CN106890560A - Deodorizing composition and deodorizing method - Google Patents
Deodorizing composition and deodorizing method Download PDFInfo
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- CN106890560A CN106890560A CN201511015966.3A CN201511015966A CN106890560A CN 106890560 A CN106890560 A CN 106890560A CN 201511015966 A CN201511015966 A CN 201511015966A CN 106890560 A CN106890560 A CN 106890560A
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- Prior art keywords
- smelly eliminating
- peg
- catechin
- composition
- smelly
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- 239000000203 mixture Substances 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims abstract description 11
- 230000001877 deodorizing effect Effects 0.000 title abstract description 11
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 50
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 48
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 claims abstract description 44
- 235000005487 catechin Nutrition 0.000 claims abstract description 44
- 229950001002 cianidanol Drugs 0.000 claims abstract description 43
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 claims abstract description 38
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000001263 FEMA 3042 Substances 0.000 claims abstract description 34
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims abstract description 34
- 229920002258 tannic acid Polymers 0.000 claims abstract description 34
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 claims abstract description 34
- 229940033123 tannic acid Drugs 0.000 claims abstract description 34
- 235000015523 tannic acid Nutrition 0.000 claims abstract description 34
- 239000012670 alkaline solution Substances 0.000 claims abstract description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 19
- 230000006641 stabilisation Effects 0.000 claims description 19
- 238000011105 stabilization Methods 0.000 claims description 19
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 18
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 18
- 238000007254 oxidation reaction Methods 0.000 claims description 18
- 230000003647 oxidation Effects 0.000 claims description 17
- AGBQKNBQESQNJD-UHFFFAOYSA-M lipoate Chemical compound [O-]C(=O)CCCCC1CCSS1 AGBQKNBQESQNJD-UHFFFAOYSA-M 0.000 claims description 12
- 235000019136 lipoic acid Nutrition 0.000 claims description 12
- 229960002663 thioctic acid Drugs 0.000 claims description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 229910001868 water Inorganic materials 0.000 claims description 11
- 239000001509 sodium citrate Substances 0.000 claims description 10
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 claims description 5
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 claims description 5
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 claims description 5
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 2
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 claims 1
- 229920002556 Polyethylene Glycol 300 Polymers 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 abstract 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 61
- 239000003153 chemical reaction reagent Substances 0.000 description 23
- 230000000694 effects Effects 0.000 description 12
- 239000002781 deodorant agent Substances 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 230000008030 elimination Effects 0.000 description 7
- 238000003379 elimination reaction Methods 0.000 description 7
- 238000004073 vulcanization Methods 0.000 description 7
- PFTAWBLQPZVEMU-UHFFFAOYSA-N catechin Chemical compound OC1CC2=C(O)C=C(O)C=C2OC1C1=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000872 buffer Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- LRBQNJMCXXYXIU-YIILYMKVSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)C(OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-YIILYMKVSA-N 0.000 description 3
- 229920001864 tannin Polymers 0.000 description 3
- 235000018553 tannin Nutrition 0.000 description 3
- 239000001648 tannin Substances 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- RYYVLZVUVIJVGH-UHFFFAOYSA-N caffeine Chemical compound CN1C(=O)N(C)C(=O)C2=C1N=CN2C RYYVLZVUVIJVGH-UHFFFAOYSA-N 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- CQOZJDNCADWEKH-UHFFFAOYSA-N 2-[3,3-bis(2-hydroxyphenyl)propyl]phenol Chemical compound OC1=CC=CC=C1CCC(C=1C(=CC=CC=1)O)C1=CC=CC=C1O CQOZJDNCADWEKH-UHFFFAOYSA-N 0.000 description 1
- OQUFOZNPBIIJTN-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;sodium Chemical compound [Na].OC(=O)CC(O)(C(O)=O)CC(O)=O OQUFOZNPBIIJTN-UHFFFAOYSA-N 0.000 description 1
- 206010006326 Breath odour Diseases 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 208000032139 Halitosis Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- -1 PEG-400 Chemical compound 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- WJEIYVAPNMUNIU-UHFFFAOYSA-N [Na].OC(O)=O Chemical compound [Na].OC(O)=O WJEIYVAPNMUNIU-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001765 catechin Chemical class 0.000 description 1
- 239000013064 chemical raw material Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 229920001461 hydrolysable tannin Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a deodorizing composition and a deodorizing method, wherein the deodorizing composition comprises an alkaline solution, tannic acid, catechin and a stabilizer. The stabilizer comprises polyethylene glycol.
Description
Technical field
The invention relates to a kind of smelly eliminating composition and smelly eliminating method, and vulcanization can be simultaneously eliminated in particular to one kind
The smelly eliminating composition and its application method of the stink that hydrogen and formaldehyde are caused.
Background technology
Deodorant market scale continuous enlargement.Stink has various different sources.Such as vulcanization with egg putrefactive odor
Hydrogen (hydrogen sulfide；H2S excrement, lower water, wind, pet, halitosis, cigarette) be may be from smelly etc..With pungent odour
Formaldehyde (formaldehyde；HCHO solid, building materials, preservative etc.) be may be from.Stink often results in the sense of discomfort of people,
Therefore deodorant is needed to use to eliminate the source for causing peculiar smell.
There are harmful effect, therefore industry development natural material to human body using the deodorant of chemical raw material.For example, day
Right material tannic acid can distinguish removal of hydrogen sulfide and formaldehyde stink with catechin.However, tannic acid easily contracts mutually with catechin
Polymerisation is closed, respective deodorizing effect can be lost, it is impossible to be steady in a long-term to preserve.Therefore existing market is no can simultaneously eliminate sulphur
Change the natural deodorant of hydrogen and formaldehyde stink.
The content of the invention
The present invention is related to a kind of smelly eliminating composition and smelly eliminating method.Smelly eliminating composition can stabilize storage, represent the deodorant of stabilization
Effect.
An embodiment of the invention, proposes a kind of smelly eliminating composition, and it includes an alkaline solution, a tannic acid, a youngster
Theine and a stabilization agent.Stabilization agent includes polyethylene glycol.
According to another embodiment of the present invention, a kind of smelly eliminating method is proposed, it includes that smelly eliminating composition is used alone to be carried out
Smelly eliminating.Smelly eliminating composition includes an alkaline solution, a tannic acid, a catechin and a stabilization agent.Stabilization agent includes polyethylene glycol.
More preferably understand to have to above-mentioned and other aspect of the invention, preferred embodiment cited below particularly, and coordinate attached
Figure, is described in detail below：
Brief description of the drawings
Nothing
Specific embodiment
A kind of smelly eliminating composition is to provide according to embodiment, is storage-stable hydrogen sulfide and formaldehyde dual effect type scavenger,
The stink that causes of removal of hydrogen sulfide and formaldehyde simultaneously can be used to, and it uses natural plant extraction material for material, to human body without
Evil, also has no adverse effects to environment, is the compositing formula of environmental protection.
According to embodiment, smelly eliminating composition includes an alkaline solution, a tannic acid, a catechin and a stabilization agent.
In one embodiment, tannic acid includes oxidation tannic acid.Oxidation tannic acid obtained by being aoxidized to tannic acid is removed
Hydrogen sulfide effect is good.Aoxidizing the manufacture of tannic acid may include tannin acid oxidase in alkaline solution to obtain aoxidizing tannin
Acid.This alkaline solution for being used to aoxidize tannic acid includes sodium carbonate liquor, sodium bicarbonate solution, sodium citrate solution or above-mentioned
Combination.Alkaline solution also can be used as buffer.
Skin, root, stem, leaf, shell of plant etc. are rich in tannic acid, by that after extraction, concentration and filtering, can obtain plant
Tannin, its chemical constitution is belonging to Hydrolysable Tannins, is many OH bases aromatic compounds, and many OH based compounds of these aromatic series are in alkali
The further effect of liquid, it is possible to be hydrolyzed to the derivative of the smaller company's triphenol of molecular weight and adjacent diphenols.These small molecules it is many
It is quinoid structure that OH base phenolic structural compounds are easily oxidized in alkaline solution, can serve as good in oxidizing process
Oxygen carrier.The structure of this phenol quinone conversion makes it have the catalysis characteristics that catalysis oxidation hydrogen sulfide is elementary sulfur.Therefore can use
Do except sulphur formula.
Catechin may be used to eliminate formaldehyde, thereby remove the stink that formaldehyde is caused.Catechin removes formaldehyde in the basic conditions
Effect is good, but is easily polymerized with tannic acid after oxidation, influences the function of smelly eliminating.According to embodiments of the present invention, peace can be used
Determine agent and avoid that polymerisation occurs between catechin and tannic acid (or oxidation tannic acid), make (or the oxidation of catechin and tannic acid
Tannic acid) can for a long time maintain respective deodorizing function.
In embodiment, stabilization agent is polyethylene glycol (poly (ethylene glycol), PEG；CAS NO:25322-68-
3), or including polyethylene glycol.Polyethylene glycol has following chemical constitution：
Polyethylene glycol is used to suppress that condensation reaction occurs between the main composition catechin of deodorant and tannic acid, it is to avoid loses and removes
Hydrogen sulfide and except effect of formaldehyde, increases the stability in storage of deodorant.
Appropriate polyethylene glycol can provide appropriate micella steric hindrance, and oxygen (O) and the catechin of stabilization agent ethers and
Hydroxyl (OH) increased hydrogen bond (hydrogen bond) on phenol between tannic acid, all be avoided that between catechin and tannic acid
Polymerisation.
In embodiment, weight average molecular weight (the Weight-average Molecular Weight of polyethylene glycol；Mw)
Can be 200~400.For example, the weight average molecular weight of polyethylene glycol can be 200,300 or 400.Too small weight average
The polyethylene glycol (instant fluid viscosity is too low) of molecular weight cannot provide enough steric hindrances, and excessive weight average molecular weight
Polyethylene glycol (instant fluid viscosity is too high) cannot dissolve in aqueous, therefore cannot cause appropriate to catechin and tannic acid
Stabilization effectiveness.
In embodiment, catechin：The weight ratio of polyethylene glycol is 1:0.1~10, such as 1:0.1~4.
The alkaline solution that smelly eliminating composition is used includes sodium carbonate liquor (Na2CO3Solution), sodium bicarbonate solution
(NaHCO3Solution), sodium citrate solution or combinations of the above.Alkaline solution can be used as buffer.
Stabilization agent can further include double carbohydrate substances, such as trehalose etc..Stabilization agent can further include lipoic acid.Stabilization agent can be wrapped
Include any combination of double carbohydrate substances and lipoic acid.
Smelly eliminating composition is alkalescence, such as such as pH value 8~12, pH value 9~11.
The solution viscosity of smelly eliminating composition also with solvent (for example can dissolve the aqueous solvent of catechin, tannic acid) or each composition
Use ratio it is relevant.Ratio need to be suitably adjusted to obtain to stablize catechin and tannic acid the smelly eliminating product of effectiveness.
Because according to embodiment, the smelly eliminating liquid product obtained in smelly eliminating is constituted is storage-stable, therefore consumer can individually make
Being constituted with smelly eliminating directly carries out smelly eliminating, such as by liquid form product sprinkling in the environment, or during standing evaporates into environment, with simultaneously
The stink that removal of hydrogen sulfide and formaldehyde are caused.Without the compound smelly eliminating product as using, must be by difference before using
Separate composition can be only achieved the purpose of removal of hydrogen sulfide and formaldehyde stink simultaneously after mixing.According to disappearing for embodiment
The used raw material of smelly composition meets every International Environmental Protection, security and disabling chemical substance testing standard, and can be applied to each
Environment space is planted, such as in fishing city, chicken house, pasture and recovery plant, and general family：Kitchen or bath lavatory etc..Therefore phase
Compared with general compound smelly eliminating product, the smelly eliminating composition according to embodiment is obtained storage-stable smelly eliminating liquid product, application method
Simple and convenient, harmless and environmental protection, more improve consumer chooses wish.
It is that the present invention can become apparent, special embodiment below is described in detail below：
[oxidation tannic acid solution]
Tannic acid (12.5g) and sodium carbonate (75g) are pressed 1:6 ratio is added in reaction bulb, and solution ph is more than 9.0,
Appropriate soft water (250ml) is added, at 80 DEG C, pumping that reaction bulb is constantly depressurized removes the carbon dioxide for producing, so to temperature control
After be passed through air oxidation stirring, oxidization time be 6 hours.Thereby obtain the oxidation tannic acid solution of alkalescence.
[deodorant]
The smelly eliminating composition with reagent numbering 21 with 22 is explained below.After weighing the addition 70g pure water dissolvings of 10g catechins,
The catechin aqueous solution is obtained, the polyethylene glycol that 1g weight molecular weights are 200 is added
(PEG-200), it is stirred for and mixes, add 0.8g oxidation tannic acid solutions, uses 7.6g sodium bicarbonate buffers
Agent adjusts pH value to 9.7.The weight concentration that PEG-200 accounts for complete soln is 1.02wt%.
[deodorant Formula Development]
Table 1 lists different smelly eliminating composition reagents to hydrogen sulfide and the elimination factor of formaldehyde, and calculation disappears with reference to Japanese fragrance
Smelly deodorant consultation from construction method (detector tube detection), wherein
C2minIt is the hydrogen sulfide/concentration of formaldehyde for detecting for 2 minutes, C30minFor the hydrogen sulfide/formaldehyde for detecting for 30 minutes is dense
Degree.
From the reagent label 1~4,8 in table 1, find catechin with the smelly eliminating composition of oxidation tannic acid simultaneously to hydrogen sulfide
There is good deodorizing rate with formaldehyde, but by 10 days afterwards (reagent label 9), color change and smelly eliminating effect declines is represented
Its stability in storage is poor.
Table 1
[stabilization agent exploitation]
Table 2 lists the different stabilization agent Vitamin Cs of addition, cyclodextrin, trehalose, sodium citrate, lipoic acid, weight molecular weight
The Initial experimental results of reagent are constituted for the smelly eliminating of 200 polyethylene glycol (PEG-200).The reagent of wherein addition Vitamin C is steady
It is qualitative not good.Using trehalose, sodium citrate, lipoic acid and PEG-200 stabilization agents smelly eliminating constitute (respectively reagent number
18th, 19,20, stability 21) is preferable.
Table 2
[stability in storage test]
Table 3 lists and constitute using the smelly eliminating of trehalose, sodium citrate, lipoic acid and PEG-200 stabilization agents (respectively reagent
Numbering 18,19,20,21), by 4 days, 12 days, 25 days, 55 days afterwards to hydrogen sulfide and the elimination factor of formaldehyde.Experimentation
Have and accelerate efficiency to degenerate with 50 DEG C.The result of table 3 is shown, afterwards, is constituted together using the smelly eliminating of PEG-200 stabilization agents by 55 days
When there is preferably elimination factor to hydrogen sulfide and formaldehyde.
Table 3
[catechin is tested with PEG-200 different proportions]
In table 4, the smelly eliminating composition of each reagent (numbering 22~25) includes catechin, oxidation tannic acid, PEG-200, carbonic acid
Sodium and water (aqueous sodium carbonate).Table 4 lists the elimination factor result of the catechin and PEG-200 reagents using different proportion.Its
Middle (the catechin of reagent numbering 24:The weight ratio of PEG-200 is 10:40, and PEG-200 accounts for the weight ratio of all solution and is
40wt%) to vulcanisation hydrogen and except effect of formaldehyde preferably, and good deodorizing rate was still maintained afterwards by 22 days, represent stability
It is good.
Table 4
[catechin is tested with PEG-400 different proportions]
In table 5, the smelly eliminating composition of each reagent includes catechin, oxidation tannic acid, the poly- second two of weight average molecular weight 400
Alcohol (PEG-400), sodium carbonate and water (aqueous sodium carbonate).Table 5 is listed and uses the catechin and PEG-400 reagents of different proportion
Initially with by the elimination factor result after a couple of days.All reagents still have good stablizing effect after by a couple of days, wherein
(the catechin of reagent numbering 27:The weight ratio of PEG-400 is 10:10, and PEG-400 account for all solution weight ratio be 10wt%)
To vulcanisation hydrogen and except effect of formaldehyde is best.
Table 5
[catechin and PEG-200 for constituting different proportion using the smelly eliminating of sodium citrate, lipoic acid are tested]
In table 6, the smelly eliminating composition of reagent numbering 30 includes catechin, oxidation tannic acid, PEG-200, sodium carbonate, water, lemon
Lemon acid sodium (1wt%), lipoic acid (0.3wt%).Wherein catechin:The weight ratio of PEG-200 is 10:1, and PEG-200 accounts for institute
There is the weight ratio of solution for 1wt%, to vulcanisation hydrogen and except effect of formaldehyde is good, and good stability.
Table 6
[catechin and PEG-300 for constituting different proportion using the smelly eliminating of sodium citrate, lipoic acid are tested]
In table 7, the smelly eliminating composition of each reagent includes catechin, oxidation tannic acid, the poly- second two of weight average molecular weight 300
Alcohol (PEG-300), sodium carbonate, water, sodium citrate (1wt%), lipoic acid (0.3wt%).Table 7 is listed and uses the youngster of different proportion
The elimination factor result of theine and PEG-300 reagents.Wherein (the catechin of reagent numbering 32:The weight ratio of PEG-300 is 10:1, and
The weight ratio that PEG-300 accounts for all solution is 1wt%) to vulcanisation hydrogen and except effect of formaldehyde preferably, and by 34 days afterwards still
Maintain good deodorizing effect, good stability.
Table 7
[catechin and PEG-400 for constituting different proportion using the smelly eliminating of sodium citrate, lipoic acid are tested]
In table 8, the smelly eliminating composition of each reagent includes catechin, oxidation tannic acid, PEG-400, sodium carbonate, water, citric acid
Sodium (1wt%), lipoic acid (0.3wt%).Table 8 lists the elimination factor knot of the catechin and PEG-400 reagents using different proportion
Really.Wherein (the catechin of reagent numbering 35:The weight ratio of PEG-400 is 10:10, and PEG-400 accounts for the weight ratio of all solution and is
10wt%) to vulcanisation hydrogen and except effect of formaldehyde preferably, and good deodorizing effect, stability were still maintained afterwards by 34 days
It is good.
Table 8
In other reagents, find when polyethylene glycol (such as weight average point using excessive weight average molecular weight
The polyethylene glycol of son amount 1000) when, polyethylene glycol cannot at room temperature be dissolved in solution, therefore be unsuitable to apply in composition.
In sum, although the present invention is disclosed as above with preferred embodiment, but it is not limited to the present invention.This hair
Bright the technical staff in the technical field, without departing from the spirit and scope of the present invention, when can make various changes and repair
Change.Therefore, protection scope of the present invention is worked as and is defined depending on the appended claims person of defining.
Claims (18)
1. a kind of smelly eliminating is constituted, it is characterised in that including：
One alkaline solution；
One tannic acid；
One catechin；And
One stabilization agent, including polyethylene glycol.
2. smelly eliminating as claimed in claim 1 is constituted, it is characterised in that the stabilization agent also includes trehalose, lipoic acid or above-mentioned
Combination.
3. smelly eliminating as claimed in claim 1 is constituted, it is characterised in that the tannic acid includes oxidation tannic acid.
4. smelly eliminating as claimed in claim 1 is constituted, it is characterised in that the alkaline solution includes sodium carbonate liquor, sodium acid carbonate
Solution, sodium citrate solution or combinations of the above.
5. smelly eliminating as claimed in claim 1 composition, it is characterised in that the weight average molecular weight of the polyethylene glycol is 200~
400。
6. smelly eliminating as claimed in claim 1 composition, it is characterised in that the weight average molecular weight of the polyethylene glycol is 200,
300 or 400.
7. smelly eliminating as claimed in claim 1 is constituted, it is characterised in that the pH value of smelly eliminating composition is 8~12.
8. smelly eliminating as claimed in claim 1 is constituted, it is characterised in that the pH value of smelly eliminating composition is 9~11.
9. smelly eliminating as claimed in claim 1 is constituted, it is characterised in that the catechin：The weight ratio of the polyethylene glycol is 1:0.1
~10.
10. smelly eliminating as claimed in claim 1 is constituted, it is characterised in that the catechin：The weight ratio of the polyethylene glycol is 1:
0.1~4.
11. smelly eliminating compositions as claimed in claim 1, it is characterised in that smelly eliminating composition is storage-stable.
12. smelly eliminating compositions as claimed in claim 1, it is characterised in that smelly eliminating composition is to removal of hydrogen sulfide and first simultaneously
The stink that aldehyde is caused.
13. smelly eliminating compositions as claimed in claim 1, it is characterised in that smelly eliminating composition includes a solvent, and the solvent includes
Water, the wherein catechin:The weight ratio of the polyethylene glycol (PEG-200) of weight average molecular weight 200 is 10:40, and should
The weight concentration that PEG-200 accounts for complete soln is 40wt%.
14. smelly eliminating compositions as claimed in claim 1, it is characterised in that smelly eliminating composition includes a solvent, and the solvent includes
Water, the wherein catechin:The weight ratio of the polyethylene glycol (PEG-400) of weight average molecular weight 400 is 10:10, and should
The weight concentration that PEG-400 accounts for complete soln is 10wt%.
15. smelly eliminating compositions as claimed in claim 1, it is characterised in that smelly eliminating composition includes a solvent, and the solvent includes
Water, the wherein catechin:The weight ratio of the polyethylene glycol (PEG-200) of weight average molecular weight 200 is 10:1, and the PEG-
200 weight concentrations for accounting for complete soln are 1wt%.
16. smelly eliminating compositions as claimed in claim 1, it is characterised in that smelly eliminating composition includes a solvent, and the solvent includes
Water, the wherein catechin:The weight ratio of the polyethylene glycol (PEG-300) of weight average molecular weight 300 is 10:1, and the PEG-
300 weight concentrations for accounting for complete soln are 1wt%.
A kind of 17. smelly eliminating methods, including the smelly eliminating composition being used alone as described in claim 1 to 16 any of which is disappeared
It is smelly.
18. smelly eliminating methods as claimed in claim 17, it is characterised in that smelly eliminating composition is to removal of hydrogen sulfide and first simultaneously
The stink that aldehyde is caused.
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| CN110755284A (en) * | 2019-11-08 | 2020-02-07 | 奥伦国际有限公司 | Deodorant fragrance-retaining composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62205018A (en) * | 1986-03-04 | 1987-09-09 | Hodogaya Chem Co Ltd | Foamable bath agent |
| JP2744572B2 (en) * | 1993-02-17 | 1998-04-28 | 鐘紡株式会社 | Method for preventing discoloration of polyphenol compound-containing external preparation for skin |
| CN1688345A (en) * | 2002-10-15 | 2005-10-26 | 伊琳娜·维克托罗维娜·瓦尔多萨尼迪泽 | Composition with stabilized redox properties and method of stabilization of redox properties |
| CN101897986A (en) * | 2009-05-29 | 2010-12-01 | 高砂香料工业株式会社 | The box privy deodorizing method of liquid deodorant and box privy |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1925840A (en) * | 2004-03-18 | 2007-03-07 | 汉高两合股份公司 | Substances with a probiotic action used in deodorants |
| US8216559B2 (en) * | 2004-04-23 | 2012-07-10 | Jnc Corporation | Deodorant fiber and fibrous article and product made thereof |
| CN100462486C (en) * | 2006-09-30 | 2009-02-18 | 秦如涛 | Viscose fibre with tea anti-bacterial anti-foul function and its preparing method |
| JP5040405B2 (en) * | 2007-04-04 | 2012-10-03 | Ｅｓファイバービジョンズ株式会社 | Antibacterial and deodorant fibers, fiber molded products and fiber products using the same |
| MX2012005683A (en) * | 2009-12-04 | 2012-06-19 | Colgate Palmolive Co | Oral compositions containing a combination of natural extracts and related methods. |
-
2015
- 2015-12-21 TW TW104142986A patent/TWI569820B/en active
- 2015-12-29 CN CN201511015966.3A patent/CN106890560B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62205018A (en) * | 1986-03-04 | 1987-09-09 | Hodogaya Chem Co Ltd | Foamable bath agent |
| JP2744572B2 (en) * | 1993-02-17 | 1998-04-28 | 鐘紡株式会社 | Method for preventing discoloration of polyphenol compound-containing external preparation for skin |
| CN1688345A (en) * | 2002-10-15 | 2005-10-26 | 伊琳娜·维克托罗维娜·瓦尔多萨尼迪泽 | Composition with stabilized redox properties and method of stabilization of redox properties |
| CN101897986A (en) * | 2009-05-29 | 2010-12-01 | 高砂香料工业株式会社 | The box privy deodorizing method of liquid deodorant and box privy |
Non-Patent Citations (1)
| Title |
|---|
| 贺近恪等: "《黑荆树及其利用》", 30 June 1991, 中国林业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110755284A (en) * | 2019-11-08 | 2020-02-07 | 奥伦国际有限公司 | Deodorant fragrance-retaining composition |
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| TWI569820B (en) | 2017-02-11 |
| CN106890560B (en) | 2020-04-21 |
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