CN106905860A - A kind of adhesive and its preparation method and application - Google Patents
A kind of adhesive and its preparation method and application Download PDFInfo
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- CN106905860A CN106905860A CN201510980043.5A CN201510980043A CN106905860A CN 106905860 A CN106905860 A CN 106905860A CN 201510980043 A CN201510980043 A CN 201510980043A CN 106905860 A CN106905860 A CN 106905860A
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- Prior art keywords
- component
- adhesive
- butyl
- raw material
- material components
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention belongs to adhering resin field, and in particular to a kind of adhesive, including component A and B component, component A includes following raw material components：Methacrylic acid, methyl methacrylate, 4,4- pair-（T-butyl peroxy）N-butyl pentanoate, 3,3- pair-（T-butyl peroxy）Ethyl butyrate, methacrylic acid diethylene glycol dilaurate, toughened resin, elastomer and initiator；B component includes following raw material components：Methacrylic acid, methyl methacrylate, hydroxyethyl methacrylate, organosilicon polymer, the peroxide diethacetic acid tert-butyl ester, t-butyl peroxybenzoate, toughened resin, elastomer and accelerator.Adhesive of the invention has good mechanical property, bin stability, weatherability, water resistance and cold resistance, at normal temperatures rapid curing, and possesses the good improving soaking of resistance to fuel oil, is particularly well-suited to the manufacture of the product of fuel tanker and similar applications.
Description
Technical field
The invention belongs to adhering resin field, and in particular to a kind of adhesive for fuel tanker and preparation method thereof and should
With.
Background technology
Recently as expanding economy, the civil aircraft demand of China is huge, Boeing's prediction, in following 20 years,
China will need the new aircraft of 3770 framves, be worth 400,000,000,000 dollars.In time span of forecast, China will be always the new people in addition to the U.S.
With the biggest market of aircraft.Boeing is predicted, by 2028, growth and the growth in airfreight market that China Aviation is travelled
Fleet scale will be made to increase to 4610 airplanes, reached more than the three times of earlier 2000s.This level and European two Pius XI
The number of aircraft just runed of recording is suitable.With increasingly strict in the world environmentally friendly law and to energy-saving and emission-reduction requirement, and people
Pursuit to low-carbon (LC) life, California, USA PGEV standards regulation, was per combustion of the airplane in 24h from 2005
Oil leakage quantity is necessarily less than 54mg.This just proposes requirement higher to aircraft fuel tank.
Fuel tank is the important safety component of aircraft, it must firmly, sealing, fire-retardant, impact resistance, not easy to leak.Tradition
Fuel tank is generally manufactured by metal, and plastic fuel tank is because its light weight, moulding are random, easy to process, safety anti-explosive plurality of advantages
Just popularized more and more widely.Aircraft plastic fuel tank is formed by the plastic co-extrusion blowing of difference in functionality, between different layers
Bonding strength is production high-barrier, the key of high performance durable fuel tank, and different layer of plastic material material soak and long-term ring in fuel oil
Not delamination in the change of border, security and stability is high as the most important performance of fuel tanker.
It is a kind of two component adhesive for reacting completely due to being second generation acrylate structural adhesive (abbreviation SGA)；Due to
Have many advantages, such as good toughness, can Sealant, strong applicability, technique it is easy, between more than 20 years for coming out till now
Development at full speed is arrived, has been widely used in fields such as space flight, aircrafts.But the SGA of current major manufacturer productions is
There is a problem of same：Insufficient strength is high, period of storage is too short, and this two big shortcoming seriously hinders the expansion of its range of application.
The content of the invention
The object of the invention is directed to the above-mentioned weak point of prior art, there is provided a kind of adhesive strength is high, period of storage is long, oil resistivity
The adhesive of fuel tanker that can be good.
To achieve the above object, the present invention is to take what following concrete technical scheme was realized：
First aspect present invention provides a kind of adhesive, including component A and B component；
Component A includes following raw material components and mass percent：
Methacrylic acid (MAA) 3~5%；
Methyl methacrylate (MMA) 25~30%；
4,4- double-(t-butyl peroxy) n-butyl pentanoates 15~20%；
3,3- double-(t-butyl peroxy) ethyl butyrates 15~20%；
Methacrylic acid diethylene glycol dilaurate 10~15%；
Toughened resin 5~10%, such as 5~8% or 8~10%；
Elastomer 1~5%；
Initiator 2~5%；
B component includes following raw material components and mass percent：
Methacrylic acid (MAA) 1~5%；
Methyl methacrylate (MMA) 25~30%；
Hydroxyethyl methacrylate 10~15%；
Organosilicon polymer 1~5%；
The peroxide diethacetic acid tert-butyl ester 15~20%；
T-butyl peroxybenzoate 15~20%；
Toughened resin 10~15%；
Elastomer 2~5%；
Accelerator 2~5%.
Preferably, the mass ratio of component A and B component is 1: 1~5.
Preferably, the toughened resin is selected from acrylonitrile-butadiene-styrene resin (ABS), polymethyl methacrylate
(PMMA), in methyl methacrylate, butadiene, styrene copolymer (MBS) and polysulfones (PSF)
Plant or various.
Preferably, body be selected from chlorosulfonated polyethylene, nitrile rubber, neoprene, fluorine-containing rubber and polyurethane in one kind or
It is various.
Preferably, agent is selected from benzoyl peroxide, isopropyl benzene hydroperoxide, TBHP and methyl ethyl ketone peroxide
One or more.
Preferably, silicon polymer is the organopolysiloxane with silicon-oxygen key as main chain.
Preferably, agent is selected from one or more in amine, Thiourea and aldehyde-amine condensate.
Preferably, agent be selected from N, N- dimethyl-paratoluidines, vinylthiourea, tetramethyl thiourea, ferric acetyl acetonade,
One or more in vanadium acetylacetonate, triethylamine, cobalt naphthenate and lead naphthenate.
Second aspect present invention provides the preparation method of above-mentioned adhesive, comprises the following steps：
1) by component A mass percent by toughened resin, methacrylic acid, 4,4- it is double-(t-butyl peroxy) valeric acid just
Butyl ester, 3,3- be double-and (t-butyl peroxy) ethyl butyrate, initiator be miscible in methyl methacrylate, forms basic
Glue；Other raw materials are added by the raw material components and mass percent of component A, the component A is obtained；
2) by B component mass percent by toughened resin, methacrylic acid, the peroxide diethacetic acid tert-butyl ester, peroxide benzene first
Tert-butyl acrylate, accelerator are miscible in methyl methacrylate, form basic glue；By the raw material components and quality of B component
Percentage adds other raw materials, obtains the B component.
During using adhesive, by component A and B component in mass ratio 1：1 stirs.
Third aspect present invention provides the purposes of above-mentioned adhesive, for fuel tanker.
Beneficial effects of the present invention are：
(1) adhesive tensile shear strength of the invention it is high, with good bin stability, weatherability, water resistance and cold-resistant
Property；
(2) adhesive of the invention rapid curing at normal temperatures, and possess the good improving soaking of resistance to fuel oil, it is particularly well-suited to
The manufacture of the product of fuel tanker and similar applications.
Specific embodiment
Technical scheme is illustrated below by way of specific instantiation.It should be understood that one or more sides that the present invention is mentioned
Method step do not repel before and after the combination step also exist other method step or between the step of these are specifically mentioned also
May be inserted into other method step；It should also be understood that these embodiments are merely to illustrate the present invention rather than limit model of the invention
Enclose.And, unless otherwise indicated, the numbering of various method steps is only the convenient tool for differentiating various method steps, rather than is limitation
The ordering of various method steps limits enforceable scope of the invention, and its relativeness is altered or modified, without substantive change
In the case of more technology contents, when being also considered as enforceable category of the invention.
Embodiment 1
Adhesive each component and content (mass fraction %) for fuel tanker are shown in Table 1：
Table 1
Wherein：Methyl methacrylate, butadiene, styrene copolymer (MBS) are purchased from Nanjing Xin Kun Chemical Co., Ltd.s
41；
Chlorosulfonated polyethylene is purchased from Dongguan City Ming Hao plastic raw materials Co., Ltd Hypalon, 4085；
Organosilicon polymer is purchased from Co., Ltd 6697 in DOW Chemical.
Specific preparation method is as follows：
1) by component A mass percent by toughened resin, MAA, 4,4- it is double-(t-butyl peroxy) n-butyl pentanoate,
3,3- double-(t-butyl peroxy) ethyl butyrates, initiator are miscible in MMA at normal temperatures, form basic glue；
Other raw materials are added by the raw material components and mass percent of component A, the component A is obtained；
2) by B component mass percent by toughened resin, MAA, the peroxide diethacetic acid tert-butyl ester, benzoyl hydroperoxide uncle
Butyl ester, accelerator are miscible in MMA at normal temperatures, form basic glue；By the raw material components and quality percentage of B component
Than adding other raw materials, the B component is obtained.
Component A and B component can be installed with aluminium collapsible tube, back cover is made adhesive for fuel tanker.
Embodiment 2
Adhesive each component and content (mass fraction %) for fuel tanker are shown in Table 2：
Table 2
Wherein：Acrylonitrile-butadiene-styrene resin (ABS) connects Industrial Co., Ltd., the trade mark 8391 purchased from Shanghai three；
Nitrile rubber is purchased from Shanghai Sheng Yi plastic cement Science and Technology Ltd., the trade mark 3095；
Organosilicon polymer is purchased from Co., Ltd 6697 in DOW Chemical.
Specific preparation method is as follows：
1) by component A mass percent by toughened resin, MAA, 4,4- it is double-(t-butyl peroxy) n-butyl pentanoate,
3,3- double-(t-butyl peroxy) ethyl butyrates, initiator are miscible in MMA at normal temperatures, form basic glue；
Other raw materials are added by the raw material components and mass percent of component A, the component A is obtained；
2) by B component mass percent by toughened resin, MAA, the peroxide diethacetic acid tert-butyl ester, benzoyl hydroperoxide uncle
Butyl ester, accelerator are miscible in MMA at normal temperatures, form basic glue；By the raw material components and quality percentage of B component
Than adding other raw materials, the B component is obtained.
Component A and B component can be installed with aluminium collapsible tube, back cover is made adhesive for fuel tanker.
Embodiment 3
Adhesive each component and content (mass fraction %) for fuel tanker are shown in Table 3：
Table 3
Wherein：Polymethyl methacrylate (PMMA) plastifies Science and Technology Ltd., trade mark SR6500 purchased from Shanghai Fu Run；
Neoprene is purchased from Shanghai treasure Chemical Co., Ltd., trade mark TA-85；
Organosilicon polymer is purchased from Co., Ltd 6697 in DOW Chemical.
Specific preparation method is as follows：
1) by component A mass percent by toughened resin, MAA, 4,4- it is double-(t-butyl peroxy) n-butyl pentanoate,
3,3- double-(t-butyl peroxy) ethyl butyrates, initiator are miscible in MMA at normal temperatures, form basic glue；
Other raw materials are added by the raw material components and mass percent of component A, the component A is obtained；
2) by B component mass percent by toughened resin, MAA, the peroxide diethacetic acid tert-butyl ester, benzoyl hydroperoxide uncle
Butyl ester, accelerator are miscible in MMA at normal temperatures, form basic glue；By the raw material components and quality percentage of B component
Than adding other raw materials, the B component is obtained.
Embodiment 4
Adhesive each component and content (mass fraction %) for fuel tanker are shown in Table 4：
Table 4
Wherein：Polysulfones (PSF) plastifies Science and Technology Ltd., trade mark S6010 purchased from Shanghai Fu Run；
Polyurethane is purchased from Hubei Xin Mingtai Chemical Co., Ltd.s, trade mark 9058CX；
Organosilicon polymer is purchased from Co., Ltd 6697 in DOW Chemical.
Specific preparation method is as follows：
1) by component A mass percent by toughened resin, MAA, 4,4- it is double-(t-butyl peroxy) n-butyl pentanoate,
3,3- double-(t-butyl peroxy) ethyl butyrates, initiator are miscible in MMA at normal temperatures, form basic glue；
Other raw materials are added by the raw material components and mass percent of component A, the component A is obtained；
2) by B component mass percent by toughened resin, MAA, the peroxide diethacetic acid tert-butyl ester, benzoyl hydroperoxide uncle
Butyl ester, accelerator are miscible in MMA at normal temperatures, form basic glue；By the raw material components and quality percentage of B component
Than adding other raw materials, the B component is obtained.
Component A and B component can be installed with aluminium collapsible tube, back cover is made adhesive for fuel tanker.
To adhesive obtained in above-described embodiment, by component A and B component in mass ratio 1:1 stirs, and measures its performance number
According to being shown in Table 1.
Tensile shear strength：GB/T6329-1996；
Bin stability：GB/T 6753.3-1986；
Weatherability：GB/T 3511-2008；
Water resistance：GB/T 1733-93；
The improving soaking of resistance to fuel oil：GB/T 1734-93；
Hardening time：GB/T 14074.7-2006.
Table 1
It can be seen from the results above that fuel tanker of the invention adhesive good mechanical properties, impact strength is high, good toughness,
And with long-term oil resistance.
The above-described embodiments merely illustrate the principles and effects of the present invention, not for the limitation present invention.It is any to be familiar with this skill
The personage of art all can carry out modifications and changes under without prejudice to spirit and scope of the invention to above-described embodiment.Therefore, such as
Those of ordinary skill in the art completed under without departing from disclosed spirit and technological thought all
Equivalent modification or change, should be covered by claim of the invention.
Claims (9)
1. a kind of adhesive, it is characterised in that including component A and B component；
Component A includes following raw material components and mass percent：
B component includes following raw material components and mass percent：
2. adhesive as claimed in claim 1, it is characterised in that the toughened resin is selected from acrylonitrile-butadiene-styrene (ABS) tree
Fat, polymethyl methacrylate, one kind in methyl methacrylate, butadiene, styrene copolymer and polysulfones or
It is various.
3. adhesive as claimed in claim 1, it is characterised in that the elastomer be selected from chlorosulfonated polyethylene, nitrile rubber,
One or more in neoprene, fluorine-containing rubber and polyurethane.
4. adhesive as claimed in claim 1, it is characterised in that the initiator is selected from benzoyl peroxide, isopropylbenzene peroxidating
One or more in hydrogen, TBHP and methyl ethyl ketone peroxide.
5. adhesive as claimed in claim 1, it is characterised in that the organosilicon polymer is having with silicon-oxygen key as main chain
Machine polysiloxanes.
6. adhesive as claimed in claim 1, it is characterised in that the accelerator is selected from amine, Thiourea and aldehyde-amine condensate
In one or more.
7. adhesive as claimed in claim 6, it is characterised in that the accelerator is selected from N, N- dimethyl-paratoluidines,
In vinylthiourea, tetramethyl thiourea, ferric acetyl acetonade, vanadium acetylacetonate, triethylamine, cobalt naphthenate and lead naphthenate
One or more.
8. the preparation method of a kind of adhesive as described in claim 1 to 7 is any, it is characterised in that comprise the following steps：
1) by component A mass percent by toughened resin, methacrylic acid, 4,4- it is double-(t-butyl peroxy) valeric acid just
Butyl ester, 3,3- be double-and (t-butyl peroxy) ethyl butyrate, initiator be miscible in methyl methacrylate, forms basic
Glue；Other raw materials are added by the raw material components and mass percent of component A, the component A is obtained；
2) by B component mass percent by toughened resin, methacrylic acid, the peroxide diethacetic acid tert-butyl ester, peroxide benzene first
Tert-butyl acrylate, accelerator are miscible in methyl methacrylate, form basic glue；By the raw material components and quality of B component
Percentage adds other raw materials, obtains the B component.
9. a kind of adhesive as described in claim 1 to 7 is any is used for fuel tanker.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510980043.5A CN106905860A (en) | 2015-12-23 | 2015-12-23 | A kind of adhesive and its preparation method and application |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510980043.5A CN106905860A (en) | 2015-12-23 | 2015-12-23 | A kind of adhesive and its preparation method and application |
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| CN106905860A true CN106905860A (en) | 2017-06-30 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1397621A (en) * | 2001-07-12 | 2003-02-19 | 住友金属矿山株式会社 | Resin bonding type compsn. for magnet and resin bonding type magnet using same |
| US20080142158A1 (en) * | 2006-12-19 | 2008-06-19 | Dershem Stephen M | Hydrolytically resistant thermoset monomers |
| CN102329574A (en) * | 2011-08-12 | 2012-01-25 | 上海邦中高分子材料有限公司 | Tackiness agent for automobile tank |
| CN104479594A (en) * | 2014-12-31 | 2015-04-01 | 广州鹿山新材料股份有限公司 | Hot melt glue used for gluing non-polar materials and preparation method thereof |
| CN104530990A (en) * | 2014-12-19 | 2015-04-22 | 广东三和化工科技有限公司 | Dual-component acrylate adhesive and preparation method thereof |
-
2015
- 2015-12-23 CN CN201510980043.5A patent/CN106905860A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1397621A (en) * | 2001-07-12 | 2003-02-19 | 住友金属矿山株式会社 | Resin bonding type compsn. for magnet and resin bonding type magnet using same |
| US20080142158A1 (en) * | 2006-12-19 | 2008-06-19 | Dershem Stephen M | Hydrolytically resistant thermoset monomers |
| CN102329574A (en) * | 2011-08-12 | 2012-01-25 | 上海邦中高分子材料有限公司 | Tackiness agent for automobile tank |
| CN104530990A (en) * | 2014-12-19 | 2015-04-22 | 广东三和化工科技有限公司 | Dual-component acrylate adhesive and preparation method thereof |
| CN104479594A (en) * | 2014-12-31 | 2015-04-01 | 广州鹿山新材料股份有限公司 | Hot melt glue used for gluing non-polar materials and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 《化工百科全书》编辑委员会: "《化工百科全书》", 30 September 1998, 化学工业出版社 * |
| 李子东等: "《胶黏剂助剂》", 30 June 2009, 化学工业出版社 * |
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