CN106903382A - A kind of die cavity electric spark machining working solution component monitoring system - Google Patents

A kind of die cavity electric spark machining working solution component monitoring system Download PDF

Info

Publication number
CN106903382A
CN106903382A CN201710123598.7A CN201710123598A CN106903382A CN 106903382 A CN106903382 A CN 106903382A CN 201710123598 A CN201710123598 A CN 201710123598A CN 106903382 A CN106903382 A CN 106903382A
Authority
CN
China
Prior art keywords
working solution
unit
die cavity
electric spark
monitoring system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710123598.7A
Other languages
Chinese (zh)
Other versions
CN106903382B (en
Inventor
韩强
李思钰
何勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Donghua University
National Dong Hwa University
Original Assignee
Donghua University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Donghua University filed Critical Donghua University
Priority to CN201710123598.7A priority Critical patent/CN106903382B/en
Publication of CN106903382A publication Critical patent/CN106903382A/en
Application granted granted Critical
Publication of CN106903382B publication Critical patent/CN106903382B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23HWORKING OF METAL BY THE ACTION OF A HIGH CONCENTRATION OF ELECTRIC CURRENT ON A WORKPIECE USING AN ELECTRODE WHICH TAKES THE PLACE OF A TOOL; SUCH WORKING COMBINED WITH OTHER FORMS OF WORKING OF METAL
    • B23H1/00Electrical discharge machining, i.e. removing metal with a series of rapidly recurring electrical discharges between an electrode and a workpiece in the presence of a fluid dielectric
    • B23H1/02Electric circuits specially adapted therefor, e.g. power supply, control, preventing short circuits or other abnormal discharges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23HWORKING OF METAL BY THE ACTION OF A HIGH CONCENTRATION OF ELECTRIC CURRENT ON A WORKPIECE USING AN ELECTRODE WHICH TAKES THE PLACE OF A TOOL; SUCH WORKING COMBINED WITH OTHER FORMS OF WORKING OF METAL
    • B23H11/00Auxiliary apparatus or details, not otherwise provided for

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The present invention relates to a kind of die cavity electric spark machining working solution component monitoring system, including gaseous mixture sample preparation unit, detector gas circuit unit, embedded control unit and computer digital animation unit;The gaseous mixture sample preparation unit includes the working solution sampling interface, degasser and the gaseous mixture sample feeding device that are sequentially connected, and the degasser and gaseous mixture sample feeding device are connected with embedded control unit respectively;The gaseous mixture sample feeding device is also connected with the detector gas circuit unit;The detector gas circuit unit is connected with the embedded control unit and computer digital animation unit respectively;It is connected by fieldbus between the embedded control unit and computer digital animation unit.

Description

A kind of die cavity electric spark machining working solution component monitoring system
Technical field
The present invention relates to die cavity spark erosion technique field, more particularly to a kind of die cavity electric spark machining working solution into Divide monitoring system.
Background technology
Die cavity electrical discharge machining is come ablation based on the galvano-cautery phenomenon between instrument and workpiece during pulse feature spark discharge Unnecessary metal, to reach size to part, shape and the predetermined processing request of surface quality.Ensure process just Often realize to make often to keep certain discharging gap between tool-electrode and working solution finished surface first, secondly spark is put Electricity must be instantaneous pulsed discharge.And spark discharge must be carried out in having the liquid medium of certain insulating properties, for example Kerosene, saponification liquor etc. mix organic liquid medium.Also known as working solution, it must have dielectric strength higher to liquid medium, to have Beneficial to the spark discharge for producing pulse feature.Liquid medium can also be the small bits of metal, the carbon produced in edm process simultaneously The galvanic corrosion product such as black suspends from discharging gap and excludes, and has preferable cooling effect to electrode and workpiece surface.
Medium in die cavity edm process between instrument and piece pole is logical by ionizing, puncturing, being formed electric discharge Behind road, for the electric energy that processing is provided is transformed into kinetic energy, kinetic energy is transformed into heat energy again by collision rift.Then in passage, it is positive and negative Pole surface respectively becomes instant therm source, reaches temperature very high.High temperature first vaporizes work liquid medium in passage, and then hot tearing Hydrogen, carbon dioxide, some hydrocarbon gas are cracked into after decomposition gasification, such as kerosene hydrocarbon working solution high temperature and are dissociated Carbon etc..These catabolites cause the composition of working solution to change in being dissolved in working solution, it is therefore desirable to working solution into Part carries out real-time monitoring.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of die cavity electric spark machining working solution component monitoring system, real Now to the analysis of mixed gas composition in electric spark machining working solution.
The technical solution adopted for the present invention to solve the technical problems is:There is provided a kind of die cavity electric spark machining working solution into Divide at monitoring system, including gaseous mixture sample preparation unit, detector gas circuit unit, embedded control unit and computer data Reason unit;The gaseous mixture sample preparation unit includes the working solution sampling interface, degasser and the mixing gas sample that are sequentially connected Product sampling device, the degasser and gaseous mixture sample feeding device are connected with embedded control unit respectively;The mixing Gas sample product sampling device is also connected with the detector gas circuit unit;The detector gas circuit unit respectively with the embedded control Unit processed is connected with computer digital animation unit;Pass through between the embedded control unit and computer digital animation unit Fieldbus is connected.
The working solution sampling interface is the sampling interface agency of two-way operation liquid, by ablation particle filter, electric three passes Valve and liquid storage fuel tank realize that the row of returning after terminating for the sampling and constituent analysis to die cavity electric machining working solution realizes work Make the recycling of liquid.
The detector gas circuit unit includes the injection port, the CO that are sequentially connected2The detection of detector, chromatograph box and zirconium oxide Device;The input of the injection port is also associated with the output end of gas circuit control element, the input of the gas circuit control element with Carrier gas is connected.
The Zirconia detector is connected by signal attenuation module with computer digital animation unit.
It is heating furnace device outside earthenware, in heating furnace in the tubular zirconium-oxide insertion earthenware of the Zirconia detector Pt100 temperature sensors are housed in device.
The CO2Detector includes infrared gas sensor and infrared light supply kit;The infrared gas sensor On have two optical filters, one of optical filter only allows CO2The wavelength that molecule can absorb is that 4.26 μm of infrared light passes through, For detecting CO2Concentration;Another optical filter constitutes 4.00 μm of optical filter passages, for detecting in air chamber except CO2In addition The change in concentration situation of other mixed gas.
The embedded control unit carries out bidirectional information by the way of bus communication with computer digital animation unit Interaction, is connected using analog-to-digital conversion and digital quantity interface mode with detector gas circuit unit, is driven using digital quantity interface and power Moving cell is connected with gaseous mixture sample preparation unit.
The embedded control unit is by temperature closed loop system to gaseous mixture sample preparation unit and detector gas circuit list The temperature of unit is controlled.
The embedded control unit receives the information of amount of liquid and amount of gas evolved in degasser, and is passed through according to relevant information Cross the amount of gas evolved of switch and aperture state the guarantee constant volume working solution that corresponding valve is controlled after calculating is processed, it is ensured that electricity fire Spend the accurate of processing work liquid constituent analysis.
The computer digital animation unit is using related chromatographic work station software and working solution constituent analysis software reality Now to the analysis and judge of die cavity electric spark machining working solution composition and processing gap state and processing effect.
Beneficial effect
As a result of above-mentioned technical scheme, the present invention compared with prior art, has the following advantages that and actively imitates Really:The present invention can realize the analysis to mixed gas composition in electric spark machining working solution, and electric spark is judged on this basis Processing gap and the assessment and anticipation of machining state, it is ensured that the stability of different operating mode lower impressions edm processes and carry Processing efficiency high and processing effect.
Brief description of the drawings
Fig. 1 is monitoring system general structure schematic diagram of the invention;
Fig. 2 is embedded control unit structural representation of the invention;
Fig. 3 is Zirconia detector structural representation of the invention;
Fig. 4 is CO of the present invention2Detector arrangement schematic diagram.
Specific embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention Rather than limitation the scope of the present invention.In addition, it is to be understood that after the content for having read instruction of the present invention, people in the art Member can make various changes or modifications to the present invention, and these equivalent form of values equally fall within the application appended claims and limited Scope.
Embodiments of the present invention are related to a kind of die cavity electric spark machining working solution component monitoring system, including mixing gas sample Product preparation unit, detector gas circuit unit, embedded control unit and computer digital animation unit;The gaseous mixture sample system Standby unit includes the working solution sampling interface, degasser and the gaseous mixture sample feeding device that are sequentially connected, the degasser It is connected with embedded control unit respectively with gaseous mixture sample feeding device;The gaseous mixture sample feeding device also with the inspection Device gas circuit unit is surveyed to be connected;The detector gas circuit unit respectively with the embedded control unit and computer digital animation list Unit is connected;It is connected by fieldbus between the embedded control unit and computer digital animation unit.
Wherein, the embedded control unit is carried out two-way by the way of bus communication with computer digital animation unit Information exchange, is connected, using digital quantity interface and work(using analog-to-digital conversion and digital quantity interface mode with detector gas circuit unit Rate driver element is connected with gaseous mixture sample preparation unit.Computer digital animation unit is by PCI board card and universal serial bus and oxygen Changing zirconium detector and embedded control unit carries out information exchange.Using related chromatographic work station software and working solution composition point Analysis software realizes the analysis and judge to die cavity electric spark machining working solution composition and processing gap state and processing effect.
Based on the present invention is for die cavity electrical discharge machining chats oil type and kerosene working solution, with reference to chromatographic technique, The regular sample introduction of headspace sampling method is used by die cavity edm process, with chromatographic technique quantitative analysis combination mass-spectrometric technique The method of qualitative analysis, it is established that component content and processing stability and the pass of processing efficiency and processing effect in different operating liquid Coefficient evidence.Data are analyzed and modeled using the method for mathematical statistics and probability theory, is that die cavity electrical discharge machining is put in the future Electricity condition detection means, processing gap state and crudy analysis and the high speed synthesis type electrical discharge machining work of high-efficiency environment friendly Liquid provides basis.
A kind of die cavity electric spark machining working solution component monitoring system as shown in Figure 1, including sampled by working solution and the row of returning The gaseous mixture sample preparation unit that circulation loop is constituted, by deaerating after sample gas and carrier gas sample introduction analysis circuit and detector telecommunications The detector gas circuit unit that number collection and air circuit needed for monitoring analysis are constituted, embedded control unit and soft equipped with research and application The computer digital animation unit of part.Wherein, the working solution sampling interface in gaseous mixture sample preparation unit uses two-way operation The sampling interface agency of liquid, including ablation particle filter, electric three passes valve and liquid storage fuel tank, for working die cavity electric machining The sampling and constituent analysis of liquid terminate after return row, realize the recycling of working solution.The detector gas circuit unit include according to The injection port of secondary connection, CO2Detector, chromatograph box and Zirconia detector;The input of the injection port is also associated with gas The output end of road control element, the input of the gas circuit control element is connected with carrier gas.
Embedded control unit as shown in Figure 2, mainly realizes in system between gas circuit and working solution loop and processor The two-way intercommunication of various status informations, is the accurate offer basis of gas component analysis in electric spark machining working solution.
The processor of the embedded control unit can be using ARM9 series STM32F103ZET6 as MCU, control association Adjust each module to operate, and gathered data is processed and is stored and with the communication of host computer etc..
As shown in Fig. 2 the embedded control unit is directed to CO2Detection signal, Pt100 temperature acquisitions and operational hydraulic cylinder liquid Pass through A/D converting transmitted informations between amount and amount of gas evolved detection and MCU.AD conversion uses 8 passage, 14 precision components, conversion Speed 16kHz.MCU is connected with Measurement &control computer by 232 interfaces, using Modbus bus protocols by embedded control unit Electric spark machining working solution monitoring system information and state transfer to showing in real time in the HMI of computer.
The embedded control unit is for Zirconia detector, chromatograph box and constant volume head space operational hydraulic cylinder in system Temperature control is realized by MCU by temperature closed loop system and relevant control algorithm, it is ensured that the control accuracy of operating temperature.Constant volume top Amount of liquid, amount of gas evolved information are converted into number by sending into AD after sensor and change-over circuit in the degasser of empty operational hydraulic cylinder Word amount is sent and MCU;MCU ensures permanent according to relevant information by switch and aperture state that corresponding valve is controlled after calculating treatment Determine the amount of gas evolved of volume working solution, it is ensured that electric spark machining working solution constituent analysis it is accurate.
Due to the zirconium oxide detection corresponding to the high concentration range of the every kind of component of gaseous mixture in detection hydraulic fluid in system Device output voltage signal peak value beyond pci signal capture card range, therefore using detector export peak value converting unit Output voltage signal between gas component high concentration region is decayed (i.e. by Zirconia detector and computer data Setting signal attenuation module between reason unit), peak value converting unit is controlled by embedded control unit, and AD conversion therein is to inspection The output voltage peak value for surveying device is acquired, according to the attenuation coefficient needed for the range restraint of crest voltage.
As shown in figure 3, be heating furnace device outside earthenware in the tubular zirconium-oxide insertion earthenware of Zirconia detector, Pt100 temperature sensors are housed in heating furnace.Sensing and the execution of temperature control system are made up of resistance heating wire and Pt100 Mechanism, uses thermostatic control algorithm in MCU, makes heating in-furnace temperature steady in a long-term at 700 DEG C, it is ensured that zirconium oxide output is electronic Gesture is accurate with gas component measuring concentration of components.
As shown in figure 4, CO2Infrared detector includes infrared gas sensor and infrared light supply kit.Infrared-gas There are two optical filters on sensor, one of passage only allows CO2The wavelength that molecule can absorb is 4.26 μm of infrared light Pass through, so the light intensity for reaching this passage reflects CO2Concentration;By another 4.00 μm of light intensity of optical filter passage then Reflect in air chamber except CO2The change in concentration situation of other mixed gas in addition.
The CO2Infrared detector applies the cycle to infrared light supply for 1S, and dutycycle is 40% DC pulse signal, will Mixed gas send into air chamber from air inlet.Infrared detector is by CO2Concentration is converted into voltage signal, will by signal front end circuit With CO2AD conversion into data signal is sent into after concentration dependent electric signal amplification, filtering.After carrying out digital filtering in MCU, adopt With fieldbus by CO2Concentration amount feeding monitoring computer, CO is obtained using electric spark machining working solution constituent analysis software2Gas Bulk concentration.

Claims (10)

1. a kind of die cavity electric spark machining working solution component monitoring system, it is characterised in that including gaseous mixture sample preparation unit, Detector gas circuit unit, embedded control unit and computer digital animation unit;The gaseous mixture sample preparation unit includes Working solution sampling interface, degasser and the gaseous mixture sample feeding device being sequentially connected, the degasser and mixing gas sample Product sampling device is connected with embedded control unit respectively;The gaseous mixture sample feeding device also with the detector gas circuit list Unit is connected;The detector gas circuit unit is connected with the embedded control unit and computer digital animation unit respectively;Institute State and be connected by fieldbus between embedded control unit and computer digital animation unit.
2. die cavity electric spark machining working solution component monitoring system according to claim 1, it is characterised in that the work Liquid sampling interface is the sampling interface agency of two-way operation liquid, by ablation particle filter, electric three passes valve and liquid storage fuel tank reality Existing, the row of returning after terminating for the sampling and constituent analysis to die cavity electric machining working solution realizes the recycling of working solution.
3. die cavity electric spark machining working solution component monitoring system according to claim 1, it is characterised in that the detection Device gas circuit unit includes the injection port, the CO that are sequentially connected2Detector, chromatograph box and Zirconia detector;The injection port Input is also associated with the output end of gas circuit control element, and the input of the gas circuit control element is connected with carrier gas.
4. die cavity electric spark machining working solution component monitoring system according to claim 3, it is characterised in that the oxidation Zirconium detector is connected by signal attenuation module with computer digital animation unit.
5. die cavity electric spark machining working solution component monitoring system according to claim 3, it is characterised in that the oxidation It is heating furnace device outside earthenware in the tubular zirconium-oxide insertion earthenware of zirconium detector, Pt100 temperature is housed in heating furnace device Degree sensor.
6. die cavity electric spark machining working solution component monitoring system according to claim 3, it is characterised in that the CO2Inspection Surveying device includes infrared gas sensor and infrared light supply kit;There are two optical filters on the infrared gas sensor, its In an optical filter only allow CO2The wavelength that molecule can absorb is that 4.26 μm of infrared light passes through, for detecting CO2Concentration; Another optical filter constitutes 4.00 μm of optical filter passages, for detecting in air chamber except CO2Other mixed gas is dense in addition Degree situation of change.
7. die cavity electric spark machining working solution component monitoring system according to claim 1, it is characterised in that the insertion Formula control unit carries out two-way information interaction by the way of bus communication with computer digital animation unit, using analog-to-digital conversion And digital quantity interface mode is connected with detector gas circuit unit, using digital quantity interface and power drive unit and gaseous mixture sample Preparation unit is connected.
8. die cavity electric spark machining working solution component monitoring system according to claim 1, it is characterised in that the insertion Formula control unit is controlled by temperature closed loop system to the temperature of gaseous mixture sample preparation unit and detector gas circuit unit.
9. die cavity electric spark machining working solution component monitoring system according to claim 1, it is characterised in that the insertion Formula control unit receives the information of amount of liquid and amount of gas evolved in degasser, and is controlled by after calculating treatment according to relevant information The switch and aperture state of corresponding valve ensure the amount of gas evolved of constant volume working solution, it is ensured that electric spark machining working solution composition That analyzes is accurate.
10. die cavity electric spark machining working solution component monitoring system according to claim 1, it is characterised in that the meter Calculation machine data processing unit is realized to die cavity electric spark using related chromatographic work station software and working solution constituent analysis software The analysis and judge of processing work liquid composition and processing gap state and processing effect.
CN201710123598.7A 2017-03-03 2017-03-03 A kind of type chamber electric spark machining working solution component monitoring system Active CN106903382B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710123598.7A CN106903382B (en) 2017-03-03 2017-03-03 A kind of type chamber electric spark machining working solution component monitoring system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710123598.7A CN106903382B (en) 2017-03-03 2017-03-03 A kind of type chamber electric spark machining working solution component monitoring system

Publications (2)

Publication Number Publication Date
CN106903382A true CN106903382A (en) 2017-06-30
CN106903382B CN106903382B (en) 2019-03-08

Family

ID=59186641

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710123598.7A Active CN106903382B (en) 2017-03-03 2017-03-03 A kind of type chamber electric spark machining working solution component monitoring system

Country Status (1)

Country Link
CN (1) CN106903382B (en)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2695969Y (en) * 2004-05-12 2005-04-27 刘春宾 Integral zirconium oxide smoke oxygen analyzer
DE102005031177A1 (en) * 2005-07-04 2007-01-11 Siemens Ag Vehicle passenger compartment gas mixture constituent measurement procedure uses electrically filtered infrared radiation passed twice through sample holder using mirror on window heat sink
CN1912585A (en) * 2005-08-12 2007-02-14 深圳迈瑞生物医疗电子股份有限公司 Method and device for automatic correcting and measuring gas concentration using infrared light absorption characteristic
CN201000424Y (en) * 2007-04-20 2008-01-02 李清波 Carbon dioxide analyzer
CN201269854Y (en) * 2008-09-28 2009-07-08 天津市圣威科技发展有限公司 Optical sensor for automobile exhaust
CN201285372Y (en) * 2008-10-16 2009-08-05 陈红岩 Wireless sensor system for measuring tail gas of automobile
CN101832923A (en) * 2010-06-03 2010-09-15 中国石油集团川庆钻探工程有限公司长庆录井公司 Infrared gas detection system suitable for oil-containing gas analysis of reservoir
CN103018355A (en) * 2012-11-28 2013-04-03 国网电力科学研究院武汉南瑞有限责任公司 Method and device for monitoring gas in transformer oil on line
CN103808784A (en) * 2014-02-17 2014-05-21 华北电力大学(保定) Oxygen content measurement device and oxygen content measurement method for zirconium oxide
CN204346990U (en) * 2015-01-05 2015-05-20 南京特种气体厂有限公司 Microamounts of Hydrogen in gas and oxygen chromatographic device

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2695969Y (en) * 2004-05-12 2005-04-27 刘春宾 Integral zirconium oxide smoke oxygen analyzer
DE102005031177A1 (en) * 2005-07-04 2007-01-11 Siemens Ag Vehicle passenger compartment gas mixture constituent measurement procedure uses electrically filtered infrared radiation passed twice through sample holder using mirror on window heat sink
CN1912585A (en) * 2005-08-12 2007-02-14 深圳迈瑞生物医疗电子股份有限公司 Method and device for automatic correcting and measuring gas concentration using infrared light absorption characteristic
CN201000424Y (en) * 2007-04-20 2008-01-02 李清波 Carbon dioxide analyzer
CN201269854Y (en) * 2008-09-28 2009-07-08 天津市圣威科技发展有限公司 Optical sensor for automobile exhaust
CN201285372Y (en) * 2008-10-16 2009-08-05 陈红岩 Wireless sensor system for measuring tail gas of automobile
CN101832923A (en) * 2010-06-03 2010-09-15 中国石油集团川庆钻探工程有限公司长庆录井公司 Infrared gas detection system suitable for oil-containing gas analysis of reservoir
CN103018355A (en) * 2012-11-28 2013-04-03 国网电力科学研究院武汉南瑞有限责任公司 Method and device for monitoring gas in transformer oil on line
CN103808784A (en) * 2014-02-17 2014-05-21 华北电力大学(保定) Oxygen content measurement device and oxygen content measurement method for zirconium oxide
CN204346990U (en) * 2015-01-05 2015-05-20 南京特种气体厂有限公司 Microamounts of Hydrogen in gas and oxygen chromatographic device

Also Published As

Publication number Publication date
CN106903382B (en) 2019-03-08

Similar Documents

Publication Publication Date Title
CN103245655B (en) A kind of experimental provision obtaining Large-Area-Uniform discharge plasma
CN202285037U (en) 10kv insulator artificial contamination laboratory based on ultraviolet imagery
CN106053306B (en) Large pollution source exhaust emission test system
CN207147973U (en) Heavy metal in water enrichment and measurement apparatus based on LIBS
CN203405441U (en) Instrument for detecting COD (chemical oxygen demand) of high-chlorine wastewater on line by basic potassium permanganate method
CN101504380B (en) X-ray fluorescence analyzer
CN103471502A (en) Device and method for detecting volume of gas-liquid two-phase flow bubbles
CN102680436B (en) Method and device for measuring content of carbon in coal ash
CN101986162B (en) Device and method for measuring conductivity of industrial aluminum electrolyte on line
CN106903382A (en) A kind of die cavity electric spark machining working solution component monitoring system
CN105675694B (en) The measuring system and method for flue gas composition concentration
CN102778194B (en) Online detection method for micro electrochemical machining gap based on electric double-layer capacitor
CN203758914U (en) Laser probe analyzer based on gas atomization and resonance excitation
CN108931491A (en) A kind of Multifunctional water portable remote monitor and water quality monitoring method
CN100567964C (en) Plasma generating equipment
CN105675698A (en) Method of measuring bromine in coal with high temperature hydrolysis and bromine ion selective electrode
CN205067272U (en) High accuracy digit viscosimeter
CN101566593B (en) Sulphuric acid dew point monitoring analyzer
CN104914045B (en) Portable pathogenic bacteria rapid detection system and device
CN110261372B (en) Accurate automatic monitor of diet oil smoke VOCs
CN105668726A (en) Waste PCB (printed circuit board) etchant and ink liquid treatment method and apparatus
CN106002486B (en) Micro- milling force measuring method based on micro- milling machine main transmission power
CN106502176A (en) Thermal decomposition test device monitoring and control system
CN207488163U (en) A kind of unburned carbon in flue dust Portable type measurement unit
CN201177610Y (en) Sulfuric acid dew point monitoring analyzer

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant