CN106883819B - A kind of ice-removing and ice-preventing liquid and preparation method thereof based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids - Google Patents
A kind of ice-removing and ice-preventing liquid and preparation method thereof based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids Download PDFInfo
- Publication number
- CN106883819B CN106883819B CN201710039535.3A CN201710039535A CN106883819B CN 106883819 B CN106883819 B CN 106883819B CN 201710039535 A CN201710039535 A CN 201710039535A CN 106883819 B CN106883819 B CN 106883819B
- Authority
- CN
- China
- Prior art keywords
- ice
- preventing liquid
- fracturing fluids
- surfactant used
- overlength chain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
- C09K3/185—Thawing materials
Abstract
Non-newtonian flow figure ice-removing and ice-preventing liquid of the present invention based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids, including component and each component mass percent it is as follows: deionized water 35%~94%, alcohol 5%~64%, overlength chain Surfactant Used in Viscoelastic Fracturing Fluids 0.5%~15%.The overlength chain Surfactant Used in Viscoelastic Fracturing Fluids is or mixtures thereof saturation or unsaturation alkane surfactant of carbon atom number 18~24；The alcohol is or mixtures thereof unitary, binary or the polynary alkylol of carbon atom number 2~5.The present invention also provides the preparation methods of above-mentioned ice-removing and ice-preventing liquid.Ice-removing and ice-preventing liquid ingredient of the present invention is simple, does not need using polymer viscosifier, can simplify ice-removing and ice-preventing liquid ingredient and preparation process, it is also ensured that the performance and safety in utilization of ice-removing and ice-preventing liquid.
Description
Technical field
The invention belongs to body surface ice-removing and ice-preventing fields, and in particular to a kind of ice-removing and ice-preventing liquid and preparation method thereof.
Background technique
Under zubzero temperature and wet environment, body surface (such as road, cable, aircraft outer surface) easily freezes,
People's life is seriously affected, and will cause great security risk.Deicing, it is anti-icing be guarantee extreme environment safety it is important
Measure, and the use of ice-removing and ice-preventing liquid is most effective deicing, anti-icing method.Ice-removing and ice-preventing liquid can not only melt body surface
It freezes, additionally it is possible to prevent from freezing within a certain period of time, it is thus possible to guarantee safety.
Ice-removing and ice-preventing liquid ingredient used at present is mostly extremely complex, mainly includes thickener, surfactant, inhibition
Agent, stabilizer, freezing point depressant, pH buffer and water etc..Thickener is key component therein, is mainly used for adjusting deicing
The rheological property of anti-freeze fluid makes it have high viscosity and shear shinning characteristic.Existing thickener is including artificial based on polymer
Synthetic polymer such as polyacrylic, polyvinyl alcohol, polyacrylamide etc., natural polymer such as guar gum, xanthan gum etc..
Polymer viscosifier is current most of essential components of ice-removing and ice-preventing liquid, however most polymers thicken
Agent preparation process is complicated, at high cost, and since its special structure and function group generally requires that stabilizer, pH buffering is added
Agent and corrosion inhibiter etc. further complicate the ingredient of ice-removing and ice-preventing liquid and preparation process to guarantee its safe handling.It is another
Aspect, ice-removing and ice-preventing liquid usually require the spraying operation of experience high-rate of shear, such ice-removing and ice-preventing liquid meeting in use
Polymer molecular chain mechanical degradation is generated, and then to ice-removing and ice-preventing liquid rheological property (such as apparent viscosity, shear thinning behavior)
Cause irreversible influence.In addition, polymer-type ice-removing and ice-preventing liquid will form spawn after body surface is dry, bring
Safety problem.The polymer ice-removing and ice-preventing liquid being such as attached in aircraft lifting and landing rudder surface can seriously affect flight peace after forming gel
Entirely.
The patent application of Publication No. CN105199671A discloses " a kind of to be thickened by low poly-cationic surfactant
Anti-freeze fluid and preparation method thereof ", obtain a kind of anti-freeze fluid based on low poly-cationic surfactant, but its sun for using from
Sub- surfactant needs just play the role of increasing stick, additive under the action of additional anionic compound under a high concentration condition
Use this not only adds the hidden danger corroded to body surface, and be easy to cause the unstable of anti-icing liquid system, Jin Erying
Ring the safety used.
Summary of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids
Non-newtonian flow figure ice-removing and ice-preventing liquid and preparation method thereof simplifying ice-removing and ice-preventing liquid so as not to use polymer viscosifier
Ingredient and while preparation process, guarantees the performance and safety in utilization of ice-removing and ice-preventing liquid.
Non-newtonian flow figure ice-removing and ice-preventing liquid of the present invention based on super Longer-chain surfactants, component and each component
Mass percentage it is as follows: deionized water 35%~94%, alcohol 5%~64%, overlength chain Surfactant Used in Viscoelastic Fracturing Fluids 0.5%
~15%.
The above-mentioned non-Newtonian ice-removing and ice-preventing liquid based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids, the overlength chain viscoelasticity table
Face activating agent is at least one of the saturation of carbon atom number 18~24, unsaturated alkane surfactant.Such as saturated alkane table
Face activating agent enuatrol, arachidic acid sodium, eicosyl dimethyl betaine, docosyl dimethyl amine etc.；It is unsaturated
Alkane surfactant N- (cis- 22 carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine, N- (cis- ten
Eight carbon -9- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine, erucic acid sodium etc..
The above-mentioned non-newtonian flow figure ice-removing and ice-preventing liquid based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids, the unsaturation alkane
Surfactant is preferably N- (cis- 22 carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine and/or N-
(cis- Octadec-9-enoic Acid amidopropyl)-N, N- dimethyl carboxylic acid glycine betaine.
The above-mentioned non-newtonian flow figure ice-removing and ice-preventing liquid based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids, the alcohol are carbon atom
At least one of the unitary of number 2~5, binary, polynary alkylol.The unitary alkylol is preferably ethyl alcohol, binary alkyl alcohol
Preferably ethylene glycol, ternary alkylol are preferably glycerine.
The above-mentioned non-newtonian flow figure ice-removing and ice-preventing liquid based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids provided by the invention
Deionized water, alcohol are uniformly mixed by preparation method, then are mixed and stirred for overlength chain sticking with overlength chain Surfactant Used in Viscoelastic Fracturing Fluids
Elastic surface activating agent is completely dissolved and is uniformly mixed.
In the present invention, the super Longer-chain surfactants are existing product, can buy or make by oneself by market.
Compared with prior art, the invention has the following advantages:
1. the present invention is body surface deicing, anti-icing operation provides a kind of new ice-removing and ice-preventing liquid.
2. ice-removing and ice-preventing liquid of the present invention does not contain polymer viscosifier, ingredient and preparation process are simple, after dry
Hydrogel will not be formed in body surface, avoid bringing security risk.
3. ice-removing and ice-preventing liquid of the present invention using when do not need to add any additive, it is easy to use, and without inorganic
Salt, small to the corrosion of body surface, environmental-friendly therefore with good stability and safety in utilization, can be mass-produced
With use.
After 4. the Surfactant Used in Viscoelastic Fracturing Fluids in ice-removing and ice-preventing liquid of the present invention is by being self-assembly of vermiculate glues
Aqueous solution can show the viscoelasticity similar to polymer solution, its viscosity after mechanical shearing and viscoelasticity can be quick
Can reverse recovery, therefore ice-removing and ice-preventing liquid of the present invention can maintain higher viscosity and shear shinning characteristic, and due to it
Non-Newton fluid characteristic is conducive to the adherency in body surface, has low surface tension, the thinning characteristic of high shear, meets conduct
The requirement of ice-removing and ice-preventing liquid.
5. ice-removing and ice-preventing liquid of the present invention have the characteristics that it is low temperature resistant, freezing point can be lower than -40 DEG C, at -40~20 DEG C
It can be used.
6. in the formula of ice-removing and ice-preventing liquid of the present invention, type, content and the surfactant of change alcohol can be passed through
Concentration etc., realize the adjusting to anti-freeze fluid rheological property.
Detailed description of the invention
Fig. 1 is N- (cis- 22 carbon -13- enoic base propyl)-N of 1.34wt% in embodiment 1, N- dimethyl
Viscosity-shear rate the relationship of carboxylic acid glycine betaine and water/ethylene glycol mixed solvent composition ice-removing and ice-preventing liquid at different temperatures
Figure.
Fig. 2 is N- (cis- 22 carbon -13- enoic base propyl)-N of 1.34wt% in embodiment 2, N- dimethyl
Carboxylic acid glycine betaine is in the viscosity-with four kinds of ice-removing and ice-preventing liquid of the water of different content/ethylene glycol mixed solvent composition at 20 DEG C
Shear rate relational graph.
Fig. 3 is N- (cis- 22 carbon -13- enoic base propyl)-N of 3.57wt% in embodiment 3, N- dimethyl
Carboxylic acid glycine betaine and water/alcohol mixed solvent composition ice-removing and ice-preventing liquid viscosity-shear rate relational graph at -20 DEG C.
Fig. 4 is N- (cis- 22 carbon -13- enoic base propyl)-N of 1.25wt% in embodiment 4, N- dimethyl
Viscosity-shear rate the relational graph of carboxylic acid glycine betaine and water/glycerine mixed solvent composition ice-removing and ice-preventing liquid at -20 DEG C.
Fig. 5 is N- (cis- Octadec-9-enoic Acid amidopropyl)-N of 7.40wt% in embodiment 5, N- diformazan yl carboxylic acid
Viscosity-shear rate the relational graph of glycine betaine and water/glycerine mixed solvent composition ice-removing and ice-preventing liquid at different temperatures.
Fig. 6 is N- (cis- 22 carbon -13- enoic base propyl)-N of 2.22wt% in embodiment 7, N- dimethyl
The anti-freeze effect picture of carboxylic acid glycine betaine and water/ethylene glycol composition ice-removing and ice-preventing liquid on aluminum flake surface.
Specific embodiment
The non-newtonian flow figure of the present invention based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids is removed below by embodiment
Ice anti-freeze fluid and preparation method thereof is described further.
In following embodiment, overlength chain Surfactant Used in Viscoelastic Fracturing Fluids used is laboratory self-control, and preparation method is referring to Chu
Z,Feng Y(2009)A facile route towards preparation of ultra-long-chain
20:2655-2658 amidosulfobetaine surfactants.Synlett, the alcohol are the purchase of market Reagent Company
It buys.
The relationship of ice-removing and ice-preventing liquid apparent viscosity and shear rate passes through rotational rheometer (Anto in following embodiment
Paar, MCR301) test.
In following embodiment, heating (50 DEG C) in ice-removing and ice-preventing liquid preparation process, its purpose is to accelerate overlength chain
It is glutinous to overlength chain can not also to heat directly stirring on the performance of ice-removing and ice-preventing liquid without influence for the dissolution of Surfactant Used in Viscoelastic Fracturing Fluids
Elastic surface activating agent is dissolved and is uniformly mixed.
Embodiment 1
In the present embodiment, the formula of the ice-removing and ice-preventing liquid is as follows:
The ethylene glycol of formula ratio: being add to deionized water uniformly mixed by preparation at room temperature, adds N- (cis- two
12 carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine, and 50 DEG C of stirrings are warming up to N- (cis- 22
Carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine be completely dissolved (1 hour time) and be uniformly mixed removed
Ice anti-freeze fluid.
The pass of ice-removing and ice-preventing liquid apparent viscosity and shear rate is measured at -20 DEG C, -10 DEG C, 0 DEG C, 10 DEG C, 20 DEG C respectively
System, as a result as shown in Figure 1.As shown in Figure 1, at low shear rates, it is shown when the above-mentioned temperature of the ice-removing and ice-preventing liquid higher
Apparent viscosity, and as shear rate increases, viscosity is decreased obviously, that is, shows apparent shear shinning characteristic, is met non-
The rheological property requirement of Newtonian liquid figure ice-removing and ice-preventing liquid.
Embodiment 2
Four kinds of ice-removing and ice-preventing liquid, the formula such as following table of each ice-removing and ice-preventing liquid are prepared in the present embodiment.
The preparation of every kind of ice-removing and ice-preventing liquid: it is equal that the ethylene glycol of formula ratio is add to deionized water mixing at room temperature
It is even, N- (cis- 22 carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine are added, and be warming up to 50 DEG C
To N- (cis- 22 carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine is completely dissolved that (time 1 is small for stirring
When) and be uniformly mixed obtain ice-removing and ice-preventing liquid.
The apparent viscosity of each ice-removing and ice-preventing liquid and the relationship of shear rate are measured at 20 DEG C, as a result see Fig. 2.It can by Fig. 2
Know: (1) at low shear rates, four kinds of ice-removing and ice-preventing liquid show biggish apparent viscosity at 20 DEG C, and with shearing speed
Rate increases, and viscosity is decreased obviously, that is, shows apparent shear shinning characteristic.(2) as ethylene glycol content increases, ice-removing and ice-preventing
Liquid apparent viscosity gradually decreases, but still has apparent shear shinning characteristic, meets non-newtonian flow figure ice-removing and ice-preventing liquid
Rheological property requirement.
Embodiment 3
In the present embodiment, the formula of the ice-removing and ice-preventing liquid is as follows:
Preparation: the ethyl alcohol of formula ratio is add to deionized water and is uniformly mixed at room temperature, adds N- (cis- two
12 carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine, and 50 DEG C of stirrings are warming up to N- (cis- 22
Carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine be completely dissolved (1 hour time) and be uniformly mixed removed
Ice anti-freeze fluid.
The relationship of shear rate and apparent viscosity is measured at -20 DEG C, as a result as shown in Figure 3.From the figure 3, it may be seen that being cut low
Under cutting speed rate, which shows higher apparent viscosity, and as shear rate increases, under apparent viscosity is obvious
Drop, that is, show apparent shear shinning characteristic, meet the rheological property requirement of non-newtonian flow figure ice-removing and ice-preventing liquid.
Embodiment 4
In the present embodiment, the formula of the ice-removing and ice-preventing liquid is as follows:
Preparation: the glycerine of formula ratio is add to deionized water and is uniformly mixed at room temperature, it is (cis- to add N-
22 carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine, and 50 DEG C of stirrings are warming up to N- (cis- 20
Two carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine be completely dissolved (1 hour time) and be uniformly mixed obtain
Ice-removing and ice-preventing liquid.
The relationship of apparent viscosity and shear rate is measured at -20 DEG C, as a result as shown in Figure 4.As shown in Figure 4, it is cut low
Under cutting speed rate, which shows higher apparent viscosity, and as shear rate increases, viscosity is decreased obviously, i.e.,
Apparent shear shinning characteristic is shown, the rheological property requirement of non-newtonian flow figure ice-removing and ice-preventing liquid is met.
Embodiment 5
In the present embodiment, the formula of the ice-removing and ice-preventing liquid is as follows:
Preparation: the glycerine of formula ratio is add to deionized water and is uniformly mixed at room temperature, it is (cis- to add N-
Octadec-9-enoic Acid amidopropyl)-N, N- dimethyl carboxylic acid glycine betaine, and 50 DEG C of stirrings are warming up to N- (cis- 18 carbon-
9- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine is completely dissolved (1 hour time) and is uniformly mixed that obtain deicing anti-
Ice liquid.
The relationship of apparent viscosity and shear rate is measured at 0 DEG C and -7.5 DEG C respectively, as a result as shown in Figure 5.It can by Fig. 5
To know, when above-mentioned temperature, the ice-removing and ice-preventing liquid shows stable shear platform at low shear rates, and apparent viscosity is larger,
And as shear rate increases, viscosity is decreased obviously, that is, shows apparent shear shinning characteristic, is met non-newtonian flow figure and is removed
The rheological property requirement of ice anti-freeze fluid.
Embodiment 6
It include five kinds of ice-removing and ice-preventing liquid, the formula such as following table of each ice-removing and ice-preventing liquid in the present embodiment.
The ethylene glycol of formula ratio: being add to deionized water by the preparation of every kind of ice-removing and ice-preventing liquid at room temperature and mixes
It is even, N- (cis- 22 carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine are added, and be warming up to 50 DEG C
To N- (cis- 22 carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine is completely dissolved that (time 1 is small for stirring
When) and be uniformly mixed obtain ice-removing and ice-preventing liquid.
The ice of five kinds of ice-removing and ice-preventing liquid is measured according to People's Republic of China (PRC) petrochemical industry standard SH/T 0090-91
The freezing point of point, five kinds of ice-removing and ice-preventing liquid is respectively -43.3 DEG C, -41.5 DEG C, -44.6 DEG C, -45.4 DEG C, -44.8 DEG C, illustrates this hair
The bright ice-removing and ice-preventing liquid has lower freezing point, can use under extremely cold environment.
Embodiment 7
In the present embodiment, the formula of the ice-removing and ice-preventing liquid is as follows:
Preparation: the ethylene glycol of formula ratio is add to deionized water and is uniformly mixed at room temperature, it is (cis- to add N-
22 carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine, and 50 DEG C of stirrings are warming up to N- (cis- 20
Two carbon -13- enoic base propyl)-N, N- dimethyl carboxylic acid glycine betaine be completely dissolved (1 hour time) and be uniformly mixed obtain
Ice-removing and ice-preventing liquid.
1.5 centimetres one wide, long 8 centimetres of aluminium flake lower half portion is immersed in above-mentioned ice-removing and ice-preventing liquid, aluminium flake lower half is made
Part of the surface adheres to ice-removing and ice-preventing liquid.It is -20 DEG C, in the environment of relative humidity is 40% that the aluminium flake, which is placed on temperature, again.
It is found after placing 3 hours, the upper half surface almost all for not adhering to the aluminium flake of ice-removing and ice-preventing liquid freezes, and has adhered to and removed
The aluminium flake lower half surface of ice anti-freeze fluid has almost no change, and shows preferable deicing properties, as shown in Figure 6.
Claims (4)
1. a kind of non-newtonian flow figure ice-removing and ice-preventing liquid based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids, it is characterised in that the deicing
The component of anti-freeze fluid and the mass percentage of each component are as follows: deionized water 35%~94%, alcohol 5%~64%, overlength chain
Surfactant Used in Viscoelastic Fracturing Fluids 0.5%~15%, the overlength chain Surfactant Used in Viscoelastic Fracturing Fluids are N- (cis- 22 carbon -13- alkene
Sour amidopropyl)-N, N- dimethyl carboxylic acid glycine betaine and/or N- (cis- Octadec-9-enoic Acid amidopropyl)-N, N- bis-
Methyl carboxylic acids glycine betaine.
2. the non-newtonian flow figure ice-removing and ice-preventing liquid based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids according to claim 1,
It is characterized in that at least one of the unitary, binary, polynary alkylol that the alcohol is carbon atom number 2~5.
3. the non-newtonian flow figure ice-removing and ice-preventing liquid based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids according to claim 2,
It is characterized in that the unitary alkylol is ethyl alcohol, binary alkyl alcohol is ethylene glycol, and polynary alkylol is glycerine.
4. the non-newtonian flow figure in claims 1 to 3 based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids described in any claim
The preparation method of ice-removing and ice-preventing liquid, it is characterised in that be uniformly mixed deionized water, alcohol, then active with overlength chain viscoelastic surface
Agent is mixed and stirred for being completely dissolved and being uniformly mixed to overlength chain Surfactant Used in Viscoelastic Fracturing Fluids.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710039535.3A CN106883819B (en) | 2017-01-18 | 2017-01-18 | A kind of ice-removing and ice-preventing liquid and preparation method thereof based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids |
| PCT/CN2017/107530 WO2018133470A1 (en) | 2017-01-18 | 2017-10-24 | Deicing and anti-icing liquid based on super-long chain viscoelastic surfactant and preparation method therefor |
| CA3042596A CA3042596C (en) | 2017-01-18 | 2017-10-24 | Deicing and anti-icing fluid based on ultra-long chain viscoelastic surfactant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710039535.3A CN106883819B (en) | 2017-01-18 | 2017-01-18 | A kind of ice-removing and ice-preventing liquid and preparation method thereof based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106883819A CN106883819A (en) | 2017-06-23 |
| CN106883819B true CN106883819B (en) | 2019-06-28 |
Family
ID=59175795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710039535.3A Active CN106883819B (en) | 2017-01-18 | 2017-01-18 | A kind of ice-removing and ice-preventing liquid and preparation method thereof based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN106883819B (en) |
| CA (1) | CA3042596C (en) |
| WO (1) | WO2018133470A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106883819B (en) * | 2017-01-18 | 2019-06-28 | 四川大学 | A kind of ice-removing and ice-preventing liquid and preparation method thereof based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids |
| CN108441171B (en) * | 2018-05-02 | 2019-04-19 | 四川大学 | A kind of aircraft deicing anti-freeze fluid and preparation method thereof that alkyl alcoholamine is surfactant thickened |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3928221A (en) * | 1973-08-15 | 1975-12-23 | Kaiser Aluminium Chem Corp | Snow and ice control compositions |
| CN1081197A (en) * | 1992-07-09 | 1994-01-26 | 王家君 | Anti-fog and antifrost agent for windscreen of vehicle |
| CN101831275A (en) * | 2010-05-24 | 2010-09-15 | 陕西高科理化技术有限公司 | Polymer-thickened non-Newton aircraft deicing/anti-icing liquid |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106883819B (en) * | 2017-01-18 | 2019-06-28 | 四川大学 | A kind of ice-removing and ice-preventing liquid and preparation method thereof based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids |
-
2017
- 2017-01-18 CN CN201710039535.3A patent/CN106883819B/en active Active
- 2017-10-24 WO PCT/CN2017/107530 patent/WO2018133470A1/en active Application Filing
- 2017-10-24 CA CA3042596A patent/CA3042596C/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3928221A (en) * | 1973-08-15 | 1975-12-23 | Kaiser Aluminium Chem Corp | Snow and ice control compositions |
| CN1081197A (en) * | 1992-07-09 | 1994-01-26 | 王家君 | Anti-fog and antifrost agent for windscreen of vehicle |
| CN101831275A (en) * | 2010-05-24 | 2010-09-15 | 陕西高科理化技术有限公司 | Polymer-thickened non-Newton aircraft deicing/anti-icing liquid |
Non-Patent Citations (1)
| Title |
|---|
| "长链阳离子表面活性剂蠕虫状胶束的剪切带转变行为研究";楚宗霖等;《化学学报》;20120728(第14期);第1551-1552页 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA3042596C (en) | 2021-04-13 |
| CA3042596A1 (en) | 2018-07-26 |
| CN106883819A (en) | 2017-06-23 |
| WO2018133470A1 (en) | 2018-07-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1149146A (en) | Agent for de-icing and protecting against icing-up | |
| CN106883819B (en) | A kind of ice-removing and ice-preventing liquid and preparation method thereof based on overlength chain Surfactant Used in Viscoelastic Fracturing Fluids | |
| CN108504346B (en) | A kind of antifreeze clean fracturing fluid and preparation method thereof | |
| CN104371695B (en) | The preparation method for the slippery water exploited applied to shale gas batch production pressure break | |
| ATE242277T1 (en) | AIRCRAFT DE-ICING FLUID THICKENED BY ASSOCIATED POLYMERS | |
| NZ612407A (en) | Wellbore servicing compositions comprising a fluid loss agent and methods of making and using same | |
| CN102329597A (en) | Novel airplane de-icing/anti-icing liquid and preparation method thereof | |
| WO2014158676A1 (en) | Antifreeze agent for tire sealants | |
| PT1994113E (en) | Aircraft de-/anti-icer | |
| CN109456751B (en) | Low-damage thickening acid and preparation method and application thereof | |
| CN108441171B (en) | A kind of aircraft deicing anti-freeze fluid and preparation method thereof that alkyl alcoholamine is surfactant thickened | |
| CN105199671A (en) | Anti-icing fluid capable of realizing thickening through at least one oligomeric cationic surfactant and preparation method of anti-icing fluid | |
| CN111592870A (en) | Composite clean fracturing fluid, preparation method and application thereof in oil-gas field fracturing | |
| CN111500261A (en) | Ecological environment-friendly road dust suppressant and preparation method thereof | |
| CN103059813A (en) | Non-Newtonian fuselage deicing and anti-icing fluid and preparation method thereof | |
| CN106634842B (en) | A kind of low-corrosiveness environment-friendly type composite non-slip deicing salt and preparation method thereof | |
| CN105948559A (en) | Negative temperature concrete antifreezer | |
| CN108659810B (en) | Elastic sand-carrying fracturing fluid, thickening agent for fracturing fluid and preparation method of thickening agent | |
| CN105733550B (en) | A kind of recyclable fracturing fluid gelatinizer of amino acids and preparation method thereof | |
| CN112094624A (en) | Surfactant/hydrophobic association polymer viscoelastic fluid with deicing function and preparation method thereof | |
| CN109957471A (en) | The preparation method of eco-friendly car bath of glass | |
| CN101230246A (en) | Leakage testing liquid preventing low-temperature icing and preparation method | |
| CN103725390B (en) | A kind of silicon chip Linear cut water-base cutting fluid and preparation method thereof | |
| CN103666728B (en) | A kind of cutting fluid for fixed-abrasive Linear cut and preparation method thereof | |
| US2767145A (en) | Low freezing liquid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |