CN1069107C - Solid slow-releasing detergent and its preparation method - Google Patents

Solid slow-releasing detergent and its preparation method Download PDF

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Publication number
CN1069107C
CN1069107C CN97114247A CN97114247A CN1069107C CN 1069107 C CN1069107 C CN 1069107C CN 97114247 A CN97114247 A CN 97114247A CN 97114247 A CN97114247 A CN 97114247A CN 1069107 C CN1069107 C CN 1069107C
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China
Prior art keywords
detergent
agent
polymer binder
preparation
releasing detergent
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Expired - Fee Related
Application number
CN97114247A
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Chinese (zh)
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CN1219577A (en
Inventor
刘文庆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Quanzhou yilijie commodity Technology Development Co Ltd
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刘文庆
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN97114247A priority Critical patent/CN1069107C/en
Publication of CN1219577A publication Critical patent/CN1219577A/en
Application granted granted Critical
Publication of CN1069107C publication Critical patent/CN1069107C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The present invention relates to a slow-released solid detergent. An anionic surfactant, a non-ionic surfactant and a high-molecular binder are mixed, granulated, dried, etc. to form a spherical detergent. The detergent is suitable for being repeatedly used by a washing machine, and the detergent has the advantages of low washing cost, little environmental pollution, etc.

Description

Solid slow-releasing detergent and preparation method thereof
The present invention relates to a kind of washing composition, especially a kind of solid granular, the slow washing composition of release bioactive agent, and relate to the preparation method of this washing composition.
The major ingredient of washing composition and auxiliary composition mostly are chemical, are one of primary pollution source of sanitary sewage.Because they are stable, biological degradation is difficult to, and influential to human body mostly, therefore study the articles for washing new raw material and new preparation extremely important.
The objective of the invention is to overcome the shortcoming of prior art, a kind of novel washing composition is provided, existing good laundry effect can reduce the pollution to environment again, and can use repeatedly, and each consumption is few, and long service life reduces the laundry cost.
Another object of the present invention provides the preparation method of above-mentioned washing composition, implements easily, and production cost is low.
When doing washing with the conventional washing agent, the part washing composition fails to dissolve fully, and in fact the dissolved part has only minority to be consumed, and a large amount of washing composition is being wasted and polluted.
The solution of the present invention is promoting agent to be added polymer binder to make solid spherical, is suitable for washing machine and uses.Slow release surface promoting agent in laundry processes is with greasy dirt emulsification.Also generating excessive hydroxide ion (OH in the friction process mutually -), water molecules is activated, and makes the combination of dirt and fiber become soft, makes the easier removal of stain.
Washing composition of the present invention with tensio-active agent and polymer binder as major ingredient.Tensio-active agent can be used anion surfactant and/or nonionogenic tenside, can be one or more mixing, and its total amount is 12～50%.Tensio-active agent commonly used has alkyl benzene sulphonate (ABS) (salt), aliphatic alcohol sulfate, alpha-sulfo fatty acid ester, alkylsulfonate, sulfonated, fatty alcohol polyglycol ether, alkyl phenol polyoxyethylene glycol ether and lipid acid etc.Polymer binder can use resin, and as Resins, epoxy, anhydrides resin, polyamide resin etc., total amount is 6～15%.
In order to improve washing effect, the present invention also adds auxiliary composition: Foam Control, foaming booster, washing assistant, anti-redeposition agent, resist, whitening agent, enzyme, water and thinner.
The preparation method of washing ball of the present invention comprises the steps: (1) solid material crushing screening (120 order); (2) mix; (3) dry (40～50 ℃, 1～3 hour); (4) adding the polymer tackiness agent mixes; (5) granulate; (6) the dry finished product that gets.
The solid detergent of gained of the present invention is a kind of slow-releasing detergent, but repeated multiple times use, each stripping seldom but obtains good washing effect equally.Therefore it has advantages such as the laundry cost is low, environmental pollution is little.And production technique is uncomplicated, implements easily.
Provide embodiment below.
One, prescription (weight %)
(1) main composition:
Tensio-active agent aliphatic alcohol sulfate 7～40
Alkyl polyglycol ether 5～10
Polymer binder Resins, epoxy 3～7
Polyamide resin 3～8 (two) auxiliary compositions:
Foam Control silicone oil 0～0.6
Foaming booster fatty monoethanol amide 0～2
Washing assistant yellow soda ash 0～20
Water glass 0～3
Sodium silicoaluminate 0～20
Disodium ethylene diamine tetraacetate 0～1
Tripoly phosphate sodium STPP 0～30
Anti-redeposition agent carboxymethyl Mierocrystalline cellulose 0～0.5
Resist Starso 0～10
Whitening agent stilbene disulfonic acid sodium 0～0.8
Protease enzyme and/or amylase 0～0.8
Water 0～5
Thinner sodium sulfate surplus
Two, preparation
By above-mentioned prescription, (1) solid material is pulverized earlier, crosses 120 mesh sieves, and (2) are except that tackiness agent, remaining all mixes, and in 40～50 ℃ times dry 3 hours, (4) added tackiness agent, stir in reactor (3), (5) granulate, (6) drying gets finished product.

Claims (3)

1. solid slow-releasing detergent, it is characterized in that concrete component and content thereof: tensio-active agent is 12～50%, polymer binder 6～15%, surplus is an ancillary component, above-mentioned percentage composition is 100 in the composition weight sum all, described tensio-active agent is a kind of or mixture of anion surfactant and/or nonionogenic tenside, and described polymer binder is Resins, epoxy and polyamide resin.
2. according to the described solid slow-releasing detergent of claim 1, it is characterized in that described ancillary component is Foam Control, foaming booster, washing assistant, anti-redeposition agent, resist, optical whitening agent, enzyme, water and thinner.
3. the preparation method of the described solid slow-releasing detergent of claim 1 is characterized in that comprising the steps:
(1) solid material is pulverized earlier, crosses 120 mesh sieves, and except that tackiness agent, all the other all mix (2), (3) in 40-50 ℃ dry 1-3 hour down, (4) add polymer binder and mixing, granulate (5), (6) dry finished product.
CN97114247A 1997-08-04 1997-09-15 Solid slow-releasing detergent and its preparation method Expired - Fee Related CN1069107C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN97114247A CN1069107C (en) 1997-08-04 1997-09-15 Solid slow-releasing detergent and its preparation method

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN97114204.1 1997-08-04
CN97114204 1997-08-04
CN97114247A CN1069107C (en) 1997-08-04 1997-09-15 Solid slow-releasing detergent and its preparation method

Publications (2)

Publication Number Publication Date
CN1219577A CN1219577A (en) 1999-06-16
CN1069107C true CN1069107C (en) 2001-08-01

Family

ID=25744347

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97114247A Expired - Fee Related CN1069107C (en) 1997-08-04 1997-09-15 Solid slow-releasing detergent and its preparation method

Country Status (1)

Country Link
CN (1) CN1069107C (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101457184B (en) * 2008-12-23 2011-01-26 深圳市成为生物科技有限公司 Environment friendly dishwashing granule and preparation method thereof
CN101457185B (en) * 2008-12-23 2010-10-13 深圳市成为生物科技有限公司 Environment friendly washing granule and preparation method thereof
CN102965213B (en) * 2012-11-29 2014-04-09 广东工业大学 Method for coating chitosan slow-release membrane on outer surface of washing ball

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1048726A (en) * 1989-07-14 1991-01-23 徐云英 Detergent for water closet
CN1096812A (en) * 1993-06-19 1994-12-28 靳松 Detergent for toilet

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1048726A (en) * 1989-07-14 1991-01-23 徐云英 Detergent for water closet
CN1096812A (en) * 1993-06-19 1994-12-28 靳松 Detergent for toilet

Also Published As

Publication number Publication date
CN1219577A (en) 1999-06-16

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