CN106916495A - A kind of moistureproof emulsion paint and preparation method thereof - Google Patents
A kind of moistureproof emulsion paint and preparation method thereof Download PDFInfo
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- CN106916495A CN106916495A CN201710104341.7A CN201710104341A CN106916495A CN 106916495 A CN106916495 A CN 106916495A CN 201710104341 A CN201710104341 A CN 201710104341A CN 106916495 A CN106916495 A CN 106916495A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of moistureproof emulsion paint and preparation method thereof, belongs to emulsion paint preparing technical field.The emulsion paint is made of the raw material of following weight portion：Polyvinyl acetate emulsion, high hydroscopic resin, bentonite, titanium dioxide, coarse whiting, AMP95, anion material, dispersant, defoamer, coalescents, propane diols, preservative, waterproofing agent, deionized water.The preparation method：(1) deionized water, defoamer, dispersant, bentonite, anion material, titanium dioxide and coarse whiting are added into 2~4h of stirring；(2) AMP95, coalescents, propane diols, preservative and remaining defoamer are added, 30~60min is stirred；(3) polyvinyl acetate emulsion, high hydroscopic resin, waterproofing agent and remaining deionized water are added, 30min is stirred；Obtain final product required emulsion paint.Emulsion paint of the present invention can not only be moistureproof, and can dry wall；Anion material can also anion releasing, purified environment.
Description
【Technical field】
The present invention relates to emulsion paint preparing technical field, and in particular to a kind of moistureproof emulsion paint and preparation method thereof.
【Background technology】
With the raising of people's quality of life, house decoration increasingly obtains the attention of people, and emulsion paint is house decoration
In indispensable material, existing emulsion paint moisture-proof function is poor, south China annual March between April it is overcast and rainy constantly,
Air humidity is big, and the globule or flowing water of cohesion often occur on the family brush wall of emulsion paint, not only causes human body not
The mouldy damage of the pleasant Damage by Short Circuit and household supplies, furniture for also resulting in household electrical appliance, therefore provide a kind of nontoxic, viscous
Knot degree is strong and emulsion paint of environment protection damp-proof be those skilled in the art's urgent need to resolve problem.
【The content of the invention】
Goal of the invention of the invention is：To solve above-mentioned problem, it is an object of the invention to provide a kind of breast
Shellac varnish and preparation method thereof, the emulsion paint can not only solve the problems, such as that existing emulsion paint moisture-proof function is poor, therein anti-
Aqua can also prevent the globule wall built-up of " going back to Nan Tian ", wall is kept drying；And the anion material in emulsion paint can also be released
Anion is put, the air of interior has effectively been purified, environmental quality is improve, the health of human body is also advantageous for.
To achieve these goals, the technical solution adopted by the present invention is as follows：
A kind of moistureproof emulsion paint of the present invention, is made of the raw material of following weight portion：Polyvinyl acetate emulsion 80~130
Part, 2.5~5 parts of high hydroscopic resin, 25~50 parts of bentonite, 25~50 parts of titanium dioxide, 30~65 parts of coarse whiting, AMP95 0.7~
1.5 parts, 3~6 parts of anion material, 2.5~5.4 parts of dispersant, 0.5~1.5 part of defoamer, 8~10 parts of coalescents, the third two
2~5 parts of alcohol, 0.5~1 part of preservative, 2~5 parts of waterproofing agent, 230~270 parts of deionized water.
Optimized, present invention protection against the tide emulsion paint is made of the raw material of following weight portion：Polyvinyl acetate emulsion 95~115
Part, 3.0~4.5 parts of high hydroscopic resin, 30~45 parts of bentonite, 30~45 parts of titanium dioxide, 35~55 parts of coarse whiting, AMP95 0.9
~1.3 parts, 3.5~5.5 parts of anion material, 3.0~4.8 parts of dispersant, 0.8~1.2 part of defoamer, coalescents 8.5~
9.5 parts, 2.5~4.5 parts of propane diols, 0.7~0.9 part of preservative, 3~4 parts of waterproofing agent, 240~260 parts of deionized water.
Through further optimization, present invention protection against the tide emulsion paint is made of the raw material of following weight portion：Polyvinyl acetate emulsion
105 parts, 4.0 parts of high hydroscopic resin, 40 parts of bentonite, 40 parts of titanium dioxide, 45 parts of coarse whiting, 1.1 parts of AMP95, anion material
4.5 parts, 3.9 parts of dispersant, 1 part of defoamer, 9 parts of coalescents, 3.5 parts of propane diols, 0.8 part of preservative, 3.5 parts of waterproofing agent,
250 parts of deionized water.
It is formulated according to more than, the preparation method of emulsion paint of the present invention is comprised the following steps：(1) by 2/3rds weight portions
Deionized water, the defoamer of 1/3rd weight portions, dispersant, bentonite, anion material, titanium dioxide and coarse whiting add vacuum
In mixer, the puddler 40~60r/min of revolution speed of mixer, while the dispersion impeller rotational velocity of mixer be 600~
1000r/min, stirs 2~4h；(2) AMP95, coalescents, propane diols, anti-is added in the de-airing mixer of step (1)
Rotten agent and remaining defoamer, then stir 30~60min with the rotating speed of 800~1200r/min；(3) in the stirring of step (2)
Polyvinyl acetate emulsion, high hydroscopic resin, waterproofing agent and remaining deionized water are added in machine, then with 8000r/min's
Rotating speed stirs 30min；Obtain final product required emulsion paint.
Dispersant of the present invention is coupling agent, and the coupling agent is in silane coupler or titanate coupling agent
Kind or two kinds of mixture, with the tension force on coupling agent reduction bentonite, anion material, titanium dioxide and coarse whiting surface, make its table
Face is easier to be soaked by other organic matters, is sufficiently mixed with organic matter.
Waterproofing agent of the present invention is the one kind in mortar waterproof agent or waterproofing agent of organosilicon, can be compensated using waterproofing agent
The contraction of metope other materials, reaches the effect of prestressed of other base materials covered by emulsion paint.
Anion material of the present invention is the mixture of one or more in tourmaline, six ring stones, opal；Bear from
Sub- material can make air ionization, produce anion；And the transition metal ion in the anion material in emulsion paint can be produced
Raw electron hole pair, so as to promote the generation of OH free radicals, formaldehyde is decomposed in the presence of OH free radicals, is reached in clean room
The effect of formaldehyde.
Defoamer of the present invention is the one kind in dimethyl silicone polymer, fluorosilicone or ethylene glycol siloxanes.It is organic
In mixed liquor, because the surface tension of bubble is too big, it is necessary to add the surface tension of defoamer reduction organic liquid mixture, while filling out
Expect to be powder, fully do not form bubble easily between the material particle of wetting, increasing defoamer and coupling agent can also make particle surface
Fully wetting, reaches the purpose of destruction bubble.
In sum, by adopting the above-described technical solution, the beneficial effects of the invention are as follows：Emulsion paint of the present invention is due to adding
Bentonite is entered as inserts, paint film can have been enriched, increased covering power, assigned emulsion paint and be difficult precipitation and good brushing
Property, it also has stronger hygroscopicity and cementability, not only natural environmental-protective and improves the hygroscopicity and cementability of emulsion paint；By
In high hydroscopic resin is added, the moisture absorption effect of space air is played, the room in wet weather is kept drying, not only made one
Body-sensing is felt pleasant and also protects household electrical appliance and household supplies, the drying of furniture.The emulsion paint can not only solve existing breast
The poor problem of shellac varnish moisture-proof function, waterproofing agent therein can also prevent the globule wall built-up of " going back to Nan Tian ", wall is kept drying；
And the anion material in emulsion paint can also anion releasing, effectively purified interior air, improve environmental quality,
It is also advantageous for the health of human body.
【Specific embodiment】
Below by way of specific embodiment, the invention will be further described.
Embodiment 1
A kind of moistureproof emulsion paint of the present invention, is made of the raw material of following weight portion：80 parts of polyvinyl acetate emulsion, height is inhaled
2.5 parts of water-resin, 25 parts of bentonite, 25 parts of titanium dioxide, 30 parts of coarse whiting, 0.7 part of AMP95,3 parts of anion material, dispersant
2.5 parts, 0.5 part of defoamer, 8 parts of coalescents, 2 parts of propane diols, 0.5 part of preservative, 2 parts of waterproofing agent, 230 parts of deionized water.
It is formulated according to more than, the preparation method of emulsion paint of the present invention is comprised the following steps：(1) by 2/3rds weight portions
Deionized water, the defoamer of 1/3rd weight portions, dispersant, bentonite, anion material, titanium dioxide and coarse whiting add vacuum
In mixer, the puddler revolution speed 40r/min of mixer, while the dispersion impeller rotational velocity of mixer is 600r/min,
Stirring 2h；(2) AMP95, coalescents, propane diols, preservative are added in the de-airing mixer of step (1) and remaining is disappeared
Infusion, then stirs 30min with the rotating speed of 800r/min；(3) poly vinyl acetate emulsion is added in the mixer of step (2)
Liquid, high hydroscopic resin, waterproofing agent and remaining deionized water, then stir 30min with the rotating speed of 800r/min；Obtain final product required breast
Shellac varnish.
Dispersant of the present invention is coupling agent, and the coupling agent is in silane coupler or titanate coupling agent
Kind or two kinds of mixture, with the tension force on coupling agent reduction bentonite, anion material, titanium dioxide and coarse whiting surface, make its table
Face is easier to be soaked by other organic matters, is sufficiently mixed with organic matter.
Waterproofing agent of the present invention is mortar waterproof agent, and the contraction of metope other materials can be compensated using waterproofing agent, is reached
To the effect of prestressed of other base materials covered by emulsion paint.
Anion material of the present invention is tourmaline；Tourmaline can make air ionization, produce anion；And latex
Transition metal ion in anion material in paint can produce electron hole pair, so as to promote the generation of OH free radicals, formaldehyde
Decomposed in the presence of OH free radicals, reach the effect of the formaldehyde in clean room.
Defoamer of the present invention is dimethyl silicone polymer.In organic liquid mixture, because the surface tension of bubble is too big,
The surface tension for adding defoamer to reduce organic liquid mixture is needed, while filler is powder, not fully between the material particle of wetting
Bubble is easily formed, increasing defoamer and coupling agent can also be such that particle surface fully soaks, and reach the purpose of destruction bubble.
Embodiment 2
A kind of moistureproof emulsion paint of the present invention, is made of the raw material of following weight portion：130 parts of polyvinyl acetate emulsion is high
5 parts of water-absorbing resin, 50 parts of bentonite, 50 parts of titanium dioxide, 65 parts of coarse whiting, 1.5 parts of AMP95,6 parts of anion material, dispersant
5.4 parts, 1.5 parts of defoamer, 10 parts of coalescents, 5 parts of propane diols, 1 part of preservative, 5 parts of waterproofing agent, 270 parts of deionized water.
It is formulated according to more than, the preparation method of emulsion paint of the present invention is comprised the following steps：(1) by 2/3rds weight portions
Deionized water, the defoamer of 1/3rd weight portions, dispersant, bentonite, anion material, titanium dioxide and coarse whiting add vacuum
In mixer, the puddler revolution speed 60r/min of mixer, while the dispersion impeller rotational velocity of mixer be 600~
1000r/min, stirs 4h；(2) AMP95, coalescents, propane diols, preservative are added in the de-airing mixer of step (1)
With remaining defoamer, 60min is then stirred with the rotating speed of 1200r/min；(3) added in the mixer of step (2) poly-
Acetate emulsion, high hydroscopic resin, waterproofing agent and remaining deionized water, are then stirred with the rotating speed of 8000r/min
30min；Obtain final product required emulsion paint.
Dispersant of the present invention is coupling agent, and the coupling agent is the mixing of silane coupler and titanate coupling agent
Thing, with the tension force on coupling agent reduction bentonite, anion material, titanium dioxide and coarse whiting surface, makes its surface be easier by other
Organic matter is soaked, and is sufficiently mixed with organic matter.
Waterproofing agent of the present invention is waterproofing agent of organosilicon, and the contraction of metope other materials can be compensated using waterproofing agent,
Reach the effect of prestressed of other base materials covered by emulsion paint.
Anion material of the present invention is in six ring stones, opal；Anion material can make air ionization, produce negative
Ion；And the transition metal ion in the anion material in emulsion paint can produce electron hole pair, so as to promote OH freedom
The generation of base, formaldehyde is decomposed in the presence of OH free radicals, reaches the effect of the formaldehyde in clean room.
Defoamer of the present invention is fluorosilicone.In organic liquid mixture because the surface tension of bubble it is too big, it is necessary to plus
Enter the surface tension of defoamer reduction organic liquid mixture, while filler is powder, easy shape between the material particle not soaked fully
Into bubble, increasing defoamer and coupling agent can also be such that particle surface fully soaks, and reach the purpose of destruction bubble.
Embodiment 3
A kind of moistureproof emulsion paint of the present invention, is made of the raw material of following weight portion：95 parts of polyvinyl acetate emulsion, height is inhaled
3.0 parts of water-resin, 30 parts of bentonite, 30 parts of titanium dioxide, 35 parts of coarse whiting, 0.9 part of AMP95,3.5 parts of anion material, dispersant
3.0 parts, 0.8 part of defoamer, 8.5 parts of coalescents, 2.5 parts of propane diols, 0.7 part of preservative, 3 parts of waterproofing agent, deionized water 240
Part.
It is formulated according to more than, the preparation method of emulsion paint of the present invention is comprised the following steps：(1) by 2/3rds weight portions
Deionized water, the defoamer of 1/3rd weight portions, dispersant, bentonite, anion material, titanium dioxide and coarse whiting add vacuum
In mixer, the puddler revolution speed 50r/min of mixer, while the dispersion impeller rotational velocity of mixer is 800r/min,
2~4h of stirring；(2) AMP95, coalescents, propane diols, preservative and residue are added in the de-airing mixer of step (1)
Defoamer, 45min is then stirred with the rotating speed of 1000r/min；(3) poly-vinegar acid second is added in the mixer of step (2)
Alkene emulsion, high hydroscopic resin, waterproofing agent and remaining deionized water, then stir 30min with 800 revs/min of rotating speed；Obtain final product institute
Need emulsion paint.
Dispersant of the present invention is coupling agent, and the coupling agent is titanate coupling agent, with coupling agent reduction swelling
The tension force on soil, anion material, titanium dioxide and coarse whiting surface, makes its surface be easier to be soaked by other organic matters, with organic matter
It is sufficiently mixed.
Waterproofing agent of the present invention is waterproofing agent of organosilicon, and the contraction of metope other materials can be compensated using waterproofing agent,
Reach the effect of prestressed of other base materials covered by emulsion paint.
Anion material of the present invention is opal；Opal can make air ionization, produce anion；And latex
Transition metal ion in anion material in paint can produce electron hole pair, so as to promote the generation of OH free radicals, formaldehyde
Decomposed in the presence of OH free radicals, reach the effect of the formaldehyde in clean room.
Defoamer of the present invention is ethylene glycol siloxanes.In organic liquid mixture, because the surface tension of bubble is too big, need
The surface tension of defoamer reduction organic liquid mixture is added, while filler is powder, is not held between the material particle of wetting fully
Bubble is easily formed, increasing defoamer and coupling agent can also be such that particle surface fully soaks, and reach the purpose of destruction bubble.
Embodiment 4
A kind of moistureproof emulsion paint of the present invention, is made of the raw material of following weight portion：115 parts of polyvinyl acetate emulsion is high
4.5 parts of water-absorbing resin, 45 parts of bentonite, 45 parts of titanium dioxide, 55 parts of coarse whiting, 1.3 parts of AMP95,5.5 parts of anion material, dispersion
4.8 parts of agent, 1.2 parts of defoamer, 9.5 parts of coalescents, 4.5 parts of propane diols, 0.9 part of preservative, 4 parts of waterproofing agent, deionized water
260 parts；Preparation method is same as Example 1.
Embodiment 5
A kind of moistureproof emulsion paint of the present invention, is made of the raw material of following weight portion：
105 parts of polyvinyl acetate emulsion, 4.0 parts of high hydroscopic resin, 40 parts of bentonite, 40 parts of titanium dioxide, 45 parts of coarse whiting,
AMP951.1 parts, 4.5 parts of anion material, 3.9 parts of dispersant, 1 part of defoamer, 9 parts of coalescents, 3.5 parts of propane diols, anti-corrosion
0.8 part of agent, 3.5 parts of waterproofing agent, 250 parts of deionized water；Preparation method is same as Example 2.
Emulsion paint of the present invention can enrich paint film due to adding bentonite as inserts, increase covering power, assign breast
Shellac varnish is difficult precipitation and good brushability, and it also has stronger hygroscopicity and cementability, not only natural environmental-protective and improves
The hygroscopicity and cementability of emulsion paint；Due to adding high hydroscopic resin, the moisture absorption effect of space air is played, make wet weather
In room keep drying, not only make that human body sensory is pleasant also to protect household electrical appliance and household supplies, the drying of furniture.The breast
Shellac varnish can not only solve the problems, such as that existing emulsion paint moisture-proof function is poor, and waterproofing agent therein can also be prevented " going back to Nan Tian "
Globule wall built-up, makes wall keep drying；And the anion material in emulsion paint can also anion releasing, effectively purified room
Interior air, improves environmental quality, is also advantageous for the health of human body.
Claims (8)
1. a kind of moistureproof emulsion paint, it is characterised in that be made of the raw material of following weight portion：Polyvinyl acetate emulsion 80~
130 parts, 2.5~5 parts of high hydroscopic resin, 25~50 parts of bentonite, 25~50 parts of titanium dioxide, 30~65 parts of coarse whiting, AMP95 0.7
~1.5 parts, 3~6 parts of anion material, 2.5~5.4 parts of dispersant, 0.5~1.5 part of defoamer, 8~10 parts of coalescents, third
2~5 parts of glycol, 0.5~1 part of preservative, 2~5 parts of waterproofing agent, 230~270 parts of deionized water.
2. a kind of moistureproof emulsion paint, it is characterised in that be made of the raw material of following weight portion：Polyvinyl acetate emulsion 95~
115 parts, 3.0~4.5 parts of high hydroscopic resin, 30~45 parts of bentonite, 30~45 parts of titanium dioxide, 35~55 parts of coarse whiting, AMP95
0.9~1.3 part, 3.5~5.5 parts of anion material, 3.0~4.8 parts of dispersant, 0.8~1.2 part of defoamer, coalescents 8.5
~9.5 parts, 2.5~4.5 parts of propane diols, 0.7~0.9 part of preservative, 3~4 parts of waterproofing agent, 240~260 parts of deionized water.
3. a kind of moistureproof emulsion paint, it is characterised in that be made of the raw material of following weight portion：105 parts of polyvinyl acetate emulsion,
4.0 parts of high hydroscopic resin, 40 parts of bentonite, 40 parts of titanium dioxide, 45 parts of coarse whiting, 1.1 parts of AMP95,4.5 parts of anion material, point
3.9 parts of powder, 1 part of defoamer, 9 parts of coalescents, 3.5 parts of propane diols, 0.8 part of preservative, 3.5 parts of waterproofing agent, deionized water
250 parts.
4. a kind of preparation method of moistureproof emulsion paint according to claim, it is characterised in that comprise the following steps：(1) will
The deionized water of 2/3rds weight portions, the defoamer of 1/3rd weight portions, dispersant, bentonite, anion material, titanium white
Powder and coarse whiting are added in de-airing mixer, the puddler 40~60r/min of revolution speed of mixer, while the dispersion impeller of mixer
Rotational velocity is 600~1000r/min, stirs 2~4h；(2) AMP95, film forming are added in the de-airing mixer of step (1)
Auxiliary agent, propane diols, preservative and remaining defoamer, then stir 30~60min with the rotating speed of 800~1200r/min；(3)
Polyvinyl acetate emulsion, high hydroscopic resin, waterproofing agent and remaining deionized water are added in the mixer of step (2), so
30min is stirred with the rotating speed of 8000r/min afterwards；Obtain final product required emulsion paint.
5. a kind of preparation method of moistureproof emulsion paint according to claim 4, it is characterised in that the dispersant is coupling
Agent, and the coupling agent is one or two the mixture in silane coupler or titanate coupling agent.
6. a kind of preparation method of moistureproof emulsion paint according to claim 4, it is characterised in that the waterproofing agent is anti-for mortar
One kind in aqua or waterproofing agent of organosilicon.
7. a kind of preparation method of moistureproof emulsion paint according to claim 4, it is characterised in that the anion material is electricity
The mixture of one or more in gas stone, six ring stones, opal.
8. a kind of preparation method of moistureproof emulsion paint according to claim 4, it is characterised in that the defoamer is poly- diformazan
One kind in radical siloxane, fluorosilicone or ethylene glycol siloxanes.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710104341.7A CN106916495A (en) | 2017-02-24 | 2017-02-24 | A kind of moistureproof emulsion paint and preparation method thereof |
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| CN201710104341.7A CN106916495A (en) | 2017-02-24 | 2017-02-24 | A kind of moistureproof emulsion paint and preparation method thereof |
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| CN107189578A (en) * | 2017-07-21 | 2017-09-22 | 国网山东省电力公司临沂供电公司 | A kind of emulsion paint for possessing capability of electromagnetic shielding |
| CN107619627A (en) * | 2017-09-29 | 2018-01-23 | 江苏亿可得电子科技有限公司 | A kind of environment-friendly type television set water-repellent paint formula |
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Application publication date: 20170704 |