CN1069107C - Solid slow-releasing detergent and its preparation method - Google Patents
Solid slow-releasing detergent and its preparation method Download PDFInfo
- Publication number
- CN1069107C CN1069107C CN97114247A CN97114247A CN1069107C CN 1069107 C CN1069107 C CN 1069107C CN 97114247 A CN97114247 A CN 97114247A CN 97114247 A CN97114247 A CN 97114247A CN 1069107 C CN1069107 C CN 1069107C
- Authority
- CN
- China
- Prior art keywords
- detergent
- agent
- polymer binder
- preparation
- releasing detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims description 8
- 239000007787 solid Substances 0.000 title claims description 7
- 238000005406 washing Methods 0.000 claims abstract description 21
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 229920005596 polymer binder Polymers 0.000 claims description 7
- 239000002491 polymer binding agent Substances 0.000 claims description 7
- 239000013543 active substance Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 238000005187 foaming Methods 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 229920006122 polyamide resin Polymers 0.000 claims description 3
- 239000011343 solid material Substances 0.000 claims description 3
- 230000002087 whitening effect Effects 0.000 claims description 3
- 102000004190 Enzymes Human genes 0.000 claims description 2
- 108090000790 Enzymes Proteins 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 230000003287 optical effect Effects 0.000 claims 1
- 229920000647 polyepoxide Polymers 0.000 claims 1
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 239000013042 solid detergent Substances 0.000 abstract description 2
- 239000011230 binding agent Substances 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- -1 sulfonated Chemical class 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- OESHKNMIKRWEEW-UHFFFAOYSA-N [Na].C1(=C(C(=CC=C1)S(=O)(=O)O)S(=O)(=O)O)C=CC1=CC=CC=C1 Chemical compound [Na].C1(=C(C(=CC=C1)S(=O)(=O)O)S(=O)(=O)O)C=CC1=CC=CC=C1 OESHKNMIKRWEEW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000012867 bioactive agent Substances 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The present invention relates to a slow-released solid detergent. An anionic surfactant, a non-ionic surfactant and a high-molecular binder are mixed, granulated, dried, etc. to form a spherical detergent. The detergent is suitable for being repeatedly used by a washing machine, and the detergent has the advantages of low washing cost, little environmental pollution, etc.
Description
The present invention relates to a kind of washing composition, especially a kind of solid granular, the slow washing composition of release bioactive agent, and relate to the preparation method of this washing composition.
The major ingredient of washing composition and auxiliary composition mostly are chemical, are one of primary pollution source of sanitary sewage.Because they are stable, biological degradation is difficult to, and influential to human body mostly, therefore study the articles for washing new raw material and new preparation extremely important.
The objective of the invention is to overcome the shortcoming of prior art, a kind of novel washing composition is provided, existing good laundry effect can reduce the pollution to environment again, and can use repeatedly, and each consumption is few, and long service life reduces the laundry cost.
Another object of the present invention provides the preparation method of above-mentioned washing composition, implements easily, and production cost is low.
When doing washing with the conventional washing agent, the part washing composition fails to dissolve fully, and in fact the dissolved part has only minority to be consumed, and a large amount of washing composition is being wasted and polluted.
The solution of the present invention is promoting agent to be added polymer binder to make solid spherical, is suitable for washing machine and uses.Slow release surface promoting agent in laundry processes is with greasy dirt emulsification.Also generating excessive hydroxide ion (OH in the friction process mutually
-), water molecules is activated, and makes the combination of dirt and fiber become soft, makes the easier removal of stain.
Washing composition of the present invention with tensio-active agent and polymer binder as major ingredient.Tensio-active agent can be used anion surfactant and/or nonionogenic tenside, can be one or more mixing, and its total amount is 12～50%.Tensio-active agent commonly used has alkyl benzene sulphonate (ABS) (salt), aliphatic alcohol sulfate, alpha-sulfo fatty acid ester, alkylsulfonate, sulfonated, fatty alcohol polyglycol ether, alkyl phenol polyoxyethylene glycol ether and lipid acid etc.Polymer binder can use resin, and as Resins, epoxy, anhydrides resin, polyamide resin etc., total amount is 6～15%.
In order to improve washing effect, the present invention also adds auxiliary composition: Foam Control, foaming booster, washing assistant, anti-redeposition agent, resist, whitening agent, enzyme, water and thinner.
The preparation method of washing ball of the present invention comprises the steps: (1) solid material crushing screening (120 order); (2) mix; (3) dry (40～50 ℃, 1～3 hour); (4) adding the polymer tackiness agent mixes; (5) granulate; (6) the dry finished product that gets.
The solid detergent of gained of the present invention is a kind of slow-releasing detergent, but repeated multiple times use, each stripping seldom but obtains good washing effect equally.Therefore it has advantages such as the laundry cost is low, environmental pollution is little.And production technique is uncomplicated, implements easily.
Provide embodiment below.
One, prescription (weight %)
(1) main composition:
Tensio-active agent aliphatic alcohol sulfate 7～40
Alkyl polyglycol ether 5～10
Polymer binder Resins, epoxy 3～7
Polyamide resin 3～8 (two) auxiliary compositions:
Foam Control silicone oil 0～0.6
Foaming booster fatty monoethanol amide 0～2
Washing assistant yellow soda ash 0～20
Water glass 0～3
Sodium silicoaluminate 0～20
Disodium ethylene diamine tetraacetate 0～1
Tripoly phosphate sodium STPP 0～30
Anti-redeposition agent carboxymethyl Mierocrystalline cellulose 0～0.5
Resist Starso 0～10
Whitening agent stilbene disulfonic acid sodium 0～0.8
Protease enzyme and/or amylase 0～0.8
Water 0～5
Thinner sodium sulfate surplus
Two, preparation
By above-mentioned prescription, (1) solid material is pulverized earlier, crosses 120 mesh sieves, and (2) are except that tackiness agent, remaining all mixes, and in 40～50 ℃ times dry 3 hours, (4) added tackiness agent, stir in reactor (3), (5) granulate, (6) drying gets finished product.
Claims (3)
1. solid slow-releasing detergent, it is characterized in that concrete component and content thereof: tensio-active agent is 12～50%, polymer binder 6～15%, surplus is an ancillary component, above-mentioned percentage composition is 100 in the composition weight sum all, described tensio-active agent is a kind of or mixture of anion surfactant and/or nonionogenic tenside, and described polymer binder is Resins, epoxy and polyamide resin.
2. according to the described solid slow-releasing detergent of claim 1, it is characterized in that described ancillary component is Foam Control, foaming booster, washing assistant, anti-redeposition agent, resist, optical whitening agent, enzyme, water and thinner.
3. the preparation method of the described solid slow-releasing detergent of claim 1 is characterized in that comprising the steps:
(1) solid material is pulverized earlier, crosses 120 mesh sieves, and except that tackiness agent, all the other all mix (2), (3) in 40-50 ℃ dry 1-3 hour down, (4) add polymer binder and mixing, granulate (5), (6) dry finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97114247A CN1069107C (en) | 1997-08-04 | 1997-09-15 | Solid slow-releasing detergent and its preparation method |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97114204.1 | 1997-08-04 | ||
| CN97114204 | 1997-08-04 | ||
| CN97114247A CN1069107C (en) | 1997-08-04 | 1997-09-15 | Solid slow-releasing detergent and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1219577A CN1219577A (en) | 1999-06-16 |
| CN1069107C true CN1069107C (en) | 2001-08-01 |
Family
ID=25744347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97114247A Expired - Fee Related CN1069107C (en) | 1997-08-04 | 1997-09-15 | Solid slow-releasing detergent and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1069107C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101457184B (en) * | 2008-12-23 | 2011-01-26 | 深圳市成为生物科技有限公司 | Environment friendly dishwashing granule and preparation method thereof |
| CN101457185B (en) * | 2008-12-23 | 2010-10-13 | 深圳市成为生物科技有限公司 | Environment friendly washing granule and preparation method thereof |
| CN102965213B (en) * | 2012-11-29 | 2014-04-09 | 广东工业大学 | Method for coating chitosan slow-release membrane on outer surface of washing ball |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048726A (en) * | 1989-07-14 | 1991-01-23 | 徐云英 | Detergent for water closet |
| CN1096812A (en) * | 1993-06-19 | 1994-12-28 | 靳松 | Detergent for toilet |
-
1997
- 1997-09-15 CN CN97114247A patent/CN1069107C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048726A (en) * | 1989-07-14 | 1991-01-23 | 徐云英 | Detergent for water closet |
| CN1096812A (en) * | 1993-06-19 | 1994-12-28 | 靳松 | Detergent for toilet |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1219577A (en) | 1999-06-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: HONGYE DEVELOPMENT CO., LTD., FUSHAN CITY Free format text: FORMER OWNER: LIU WENQING Effective date: 20030822 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20030822 Address after: Guangdong province Foshan City Gate Road No. 2 Patentee after: Foshan Hongye Integrated Development Corporation Address before: Foshan, Foshan, Guangdong province Yong Fu Road, 7 floor hung long Industrial Co., Ltd. Patentee before: Liu Wenqing |
|
| ASS | Succession or assignment of patent right |
Owner name: FOSHAN YI LI JIE TECHNOLOGY DEVELOPMENT CO., LTD. Free format text: FORMER OWNER: HONGYE DEVELOPMENT CO., LTD., FUSHAN CITY Effective date: 20031215 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20031215 Address after: 8, building 1, 528000 Industrial Zone, Chengnan Road, hi tech Development Zone, Chancheng District, Foshan, Guangdong Patentee after: Foshan Elite Technology Development Co., Ltd. Address before: 528000 Guangdong Province, Foshan city and West Road No. 2 Patentee before: Foshan Hongye Integrated Development Corporation |
|
| ASS | Succession or assignment of patent right |
Owner name: QUANZHOU CITY YILIJIE DAILY NECESSITIES TECHNOLOGY Free format text: FORMER OWNER: FOSHAN ELITE TECHNOLOGY DEVELOPMENT CO., LTD. Effective date: 20100819 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 528000 8/F, BUILDING 1, CHENGNANYUAN INDUSTRY ZONE, NEW+HIGH TECHNOLOGY DEVELOPMENT ZONE, GANGKOU ROAD, CHANCHENG DISTRICT, FOSHAN CITY, GUANGDONG PROVINCE TO: 362211 PANCUO VILLAGE, NEIKENG TOWN, JINJIANG CITY, FUJIAN PROVINCE |
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| TR01 | Transfer of patent right |
Effective date of registration: 20100819 Address after: 362211, Fujian, Jinjiang Province town pit village Patentee after: Quanzhou yilijie commodity Technology Development Co Ltd Address before: 8, building 1, 528000 Industrial Zone, Chengnan Road, hi tech Development Zone, Chancheng District, Foshan, Guangdong Patentee before: Foshan Elite Technology Development Co., Ltd. |
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| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20010801 Termination date: 20120915 |