CN106916391A - Rice husk composite imitation solid wood board and preparation method thereof - Google Patents

Rice husk composite imitation solid wood board and preparation method thereof Download PDF

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Publication number
CN106916391A
CN106916391A CN201710182687.9A CN201710182687A CN106916391A CN 106916391 A CN106916391 A CN 106916391A CN 201710182687 A CN201710182687 A CN 201710182687A CN 106916391 A CN106916391 A CN 106916391A
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parts
rice husk
solid wood
wood board
imitation solid
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涂孝志
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CHONGQING SHUAIZHIDUN DOOR INDUSTRY Co Ltd
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CHONGQING SHUAIZHIDUN DOOR INDUSTRY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102Azo-compounds
    • C08J9/103Azodicarbonamide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/04N2 releasing, ex azodicarbonamide or nitroso compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2497/00Characterised by the use of lignin-containing materials
    • C08J2497/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

The present invention relates to building material field, and in particular to a kind of rice husk composite imitation solid wood board, it is made up of the component of following weight portion:20 23 parts of the rice husk that 120 160 mesh are crushed to after drying, 20 25 parts of the bentonite, 0.7 1.2 parts of AC foaming agents, 1.5 1.8 parts of foaming control agent, 145 151 parts of polyvinyl chloride resin, 47 parts of stabilizer, the N that are crushed to 240 270 mesh, 0.4 0.6 parts of N' ethylene bis stearamides, 0.2 0.5 parts of glycerin monostearate, 0.3 0.6 parts of coupling agent, 57 parts of haloflex.The composite imitation solid wood board is with rice husk as primary raw material, it is to avoid the destruction caused to environment using wood chip, and does not contain the harmful substances such as formaldehyde.Obtained composite imitation solid wood board flawless, without bubbling, without bulge, without scar, without joint tongue, corner defect.Surface bonding intensity is high.

Description

Rice husk composite imitation solid wood board and preparation method thereof
Technical field
The present invention relates to building material field, and in particular to a kind of rice husk composite imitation solid wood board and preparation method thereof.
Background technology
Composite imitation solid wood board is one of a large amount of construction materials for using in modern society's fitment process, with diversity, Economy, installs facility, and cost-effective, planarization is good, and low-carbon environment-friendly is easy to use, the advantages of comfortableness is good.
However, current composite imitation solid wood board is mostly using wood chip as primary raw material, because current extensive market needs Derivation causes substantial amounts of wood chip demand, causes to consume substantial amounts of trees every year, and vegetation is caused greatly to destroy, and has run counter to and has worked as premise The theory of the ecological, environmental protective advocated.Meanwhile, environment is caused secondary containing poisonous and harmful substances such as formaldehyde mostly in existing formula Pollution.
The content of the invention
In view of this, it is an object of the invention to provide a kind of rice husk composite imitation solid wood board, the composite imitation solid wood board With rice husk as primary raw material, it is to avoid the destruction caused to environment using wood chip, and the harmful substances such as formaldehyde are not contained.
To achieve the above object, the technical solution adopted by the present invention is as follows:
Rice husk composite imitation solid wood board, is made up of the component of following weight portion:The rice husk of 120-160 mesh is crushed to after drying 20-23 parts, be crushed to 240-270 mesh bentonite 20-25 parts, 0.7-1.2 parts of AC foaming agents, foaming control agent 1.5-1.8 parts, Polyvinyl chloride resin 145-151 parts, stabilizer 4-7 parts, N, 0.4-0.6 parts of N'- ethylene bis stearamides, glycerin monostearate 0.2- 0.5 part, coupling agent 0.3-0.6 parts, haloflex 5-7 parts.
The rice husk is one layer of shell outside paddy.
The bentonite also known as bentonite, bentonite or amargosite, are the nonmetallic ores with montmorillonite as main mineral constituent Produce, smectite structure presss from both sides one layer of alumina octahedral is constituted 2 by two silicon-oxy tetrahedrons:1 type crystal structure, due to montmorillonite There is the work of some cations, such as Cu, Mg, Na, K, and these cations and montmorillonite structure cell in the layer structure that structure cell is formed With very unstable, easily it is partially or completely exchanged by other cations, therefore with preferable ion exchangeable.Bentonite.
The AC foaming agents have stable performance, it is nonflammable, do not pollute, it is nonpoisonous and tasteless, to mould not burn into product not The features such as dyeing, decomposition temperature can adjust, not influence solidification and shaping speed.
The foaming control agent has the effect that:Promote the plasticizing of polyvinyl chloride resin;The melt for improving PVC foam material is strong Degree, prevents bubble from merging;Ensure that melt has good mobility.
The polyvinyl chloride resin is important organic synthesis material, and its product has good physical property and chemical property, Polyvinyl chloride resin is polarity amorphism high polymer, there is stronger active force between molecule, is a kind of hard and crisp material.
The stabilizer refers to keep the stabilization such as high polymer plastics, rubber, synthetic fibers, prevents it from decomposing and aging examination Agent.
The coupling agent is also called surface modifier, refers in plastics compounding, to improve synthetic resin and inorganic filler Or a kind of plastic additive of the interface performance of reinforcing material.
Further, the bentonite by sodium bentonite and calcium-base bentonite according to 4:1 mass ratio composition.
Further, the foaming control agent is hydroxy-ethyl acrylate/copolymer-maleic anhydride.
Further, the degree of polymerization of the polyvinyl chloride resin is 650-700.
Further, the stabilizer is made up of castor oil acid calcium, zinc ricinate and epoxidized soybean oil.
Further, the stabilizer by castor oil acid calcium, zinc ricinate and epoxidized soybean oil according to 4:3:3 mass ratio Composition.
It, by obtained a kind of chemical products after oxidation processes, is pale yellow under normal temperature that the epoxidized soybean oil is with soybean oil Color viscous oil-like liquid, is a kind of widely used nontoxic polyvinyl chloride plasticizer and stabilizer:It is good with polyvinyl chloride resin compatibility, Volatility is low, animal migration is small.With excellent heat endurance and photostability, water resistance and oil resistivity are also good, can assign product Good mechanical strength, weatherability and electrical property, and it is non-toxic.
Further, the coupling agent is amino silane.
Preparation method the present invention also aims to protect the rice husk composite imitation solid wood board, it is concretely comprised the following steps:
A. by the polyvinyl chloride resin addition batch mixer of above-mentioned mass parts, 125-130 DEG C is heated to, adds above-mentioned mass parts Haloflex, AC foaming agents, foaming control agent, stabilizer, ethylene bis stearamide and glycerin monostearate, then will be even Connection agent is sprayed into batch mixer, stirs 16-20min;
B. by the rice husk of above-mentioned mass parts and bentonite addition batch mixer, 25-30min is stirred;
C. step B gained mixtures are stirred at room temperature 10-15min, pour into extruder hopper, existed by extruding machine Die shaping at a temperature of 180-200 DEG C;
D. by shaping blank Vacuum shaping mould, then draw, then be placed in immersion in water at room temperature and shape for 50-60 seconds, vacuum Dehumidifying, obtains final product the rice husk composite imitation solid wood board.
Further, polyvinyl chloride resin described in step A is uniformly to be divided into two parts to be divided into add twice, and the coupling agent is uniform It is divided into three parts and is divided into three penetratings.
The beneficial effects of the present invention are:
The composite imitation solid wood board of the application is with rice husk as primary raw material, it is to avoid use that wood chip causes to environment is broken It is bad, and do not contain the harmful substances such as formaldehyde.Obtained composite imitation solid wood board flawless, without bubbling, without bulge, without scar, nothing Joint tongue, corner defect.Surface bonding intensity is high.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will Understand, the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.It is unreceipted in preferred embodiment The experimental technique of actual conditions, generally according to normal condition.
Embodiment 1
Rice husk composite imitation solid wood board, consisting of:The rice husk 20kg of 120-160 mesh is crushed to after drying, is crushed to The sodium bentonite 20kg of 240-270 mesh, calcium-base bentonite 5kg, AC foaming agent 0.7kg, the acrylic acid that are crushed to 240-270 mesh Hydroxyl ethyl ester/copolymer-maleic anhydride 1.5kg, the degree of polymerization are polyvinyl chloride resin 145kg, castor oil acid calcium 1.6kg, the castor-oil plant of 650-700 Zinc oleate 1.2kg, epoxidized soybean oil 1.2kg, N, N'- ethylene bis stearamides 0.4kg, glycerin monostearate 0.5kg, amino Silane 0.6kg, haloflex 5kg.
The preparation method of the rice husk composite imitation solid wood board is:
A. polyvinyl chloride resin is uniformly divided into two parts is divided into and add twice in batch mixer, be heated to 125 DEG C, add chlorinated polyethylene Alkene, AC foaming agents, hydroxy-ethyl acrylate/copolymer-maleic anhydride, castor oil acid calcium, zinc ricinate, epoxidized soybean oil, ethylene Bis-stearamides and glycerin monostearate, then amino silane are uniformly divided into three parts and are divided into three penetrating batch mixers, are stirred Mix 20min;
B. by rice husk, sodium bentonite and calcium-base bentonite addition batch mixer, 25min is stirred;
C. step B gained mixtures are stirred at room temperature 15min, extruder hopper are poured into, by extruding machine at 200 DEG C At a temperature of die shaping;
D. by shaping blank Vacuum shaping mould, then draw, then be placed in immersion in water at room temperature and shape for 5 seconds, vacuum dehumidifying, Obtain final product the rice husk composite imitation solid wood board.
Obtained composite imitation solid wood board flawless, without bubbling, without bulge, without scar, without joint tongue, corner defect.
Embodiment 2
Rice husk composite imitation solid wood board, consisting of:The rice husk 23kg of 120-160 mesh is crushed to after drying, is crushed to The sodium bentonite 16kg of 240-270 mesh, calcium-base bentonite 4kg, AC foaming agent 1.2kg, the acrylic acid that are crushed to 240-270 mesh Hydroxyl ethyl ester/copolymer-maleic anhydride 1.8kg, the degree of polymerization are polyvinyl chloride resin 151kg, castor oil acid calcium 2.8kg, the castor-oil plant of 650-700 Zinc oleate 2.1Kg, epoxidized soybean oil 2.1kg, N, N'- ethylene bis stearamides 0.6kg, glycerin monostearate 0.2kg, amino Silane 0.3kg, haloflex 6kg.
The preparation method of the rice husk composite imitation solid wood board is:
A. polyvinyl chloride resin is uniformly divided into two parts is divided into and add twice in batch mixer, be heated to 130 DEG C, add chlorinated polyethylene Alkene, AC foaming agents, hydroxy-ethyl acrylate/copolymer-maleic anhydride, castor oil acid calcium, zinc ricinate, epoxidized soybean oil, ethylene Bis-stearamides and glycerin monostearate, then amino silane are uniformly divided into three parts and are divided into three penetrating batch mixers, are stirred Mix 18min;
B. by rice husk, sodium bentonite and calcium-base bentonite addition batch mixer, 27min is stirred;
C. step B gained mixtures are stirred at room temperature 12min, extruder hopper are poured into, by extruding machine at 180 DEG C At a temperature of die shaping;
D. by shaping blank Vacuum shaping mould, then draw, then be placed in immersion in water at room temperature and shape for 54 seconds, vacuum is removed It is wet, obtain final product the rice husk composite imitation solid wood board.
Obtained composite imitation solid wood board flawless, without bubbling, without bulge, without scar, without joint tongue, corner defect.
Embodiment 3
Rice husk composite imitation solid wood board, consisting of:The rice husk 21kg of 120-160 mesh is crushed to after drying, is crushed to The sodium bentonite 19.2kg of 240-270 mesh, calcium-base bentonite 4.8kg, AC foaming agent 0.8kg, third that are crushed to 240-270 mesh Olefin(e) acid hydroxyl ethyl ester/copolymer-maleic anhydride 1.6kg, the degree of polymerization are the polyvinyl chloride resin 150kg of 650-700, castor oil acid calcium 2.4kg, Zinc ricinate 1.8kg, epoxidized soybean oil 1.8kg, N, N'- ethylene bis stearamides 0.5kg, glycerin monostearate 0.4kg, Amino silane 0.5kg, haloflex 7kg.
The preparation method of the rice husk composite imitation solid wood board is:
A. polyvinyl chloride resin is uniformly divided into two parts is divided into and add twice in batch mixer, be heated to 126 DEG C, add chlorinated polyethylene Alkene, AC foaming agents, hydroxy-ethyl acrylate/copolymer-maleic anhydride, castor oil acid calcium, zinc ricinate, epoxidized soybean oil, ethylene Bis-stearamides and glycerin monostearate, then amino silane are uniformly divided into three parts and are divided into three penetrating batch mixers, are stirred Mix 16min;
B. by rice husk, sodium bentonite and calcium-base bentonite addition batch mixer, 30min is stirred;
C. step B gained mixtures are stirred at room temperature 10min, extruder hopper are poured into, by extruding machine at 190 DEG C At a temperature of die shaping;
D. by shaping blank Vacuum shaping mould, then draw, then be placed in immersion in water at room temperature and shape for 60 seconds, vacuum is removed It is wet, obtain final product the rice husk composite imitation solid wood board.
Obtained composite imitation solid wood board flawless, without bubbling, without bulge, without scar, without joint tongue, corner defect.
Embodiment 4
Rice husk composite imitation solid wood board, consisting of:The rice husk 22kg of 120-160 mesh is crushed to after drying, is crushed to The sodium bentonite 16kg of 240-270 mesh, calcium-base bentonite 4kg, AC foaming agent 0.9kg, the acrylic acid that are crushed to 240-270 mesh Hydroxyl ethyl ester/copolymer-maleic anhydride 1.7kg, the degree of polymerization are polyvinyl chloride resin 148kg, castor oil acid calcium 2.8kg, the castor-oil plant of 650-700 Zinc oleate 2.1Kg, epoxidized soybean oil 2.1kg, N, N'- ethylene bis stearamides 0.6kg, glycerin monostearate 0.3kg, amino Silane 0.5kg, haloflex 7kg.
The preparation method of the rice husk composite imitation solid wood board is:
A. polyvinyl chloride resin is uniformly divided into two parts is divided into and add twice in batch mixer, be heated to 129 DEG C, add chlorinated polyethylene Alkene, AC foaming agents, hydroxy-ethyl acrylate/copolymer-maleic anhydride, castor oil acid calcium, zinc ricinate, epoxidized soybean oil, ethylene Bis-stearamides and glycerin monostearate, then amino silane are uniformly divided into three parts and are divided into three penetrating batch mixers, are stirred Mix 18min;
B. by rice husk, sodium bentonite and calcium-base bentonite addition batch mixer, 26min is stirred;
C. step B gained mixtures are stirred at room temperature 14min, extruder hopper are poured into, by extruding machine at 195 DEG C At a temperature of die shaping;
D. by shaping blank Vacuum shaping mould, then draw, then be placed in immersion in water at room temperature and shape for 60 seconds, vacuum is removed It is wet, obtain final product the rice husk composite imitation solid wood board.
Obtained composite imitation solid wood board flawless, without bubbling, without bulge, without scar, without joint tongue, corner defect.
Embodiment 5
Rice husk composite imitation solid wood board, consisting of:The rice husk 22kg of 120-160 mesh is crushed to after drying, is crushed to The sodium bentonite 20kg of 240-270 mesh, calcium-base bentonite 5kg, AC foaming agent 1.1kg, the acrylic acid that are crushed to 240-270 mesh Hydroxyl ethyl ester/copolymer-maleic anhydride 1.7kg, the degree of polymerization are polyvinyl chloride resin 145kg, castor oil acid calcium 2kg, the castor oil of 650-700 Sour zinc 1.5kg, epoxidized soybean oil 1.5kg, N, N'- ethylene bis stearamides 0.5kg, glycerin monostearate 0.3kg, amino silicone Alkane 0.4kg, haloflex 6kg.
The preparation method of the rice husk composite imitation solid wood board is:
A. polyvinyl chloride resin is uniformly divided into two parts is divided into and add twice in batch mixer, be heated to 127 DEG C, add chlorinated polyethylene Alkene, AC foaming agents, hydroxy-ethyl acrylate/copolymer-maleic anhydride, castor oil acid calcium, zinc ricinate, epoxidized soybean oil, ethylene Bis-stearamides and glycerin monostearate, then amino silane are uniformly divided into three parts and are divided into three penetrating batch mixers, are stirred Mix 19min;
B. by rice husk, sodium bentonite and calcium-base bentonite addition batch mixer, 28min is stirred;
C. step B gained mixtures are stirred at room temperature 13min, extruder hopper are poured into, by extruding machine at 185 DEG C At a temperature of die shaping;
D. by shaping blank Vacuum shaping mould, then draw, then be placed in immersion in water at room temperature and shape for 50-60 seconds, vacuum Dehumidifying, obtains final product the rice husk composite imitation solid wood board.
Obtained composite imitation solid wood board flawless, without bubbling, without bulge, without scar, without joint tongue, corner defect.
Rice husk composite imitation solid wood board performance test
The burst size of methanal of rice husk composite imitation solid wood board, surface bonding intensity obtained in testing example 1-5, as a result such as Shown in table 1:
The composite imitation solid wood board the performance test results of table 1
Remarks:Burst size of methanal according to《GB/T18580-2001 indoor decorating and refurnishing materials, wood-based plate and its first in product Aldehyde release limitation》Tested;Surface bonding intensity according to《GB/T15102-2006 Surface decorated woodbased panels with paper impregnated thermosetting resins》6.3.8 Section is measured, and sample size is 50.0mm × 50.0mm, and quantity is 6, takes 6 average values of sample surfaces bonding strength.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, this area it is general It is logical it will be appreciated by the skilled person that can be modified to technical scheme or equivalent, without deviating from technical solution of the present invention Objective and scope, it all should cover in the middle of scope of the presently claimed invention.

Claims (9)

1. rice husk composite imitation solid wood board, it is characterised in that be made up of the component of following weight portion:120- is crushed to after drying Rice husk 20-23 parts of 160 mesh, be crushed to 240-270 mesh bentonite 20-25 parts, 0.7-1.2 parts of AC foaming agents, foaming regulation Agent 1.5-1.8 parts, polyvinyl chloride resin 145-151 parts, stabilizer 4-7 parts, N, 0.4-0.6 parts of N'- ethylene bis stearamides, single tristearin Acid glyceride 0.2-0.5 parts, coupling agent 0.3-0.6 parts, haloflex 5-7 parts.
2. rice husk composite imitation solid wood board according to claim 1, it is characterised in that:The bentonite is by sodium bentonite With calcium-base bentonite according to 4:1 mass ratio composition.
3. rice husk composite imitation solid wood board according to claim 1, it is characterised in that:The foaming control agent is acrylic acid Hydroxyl ethyl ester/copolymer-maleic anhydride.
4. rice husk composite imitation solid wood board according to claim 1, it is characterised in that:The degree of polymerization of the polyvinyl chloride resin is 650-700。
5. rice husk composite imitation solid wood board according to claim 1, it is characterised in that:The stabilizer is by castor oil acid Calcium, zinc ricinate and epoxidized soybean oil composition.
6. rice husk composite imitation solid wood board according to claim 5, it is characterised in that:The stabilizer is by castor oil acid Calcium, zinc ricinate and epoxidized soybean oil are according to 4:3:3 mass ratio composition.
7. rice husk composite imitation solid wood board according to claim 1, it is characterised in that:The coupling agent is amino silane.
8. the preparation method of the rice husk composite imitation solid wood board described in claim 1, it is characterised in that concretely comprise the following steps:
A. by the polyvinyl chloride resin addition batch mixer of above-mentioned mass parts, 125-130 DEG C is heated to, adds the chlorination of above-mentioned mass parts Polyethylene, AC foaming agents, foaming control agent, stabilizer, ethylene bis stearamide and glycerin monostearate, then by coupling agent Spray into batch mixer, stir 16-20min;
B. by the rice husk of above-mentioned mass parts and bentonite addition batch mixer, 25-30min is stirred;
C. step B gained mixtures are stirred at room temperature 10-15min, extruder hopper are poured into, by extruding machine in 180- Die shaping at a temperature of 200 DEG C;
D. by shaping blank Vacuum shaping mould, then draw, then be placed in immersion in water at room temperature and shape for 50-60 seconds, vacuum dehumidifying, Obtain final product the rice husk composite imitation solid wood board.
9. the preparation method of rice husk composite imitation solid wood board according to claim 8, it is characterised in that:PVC described in step A Resin is uniformly to be divided into two parts to be divided into add twice, and the coupling agent is that uniformly being divided into three parts is divided into three penetratings.
CN201710182687.9A 2017-03-24 2017-03-24 Rice husk composite imitation solid wood board and preparation method thereof Pending CN106916391A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109251548A (en) * 2018-08-23 2019-01-22 安徽美林凯迪木业有限公司 A kind of composite gate stalk emulating solid wood

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102922838A (en) * 2012-11-17 2013-02-13 中国化学工程第十四建设有限公司 Three-layer coextruded PVC (polyvinylchloride) wood-plastic composite foam board and preparation method thereof
DE202013007233U1 (en) * 2013-08-12 2013-08-26 Patenta Asia Ltd. Foamed / co-extruded board-like hollow chamber profiles made of natural fiber compound
CN103554751A (en) * 2013-10-24 2014-02-05 南京聚锋新材料有限公司 Plastic-wood composite floor and preparation method thereof
CN103790339A (en) * 2014-01-29 2014-05-14 贾留欣 Wood-plastic floor and manufacturing method thereof
CN103965566A (en) * 2014-04-08 2014-08-06 江苏润聚新材料科技有限公司 Environment-friendly single-layer microcellular foam PVC (polyvinyl chloride) wood-plastic composite board and preparation method thereof
CN104448630A (en) * 2014-12-11 2015-03-25 李银亭 Highly filled wood-plastic foaming material and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102922838A (en) * 2012-11-17 2013-02-13 中国化学工程第十四建设有限公司 Three-layer coextruded PVC (polyvinylchloride) wood-plastic composite foam board and preparation method thereof
DE202013007233U1 (en) * 2013-08-12 2013-08-26 Patenta Asia Ltd. Foamed / co-extruded board-like hollow chamber profiles made of natural fiber compound
CN103554751A (en) * 2013-10-24 2014-02-05 南京聚锋新材料有限公司 Plastic-wood composite floor and preparation method thereof
CN103790339A (en) * 2014-01-29 2014-05-14 贾留欣 Wood-plastic floor and manufacturing method thereof
CN103965566A (en) * 2014-04-08 2014-08-06 江苏润聚新材料科技有限公司 Environment-friendly single-layer microcellular foam PVC (polyvinyl chloride) wood-plastic composite board and preparation method thereof
CN104448630A (en) * 2014-12-11 2015-03-25 李银亭 Highly filled wood-plastic foaming material and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
李增学: "《矿井地质手册 地质.安全.资源卷》", 30 September 2015, 煤炭工业出版社 *
齐贵亮: "《塑料压延成型实用技术》", 31 May 2013, 机械工业出版社 *
齐贵亮等: "《常用塑料品种速查手册》", 31 January 2016, 文化发展出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109251548A (en) * 2018-08-23 2019-01-22 安徽美林凯迪木业有限公司 A kind of composite gate stalk emulating solid wood

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Application publication date: 20170704