢疾、霍乱等各种致病生物菌,有效杀菌消毒率达99.99%。对汽车抛锚机械油漆人员涂少量就能有效杀菌消毒双手。
Description
技术领域:
本发明公开了一种杀菌消毒无水清洗剂,是属于现代小化工产品无水清洁剂生产配制技术领域。
背景技术:
清洁剂是属于日用小化工产品洗涤剂范畴,对于人体健康和卫生有着非常积极、有效的作用。随着社会的发展、科学技术水平的提高、原料工业的进步,洗涤用品工业得以快速发展。而人们健康意识和文明水平的不断提高,也推动着洗涤剂市场发生日新月异的变化。中国自改革开放以来,国内商品市场上各种优质、多效、安全的洗涤剂、肥皂、香波、浴液等琳琅满目,这充分显示了中国洗涤用品工业的繁荣景象,也同时反映了洗涤剂的基本原料——表面活性剂生产的蓬勃发展。目前市场上洗涤剂产品种类繁多,趋向多样化、专用化,产品越分越细。无疑,洗涤用品将朝着更加专业的方向发展,将出现更多的新产品。
洗涤剂要具备良好的润湿性、渗透性、乳化性、分散性、增溶性及发泡与消泡等性能。这些性能的综合就是洗涤剂的洗涤性能。洗涤剂的产品种类很多,基本上可分为肥皂、合成洗衣粉、液体洗涤剂、固体状洗涤剂及膏状洗涤剂几大类。洗涤剂是配方密集型产品,配方设计和工艺研究是洗涤剂开发的关键,而配方实例的研究、改变与调整,往往可以以较快的速度、较小的代价而获得较满意的配方。需要说明的是,消毒洗涤剂等特殊产品除要考虑技术指标外,还必需考虑有关法规要求。
发明内容:
本发明的目的在于提供一种杀菌消毒无水清洗剂。
本发明技术解决的方案是:
1、一种杀菌消毒无水清洗剂,其特征是:所述蛇油芦荟油润肤护肤杀菌消毒无水清洗剂,按下列质量配比组成%
制备方法:
①先将消毒杀菌剂洗必泰、烷基苄基氯化铵和乙二醛混合,再加入月桂基甜菜碱和水。搅拌均匀在不锈钢加盖反应锅中加入纯水,将卡波泊分3-5次缓慢地加入到纯水中,边加边搅拌,以80-100r/min的速度机械搅拌150min,充分分散得到均匀浑浊分散体,充分溶胀,所得作为甲液;
②在另一不锈钢加盖反应锅中加入部分乙醇,然后加入烷基苄基氯化铵、35%月桂基甜碱、40%乙二醛及三氯生,混合溶解,以50-80r/min的速度机械搅拌10min,直至液体澄清透明,所得作为乙液,密封保存,备用;
③将乙液倒入甲液中,并加入剩余的乙醇,以50-80r/min的速度机械搅拌30min,混合均匀;
④向物料③中依次加入护肤剂、蛇油、芦荟油、茶树油、保湿剂、助溶剂,混合溶解,以80-100r/min的速度机械搅拌10min至均匀分散,加入pH调节剂,调节pH至6.7-8.7,再加入香精,补充纯水至足量后再搅拌20min,即得成品。
芦荟油、茶树油、蛇油、维生素E、卡波树脂有保湿护肤、润肤、防冻裂、祛斑、杀螨虫和去除污垢的作用;乙醇具有杀菌分解污染作用,与洗必泰杀菌消毒剂合用具有强力杀灭各种致病生物菌作用;是强效广谱杀菌剂,对大肠杆菌、金黄色葡萄球菌的杀菌率达99.99%。它们合用有协同杀菌作用。香精可使气味清香自放、释放出茉莉花精油的香味;去离子水可起到稀释的作用。
2、一种杀菌消毒无水清洗剂,其特征是:所述松油醇甲基硅油爽肤洁肤杀菌消毒无水清洗剂,按下列质量配比组成%
制备方法:
取50mL乙醇与蓖麻酸混合使之溶解,然后取出3mL备用,将适量的氢氧化钾加入上述溶液中,持续搅拌至皂化完全(加酚酞试验呈紫红色),再加入备用的3mL溶液,并将二氯甲酚溶于150mL乙醇中所得溶液与松油醇混合,溶解完全后加入上述皂化液中,其余按配方将原料逐一放入去离子水中,进行搅拌,直至分散均匀,全部溶解后即得成品。本品有杀菌消毒作用,并有紫丁香的香味。
本品是一种免水杀菌消毒无水清洁液。使用时,将本剂挤几滴在手上,反复搓擦数次即可,不需用水冲洗。本产品配方合理,去污力强,香味持久,无毒性,对皮肤无刺激,用后感觉滑爽舒适;兼具消毒、清洁剂护肤的功能,使用及携带方便。
3、一种杀菌消毒无水清洗剂,其特征是:所述豆油甘油去污垢清肤杀菌消毒无水清洗剂,按下列质量配比组成%
制备方法:
先将氢氧化钠溶于蒸馏水中,加入豆油于水上加热并不断搅拌至皂化完全(可取溶液1滴加蒸馏水9滴,如无油滴析出即可),再加苯酚及其余物料,按比例将硬脂酸用三乙醇胺按常规方法使其皂化,然后加入凡士林、甘油、洗洁精充分搅拌均匀后,加入防腐剂尼泊金甲酯、香精、水再次搅拌均匀,冷却,再加适量水即得消毒用来苏水。
本品主要用作清洁剂,特别是一种机修工、司机使用的去污垢清肤无水清洁剂。本产品解决了目前无水清洁液生产工艺复杂、价格高、清洗效果差、留有异味、而本品对手皮肤无损害、使用方便的特点。
4、一种杀菌消毒无水清洗剂,其特征是:所述貂油松油VE强力去污滋润肌肤杀菌消毒无水清洗剂,按下列质量配比组成%
制备方法:
按比例取硬脂酸、貂油、鲸蜡、液体石蜡、羊毛脂、硬脂酸钾、聚乙烯醇、三乙醇胺、油酸、月桂醇硫酸钠全部混合一起,放入容器中加热溶解,边溶解边搅拌,在搅拌中加入70℃的水,待混合物体成稀乳状页时,随着搅拌加入凡士林、松油、氧化锌晶须ZnOw广谱强效,然后缓慢搅拌冷却至50℃加入香料,继续搅拌冷却至35℃时,即成无水清洁剂成品。
本品是一种无水清洁剂。使用方法:取少许无水清洁剂,在手上搓擦后,用软纱布或卫生纸即可将手擦干净。由于采用了上述方案,配方中全部使用安全、无毒、无残留的物质,然后加上便捷的制作方法制作而成,材料易取,配方及制备方法简单,制备物质低廉。该配方配伍简单,制备物质低廉,可快捷地清除手上油脂、焦油质、油漆等各种污垢,搓擦时润滑性能好,去污力强,无毒、不刺激皮肤,去异味性好,并对皮肤有滋润保护的作用,擦净后无油腻感,且具有杀菌作用。特别能够适应长途运输、车间修理、室内外油漆等人员使用,有效地解决了无水使残留在手上的油污,刺激皮肤、异味大,易造成皮肤受到伤害的难题。
5、一种杀菌消毒无水清洗剂,其特征是:所述白色矿油溶剂油即效杀菌消毒无水清洗剂,按下列质量配比组成%
制备方法:
①将烷基酚聚氧乙烯10醚、烷基酚聚氧乙烯5醚、油酸、液体石蜡混合搅拌均匀待用;
②将氢氧化钠溶液与纳米钛白粉、壳聚糖纳米粉置于水中,搅拌使其充分混合溶解待用;
③在不断搅拌下,将步骤①制得的溶液倒入步骤②制得的溶液中,继续搅拌5-10min;
④按比例取烷基苯硫酸、白色矿油、斯盘20、卵磷脂、氢氧化钠混合一起,放入容器中加热溶解,边溶解边搅拌,在搅拌中加入70℃的水,待混合物体成稀乳状液时,随着搅拌加入溶剂油、皂片,然后缓慢搅拌冷却至50℃,加入香精,继续搅拌冷却至35℃时,即成无水清洁剂成品。
本品是一种无水清洁剂。使用方法:取少许无水清洁剂,在手上搓擦后,用软纱布或卫生纸即可将手擦干净。由于采用了上述方案,配方中全部使用安全、无毒、无残留的物质,然后加上便捷的制作方法制作而成,材料易取,配方及制备方法简单,制备物质低廉。该配方配伍简单,制备物质低廉,可快捷地清除手上油脂、焦油质、油漆等各种污垢,搓擦时润滑性能好,去污力强,无毒、不刺激皮肤,去异味性好,并对皮肤有滋润保护的作用,擦净后无油腻感,且具有杀菌作用。特别能够适应长途运输、车间修理、室内外油漆等人员使用,有效地解决了无水使残留在手上的油污,刺激皮肤、异味大,易造成皮肤受到伤害的缺陷。
6、一种杀菌消毒无水清洗剂,其特征是:所述芦荟油茶树油护肤保湿灭菌杀菌消毒无水清洗剂,按下列质量配比组成%
制备方法:
按配方比例称取个组分,先在不锈钢加盖反应锅内加入总质量20%的纯水,将卡波泊分3-5次缓慢地加入到纯水中,边加边搅拌,以80-100r/min的速度进行机械搅拌150min,充分分散得一均匀浑浊分散体,静置过夜,充分溶胀,制得甲液。在另一不锈钢加盖反应锅内加入占洗总质量10%的乙醇,然后加入5-氯-2-2,4双氯苯氧酚,混合溶解,以50-80r/min的速度进行机械搅拌10min,直至液体澄清透明,制得乙液,密闭保存,备用。将乙液倒入甲液中,并加入剩余量的乙醇,以50-80r/min的速度搅拌30min混合均匀。然后依次加入壬基酚乙氧基化物、壬基酚聚氧乙烯30醚、75%磷酸芦荟油、护肤季、茶树油、保湿剂、助溶剂,混合溶解。以80-100r/min的速度,充分搅拌10min至均匀分散,加入pH调节剂调节pH值6.7-8.7,再加入香蕉,充分纯水至足量后再搅拌20min,即得本品手用洗涤剂。
上述配方中,乙醇作为溶剂,同时起到消毒的作用,其最佳用量为62%(以质量计)。
茶树油为载体,具有包合溶剂乙醇刺鼻性气味的作用。卡波泊不仅作为增稠剂,同时能增强茶树油的包合作用。5-氯-2-2,4-双氯苯氧酚、壬基酚乙氧基化物及醚为杀菌消毒剂。助溶剂采用非离子型表面活性剂,具有亲水亲油功能,从而有助于内含物与溶剂的共溶,例如可采用吐温-20。pH值调节剂宜采用亲肤性的调节剂,如三乙醇胺。
此外,为增加清洁液的护肤、保湿效果,本品清洁液还可以包括保湿剂,用量为0.1-1.0%,可选用透明质酸、氨基酸乳液、甘油等,其中以甘油为佳:护肤剂,用量为0.5%-1.5%,可选用维生素E、芦荟油等中的一种或多种:香精用量为0.1-0.3%。
本品是一种不需用水冲洗的消毒洗剂。不需用水冲洗,即可对手部清洗消毒,使用方便,尤其适用于野外使用。乙醇含量高达57%-65%,起到消毒灭菌的作用,从而使含氯消毒剂的使用量降至0.05-0.1%,比传统产品用量少,对手部的副作用小。
本清洁液采用高分子包合技术,消除了高浓度乙醇的刺鼻性气味。本产品方法工艺简单,使用设备少。
7、一种杀菌消毒无水清洗剂,其特征是:所述橄榄油蓖麻油广谱持久抑菌杀菌消毒无水清洗剂,按下列质量配比组成%
制备方法:
按配方量分别称取AES、LAS、TX-10、6501于烧杯中,加入去离子水加热搅拌使其溶解,加入EDTA,搅拌溶解后,用稀醋酸调pH值至6.4-6.8,再加入戊二醛及增效剂和稳定剂,充分混合均匀,将护肤剂和氯已啶盐加入醇类物质中,在30-70℃时溶解,形成醇溶液;将增稠剂、氯化钠调节黏度表面活性剂和广谱强效消毒剂氧化锌晶须ZnOw加入去离子水中形成水溶液;然后将水溶液加入醇溶液中,再加入pH调节剂,在均质化速度为1000-10000r/min下搅拌10-30min。
氯已啶盐为醋酸氯已啶和/或葡萄糖酸氯已啶。醇类物质为乙醇或异丙醇。护肤剂为硬脂酸、橄榄油、椰子油、蓖麻油、凡士林、羊毛醇、羊毛脂酸、纯羊毛蜡、乙酸化羊毛豆油、芝麻油、杏仁油、欧洲坚果油、胡桃油、可可油、甘油、卵磷脂、液体石蜡、聚硅氧烷和/或C16醇。
增黏剂为卡波姆940、羟乙基纤维素、羟乙基纤维素、羟丙甲基纤维素、羟甲基纤维素、甲基纤维素、羧甲基纤维素钠、聚乙烯醇和/或聚乙烯吡咯烷酮。
表面活性剂为吐温80、吐温60、吐温20、斯盘60、十二烷基苯钠、聚乙二醇甘油酯、甘油硬脂酸酯和/或PEG20失水山梨醇异酸酯。
pH调节剂为乳酸、二乙醇胺、柠檬酸、酒石酸、苹果酸、琥珀酸、戊二酸、马来酸、谷氨酸、扁桃酸、富马酸和/或磷酸。
本剂具有消毒和洗涤功效,在30℃时消毒洗剂的杀菌效果随其浓度增加、作用时间延长而提高。当戊二醛浓度为200mg/kg时,对金色葡萄球菌作用5min,杀灭效果达到99.99%。可用于洗涤餐具、水果、衣物、被褥、家庭用具等。
质量指标
①中和剂鉴定试验(菌数)菌种为金黄色葡萄球菌ATCC6538。
②定量杀菌试验(微生物平均杀灭率/%)
本品主要用作在特殊情况下无水医用抗菌清洁液。本品产品中含有多种抗菌成分,具有相当强的广谱抑菌、杀菌的作用。在本品中,采用悬液进行定量杀菌试验,在体外抗菌实验中,当作1min,对金黄色葡萄杆菌、铜绿假单胞菌、白色念珠菌和大肠杆菌的平均杀灭率均>99.9%,对伤寒沙门菌作用2min,平均杀灭率均>99.9%。人体消毒实验结果,本品对革兰阳性杆菌、革兰阴性杆菌、金黄色葡萄球菌、腐生葡萄球菌、真菌、肠球菌、变形杆菌有显著的杀菌作用。在作用时间为2min、2h、6h时,左手、右手平均灭菌率都超过99.90%。而在10h时,平均灭菌率超过97.62%。将产品置54℃温箱内储存14d后取出,氯已啶下降率为1.97%。该清洁液具有广谱持久的杀菌效果。
免洗抗菌清洁液含有高效润肤成分,对皮肤起滋润和保湿的作用,且油性润肤成分覆盖在皮肤表面,使抗菌剂不完全接触皮肤,减小了对皮肤的损害。
本品的制备方法工艺简单,设备简单,只需要进行简单的搅拌。合成原料(比如乙醇)来源丰富,价格便宜,成本低。
本发明主要用于突发事故如地震、泥石流等自热灾害,断水、断电、野外工作人员、沙漠干旱地区缺水、少雨地区及突发伤害事故又急需手术的医院、制药、油漆、机械、煤矿、铁矿工人,可快捷地用于无水情况下清洁双手,能强效广谱杀灭大肠埃希菌、金黄色葡萄球菌、伤寒杆菌、痢疾、霍乱等各种传染性致病生物菌,而且杀菌率达99.99%,并起到能有效地防冻裂、滋润、营养肌肤、杀菌、消毒的作用。本发明生产工艺成熟,设备简单,原材料容易解决,经济效益显著,使用方便,机械工人、油漆工人、司机只要去除少量无水清洁剂均匀地涂在手上,用布反复抹擦,就能将手上的油污除掉。由于像雪花膏一样,因此旅途携带方便,特别是在一些无水源的地方,汽车抛锚,司机修车后使用更为特殊,具有润肤和防治皮肤开裂的作用,是广大人们应付突发事故清洁双手、杀菌、消毒必备之宝。
下面结合实施例对本发明进一步说明
具体实施方法:
实施例1:一种杀菌消毒无水清洗剂,其特征是:所述蛇油芦荟油润肤护肤杀菌消毒无水清洗剂,按下列质量配比组成%
实施例2:一种杀菌消毒无水清洗剂,其特征是:所述松油醇甲基硅油爽肤洁肤杀菌消毒无水清洗剂,按下列质量配比组成%
实施例3:一种杀菌消毒无水清洗剂,其特征是:所述豆油甘油去污垢清肤杀菌消毒无水清洗剂,按下列质量配比组成%
实施例4:一种杀菌消毒无水清洗剂,其特征是:所述貂油松油VE强力去污滋润肌肤杀菌消毒无水清洗剂,按下列质量配比组成%
实施例5:一种杀菌消毒无水清洗剂,其特征是:所述白色矿油溶剂油即效杀菌消毒无水清洗剂,按下列质量配比组成%
实施例6:一种杀菌消毒无水清洗剂,其特征是:所述芦荟油茶树油护肤保湿灭菌杀菌消毒无水清洗剂,按下列质量配比组成%
实施例7:一种杀菌消毒无水清洗剂,其特征是:所述橄榄油蓖麻油广谱持久抑菌杀菌消毒无水清洗剂,按下列质量配比组成%
Claims (7)
1.一种杀菌消毒无水清洗剂,其特征是:所述蛇油芦荟油润肤护肤杀菌消毒无水清洗剂,按下列质量配比组成%
2.一种杀菌消毒无水清洗剂,其特征是:所述松油醇甲基硅油爽肤洁肤杀菌消毒无水清洗剂,按下列质量配比组成%
3.一种杀菌消毒无水清洗剂,其特征是:所述豆油甘油去污垢清肤杀菌消毒无水清洗剂,按下列质量配比组成%
4.一种杀菌消毒无水清洗剂,其特征是:所述貂油松油VE强力去污滋润肌肤杀菌消毒无水清洗剂,按下列质量配比组成%
5.一种杀菌消毒无水清洗剂,其特征是:所述白色矿油溶剂油即效杀菌消毒无水清洗剂,按下列质量配比组成%
6.一种杀菌消毒无水清洗剂,其特征是:所述芦荟油茶树油护肤保湿灭菌杀菌消毒无水清洗剂,按下列质量配比组成%
7.一种杀菌消毒无水清洗剂,其特征是:所述橄榄油蓖麻油广谱持久抑菌杀菌消毒无水清洗剂,按下列质量配比组成%
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CN114672373B (zh) * | 2022-03-21 | 2023-09-19 | 深圳市荣强科技有限公司 | 一种金刚石研磨液专用弱碱性清洗剂及其制备方法 |
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