CN106893432A - Zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating - Google Patents
Zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating Download PDFInfo
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Abstract
Zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating of the present invention, is belonging to novel environment friendly health paint formula and production technical field.Present office and the luxurious finishing in house lived, household electrical appliance and a large amount of of office equipment use, although the life, work to us bring Shu Yi, conveniently and while quick also generate the pollution of electromagnetic wave, harmful heavy metal lead, mercury, arsenic, cadmium are injured to health in room air, very little, harmful levels of pathogens, viral moment attack health, or even the new house decorateed to anion in air, people moves into does not have several years, and man and wife has successively seized life by tumour in pairs.Therefore room habitat environment build that a kind of full of life, with fresh air, anion is more, micronutrient levels is more and it is complete, can launch far infrared prevent the pollution of ultraviolet anti electromagnetic wave, the drug abuse of Powerful purification air, water purification can decompose antagonism harmful substance, adsorb toxic gas, the multifunction green environment protection coating of elimination germ is the purpose of the present invention.
Description
Technical field：
Zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating of the present invention, is belonging to new type environment friendly coating formula with production skill
Art field.
Background technology：
Coating is that development is very fast in chemical industry, update more frequently product, and coating especially related to building, household has
Environmentally friendly, safe and healthy, functionalization trend.It is related to interior wall, ground, anti-corrosion, fire prevention, waterproof, radiation proof, antirust, guarantor
The paint fields such as temperature, high temperature resistant, road.The characteristics of there is small investment, instant effect due to coating material production, thus reform and opening-up with
Come, various regions township enterprise, private enterprise and overseas-funded enterprise quickly enter coating industry, and production enterprise is generally bloomed, and is developed into
So far, national coatings enterprises have reached family more than 8000.Main integrated distribution is in economically developed Yangtze River Delta and the Zhujiang River
Delta, wherein East China coating yield are maximum, account for the 45% of national total output, ALFISOL IN CENTRAL point 30%, and North China accounts for
15%, northeast, southwest proportion are only 10% or so.From product structure, wholly foreign-owned, joint venture and the country
Product that fairly large manufacturer is produced, market orientation are medium and high-grade goods, and individual, small towns small enterprise is general producing
Based on low grade products.
The content of the invention：
It is an object of the invention to provide a kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating.
Its technical solution is：
1st, a kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The natural seashell ore selenium-rich
Germanium discharges element negative ion far-infrared wind-dispelling restoring consciouness coating, by following mass component proportioning composition %
Wherein, expelling wind and activating blood flow restoring consciouness Chinese medicine mixing nano powder, is constituted by following proportion by weight
Expelling wind and activating blood flow restoring consciouness Chinese medicine mixing process for preparing nm powder：
By medicine-feeding, equal low temperature drying grinds into impalpable powder on the rocks broken fine powder mixing, Ran Houtian again after bleaching in addition to borneol
It is added in coating.
Drug molecule in we discharges in atmosphere from coating, and human body respiration absorbs can effectively dispelling wind and eliminating dampness promoting blood circulation
Dissolving stasis, consciousness regaining.We with pungent-warm dampness elimination, walk to alter, pungent to have one's ideas straightened out, and makes mechanism of qi fluent, and channels and collaterals are unimpeded by pungent-warm, and sick self-healing,
To because chill it is damp and hot caused by headache, the nose heave, head it is unclear, cerebral arteriovenous malformation, cerebral thrombus, neurasthenia has good effect.
Natural seashell ore rich selenium germanium discharges element negative ion far-infrared wind-dispelling restoring consciouness preparation method for coating：
1. recipe requirements are pressed, by mass parts, Se-rich lucid ganoderma bacterium drying nano powder, germanium-rich glossy ganoderma drying nano is weighed respectively
Powder, zinc oxide nano, medical stone nano powder, tourmaline nano powder, silica SiO2Nano powder, titanium dioxide TiO2Nanometer
Powder is placed in blending tank and stirs, full and uniform mixing；
2. the water that 0.12 part of PA-1 dispersants add 30% is weighed, water is uniformly mixed with PA-1 dispersants, then spray
It is spread across in the 1. well mixed blending tank equipped with nanometer mixed powder, is allowed to the abundant mix of nanomaterial uniformly, sealing and standing
It is standby after 6-7h；
3. 25.7% part of water is added in the Scattered Kettle with high speed agitator, step is sequentially added and has 1. been treated
Nanomaterial and 0.06 part of calgon and remaining PA-1 dispersants, then high-speed stirred 20min is allowed to fully dispersed；
4. slow down stir speed (S.S.), sequentially add calcium carbonate superfine powder nano powder, chitin viscose, shitosan viscose glue fine
Dimension, thickener hydroxyethyl cellulose, titanium dioxide, wollastonite nano powder, talcum powder, 0.15 part of NXZ defoamer of KS-2 preservatives, then
High-speed stirred disperses 60min, is allowed to fully dispersed；
5. slow down stir speed (S.S.) again, sequentially add the pure third or stupid acrylic emulsion and remaining 0.10 part of NXZ defoamer, alcohol ester-
12 coalescents, L-150 levelling agents, propane diols antifreezing agent, low rate mixing, it is appropriate to be adjusted to coating with 77-935 thickeners
Viscosity, i.e. tinning finished product storage are preserved；
The water of 8% coating total amount, stirring 10min are added when 6. constructing makes it be sufficiently mixed uniformly, you can use.Brushing
It is with 888 coating bottoming before coating and smooth with sand papering, then with felt roller brush application.The characteristics of this coating：Apply
Layer surface is smooth, and flow leveling is remarkable, and deep layer surface is beautiful, and stain resistant scrub resistance is good, energy release of trace elements, permanent continuous
The spontaneous generation negative ion far-infrared anti-electromagnetic wave pollution in ground, harmful substance gas in absorption antagonism air.Due to rich selenium germanium nanometer
Material in coating processes, crosses the nano-powder of 1000 mesh sieves, 0.1-10 μm of medium particle diameter with Nano Particle ultramicronising device
Pretreatment, dispersant composition is with the addition of in subsequent technique, can guarantee that nanomaterial is fully dispersed, non-agglomerate, make a nanometer group
There is good intermiscibility, stability into emulsion, auxiliary agent and color stuffing component, while can be played using various nanomaterials
The cooperative effect and performance complement of each group nano-component material, so as to reduce and avoid what is individually brought with nano-component
Deficiency, so as to greatly increase the combination property of coating, it is most important that occupied for Modern Family, room, working environment is designed
The sterilized absorption antagonism harmful heavy metal lead of energy release of trace elements negative ion far-infrared anti-electromagnetic wave pollution, mercury, arsenic etc. to people
Body injury, purify air, purify air water quality, being conducive to that health lengthens one's life, a kind of low free of contamination high-performance of evil, many work(
The environmental type interior wall rich selenium germanium nanometer building paint of effect.
2nd, a kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The anti-silly paralysis of the brain-benefiting blood pressure-reducing is anti-
Bacterium deodorization anti electromagnetic wave interior wall coating, % is constituted by following proportion by weight
Wherein, the anti-silly paralysis Chinese medicine mixing nano powder of brain-benefiting blood pressure-reducing, is constituted by following proportion by weight
The anti-silly paralysis Chinese medicine mixing process for preparing nm powder of brain-benefiting blood pressure-reducing：
Will medicine-feeding clean bleaching dry grind superfine powder with as the filler in coating.
With heat clearing and blood cooling removing toxic substances, dredging collateral promoting blood circulation and removing blood stasis effect can lipid-loweringing, hypotensive, anti-cerebral thrombus, old silly for we
It is slow-witted, breathed with human body skin by the continuous release of said medicine molecule and absorb durable contact and nutrient absorption, not only beneficial to disappearing
Except inflammation, cholesterol and triglyceride is reduced, and cerebrovascular microcirculation can be promoted, improve cerebral anoxia situation, promote brain cell new
Old metabolism, is beneficial to brain cell and obtains newborn and rehabilitation.The incidence of disease is higher in recent years for hypertension, cerebral thrombus, senile dementia, once
Affected treatment is difficult recovery from illness, and easily breaking-out.Therefore meet and suffer from and control not as preventing trouble before it happens.The anti-effective Chinese medicine ancestral that is crazy about of the anti-paralysis of brain-benefiting blood pressure-reducing
Pass secret recipe and be made nano ecological health environment-friendly coating as the active ingredient in coating, because of oxidation year in and year out, wind-force and shake
It is dynamic to make effective drug effect molecule in coating, constantly discharge and people is absorbed into by human body skin, pore, sweat pore, breathing
Body blood circulation, diseased region reaches expansion of blood vessels, dredges microcirculation, improves the blood circulation supply situation of brain tissue, reduces
Blood viscosity, makes body be in hypocoagulability.So as to reach, muscle is strong, qi and blood is smooth, and persistent ailment is removed.One kind traditional Chinese medicine secret recipe is used as coating
In filler, can make in coating that effectively Chinese traditional medicine molecule continues persistently release permanent action in human body, be a kind of effective molecule of Chinese medicine,
It is mixed in coating and reaches inner disease outer treat applications room decoration, is that a kind of current newest preventing and treating combined treatment cranial vascular disease is non-
Often preferable effective ways, are a kind of new innovation designs of external therapy of Chinese herb.
The anti-silly paralysis antibacterial deodourizing anti electromagnetic wave interior wall coating preparation method of brain-benefiting blood pressure-reducing：
1. by the deionized water in above-mentioned material, ethylene glycol, wetting dispersing agent, NXZ defoamers, silica SiO2Nanometer
It is that one kind has photocatalyst-type inorganic nano titanium dioxide TiO2 antiseptics that powder has the deodorant antiultraviolet effect of antibiotic and sterilizing；Again
With nanometer silver-based inorganic antibacterial agent, nanometer selenium, organic germanium Ge-132, chitin nano powder, medical stone nano powder, tourmaline or sea
Algae charcoal nano powder, kaolin nano powder, precipitated calcium carbonate nano powder, silicic acid aluminum nano, talcum powder nano powder, lithopone nanometer
Powder, brain-benefiting blood pressure-reducing prevents that the material that silly anti-paralysed Chinese medicine mixes nano powder jointly is mixed and puts rotating speed into for 1500-2000r/min is high
In fast dispersion machine, jitter time is 40-60min；
2. the mixture that the material by step 1. is obtained is ground by grinder or uses Nano Particle ultra micro
Makeup put treatment nano-powder cross 2000 mesh sieves, 0.1-10 μm of medium particle diameter become the present invention reached for nano paint
Requirement, there occurs surprising change due to being worked into the physicochemical property of its material of nanometer scale, inherent quality, it is this by receiving
The nano-substance of these odorless, tasteless such as pure natural mineral matter medical stone, tourmaline, the chitin of rice complex technique treatment can be molten
Go out substantial amounts of trace element and it is spontaneous be constantly be generated harmful substance in anion, absorption air, and can be by big point in air
Son group water becomes small-micelle water, and this small-micelle water oxygen content is high, penetration is strong, extension is strong, and this disperse is in air
Between each material of Chinese medicine nano micromolecule, be easy to be absorbed by cell in human body suction body, so as to accelerate human body new old generation
Thank, improve microcirculation, promote cytotrophy, strengthen cell viability, improve immunity of organisms, strengthen the ability of resist the disease, it is right
Health is extremely helpful；
3. the above-mentioned material being ground is added into mixer, is slowly added under the mixing speed of 200-400r/min
Stating the acrylic emulsion in formula components, alcohol ester-12 coalescents, 77-935 thickeners, L-150 levelling agents, preservative is carried out
Stirring mixing；
4. 2000 mesh sieves being crossed by mixed material obtained by 3. step, to obtain final product release of trace elements anion of the present invention remote
The rich selenium germanium nano paint of infrared absorption nuisance.
3rd, a kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The replenishing qi and blood tonifying spleen kidney is adjusted cloudy
Sun is promoted longevity environment protective nano-paint, and % is constituted by following proportion by weight
Wherein, replenishing qi and blood tonifying spleen kidney adjusts negative and positive to lengthen one's life Chinese medicine nano powder, is constituted by following proportion by weight
Replenishing qi and blood tonifying spleen kidney adjusts negative and positive to lengthen one's life Chinese medicine nano powder preparation method：
Medicine-feeding drying is ground, and is made among the making that nano powder adds coating.
Originally can replenishing qi and blood, tonifying spleen kidney, tune negative and positive, macrobiosis longevity.
We be applicable to deficiency of qi and blood, imbalance of yin and yang, all abdomen pain, receive poor burnout, have a dizzy spell, internal organ sink, long
Rush down uncomfortable prolapse of the anus, mirror water, uterine bleeding under band, cold uterus etc..Such as gastritis, chronic enteritis, gastric ulcer, duodenal ulcer, stomach
Palace is sagging, chronic gynaecological imflammation and disease-prevention health.
Existing tonifying middle-Jiao and Qi, medicinal piece of shiquan dabu in this secret recipe, there is the medicine such as kidney tonifying negative and positive, promoting blood circulation and removing blood stasis, qi-regulating again.After it reconciles
Its taste and congenital kidney qi, strengthening vital QI to eliminate pathogenic factors.Both the warm nature that stilbene joins osmanthus ginger had been deposited in side, the category grown with knowing cypress of residing again is mended without dry, is grown not
It is greasy.Arriving card imposes on various diseases for many years, and good effect is obtained repeatly.Disease-prevention health Chang Xianqi work(.In terms of pharmacological mechanism, except treatment
Outward, for health care, from modern pharmacology analysis, above-listed medicine, for protein and Nucleic acid dysfunction, fatty generation
Thank, endocrine dysfunction is reduced, the deficiency of immunologic function can be allowed to strengthen.
Medicament nano small molecule in coating is acted on through wind-force oxidation wind power, makes its dispersion in atmosphere, through human body respiration
Into blood, can make to link up the five internal organs, six internal organs, four limbs bones of the body collectively, face nine orifices, skin manadesma through gas circulation.Therefore tool spleen-invigorating and kidney-strengthening, return
Sun rescues inverse, and mediation stomach and intestine, scattered gas leads to stagnant, fortune Li Shui, and promoting blood circulation for regulating menstruation cures all diseases.Breathed by mouth and nose and absorbed and percutaneous
Skin capillary pore, sweat pore, and its Medicine small molecule that meridian point breathing absorbs, than for cannot be administered orally patient
It is more suitable.Congenital, the day after tomorrow medicine is nursed one's health with this to be blended in coating with the Medicine small molecule with itself regulation yang blood and qi,
It is the another new invention of nano paint.
Replenishing qi and blood tonifying spleen kidney adjusts negative and positive to promote longevity environment protective nano-paint preparation method：
1. by deionized water, chitin viscose, shitosan viscose rayon, dispersion moisture agent, defoamer, propane diols into
Film auxiliary agent sequentially adds high speed dispersor and stirs, and rotating speed 600r/min, the time is 2min；
2. by silver system nano inorganic antimicrobial agent, nanometer selenium, organic germanium Ge-132, Nano-meter SiO_22, medical stone nano powder, electrically
Stone nano powder sequentially adds high speed dispersor and stirs, and rotating speed 600r/min, the time is 2min；
3. adjustment rotating speed is 400r/min, sequentially adds titanium dioxide, heavy calcium carbonate, talcum powder, wollastonite nano powder,
Plus it is 1600r/min to improve rotating speed after getting well, the time is 15min；
4. scattered said mixture material is carried out into fine sand mill by sand mill again, cross 2000-2200 mesh sieves so as to
Its nanometer particle size is reached 0.1-5 μm, then the good material of fine grinding is poured into again and is further stirred in stirring at low speed tank, stir
Speed is mixed for 600r/min, emulsion acrylic resin, antifreezing agent, thickener are slowly added while stirring, be eventually adding pH tune
Section agent；
5. mix colours, cross 2000 mesh sieves, the nano paint tinning of 0.1-5 μm of medium particle diameter, storage, constant temperature is preserved.
Product performance：The ageing-resistant property of this product, wash-resistant property are high, and paint film can be directly micro- to being discharged in air for a long time
Secondary element, negative ions radiation far infrared absorption poisonous and harmful substance, kill bacterial virus, deodorant, antiultraviolet and prevent with strength
The natural green environment protection multifunctional physical fitness dope for inner wall of architecture of electromagenetic wave radiation far infrared, fresh air and haze.
4th, a kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The antiasthmatic-antitussive eliminating the phlegm moistening lung
Kidney tonifying rich selenium germanium environment protective nano-paint, % is constituted by following proportion by weight
Wherein, warm livering phlegm Dingchuan Chinese medicine nano powder, is constituted by following proportion by weight
Warm livering phlegm Dingchuan Chinese medicine nano powder preparation method：
Medicine-feeding was ground into 2200 mesh in addition to sesame oil, honey and was made Chinese medicine nano powder of the particle diameter at 0.5-5 μm, with preparation
The filler base-material of coating, sesame oil, honey are made the functional coating of disease-prevention health jointly.To chronic bronchitis, asthma, lung qi
It is swollen, it is possible to use the Chinese medicine nano powder of coating be released to air through the effect of wind-force, sunlight in Medicine small molecule through human body respiration
The circulation of blood in human body in liquid is absorbed into, the purpose of inner disease outer treat is reached.
5th, a kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The refreshment and tranquilization clears away heart-fire improving eyesight
Acupuncture-stimulating blood stasis dispersing is depressured environment protective nano-paint, and % is constituted by following proportion by weight
Wherein, (1) described refreshment and tranquilization clears away heart-fire improving eyesight acupuncture-stimulating blood stasis dispersing Chinese hypotensor nano powder, by following proportion by weight group
Into
Chinese medicine nano powder preparation method：
1. standby material is selected：By ingredient names and the standby various materials of corresponding content choosing, it is ensured that various material non-toxic corruption phenomenons, nothing
Impurity；
2. powder processed：The various material co-grindings got ready will be selected, powder is made, and the granularity of the powder is reached 2000-
The nano powder of 2200 mesh, 0.5-5 μm of medium particle diameter；
3. baking powder：The powder that upper sequence is made is put into tin matter container, under the conditions of 50-60 DEG C, roasting 20-30min is turned over, stopped
Only turn over roasting；
4. finished product packing：Upper sequence is turned over the powder after roasting and packs sealing, you can finished product is put in storage.
Effect：Dispelling wind improving eyesight, promoting the circulation of qi inducing diaphoresis, clearing away heat to and alleviating pain, promoting blood circulation to remove blood stasis.Dizziness, palpitaition.
The medicine gasification energy that this coating is discharged out has refreshment and tranquilization, the improving eyesight that clears away heart-fire, acupuncture-stimulating blood stasis dispersing, the work(tonified the kidney and support yang
Effect.To hypertension, the disease such as cerebral blood supply insufficiency, tinnitus, insomnia and dreamful sleep, cerebral embolism sequela has preferably to be controlled the pharmaceutical gas
Treat.So this coating is not only nontoxic, but also with body-care with control treatment functions,.
Fang Xie：Dizziness, is spent with dizzy mesh, and then dizziness is aggravated when sitting up suddenly, and tinnitus, palpitaition, body is tired powerless, sleep disorder
Deng being principal character.With chrysanthemum, root bark of tree peony radiating improving eyesight, pancake liver-yang, and the clear ying blood heat toxin of energy in side, scattered stagnation resolvation is stagnant, makes qi and blood
It is smooth；The root of Dahurain angelica, Ligusticum wallichii are obvious to various migraine and general headaches, its effect of dizziness.All formulas are matched to the deficiency of both the heart and spleen of asthenic symptoms, it is impossible to Rong Yu
Brain, or real example wind-yang and up-boring, phlegm resistance, the lucid yang failing to raise dizziness, the palpitaition effect is significant that cause, these active drug molecules are oozed
Enter to reach in coating the purpose of inner disease outer treat.
(2) high strength bright shell rich selenium germanium disease-prevention health nano inner wall coating, it is characterized in that：By following proportion by weight group
Into
Preparation method：Finished product is made after above-mentioned each raw material is well mixed；
This coating is that a kind of high strength bright refreshment and tranquilization clears away heart-fire the both effectiveness interior wall coating of improving eyesight disease-prevention health.
Product performance：With this product brushing interior walls, with hardness is high, water-proof, Storage period is long, whiteness is high, anti-general
The good advantage of yellow performance,, through 96h soak tests, without coming off, elephant skin, this product difficulty of construction is low for it, after parching, light Gao Rujing,
Hard such as porcelain, never fades.
In order to improve the overall technology level of coating industry, in " eight or five ", the enforcement period of the ninth five-year plan, country has organized 63 coating
Creative Science and Technology Co. Ltd's project development, major part realizes industrialized production at present, and its main innovation achievement has：Thick-film type negative electrode electricity is heavy
Product coating, metallized coating, thick-film type building coating, aqueous industrial coating, watery anti-corrosion paint, polyurethane carpentry paint,
Weatherability coil coating, marine ship coating, fast light molybdate red pigment, pearly-lustre produce material and building coating, car paint, ship
The advanced production technology and key equipment of all kinds of special coatings such as coating, anticorrosive paint, form the main of all kinds of special coatings
Production base, effort shortens gap with foreign well-known enterprise production firm product, but with the inhabitation of China people Shu Yi
Conditions environmental is still inadequate.Present office uses with a large amount of of the luxurious finishing in the house lived, household electrical appliance and office equipment,
Although life to us, work bring Shu Yi, convenient and quick, simultaneously using non-natural synthetic material, paint,
Harmful heavy metal lead, mercury, arsenic, cadmium in produced electromagnetic pollution, room air when coating, office equipment and household electric appliance operation
Pollution, anion is reduced in air, harmful levels of pathogens, viral moment encroach on the health of human body, or even has some new to decorate
House, people moves into and has successively seized life by tumour in pairs without several years men and wives, and this example is not within minority.Therefore indoors
Building environment one kind of inhabitation is full of life, the clear fresh, anion concentration of air is high, micronutrient levels is more and it is complete, can launch far
It is infrared prevent and shield Contamination of Electromagnetic Wave, Powerful purification air, water purification take drugs again can decomposing harmful substances, absorption toxic gas,
The multifunction green environment protection coating for eliminating malignant bacteria is the purpose of the present invention.
Chitin be it is a kind of collect disease-resistant body-building, on the earth storage extremely enrich, unique positively charged natural green antibacterial
Element and tunicin.Due to carrying undersaturated cation gene in its molecular structure, thus to all kinds of of negative electrical charge
Harmful substance has powerful suction-operated.Equally, it can also remove the rubbish in human body, reach prevention disease, promote longevity
Purpose.Chitin is that the one kind for refining out from shrimp, crab, the shell of insect, shell and mushroom, the cell membrane of algae is natural
Biopolymer, the year biosynthesis amount of chitin, about more than more than 1000 tons, is a kind of extremely abundant have in nature
Machine regenerated resources.Collagen and higher plant during chitin is both the fiber composition in lower animal and simultaneous higher mammal is organized is fine
The biological function of both celluloses in dimension.Therefore its biological characteristic is very excellent, and it is mainly characterized by：(1) Bc
It is especially good.Chitin and its derivative are the natural high polymer of no side effectses, its chemical property and biological property and people
Body tissue is close, therefore its manufactured goods does not exist exclusive problem with human body.(2) bioactivity is excellent.Chitin and its derivative
Because itself containing the space structure of complexity, and multiple biological activities are shown, its manufactured goods has antibacterial, reduction serum and courage solid
Alcohol content, suppress fibroblast growth, directly suppress tumour cell and promote epithelial cell growth, promote humoral immunity and carefully
Born of the same parents are immune to wait effect.(3) moisturizing, good heat insulating.Chitin fiber due to its unique fibrous molecular structure, with very strong
Moisturizing factor, thus with moisturizing high, heat insulation function high, can there is moist, moisturizing and maintenance action well to skin.(4) it is raw
Thing degradation property is good.Chitin and its derivative can be decomposed into lower-molecular substance in the presence of enzyme, therefore its manufactured goods is used for
General organic organization can be biodegradable and be fully absorbed by human body.Chitin belongs to polysaccharide, is processed through concentrated base, can slough
Acetyl group therein, when the N- acetyl group in chitin structure is divested more than 55%, then spreads out as chitin is most important
It is biological --- shitosan.Contain active hydroxyl and amino in the molecule of chitin and chitosan, they can under certain condition
The chemical reactions such as generation hydrolysis, alkylation, acylation, carboxy methylation, sulfonation, nitrification, halogenation, redox, condensation and complexing,
So as to generate derivative of different nature, the range of application of chitin and chitosan is thus expanded.
Acted on after bacterium through electron microscope observation on shitosan, bacterium there occurs obvious morphological change：Leather
Lan Shi positive bacterias such as staphylococcus aureus, its cell membrane is thinning so that damaged, and the duplication of bacterium is suppressed；Gram-negative
The bacterial cytoplasm concentration of bacterium such as Escherichia coli, space substantially expands, it is seen that shitosan significantly have impact on the life of bacterial cell
It is long.Shitosan is to head mold, bacillus subtilis, pseudomonas, thermophilic fat glue bacillus, Escherichia coli, Mucor, golden yellow in a word
The various bacterias such as color staphylococcus, salmonella, vibrio parahaemolytious, intestines streptobacillus have good inhibiting effect, are very excellent
Natural green anti-biotic material, be also one of optimal environment-friendly materials in coating of the present invention production.
The aseptic antiseptic of Nano Silver system, at 0.1-5 μm, silver particles spherical in shape are equably for its nano-class silver colloidal solution particle diameter
It is dispersed in coating, is distributed in atmosphere through certain temperature, air, water droplet, with broad spectrum high-effect durable antibiotic bactericidal effect,
Suppress well or killing action to having including the various harmful bacterias including bacterium, fungi, trichomonad, mycoplasma, to resistance
Flora has an equal killing power, and antibiotic rate is up to more than 99.9%.The stink gas produced by various organic matter corruption can be dispelled simultaneously
Body and Contamination of Electromagnetic Wave and the isolation to ultraviolet, effective antistatic, safety and environmental protection are non-stimulated, harmless to the human body, in the world
It is widely used for the fields such as construction material, chemical materials, health care, daily necessities.Nano Silver chemistry painting industry etc. applies them
Attached various germs on the surface can be killed on surfaces such as sheet materials, its sterilization has permanent ageing.General antibiotic energy
6 kinds of pathogenic organisms bacterium are killed, and silver can kill 650 kinds, and effectively empty can make obstinate, resistance bacterial strain flora, very small amount
Silver just can eliminate substantial amounts of genic organisms.Under lab, do not find that any microorganism can not be by 6min still
Silver is killed.
Medical stone and tourmaline, astroies, bottom sediment, aethiops vegetabilis, Strange ice stone, three celestial stones, serpentine, violet cyanines
Main component in stone, mullite, diatomite these raw materials have the oxide of common far infrared radiation material, magnesia MgO,
Alundum (Al2O3) Al2O3, it is again the sterilized representative of far infrared radiation；Titanium dioxide TiO2It is again the sterilized representative of photocatalysis formula；
And have the di-iron trioxide Fe of shielding action to Contamination of Electromagnetic Wave2O3；Have magnetic ferrite FeO nano powders, four oxidations three
Iron Fe3O4Nano carbon-base iron powder, and ZnO, MgCl with antibacterial and deodouring function2、SiO2, this antibacterial action is because coating
In these antiseptic nano powders distribute and contacted with skin in atmosphere, its antibacterial action can prevent skin infection, eliminate germ and
Sweat etc. is converted into the bacterium of stink substance for the toxin of its secretion, kill, can also adsorb a large amount of harmful substances, is received by it
Nano material surface property high and high activity in rice coating, the extremely strong freedom of oxidisability is converted into by the oxygen or water in air
Base carrys out oxidation Decomposition these foul smell；A certain amount of tourmaline nano powder is dissolved in another aspect coating, in certain external energy
Under fluctuation status, such as temperature, sunlight, pressure it is even very small in the presence of, i.e., nano-tourmaline is born in causing coating
1.0X10 is up between ionic crystals6Ev electrostatic potentials are poor, so as to form electric field, high voltage, make the air ionization in electric field, quilt
The permanent positive and negative polarity that the electronics for hitting has by tourmaline nanocrystalline powders two ends, in common water, air
Hydrone or after being contacted with the hydrone of human skin, just can produce the ionisation effect that sparks, and hydrone is electrolysed as H+And OH-。H+Combined with the electronics that tourmaline is discharged and be neutralized into H atom, and OH-With other water his sub- combinations, can be even
Continuous generation hydroxyl group anion H3O2 -.By the water of this process, either alkaline water or acid water, can all present beneficial to people
The alkalescent of body, substantial amounts of cation is generated due to environmental pollution, in air, and the quantity of anion is being significantly reduced, people
Wish to improve the air quality of room and working environment, enjoy the concentration of the Nature negative aeroion.Seashore, forest, waterfall
Other anion concentration is in 50000-200000/cm3, suburb field anion concentration is in 5000-50000/cm3, Green Park
Anion concentration is in 800-2000/cm3, Urban House room anion concentration is in 20-50/cm3, and the air-conditioned room closed
Between only anion concentration in 0-10/cm3.Negative aeroion is the material being highly profitable to human body, is referred to as by people " long-lived
Element ", " vitamin in air ", the nano powder body of tourmaline of the addition in the coating in room residence or the room of work is through light
Line, temperature, human body are walked about under small pressure state, and just the spontaneous automatically continuous generation anion of energy is distributed in space, works as people
By breathing during by anion inspiration alveolar in air, the nervous system of human body can be stimulated to produce good effect, make one essence
The full, brains of god is salubrious, and the anion of institute's band is transported in systemic cell tissue through blood circulation, can improve myocardial function,
Enhancing myocardial nutrition and cell metabolism, raising immunocompetence, regulation nervous function, stimulate circulation, can also drive away heavy breathing
Breathe heavily, various diseases such as hypertension, high fat of blood, hyperglycaemia, pulmonary emphysema, coronary heart disease, make one energetic, good health and a long life.Human body is certainly
So the ability of defence, can only tackle the flue dust of bulky grain, and the little particle for being less than 1-2 μm is just helpless, therefore these are thin
Small particle can smoothly enter human lung so as to cause various diseases.The anion powder added in coating is discharged
Anion in atmosphere in " Z " font move, it is easy to give bacterium, dust, smoke particles and water droplet etc. conveying negative electrical charge, electricity
Lotus can neutralize the materials such as dust, bacterium, the virus in air, with these material aggregation balling-up after drop to ground, make dirt
Air changes into peace and quiet air fresh, rich in anion, so as to improve and improve the air matter in room and working environment
Amount.This is also an object of the present invention.
On the other hand, contained macro micro element needed by human is relatively more in these mineral matters, selenium Se, germanium Ge, strontium
Sr, vanadium V, gallium Ga, zinc Zn, copper Cu, molybdenum Mo, chromium Cr, nickel, niobium Nb, tantalum Ta, cobalt Co, tin Sn, europium Fu, zirconium Zr, tungsten W etc. more than 50
Kind of element, wherein especially selenium, is the most important most required trace element of human body, but it again can not from human body idiomorphism synthesis,
Must be obtained by external world's intake, but selenium deficiency is the problem in the whole world, it has now been found that there is selenium deficiency and ask in tens, whole world country
Topic.China is selenium deficiency big country generally acknowledged in the world, and the area for having 72% has selenium deficiency state, and the serious selenium deficiency of China has 70%
Selenium deficiency or serious selenium deficiency in population body above, so malignant tumour has the trend of rising, so Chinese need many selenium-supplies.Why
Sample selenium-supply, this is significant problem of the pendulum in face of the mankind.So the present invention increases selenium in the people room in the coating of luxurious decoration
The content of element, though coating cost increase, but its effectively generation development of pre- anti-cancer, poisonous in antagonism adsorption chamber
The pernicious gas such as harmful substance and sulfur dioxide hyponitric acid, promotes the health of human body.The life of people only once, effectively in advance
Anti- disease, promote longevity, this input or calculate.Besides the acquisition of selenium element can use Fermentation Engineering completely, pass through
The microbiological transformation technology of ganoderma lucidum edible mushroom selenium-rich culturing selenium resource, obtains and is dried rich in Organic Selenium, organic germanium, selenium accumulation of Ganoderma Lucidum germanium
Mycelium, this much should not simultaneously put into, complicated technology, all general universities, all Bacteriology Rooms of Research Center, the place of microbial room
Will have what this ability was accomplished.Ganoderma fungi, except containing rich in protein, polysaccharide, vitamin and other active matters
Outside matter, also with the ability of very strong rich selenium germanium, the selenium germanium being enriched with mainly have albumen selenium, albumen germanium, polysaccharide selenium, holoside Ge,
The Organic Seleniums such as nucleic acid selenium, nucleic acid germanium, organic germanium are present.Na is added in culture medium2SeO3Concentration is advisable with 50mg/kg.Can make
Selenium content reaches 8000mg/kg, or the training that saccharomycete is namely put into sodium selenite liquid with Se-enriched yeast in ganoderma lucidum mycelium
Culture is obtained in supporting base, is the Biological Selenium selenium preparation by a kind of high content of Se-enriched yeast microorganism conversion.In Se-enriched yeast
Biopotency be 10-20 times of inorganic selenium.More than the 80 kinds of generation development of disease is currently known with selenium level reduction in human body
It is relevant, with selenium treat and auxiliary treatment have good effect, especially in anti-cancer, anticancer, prevent AIDS, it is understood that body
Inside at any time with can all produce free radical quarter, excessive free radical is the major reason that cell occurs canceration, and selenium has powerful antioxygen
Change ability, can remove unnecessary free radical, and selenium germanium conjunctive use removes the ability of free radical, and active cell with strength
Interior tumor suppressor gene, prevents the canceration of normal cell, improves immunologic function, kills or suppress the growth and transfer of cancer cell.It is real
Checking is bright, in cell culture fluid, as long as during the selenium of several millimolar concentrations, can just play a part of to suppress growth of cancer cells,
More than ten selenium of millimolar concentration can promote cancer cell to adjust nothing, and the selenium of higher doses can then promote the necrosis of cancer cell.While selenium
Tumor vascular formation can also be suppressed, limitation cancer cell obtains the source of nutrition, and so as to delay the growth of cancer cell, selenium can also
Suppress drug resistance of the cancer cell to chemotherapeutics.The time that usual chemotherapeutics is used is more long, and cancer cell often produces drug resistance,
Decline curative effect, this is the difficult point in treatment of cancer, and selenium can make cancer cell recover the sensitiveness to chemotherapeutics.
Germanium is a kind of trace element with multiple biological activities, has positive effect to health, have it is antitumor,
Anti-inflammatory, antiviral, anti-ageing physiological action of waiting for a long time.Germanium all contains in rice, coconut, grape, apple fruits and vegetables, beans, but very micro-
It is few, belong to typical rare and scatter element, it is very rare on the whole in nature.But the daily germanium intake of human body should be 400-3500
μ g are often not enough.Cortex and ash in part zymoprotein of the germanium in human body, such as guanidine propylhomoserin enzyme, cytochromes enzyme and brain
In matter, contain limited amount germanium in cell membrane, mitochondria, chromosome, vesica and lysosome and each histoorgan of human body.Science
Test result indicate that, organic germanium Ge-132 is not only a kind of immunopotentiator, and is immunomodulator, its anticancer, anti-height
Blood pressure, anti-aging effects are to induce interferon and enhancing NK (NK) cytoactive, macrophage work by body
Change what is realized.Zoopery confirms that germanium, selenium, zinc have synergy, and medical stone composition germanium, selenium, zinc contain.Organic germanium is adjusted
Potential field, potential anticancer jinx, blood clean, the prevention and treatment of AIDS are captured in immune function of human body, recently research
It is old that angiocardiopathy, oxygen-rich health function, reinforcing blood cause to the affine of oxygen molecule, anti-aging, the internal brown matter of removing
The free radical of people's spot and excess, therefore organic germanium is described as " the help germanium of 21 century ", " jinx of human diseases ", " 21 century
Lifespring ", " nova in the vibrations world ", " bodyguard of human health ".The pharmacological action of organic germanium mainly shows it to be had
There are three keys with oxygen in independent molecule structure, oral absorption can provide substantial amounts of oxygen to systemic cell.Have in coating of the present invention
Machine germanium nano-powder is distributed in atmosphere, and the organic germanium nano-powder of oral nasal respiration suction sucks lung's mucous membrane through respiratory tract,
A large amount of oxygen are provided to systemic cell through blood circulation, improves blood circulation and organ dysfunction, improve metabolism, strengthen anticancer energy
Power, suppresses the formation of cancer cell, reduces blood viscosity, increases CBF, reduces blood pressure, and prevents cerebral thrombus, senile dementia etc. various
Disease.
Indoor decoration rich in having the coating of medical stone, run into water vapor in air invade profit be easy to dissolution calcium, magnesium,
The elements such as the metasilicic acids such as potassium, sodium, strontium, selenium, germanium, zinc, iodine and mineral matter, and adsorb harmful cadmium in water and air, mercury,
The heavy metal elements such as lead, and the odorous gas such as hydrogen sulfide.The microorganisms such as Escherichia coli, bacterium, virus can also be adsorbed simultaneously
With other organic matters, it more difficult to it is valuable be to blend coating in containing medical stone, tourmaline nano-powder due to its particle
Very little, takes its fine particle for crossing 600 mesh sieves and is placed on observed under electron microscope, moreover it is possible to clearly find this tiny wheat
Meal stone particle is completely as coral reef, spongy presentation porous.The particle of 600 mesh sieves so thickness, what kind of this is
ConceptOne powder powder only has 100 mesh sieves, and it also carefully goes up 5-6 times than the particle of fabric, still it can be seen that pore cave, is really phase
When it is marvellous, their the nano-powder specific surface area blended in coating is very large.So its adsorption capacity is especially strong,
Because their chemical composition is mainly silica SiO2, titanium dioxide TiO2, alundum (Al2O3) Al2O3, di-iron trioxide
Fe2O3, ferroso-ferric oxide Fe3O4, and iron oxide, ferrous oxide, calcium oxide, chromium oxide, titanium oxide, zirconium oxide, manganese oxide
Deng, they are both far infrared radiation material, are again that good anti-electromagnetic wave pollutes optimal shielding material, and with TiO2Etc. for
The light of representative urges formula Fungicidal substance and with Al2O3It is the Far infrared radiation type bactericide for representing, nano zine oxide belongs to broad spectrum activity again
Photocatalyst-type inorganic antiseptic is nontoxic to human body, the features such as antibacterial is excellent.With the quantitative disinfecting test of ZnO：When ZnO concentration is
When 1%, the sterilizing rate to staphylococcus aureus after 5min is 98.86%；Sterilizing rate to Escherichia coli is 99.93%.
For heavy metal, in the solution containing 0.1ppm cadmiums, adsorbable removing 43.2% is determined after the medical stone 3h for adding 10%,
24h absorption removes 61.4%, 48h absorption and removes 84.5%；So by medical stone, the addition of tourmaline nano powder in formulation for coating material
Not only can release of trace elements, continuously to automatically generate the pollution of anion emission far infrared anti-electromagnetic wave, strong adsorption empty
Various specific functions such as the harmful substance deodorization and sterilization of the heavy metal in gas etc..
The Source of life of people is water, and the bodily tissue 65% of people is made up of water, and 80% is water in the blood of people, people's
Eyeball 99% is all water, and the water of high-quality is the important channel of the nutriment macro micro element supply of human body, and it is conveyed for human body
The nutritional ingredients such as mineral matter, fat, oxygen, hormone, while water plays a variety of effects such as radiating, dilution, excretion again, it may be said that people
The all of physiological activity of body all be unable to do without the participation of water.The various diseases of human body, especially angiocardiopathy, cancer etc. be all with
Daily drunk water pollution or the beneficial trace element of shortage, the acid-base imbalance of water quality has very big relation.Discharged in coating
Medical stone nano powder grain out can make one internal water through in the absorption inspiration body of people, bringing into each histocyte of whole body
Purifying, mineralising, activation, while being similar to warehouse, the shape of trace element necessary to human body in the micropore cave of medical stone nano particle
The cradle and source of trace element necessary to adult body, trace element necessary to human body is supplemented at any time, adjust, supplement,
Antagonism human elementary is balanced.Medical stone is again " cleaning agent of cell ", " detergent " simultaneously.
The present invention is further elucidated with reference to examples of implementation：
Specific implementation method：
Embodiment 1：A kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The natural seashell ore deposit
Stone rich selenium germanium discharges element negative ion far-infrared wind-dispelling restoring consciouness coating, by following mass component proportioning composition %
Wherein, expelling wind and activating blood flow restoring consciouness Chinese medicine mixing nano powder, is constituted by following proportion by weight
Embodiment 2：A kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The brain-benefiting blood pressure-reducing is prevented
Silly paralysis antibacterial deodourizing anti electromagnetic wave interior wall coating, % is constituted by following proportion by weight
Wherein, the anti-silly paralysis Chinese medicine mixing nano powder of brain-benefiting blood pressure-reducing, is constituted by following proportion by weight
Embodiment 3：A kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The replenishing qi and blood tonifying spleen
Kidney adjusts negative and positive to promote longevity environment protective nano-paint, and % is constituted by following proportion by weight
Wherein, replenishing qi and blood tonifying spleen kidney adjusts negative and positive to lengthen one's life Chinese medicine nano powder, is constituted by following proportion by weight
Embodiment 4：A kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The antiasthmatic-antitussive is dispelled
Phlegm moistening lung kidney tonifying environment protective nano-paint, % is constituted by following proportion by weight
Wherein, warm livering phlegm Dingchuan Chinese medicine nano powder, is constituted by following proportion by weight
Embodiment 5：A kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The refreshment and tranquilization is clear
Heart improving eyesight acupuncture-stimulating blood stasis dispersing is depressured environment protective nano-paint, and % is constituted by following proportion by weight
Wherein, (1) described refreshment and tranquilization clears away heart-fire improving eyesight acupuncture-stimulating blood stasis dispersing Chinese hypotensor nano powder, by following proportion by weight group
Into
(2) high strength bright shell rich selenium germanium disease-prevention health nano inner wall coating, it is characterized in that：By following proportion by weight group
Into
Claims (5)
1. a kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The natural seashell ore rich selenium germanium is released
Element negative ion far-infrared wind-dispelling restoring consciouness coating is put, by following mass component proportioning composition %
Wherein, expelling wind and activating blood flow restoring consciouness Chinese medicine mixing nano powder, is constituted by following proportion by weight
2. a kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The anti-silly paralysis antibacterial of the brain-benefiting blood pressure-reducing is prevented
Smelly anti electromagnetic wave interior wall coating, % is constituted by following proportion by weight
Wherein, the anti-silly paralysis Chinese medicine mixing nano powder of brain-benefiting blood pressure-reducing, is constituted by following proportion by weight
3. a kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The replenishing qi and blood tonifying spleen kidney adjusts negative and positive to prolong
Lengthened one's life in year environment protective nano-paint, and % is constituted by following proportion by weight
Wherein, replenishing qi and blood tonifying spleen kidney adjusts negative and positive to lengthen one's life Chinese medicine nano powder, is constituted by following proportion by weight
4. a kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The antiasthmatic-antitussive eliminating the phlegm moistening lung kidney tonifying
Environment protective nano-paint, % is constituted by following proportion by weight
Wherein, warm livering phlegm Dingchuan Chinese medicine nano powder, is constituted by following proportion by weight
5. a kind of zinc-rich selenium oyster shell whiting disease-prevention health nano inner wall coating, it is characterized in that：The refreshment and tranquilization clears away heart-fire improving eyesight dredging collateral
Stagnation resolvation is depressured environment protective nano-paint, and % is constituted by following proportion by weight
Wherein, (1) described refreshment and tranquilization clears away heart-fire improving eyesight acupuncture-stimulating blood stasis dispersing Chinese hypotensor nano powder, is constituted by following proportion by weight
(2) high strength bright shell rich selenium germanium disease-prevention health nano inner wall coating, it is characterized in that：Constituted by following proportion by weight
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| CN102816493A (en) * | 2012-07-05 | 2012-12-12 | 成钢 | Multi-element multifunctional healthy longevity-promoting nanometer environment-friendly interior-wall paint rich in silver, selenium and germanium |
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| Title |
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| 董发勤 等: "生态环境矿物功能材料", 《功能材料》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112166213A (en) * | 2018-04-04 | 2021-01-01 | 尤尼弗瑞克斯 I 有限责任公司 | Activated porous fibers and products including the same |
| US11987914B2 (en) | 2018-04-04 | 2024-05-21 | Unifrax I Llc | Activated porous fibers and products including same |
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Application publication date: 20170627 |