CN106857641A - A kind of insecticide and preparation method thereof - Google Patents
A kind of insecticide and preparation method thereof Download PDFInfo
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- CN106857641A CN106857641A CN201611268166.7A CN201611268166A CN106857641A CN 106857641 A CN106857641 A CN 106857641A CN 201611268166 A CN201611268166 A CN 201611268166A CN 106857641 A CN106857641 A CN 106857641A
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- alkali
- mazz
- insecticide
- banlangen
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
Abstract
The invention provides a kind of insecticide and preparation method thereof, the insecticide is made up of Banlangen, Aconitum flavum Hand-Mazz total alkali, the following material containing weight percentage：10 20 parts of Banlangen, 10 20 parts of Aconitum flavum Hand-Mazz total alkali, 25 parts of synergist, 50 70 parts of solvent.Compounded pesticides of the present invention not only have preventive effect higher, and composition used is all natural plant extracts, degrade in the environment rapid thorough, and noresidue is environmentally safe, alleviates due to the harm that the administration of agricultural chemicals is caused to ecological environment.
Description
Technical field
The present invention relates to pesticidal preparations and its preparation method of preparation, more particularly to a kind of Banlangen and Aconitum flavum Hand-Mazz
Biology total alkali composite insecticide and preparation method thereof.
Background technology
With the economic development of China, the country of chemurgy is gradually transformed into modern country, the chemurgy level of production
Increased it is many, in the case of being produced for the present metaplasia of China, pesticide development be also it is rapid, the nineties with
Come, it is the insecticide single varieties of changing over, of poor quality, raw as China pesticide processing industry, fine chemical industry are developed rapidly
Produce looks backward in technique.At present, existing panoramic insecticide is put on market, and presentation increases trend rapidly.State gives birth at present
By active ingredient gauge, every year more than 200,000 tons, but wherein only seldom part (is according to estimates 1% to the insecticide for producing and using
One is 5%) real and controlling object is contacted and played a role, and insecticide is only passed by semicentennial distance, and the mankind are just to its utmost disappointment
And detest, pesticide pollution environment, person poultry poisoning is caused, beneficial insect and birds are killed, the ecological balance is destroyed, produce insect
The resistance to the action of a drug.So, strengthen exploitation particularly important to existing insecticide novel form and reinforcing specific aim desinsection.
Banlangen is made up through Solvent Extract methods such as ethanol of the dry root of legume kuh-seng, plant, fruit
Alkaloid, its main component has various alkaloids such as matrine, sophocarpine, N-Oxysophocarpine, Sophoridine, with matrine, oxidation
Matrine content highest.Other sources are subprostrate sophora and subprostrate sophora aerial part, and sterling outward appearance is white powder.Matrine first
It is a kind of botanical pesticide, the characteristics of with specificity, natural sex, only specific biology is acted, the energy in the Nature
Rapid to decompose, final product is carbon dioxide and water.Secondly matrine is the plant endogenous chemistry active to harmful organism
Material, composition is not single, but the not close multigroup combination of the close multigroup and chemical constitution of chemical constitution, Xiang Fuxiang
Into playing a role jointly.3rd, matrine make it not be easily caused nuisance and produce and resist because various chemical substance collective effects
The property of medicine, can long-term use.4th, corresponding insect directly will not be killed completely, but control insect biotic population quantity is not
The production and procreation of the plant population can be badly influenced.This mechanism and chemical pesticide protection side effect highlight after by several
It is very approximate to study within 10 years the principle of harmful organism control in the Synthetical control system for drawing.To sum up 4 points can illustrate hardship
Ginseng alkali and general high poison, the chemical pesticide obvious differences of high residue, are very green, environmentally friendly.In recent years in agricultural
Upper extensive use, and have good prevention effect, it is a kind of low toxicity, low-residual, eco-friendly pesticide.Mainly prevent and treat various pine tags
The insects such as worm, Euproctis pseudoconspersa, cabbage caterpillar.With various functions such as insecticidal activity, bactericidal activity, coordinate plant growth functions.
The alkaloid extracted from Aconitum flavum Hand-Mazz contains aconitine, anepline, Aconitum flavum Hand-Mazz alkali, the dehydrogenation Europe rhizome of Chinese monkshood
Alkali, lucidusculine, benzoyl crow original alkali, Xin Wuning alkali, Aconitum flavum Hand-Mazz phenanthrene alkali etc..Alkaloid is the earliest plant of human use
Thing insecticide, can act on insect by various ways such as poisoning, deterrent, food refusal, Developing restraint developments.From Aconitum flavum Hand-Mazz
Active insecticidal components are extracted, researching and developing new and effective plant insecticide has turned into new research hot topic.
The content of the invention
The technical problem to be solved in the present invention is to provide that a kind of environmental pollution is few, low production cost insecticide, and
A kind of method for producing insecticide is provided, the preparation method is simple to operate, low cost of manufacture.
In order to solve the above-mentioned technical problem, the present invention is adopted the following technical scheme that：
A kind of insecticide, is made up of Banlangen, Aconitum flavum Hand-Mazz total alkali, it is characterised in that following containing weight percentage
Material：Banlangen 10-20 parts, 10-20 parts, synergist 2-5 parts, solvent 50-70 parts of Aconitum flavum Hand-Mazz total alkali；
Above-mentioned Banlangen is one or more mixtures in matrine, sophocarpine, N-Oxysophocarpine, Sophoridine；
Above-mentioned Aconitum flavum Hand-Mazz total alkali is aconitine, anepline, Aconitum flavum Hand-Mazz alkali, dehydrogenation anepline, the gloss rhizome of Chinese monkshood
One or more mixtures in alkali, benzoyl crow original alkali, Xin Wuning alkali, Aconitum flavum Hand-Mazz phenanthrene alkali；
Above-mentioned synergist is one or more mixtures in cyclohexasiloxane, the phenolic ether of trichlorine hydroxyl two, chenopodium ambrosiodies essential oil.
Above-mentioned solvent is one or more mixtures in ethyl acetate, methyl alcohol, ethanol, water；
Present invention also offers above-mentioned method for producing insecticide, comprise the following steps：Add Aconitum flavum Hand-Mazz total in a solvent
Alkali and Banlangen, are heated to being completely dissolved under the conditions of 50-55 C water baths, add synergist mixing, and stirring is to complete
CL, i.e., final obtained insecticide.
Insecticide is prepared using this method, the insecticide for can reduce manufacturing cost, producing easily is degraded, to environment without
Pollution.
Preparation method dissolving Aconitum flavum Hand-Mazz total alkali of the present invention and Banlangen temperature are 50-55 degrees Celsius, the humidity province
Between under, more preferable extraction effect can be obtained, can to greatest extent extract Aconitum flavum Hand-Mazz total alkali effective with Banlangen
Material.
Compounded pesticides of the present invention not only have preventive effect higher, and composition used is all natural plant extracts, in ring
Degraded in border rapid thorough, noresidue is environmentally safe, alleviates due to the danger that the administration of agricultural chemicals is caused to ecological environment
Evil.
Specific embodiment
For a better understanding of the present invention it is substantive, illustrate technology contents of the invention with example below, but the present invention
Content be not limited to this.
Embodiment 1
Above-mentioned compounded pesticides are made up of following component by mass fraction：15 parts of Banlangen, 10 parts of Aconitum flavum Hand-Mazz total alkali,
5 parts of synergist, 70 parts of solvent；Above-mentioned Banlangen is matrine, sophocarpine, and above-mentioned Aconitum flavum Hand-Mazz total alkali is the rhizome of Chinese monkshood
Alkali, anepline, above-mentioned synergist are cyclohexasiloxane, the phenolic ether of trichlorine hydroxyl two, and above-mentioned solvent is ethyl acetate, methyl alcohol.
Can be prepared by the following method：
10 parts of Aconitum flavum Hand-Mazz total alkalis and 15 parts of Banlangens are added in 70 parts of solvents, under the conditions of 50-55 C water baths
Be heated to being completely dissolved, add 5 parts of synergist mixing, stir to being completely dissolved, i.e., final obtained insecticide.
Embodiment 2
Above-mentioned compounded pesticides are made up of following component by mass fraction：20 parts of Banlangen, 10 parts of Aconitum flavum Hand-Mazz total alkali,
5 parts of synergist, 65 parts of solvent；Above-mentioned Banlangen is N-Oxysophocarpine, Sophoridine, and above-mentioned Aconitum flavum Hand-Mazz total alkali is crow
Head alkali, Xin Wuning alkali, Aconitum flavum Hand-Mazz phenanthrene alkali, above-mentioned synergist is chenopodium ambrosiodies essential oil, the phenolic ether of trichlorine hydroxyl two, above-mentioned solvent
It is ethyl acetate, methyl alcohol.
Can be prepared by the following method：
10 parts of Aconitum flavum Hand-Mazz total alkalis and 20 parts of Banlangens are added in 65 parts of solvents, under the conditions of 50-55 C water baths
Be heated to being completely dissolved, add 5 parts of synergist mixing, stir to being completely dissolved, i.e., final obtained insecticide.
Embodiment 3
Above-mentioned compounded pesticides are made up of following component by mass fraction：20 parts of Banlangen, 18 parts of Aconitum flavum Hand-Mazz total alkali,
2 parts of synergist, 60 parts of solvent；Above-mentioned Banlangen is matrine, N-Oxysophocarpine, Sophoridine, above-mentioned Aconitum flavum Hand-Mazz
Total alkali is Xin Wuning alkali, anepline, and above-mentioned synergist is cyclohexasiloxane, chenopodium ambrosiodies essential oil, and above-mentioned solvent is acetic acid
Ethyl ester, ethanol.
Can be prepared by the following method：
18 parts of Aconitum flavum Hand-Mazz total alkalis and 20 parts of Banlangens are added in 60 parts of solvents, under the conditions of 50-55 C water baths
Be heated to being completely dissolved, add 2 parts of synergist mixing, stir to being completely dissolved, i.e., final obtained insecticide.
Embodiment 4
Above-mentioned compounded pesticides are made up of following component by mass fraction：20 parts of Banlangen, 20 parts of Aconitum flavum Hand-Mazz total alkali,
5 parts of synergist, 55 parts of solvent；Above-mentioned Banlangen is N-Oxysophocarpine, Sophoridine, and above-mentioned Aconitum flavum Hand-Mazz total alkali is benzene
Formyl crow original alkali, Xin Wuning alkali, above-mentioned synergist is chenopodium ambrosiodies essential oil, and above-mentioned solvent is ethanol.
Can be prepared by the following method：
20 parts of Aconitum flavum Hand-Mazz total alkalis and 20 parts of Banlangens are added in 55 parts of solvents, under the conditions of 50-55 C water baths
Be heated to being completely dissolved, add 5 parts of synergist mixing, stir to being completely dissolved, i.e., final obtained insecticide.
Embodiment 5
Above-mentioned compounded pesticides are made up of following component by mass fraction：19 parts of Banlangen, 18 parts of Aconitum flavum Hand-Mazz total alkali,
3 parts of synergist, 60 parts of solvent；Above-mentioned Banlangen is sophocarpine, Sophoridine, and above-mentioned Aconitum flavum Hand-Mazz total alkali is gloss crow
Head alkali, benzoyl crow original alkali, above-mentioned synergist is cyclohexasiloxane, chenopodium ambrosiodies essential oil, and above-mentioned solvent is water, ethanol.
Can be prepared by the following method：
18 parts of Aconitum flavum Hand-Mazz total alkalis and 19 parts of Banlangens are added in 60 parts of solvents, under the conditions of 50-55 C water baths
Be heated to being completely dissolved, add 3 parts of synergist mixing, stir to being completely dissolved, i.e., final obtained insecticide.
Embodiment 6
Above-mentioned compounded pesticides are made up of following component by mass fraction：15 parts of Banlangen, 15 parts of Aconitum flavum Hand-Mazz total alkali,
1 part of synergist, 69 parts of solvent；Above-mentioned Banlangen is matrine, Sophoridine, and above-mentioned Aconitum flavum Hand-Mazz total alkali is gloss crow
Head alkali, benzoyl crow original alkali, Xin Wuning alkali, above-mentioned synergist is cyclohexasiloxane, and above-mentioned solvent is methyl alcohol, ethanol.
Can be prepared by the following method：
15 parts of Aconitum flavum Hand-Mazz total alkalis and 15 parts of Banlangens are added in 69 parts of solvents, under the conditions of 50-55 C water baths
Be heated to being completely dissolved, add 1 part of synergist mixing, stir to being completely dissolved, i.e., final obtained insecticide.
Below by way of the prevention effect of experiment explanation above-mentioned composition.
The similar rice-stem borer 280 of upgrowth situation is randomly selected, is divided into 7 groups, every group of two parallel tests, each is put down
Row 20, wherein five groups is experimental group, corresponds to embodiment 1-6 respectively, and the 7th group is control group.Experimental group sprays compound insecticidal
Agent, control group sprays the clear water of equivalent.After 3h, 6h, 9h, 12h, 24h is observed and is recorded the survival number of insect for treatment, and statistics is simultaneously
Analysis result.Result of the test see the table below.
Upper table shows：Embodiment 1-6 is respectively provided with preferable prevention effect to rice-stem borer.Synergist is hexamethylene silica
After alkane, the phenolic ether use of trichlorine hydroxyl two, medicament can be made to act rapidly.
Technological means disclosed in the present invention program is not limited only to the technological means disclosed in above-mentioned implementation method, also includes
Constituted technical scheme is combined by above technical characteristic.It should be pointed out that for those skilled in the art
For, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications are also considered as
Protection scope of the present invention.
Claims (7)
1. a kind of insecticide, it is characterised in that the following material containing weight percentage：Banlangen 10-20 parts, lie prostrate pig-iron
Rod hammers 10-20 parts, synergist 2-5 parts, solvent 50-70 parts of total alkali into shape.
2. insecticide according to claim 1, it is characterised in that Banlangen be matrine, sophocarpine, oxidation Chinese scholartree really
One or more mixtures in alkali, Sophoridine.
3. insecticide according to claim 1, it is characterised in that Aconitum flavum Hand-Mazz total alkali is aconitine, anepline, volt
In hair Aconitum Szechenyianum Gay alkali, dehydrogenation anepline, lucidusculine, benzoyl crow original alkali, Xin Wuning alkali, Aconitum flavum Hand-Mazz phenanthrene alkali one
Plant or more than one mixtures.
4. insecticide according to claim 1, it is characterised in that synergist is cyclohexasiloxane, the phenolic ether of trichlorine hydroxyl two, soil
One or more mixtures in schizonepeta essential oil.
5. insecticide according to claim 1, it is characterised in that solvent is in ethyl acetate, methyl alcohol, ethanol, water
Plant or more than one mixtures.
6. method for producing insecticide according to claim 1, it is characterised in that comprise the following steps：
Aconitum flavum Hand-Mazz total alkali and Banlangen are added in a solvent, and heating water bath adds synergist mixing to being completely dissolved,
Stir to being completely dissolved, i.e., final obtained insecticide.
7. method for producing insecticide according to claim 6, it is characterised in that dissolving Aconitum flavum Hand-Mazz total alkali and kuh-seng
Total alkali temperature water bath is 50-55 degrees Celsius.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611268166.7A CN106857641A (en) | 2016-12-31 | 2016-12-31 | A kind of insecticide and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611268166.7A CN106857641A (en) | 2016-12-31 | 2016-12-31 | A kind of insecticide and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN106857641A true CN106857641A (en) | 2017-06-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201611268166.7A Pending CN106857641A (en) | 2016-12-31 | 2016-12-31 | A kind of insecticide and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110974826A (en) * | 2019-07-03 | 2020-04-10 | 川北医学院 | Use of ouwu alkali or 12-epi-ouwu alkali in preparing medicine for treating leukemia |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104206431A (en) * | 2014-08-24 | 2014-12-17 | 青岛保利康新材料有限公司 | Environment-friendly residue-free pesticide |
| CN105123777A (en) * | 2015-08-26 | 2015-12-09 | 青岛文创科技有限公司 | Botanical insecticide |
-
2016
- 2016-12-31 CN CN201611268166.7A patent/CN106857641A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104206431A (en) * | 2014-08-24 | 2014-12-17 | 青岛保利康新材料有限公司 | Environment-friendly residue-free pesticide |
| CN105123777A (en) * | 2015-08-26 | 2015-12-09 | 青岛文创科技有限公司 | Botanical insecticide |
Non-Patent Citations (1)
| Title |
|---|
| 吕香梅等: ""农药用生物碱的研究进展"", 《农药》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110974826A (en) * | 2019-07-03 | 2020-04-10 | 川北医学院 | Use of ouwu alkali or 12-epi-ouwu alkali in preparing medicine for treating leukemia |
| CN110974826B (en) * | 2019-07-03 | 2023-08-29 | 川北医学院 | Application of ouabain or 12-epi-ouabain in preparation of medicine for treating leukemia |
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